Professional Documents
Culture Documents
Module 2A
Module 2A
General Chemistry 2
Quarter 3: Week 2 - Module 2A
Properties of Liquids and
Intermolecular Forces
STEM – General Chemistry 2
Grade 11 Quarter 3: Week 2 - Module 2A: Properties of Liquids and
Intermolecular Forces
First Edition, 2021
Copyright © 2021
La Union Schools Division
Region I
All rights reserved. No part of this module may be reproduced in any form
without written permission from the copyright owners.
Management Team:
Jumpstart
Before going on, let’s check how accurate your observation and
thinking skills are as you do the first activity.
Have fun and good luck! Are you ready? Let’s start!
1. 2.
3. 4.
5. 6.
7. 8.
9. 10.
Matter is anything that occupies space and has mass. Matter is divided into
different phases such as solid, liquid, gas, plasma, and Bose-Einstein Condensates.
The first three phases of matter differ in various properties such as volume/shape,
density, compressibility, motion of their molecules, and their molecular behavior.
I. Surface Tension
The cohesive forces between liquid molecules are responsible for the
phenomenon known as surface tension. The cohesive forces between molecules
down into a liquid are shared with all neighboring atoms. Those on the surface have
no neighboring atoms above, and exhibit stronger attractive forces upon their nearest
neighbors on the surface. This enhancement of the intermolecular attractive forces
at the surface is called surface tension.
Surface tension is the measure of the elastic force in the surface of a liquid.
It is the amount of energy required to stretch or increase the surface of a liquid by a
unit area. It is the energy, or work, required to increase the surface area of a liquid
due to intermolecular forces. It is manifested as some sort of skin on the surface of
a liquid or in a drop of liquid.
Molecules within a liquid are pulled in all directions by intermolecular forces.
Molecules at the surface are pulled downward and sideways by other molecules, not
upward away from the surface (See next page).
Figure 2: Molecules within a liquid (Image Source: wps.prenhall.com)
These intermolecular forces tend to pull the molecules into the liquid and cause
the surface to tighten like an elastic film or “skin”.
Liquids that have strong intermolecular forces also have high
surface tension.
FYI:
Surface tension is typically measured in dynes/cm, the force in dynes required
to break a film of length one cm. Equivalently, it can be stated as surface energy
in ergs per square centimeter. Water at 20°C has a surface tension of 72.8
dynes/cm compared to 22.3 for ethyl alcohol and 465 for mercury.
Figure 5. Water strider walking on the surface of a quiet pond. (Image Source:
http://hyperphysics.phy-astr.gsu.edu/hbase/surten.html)
It’s Viewing Time!
To view how water droplets form on the surface of the water pool because of
surface tension, you may refer to this link:
https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Tex
tbook_Maps/Supplemental_Modules_(Physical_and_Theoretical_Chemistry)/Physic
al_Properties_of_Matter/States_of_Matter/Properties_of_Liquids/Surface_Tension.
Capillary Action
Figure 6. Colored water seen rising up in glass tubes. Without capillary action,
the water level in all tubes would be the same. Smaller diameter tubes have more
relative surface area inside the tube, allowing capillary action to pull water up higher
than in the larger diameter tubes (Image Source:
http://water.usgs.gov/edu/capillaryaction.html)
Credit: Dr. Keith Hayward
Figure 7. A doctor takes blood sample from a patient’s finger using a capillary
tube. (Image Source: https://www.colourbox.com/image/blood-testing-image-
6891015)
Figure 8. Water mixed with food coloring rises up freshly-cut stalks of
celery (Image Source: http://water.usgs.gov/edu/capillaryaction.html)
REMEMBER:
Capillary action is a phenomenon wherein a liquid is able to rise up on a
narrow tube. Adhesive forces between the tube and the liquid allow the liquid to
exceed its weight. The narrower the tube, the higher the liquid will reach.
Capillary action is the result of cohesive and adhesive forces. When liquid
flows through a narrow space, the cohesive and adhesive forces act together to lift
it against the natural force of gravity.
FYI:
Viscosity is expressed in units of centipoise (cP), also known as stoke. It
is a metric system unit. The SI unit is Pascal-second (Pa-s) or Newton-
second/meter2 (N-s/m2).
Table 1 below shows the viscosities of liquids of some pure substances. Water
has viscosity of 1 centipoise or 0.001 Pa/s at 20 oC.
Substances with lower viscosities include carbon tetrachloride and benzene.
Glycerol has a resistance to flow of more than a thousand times greater than water.
REMEMBER:
The more viscous a liquid is, the thicker is its consistency. The liquid with
the longest time to flow is, the most viscous while the one with the shortest time is
the least viscous.
In general, stronger intermolecular forces leads to higher viscosity.
Thus, the most viscous liquid has the strongest intermolecular force and
the least viscous liquid has the weakest intermolecular force.
Examples:
1. Given the molecular structures of water and glycerol, can you tell why
glycerol has a higher viscosity than water?
REMEMBER:
The larger number of –OH groups allow glycerol to form more H-bonds
with other glycerol molecules, making its intermolecular forces stronger than
those of water, and its resistance to flow greater.
REMEMBER:
The size of the molecules affects the viscosities of the hydrocarbons. The
larger the molecule, even if it is nonpolar, the stronger the intermolecular
forces and the greater the viscosity compared to nonpolar substances made up
of small molecules.
It’s Thinking Time!
The Idea:
Viscosity and temperature are inversely proportional with each other.
Figure 10. Evaporation of water in open and in closed containers (Image Source:
http:// boomeria.org/physicslectures/heat/equilibrium.jpg)
(a) The water molecules in the liquid evaporate and go into the vapor phase. In the
open flask, some of the water molecules in the vapor phase find their way out of
the flask are lost to the atmosphere.
(b) When a liquid evaporates to a gas in a closed container, the molecules cannot
escape.
Gas molecules move in random directions, collide with other gas particles and
the walls of the container.
Some will strike the liquid surface and condense back into it. In the closed
flask, none of the gas particles are able to get out of the container, and eventually,
the number of molecules that go into the gaseous state would equal the number of
molecules that condense back.
When the rate of condensation of the gas becomes equal to the rate of
evaporation of the liquid, the gas in the container is said to be in equilibrium with
the liquid.
liquid ⇋ vapor (gas)
Figure 11. Equilibrium between liquid and gas (Image Source: http://
wpscms.pearsoncmg.com/wps/media/objects/3662/3750037/Aus_content_10/Fi
g10-20.jpg)
Look at the given Figure below. Study the following plot of vapor pressure of
water as it varies with temperature.
Ethyl alcohol and water have very low vapor pressures. Both liquids have the
strong dipole-dipole interaction called hydrogen bonding. Acetone is polar but does
not have H-bonding. Its vapor pressure is of intermediate value. Pentane is a
nonpolar substance, and its vapor pressure is high compared to those of water and
ethyl alcohol.
When liquids evaporate, the molecules have to have sufficient energy to break
the attractive forces that hold them in the liquid state. The stronger these
intermolecular forces are, the greater the amount of energy needed to break them.
For some substances with weak intermolecular forces, the energy requirement
is easy obtained from collisions with other molecules and absorption of energy from
the surroundings. Many molecules can vaporize, resulting in a high vapor pressure.
For molecules with strong intermolecular forces, gathering enough energy may not
be as easy, and register low vapor pressures.
The Idea:
The stronger the intermolecular forces of attraction, the lower the vapor
pressure of a liquid.
Remember:
The relationship between vapor pressure and strength of intermolecular
forces is consistent with the trends in two other properties of liquids, the enthalpy
or molar heat of vaporization, and the boiling point of the liquid.
It is easier to vaporize acetone (lower Hvap) than water (higher Hvap) at a given
temperature, and more acetone escapes into the vapor phase at a given temperature.
Acetone is a polar substance but has no H-bonding. It has weaker intermolecular
forces than water, and therefore acetone molecules are held less tightly to one
another in the liquid phase.
Boiling Point
The boiling point of a liquid is the temperature at which the liquid converts
into a gas. A liquid boils when its vapor pressure equals the pressure acting on the
surface of the liquid. The boiling point is the temperature at which the vapor pressure
of a liquid is equal to the external pressure. Also, it is the temperature at which liquid
boils. The boiling point of a liquid when the external pressure is 1 atm is called the
normal boiling point.
The normal boiling point is the temperature at which the liquid converts to
a gas when the external pressure is 1 atm. The normal boiling point of water is 100 oC.
Remember:
The boiling point of a liquid depends on the external pressure. For
example, at 1 atm, water boils at 100oC, but if the pressure is reduced to 0.5 atm,
water boils at only 82oC.
Remember:
The boiling point is directly related to molar heat of vaporization: the higher
ΔHvap, the higher the boiling point.
The boiling points of substances often reflect the strength of the intermolecular
forces operating among the molecules. At the boiling point, enough energy must
be supplied to overcome the attractive forces among molecules before they can
enter the vapor phase.
Can you identify substances other than water that can exist naturally in all
three states? Can you identify some unusual properties of water? Can you explain
why water is said to be one of the most unusual substances on earth?
Unlike all other liquids, the molecules in solid water are actually farther
apart than they are in liquid water. When solid water forms, the hydrogen
bonds result in a very open structure with unoccupied spaces, causing the
solid to occupy a larger volume than the liquid. This makes ice less dense than
liquid water, causing ice to float on water.
Explore
Objectives:
A. To determine the properties of liquids;
B. To explain how intermolecular forces affect the properties of liquids; and
C. To explain the how the properties of water are related to its structure and
intermolecular forces.
Materials:
liquid samples: water, ethyl alcohol, kerosene three droppers
beakers or glass jars with wide mouth three pieces blade
small piece of wax paper or plastic sheet glass jar
old newspapers to catch drips and spills one-peso coins
plastic straw plastic sheet
salt pepper
sugar talcum powder
Procedure:
Part A: “Liquid and Drops on A Wax Paper”
a. Lay a piece of wax paper flat on the surface of the table.
b. Using a dropper, place a drop of a liquid sample on the wax paper.
Do the same for the two other liquids. Make sure a different dropper
is used for each of the liquid samples to avoid contamination.
c. Observe and record the appearance of the drops of the liquid samples
on wax paper.
REMINDER:
1. Use the different materials for their intended purposes only for this
activity.
2. Do not play with the materials especially the sharp ones.
3. Dispose the used materials and liquids properly.
4. Do NOT mix the liquids.
5. Never taste the liquids.
Part A:
1. How would you describe the appearance of the drops of the liquid samples
on wax paper?
________________________________________________________________________
________________________________________________________________________
________________________________________________________________________
________________________________________________________________________
________________________________________________________________________
Part B:
1. Did the blade float on the surface of the liquids? Why or why not?
________________________________________________________________________
________________________________________________________________________
________________________________________________________________________
________________________________________________________________________
________________________________________________________________________
Part C:
1. What happened to the level of the water in the glass jar?
________________________________________________________________________
________________________________________________________________________
2. What happened to the water in the jar when you added more one-peso
coins?
________________________________________________________________________
________________________________________________________________________
3. How many coins were added without causing the water to overflow?
________________________________________________________________________
Part D:
3. What are the properties of water and how do they relate to its structure
and intermolecular forces?
________________________________________________________________________
________________________________________________________________________
________________________________________________________________________
________________________________________________________________________
________________________________________________________________________
________________________________________________________________________
Performance Task:
Goal: To draw and explain the relationship of the properties of water to an
environmental phenomenon
Note: On a short bond paper, draw and explain how the property of water
is related to one of the following situations:
Standard: Criteria for your task is shown in the given rubric on the next page:
Rubric for Essay: High School
Highly
Proficient Developing Beginning
CRITERIA Proficient SCORE
(3) (2) (1)
(4)
The essay is The essay is The essay is The essay
focused, focused on the focused on topic poorly
Focus/ Main
purposeful, and topic and and includes addresses topic
Point
reflects clear includes few loosely and includes
insight and relevant ideas. related ideas. irrelevant ideas.
ideas.
Persuasively Supports main Supports main Provides little or
supports main point with point with some no support for
point with well- developed underdeveloped the main point
Support developed reasons and/or reasons and/or
reasons and/or examples examples
examples
Effectively Organizes ideas Some Little or no
Organization
organizes ideas to build an organization of organization of
& Format
to build a argument ideas to build ideas to build
(Paragraphs,
logical, coherent an argument an argument
Transitions)
argument
Effective and Appropriate use Some use of Little or no use
Language creative use of of elements of elements of of elements of
Use, Style & elements of style Uses style Contains style Many
Conventions style to enhance correct frequent errors errors in
(Sentence meaning Uses grammar, in grammar, grammar,
structure, correct spelling, and spelling, and spelling, and
word choice, grammar, punctuation punctuation punctuation,
grammar, spelling, with few errors makes reader’s
spelling, punctuation comprehension
punctuation) throughout with difficult
very few errors
Distinctive Sufficient Very little No
experimentation experimentation experimentation experimentation
with language with language to enhance nor
Originality and usage to and usage to concepts Does enhancement of
(Expression enhance enhance not exhibit concepts No
of the theme concepts concepts creativity adherence to
in a creative Applies higher Applies basic the theme
way) order thinking creative skills to
and creative relay ideas
skills to relay
complex ideas
Gauge
Direction: Write the CAPITAL letter of the correct answer on a separate paper.
(15 points)
A. Books
Buthelezi, Thandi, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom, and Dina
Zike. Chemistry Matter and Change. Quezon City, Metro Manila: Phoenix
Publishing House, Inc. 2013.
B. Government Publications
Commission on Higher Education. Teaching Guide for Senior High School General
Chemistry 2. n.d.
Commission on Higher Education. Teaching Guide for Senior High School Physical
Science. n.d.