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ARJUNA JEE 2023

GOC-Isomerism DPP-02

1. The inductive effect of the groups: –NH3⊕; –D; 5. Arrange the following groups in the order of
–CO2Θ; –COOH are respectively decreasing (–I) effect.
(1) –I, +I, +I, –I (1) CN > F > Br > Cl > COOH > I > H
(2) –I, –I, –I, +I (2) COOH > CN > F > Br > Cl > I > H
(3) +I, No effect, –I, –I (3) H > COOH > CN > I > Cl > F > Br
(4) +I, –I, –I, –I (4) CN > COOH > F > Cl > Br > I > H

2. Choose the correct statement 6. The +I.E. (inductive effect) is shown by:
(1) I effect operates in both σ and π bonds (1) –CH3 (2) –OH
(2) I effect creates net charge in molecule (3) –F (4) –C6H5
(3) I effect transfers electron from one carbon to
another 7. The –I effect is shown by:
(4) I effect creates partial charges and it is distance (1) –COOH (2) –CH3
dependent (3) –CH2CH3 (4) –CHR2

3. The most stable carbocation among the following is: 8. The increasing order of +ve I-effect shown by H,
CH3, C2H5 and C3H7 is:
(1)
(1) H < CH3 < C2H5 < C3H7
(2) (2) H > CH3 > C2H5 >C3H7
(3) H < C2H5 < CH3 < C3H7
(3)
(4) None of the above

9. The most acidic compound among following is:

(4)
(1) F – CH2 – COOH
(2) Cl – CH2 – COOH
(3) Br – CH2 – COOH
4. Order of stability of given free radical is: (4) I – CH2 – COOH

10. Which order is correct regarding the –I effect of the

substituents?
(1) –NR2 < –OR < –F
(2) –NR2 > –OR < –F
(3) NR2 > –F > –OR
(1) III > I > II (2) I > II > III
(4) –NR2 > –OR > –F
(3) II > I > III (4) III > II > I
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.

Answer Key
1. (1) 6. (1)
2. (4) 7. (1)
3. (3) 8. (1)
4. (4) 9. (1)
5. (4) 10. (1)

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