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Adobe Scan 05-Jan-2023
Adobe Scan 05-Jan-2023
raaotle.-f
CaJfsBr A its (A) Aal. It
(A) CHI = CH2(8) CH,,CH20H
( B) Subltltutioft ~••-
(C) CH,,CHpCH2CH, ( C) Both CA) and (&J
._.ahlorido ( D ) none of these
pt (N} (D) None of these
Which one of the following is the
- - chlorido pt (Il) Which of the followillf la M
oMoride reacts with main product of the reaction
electrophilic reagent?
,as and for'"s white CHCl.!J + 02 ~I •••••••••+ HCI ? (A) BF,(B)NH3
at. The niotecular forrnull!I (A) CO (B) C/ r_: ._..,~/j (C) HO (D) None of thue
IIIMt-. precipit1:1te is 2 2 2 • fl
(C) COCI (D) None of these ~ • . Catenation property is maXlfflUffl
IIJC'1 • 2NH,(B)H9 (NH5 ) 2 C/2 S 2 n,e~hanism proc eeds via (A) phosphorus
) Hf (NIil) C/2 N
formation of ~ _ ~ • .:
' (B) carbon (C) sulphur
)Hf (NH2 ) Cl ( A) Carbocation
J
(D) zinc .
Ylh ch co'"plex has rnax.imurn The organic compound must contain
( B) Transition state
p.-on,agnetic moment value amongst an element
( C) Free radical
the foltowino- · · (A) oxygen (B) carbon
(A) [CdHJJLP..
-
) [Fe(HP\JCt 2
. (D) Carbanion
, . The molecular formula of benzene
is
( c) hydrogen (D) nitrogen
1 The hybridization of carbon in
(C) [Fe( CN) 6 t·
(A) C6H5 (B) C6H6 diamond is
(D) [Ni(CO)J (A) sp3 ( B) sp2
(C) C H (D) none of these
6 12 (C)sp (D)dsp2
Valency of carbon is- Number of 1t bonds in ethyne is-
(A) 1 (8)2
1 (A) 2. (B) 3.lD) 4.(A) (A) One ( B) Two
(C)3 (D)4
5. CB) 6. (B) 7.(C) 8.(D) Single bond length between carbon- (C) Three (D) Four
9 {C) 10. (B) ll. \C) 12 (D) () .". Hybridisation of carbon in ethane
carbon is
13 (C) 14. (C) 15.(B) 16.(B) (A) 1.34A is-
17 (B) 18. (D) 19. (C) 20 . (B) (B) 1.20A (C) 1.54A (A) sp 3 (B) sp 2
21 CA) 22. (B) 23.(B) 24 .\C) ( D ) None of these ( C) sp ( D ) sp 3d2
25. CD) 26. (C) 27.(A) 28 .(D) Which alkyl halide follows only SN2 General formula of atkene is-
29. (A) 30. (C) 31. (D) 32 . (C) hydrolysis mechanism?
33. (D) 34. (A) 35.(A) 36.(B) (A) CH 3 - CH 2 -X
37. {A) 38. (A) 39. (C) 40. (C) (A) Cfizn (B) Cfi2n+ 2
41.CA) 4 2. (A) 43. (A) 44 (D) (B) Cdf?CH-X (C) Cfizn- 2 (D) None of these
46. (C) 4-_(B) 48.(D) ~ . The compound having general formula
45. (C) (C) (CH3 ) 3 C-X
49 (B) 50. (A) 51. (D) 52. (A) CJi2n .. 2 is-
(D ) C6H5 -CH 2 X
----~
53 {D) 54.(B) (A) Atkene (B) Alkyne
'.l. Rate of hydration in aq,ueous acid ( C) Alkane (D) None of these
-~ ~ ... ~·••)""
wilt be in the order-
~ ; 1_..,,,.~- The antiseptic action of CHI3 is due
-- ~--- [:>-cH=CH 2
(I)
to
(A) Iodoform
UNIT-X : HALOALKANES AND
( B ) liberation of free iodine
HALOARENES [>-cH=CH-CH3 (C) partially due to iodine and
(II)
partially due to CHI3 itself
Reac-1on 20 2 X
+ Na etrer .,
[>--c
CH3
= CH2 "
(D) None of these
Alkythalide is converted into alcohol
0-0 + 2NaX is kno~n as (ill)
(A)l<II<ill
by
(A) addition reaction
(A) Fittig reaction
(B) Wurt2 reaction (B)ill<II<I ( B) substitution reaction
C) Wurtz fitt,g reaction (C)I<ill<II ( C) elimination reaction
CD) Kolbe's reaction (D) II < I < ill (D) Dehydrohalogenation reaction
The reaction between alkyl halide In a given reaction CH,-CH2-CH = Reaction between alk1JI halide and
llnd sodu»n metal is callr2d . CH2+ HI--+ X, the product is sodium metal is called:
A) Wurtz reaction (A) 1-lodobutane ( A ) Wurtz reaction
B) Kolbe's reaction ( B ) 2-Iodobut ane ( B) Kolbe 's reaction
C Oemmensen's reaction (C) 2-Butene
) None of these ( C) Clemmenson 1s reaction
(D ) 1,2-di iodobutane ( D ) None of these
1■111• CHEMISTRY
. • O.
).M•tein reaction
( 8) Swarts reaction
RI+ N•'K
Sr. This reaction Is
3 1. Which of the follo1A1ln9 under9oes
nucleophllic substitution exclusively
by SN' mechanism?
(A) ethyl chloride
( B) isopropyl chloride
40 When CH8CHBrCHP•
. 1A1ith alcoholic KOH.
product is :
(A) CH5 -CH=CH-CHa
(B) CH2 =CH-CH2-CHa
(C) CH,-CH<OH)-CHz-CHa
(C) Sandnteyer's reaction ( C) chlorobenzene
(D) Friedel-Crafts reaction CD) CH5-CH2 -CH2-CH5
( D ) benzyl chloride 41. c-CI bond in ehlorobenzene
5. O" + N• + RK D,y1tNr OR♦ NaX ~ 2. A primary alklJlhalide would pref er
to undergo-
comparison to C-CI bond in "'
chloride is :
(AlklJI ben211ne) (A) SN' reaction (A) Lon 9 er and weaker
This reaction is an ex.ample of 2
( B) SN reaction ( B) Shorter and weaker
(A) Fittlg reaction (C) 0t-Elimination ( c) Shorter and stronger
( B) Wurtz-Fittig reaction CD) Racemisation (D) Longer and stronger
( C) Wurtz reaction ~-"J. Which of the following would undergo 4 2. Which one of these is formed 0 11
( D ) SandmelJer' s reaction SN1 reaction most readitlJ? heating sodium phenox.ide with e~hyl
26. CH3 8r + A9F-. CH3 F + A9Br. This (A) (CH.d)?, C - F iodide ?
( B ) ( CH3 ) 3 C - Cl (A) Phenetole
reaction is known as
(C) (CH 3 \ C - Br
( B) EthlJI phenlJI alcohol
(A) Finkelstein reaction
( D ) ( CH3 ) 3 C - I ( C) Phenone
( B) Swarts reaction
(D) None of these
( C) SandmelJer' s reaction 34. Reaction of C6 H5 CH 2Br with aq,.
4 -~ . The compound used as refrigera
~
... 7.
(D) Wurtz reaction
O Nj< Cu.)<, ►
ox
I ,,-:;
Ar yl hoide
+ N
X
•
= Cl, Br
sodium hl.Jdroxide follows-
( A) SN1 mech .
(B) SN2 mech
( C) SN1 or SN2 depending on temp.
are-
( A ) CHCI 3
(C) CF4
( B ) CC/ 4
(D) CF2 Cf 2
44 . Substitution of chlorine takes plac
This reaction is known as ( D) sa\Jtzelf rule readily at higher temperature in :
(A) Finkelstein reaction .:: '.;_ Select the product formed in the (A) CH 3 -CH=CH 2
( B) Swarts reaction reaction ROH+ PC/5 --+ RC/+ ... ... . (B) CH 2 =CH 2
( C) Sandme1Jer's reaction (A) POC/ 3 + HCI ( C) CH::CH (D) None of these
(D) Fittig's reaction ( B ) H3 PO 3 + No other byproduct 5. Which of the following is not industr11
28. The correct IUPAC name for (C) HpO 3 + HCI solvent?
diethlJlbromo methane is- ( D) POCI 3 + No other hyproduct (A) CHCI?, (8) CHJ3
(A) 1-Bromo-1 , 1-diethlJlmethane 06. R-X + Na!--+ R - I+ NaX. The (C) CC/4 CD) C 2H5 -O- C 2H'!
(B) .3-Bromopentane solvent used in this reaction is 46 Which of the following wilt not giv
(C) 1-Bromo -1-ethylpropane (A) Acetone ( B) dry acetone iodoform test?
(D) 1-Bromopentane ( C) water (D) ethlJlacetate (A) Ethanal CB) Ethanol
2 J. In which of the following molecules ( C) pentan-2 -one
"" ~ Name the poisonous gas produced
carbon atom marked with asterisk (D) pentan-3-one
during the oxidation of chloroform.
( *) is as1Jmmetric 7 (A) carbon monoxide The number of stereoisomers c
the compound 2 -Chloro - 4
H
<1 > r4~c, ( 2)
t
rf,c1
( B) carbonyl chloride
( C) phosgene
methylhex.-2-ene is/are?
(A)1 (8)2
Br (D) Both (B) and (C) (C) 4 (D) 16
Br 2
..... _. Which would undergo SN reaction 4 ° Which of the following is an ex~.,.p!
1 faster? of vie -dihalide?
( .3) H0/1'-CH, ( (A )CH3 CH 2CH2 CH 2 F (A) Dichlorometha1'1e
C?H~ (B) CH3 CH 2CH 2 CH 2 CI
CB) 1,2-dichlorodr..:ine
(A) 1. 2, 3, 4(8) 1, 2, 3 (C) CH 3 CH2 CH 2 CH 2Br
( C) Ethylidene chloride
(C) 2, .3, 4 (D) 1. 3, 4 (D ) CH?,CH2CH lCH /
.• . Which type ( s ) of the reaction is/ ( D ) Allyl chloride
,. . Which of the fo!lowin9 molecules is
-' J.
are given blJ hcJloalkane 7 The position of bromine in t
chiral in nature?
(A) Nucleophilic. subs liiution compound in CH ?,CH = CHC CB
(A) 2-Bromobutane
(B) Elimin~tion reactions (CH 3 ) 2 can be classified as-
(B) 1-Bromobutane
cc) 2 -Bromopropane (C) Reaction wilh tnt>lal ( A ) AtllJI ( B) Ary!
CD) 2-Bromopropan-2-ol (D) All of these ( C) Vinljl ( D) Secondary
-----,--·•-·--, ---- -·- - ---
CMF M l~ TRV
G ' • i I li\. ~ cl ' ' ' ' ·, . ~
--.;?.,t.p,..
CH3
1 . --...(C) Reimer-Tiemann reaction \A) H,Jdrcxyl group . ,
(D) Canr.izzaro' s reaction ( B) Allfohyd1,1 ,}rnt ,p
56. Toulene on reaction with halogen in
2. The general formula of monoh9dri~ (C) Cc.rboxul:c, arouI)
,
presence of FeCI 3 gives ortho and
alcohol is ., . (D) Chlo, o group
para halo compounds the reaction is
(A) Electrophilic elemination reaction ---(-A.) CJlzn + (B} pH
CJl2n+20H 12. The functional 9rol,p of atcohoi i'>-
(B) Electrophilic substitut i on (C) C 2 JI pH
(D) None of these
reaction Which is ethox.y ethane 7 _
(A) -COOH . ( B) - Cl-'O
( C) Free radical addition reaction (A) C2H5 0CH 3 ( B) CH 3 0CH
3
(D) Nucleophilic substitution reaction ----L£) C2 H5 0C 2H5 (D) !'lone. of tf,£s~ (C) -f-=l1 ~ -·C,I
f, ,Y=$
Alcohol is use d as beverage in- OH (A) HCHO (B) CH 3 -0- CH 3
( A) Met han ol (B) Etha nol Br-. Br
(C) But an- 1-o l
X= O (C) CGHSCHO "w ) CH3CHO
The nam e of ace tone in IUPA
(D) Pro pan -1-o l r Br C
syst em is
!'f!B', =f
Which is max imu m soluble in wat
er? .......______(A) Met han al (B) Etha nal
(A) n-B utyl alco hol
"(-C ) Propanone (D) Ethanone
( B) lsob utlJ l alco hol (D) >< y ThP- hyb ridis atio n of carb on
'{..C) tert -Bu hJl alco hol in
(D) sec -Bu tyl alco hol
Which one of them is an inco rrec
Which of the following compounds
is
carbonljl group (- t=
O) is
t arom atic alcohol? (A) sp ~ ) sp 2
mat ch? (C) sp 3 (D) sp 3 d
(A) Die thl)l ethe r-sim ple ethe r J!f_ 5!!_20H 5-!!20H J!f_ Formaldehyde on heating with NaO
(B) C/f5 0C H -mix .ed ethe r H
6 5
(C) C/f5 0CH -uns1Jmmetrical ethe
3 r
l9] lQJ ~ H ~ H 3
solution gives
~D ) C/f 0C H -uns1Jmmetrical (1) (2) (3) (4)
3
(A) Formic acid( B) Acetone
5 2 5 ether
(A) 1,2 , 3 ,4 (B) 1,4 ~ ) Methyl alcohol
3
2 2
~ ) CH CH<OH)CH (Propan-2- ol)
3
(C) HOCH CH=CH (Prop-2- en - 1-ol)
2 2
(C) CH.,fOOH (D) CH CHO
...••
given by \.
~o. 49. (B) 50 CD)
..,.,1
1
51. (C) 52 . (C) (A) For mal deh yde (~ Acetaldehl/
NO, 53. (B) de
, CHEMISTRY
( C) Ben zald ehy de(D ) Furf ural
..... 0 ~
,:10. /C- -H,0
22. Which of the following acids Is found ,u KOJl/cftrtl: ... "1loJ llt
fltMPDUnd gives iodoform 'c=NNrrz- ,-t
•o gives positive test in Vinegar?~ _
(A) HCOOH C~ CHlOOH (CH + N This reaction is
folans reagent. The compound (C) C~ COOH (D) None of these / z z d t
Is- [2018A] ( A) Ctemmensen re uc l~n
0
23. Select the ragent (s) used in the
18 )Wolff-Kishner reduction
Rosenmund reduction.
) CH,-CHO (B) CH,- 2- CH, '--....(A) H2 CB) Pd-BaS04
( C) HVZ reaction
(D) none
1£) Both (A) and CB)
(C) CH,-CH20H(D) ~?CH - OH R-CH2 -C00H
(D) none of these 31.
a. R- ~ - x H.J'dl:.so. R- i- H + Hx
24. Which of the following can not be
R~c = 0
used for the reduct ion R/
(ilX',IR•d p1,ospho<us
(u) H20
➔
18 Functional group of ketone is This reaction is called a.: The compound formed by t.
~ ) >C = 0 (B) -CHO [202 0A] (A) Stephen reaction oxidation of ethyl ben:zene w1
--r:ii)
-COOH (D) -OH ( B) Etard reaction KMn0 4 is-
:. ~· Which of the following undergoes Aldot ~ ) Gatterman -Koch reaction ( A) benzyt olcchol
condensation(.._ [2020A] (D) Friedel-Crafts acylation reaction ( B) benzophenone
CA) CH,COOH~) CH 3 CHO (C) acetophenone
CH, CS OCH<OCrOHCI,) ,
CC) C6 H5 CHO CD) CH,-COOCH3 --, + CrO,CI, ~ I
0
c...; . O .& ~ ) benzoic ac id
2C.. The general molecular formula of Toluene Chromium complex.
monobasic aliphatic carbox.ylic acid , ':4"hich is the str.:,nces.t acic?
H OCHO '\-A) HCOOH (B), C,4 ,COOrl
is ~I
~> c.H _,0 2 2
cs> cj1
o 2
.&
Ben2ntder.\Jdt (C) (CH ?, )lCHCOOH -
CC) Cjl2,,.. 20 CD) Cj12:+ 10H This reaction is called (D) (CHO) ?,CHCOOH
The general formula of aldehyde (A) Stephen reaction - 7 . Formic acid when heated with }",S
ketone is--........... <"B) Etard reaction gives •
(A) C.Hln>2 0 ('B) C,H2 ,0 ( C) Gatterman-Koch reaction (A) (COOH) 2 (B) CH~CCOH
CC) C.H~ .. - 2 0 CD) C_H2 • + 4 0 (D) Friedel -Crafts readion CC) C.j{~OH jj>) CO-
• ~ of the following products ~ ANSVv L ,-
be formed on addition of water to
(I) CHaCOOH but-1-yne in acidic medium in t
1 IIJ CH/JH presence of Hgz• ions as catalyst. 5. (8)
tA h folowing on treatment 9. (8) 1'1.(1) 1f
.a ~ sodium hydrox.ide will (A) CH,CH2CH2CHO
13. (C) 14 (8) 15 (8)
;ve corresponding alcohol and acid? '-.fB.) CH -CfflC-CH
?i 17. (B) 18. (A) 19. (8) at.Mt
) CJlsCHO 5 5 21 . ( B) 22 . (B) 23. (C) 24 (I)
(I) CH,CH2CH2CHO 25. (A) 26 . (D) 27. (A) 28.(C)
0
0 29. (B) 30 . CB) 31. (C) 32. (8 )
II (C} CHscH}OH + col
(C) CH-,-C-CH.,
aa. cc> a4. (B) 35.(D) 36. CA)
(D) CH3COOH + Hl03
a7. CD) 38. (A) 39. (A) 40. (A)
(D) C6H,CH 2CHO (1) CH,M9Br 41 . (C) 42.(D) 43. (8) 44. CB)
4i3. CH,CH0 - - - ~..
. Which undergoes aldol condensation (2)H,O 45 . (C) 46. (A ) 47 . (B) 48.CB)
in the presence of dilute NaOH? [A] H,S0,6. [B] 49. CC) 50. CD) 51. (B)
) Salicyaldehyde
Hljdroboration ~ (C]
( B) Benzophenone UNIT-XIII : ORGANIC
Oxidation
(C) BenzaldehlJde COMPOUNDS CONTAINING
The products [A] and [C] are-
(D} Acetaldehyde and forrnalde-hyde (A) identical NITROGEN (AMINES)
mix.ture ~ ) positional isomerism
• The aq_ueous solution. formoline , is ( C) function isomerism The main product of the following
of (D) optical isomerism
reacti on is U CC~ L2:,;;- • i
O -----
(A) Formic acid N02
Name the reag ent used for Sn+ HCI
( B) Fluoroscine
conversion of following reactant to
C) Formaldehyde
product (A) C6H5 0H ~ ) C6H NH
(D) Furfuraldehyde 5 2
. Which of the following is used for (C) C6H5 CH 3 (D) C6 H6
the distinguish between formatdehyde CH0 -CH = CH- CH2-i-CH0 - : /11ethylamine can be prepared by
and acetaldehyde. -----.{_A) Wurtz reaction ~, '.'., ~:, : ::- ,--· - ·
(A) Schif's reagent ?i (B) Hofmann bromamide reaction
CH.CH = CH -CHZ-C-OH ( C) Friedel-Crafts reaction
(B) Totlen's reagent (A) Tollen's reagent (D ) None of these
(C) Fehting's sotution ( B) Benzoyl peroxide
Iodine and base Which one i5 capable of forming
~ ) / and NaOH soln. zwitterion? .
2
Which of the following compounds
(D) Sn and NaOH sotution (A) CH3 N0 2 \{_B) CH COO.H
on oxidat ion gives benzoic acid? 3
CH C CH (C) CH 3 CH 2NH/"i5._) H NCH COOH
(A) Phenot ~ ) Toluene - ' 3 - :=
40UH,so.
---;-1;;;;0)/7:'Hg';,;SO',- X 2 2
Primary amine is detected by
{It) Chtorobenzene r ,
lsornerisation
(D) Benzene
4. Which of the fotlowing compounds
---+ CH 0-fiCH 0
0
(A) HCI '\a) CHCI +. ~;H 3
(C) NaOH (D) CHCI
1vitl gave butanone on oxidation with Identify the product 'X' and type of
• Which of the most bas:;? · : - :: -.
alkaline kMnO 4 solution? isomerisation in the reaction-
(A) C6H5 N/-1 2 (B) (C H )iJJ--I .
"-~~ ) Bu.tane -1-ol ( A) Prop-1-en-2-ol, metamerism 6 5
(C) CH.3NH2 ~D) (C/-1 )pH
~) Butan - 2 -ol (B) Prop-1 -en- 1-ol, tautomerisrn 3
, CH 3CN on reduction gives · _ ,.
(C) both (D) none ( C) Prop- 2-en-2- ol, ge ometrical (A) CH 4 (B) CH COOH
The reagent which does not react
with both acetone and benzaldehyde
isomerism
N)) Prop-1-en-2-ol, tautomerism
~ C) C2HIJH 2 (D)
5
COOH c/t
· The product of t~e reaction
(A) NaHSO!J
When @-cHO is treated with . -
C6 H5 N = N Cl ~.n· L; :. 4
~
' -(B) Phe nylh~ dro zine ~
ri
~,WI,
,),.
~
2
Xis
(Bl Aceto re (CH. j COCH3 ) (A) LiAIH4
(C' ac(!ti" acid (Ch 3 COOH) 0 (B) Sn/HCI
<D)Benzaoehyde (C~lHO ) <D) @-J;-o-K· + @--OK -f-C ) Na 2 S/(NH4 ) S
2
(D) all of these
·••ma■ CHE Ml~TPY