Roll No. QORLHOSS Pandit Deendayal Energy University Mid Semester Examination - February 2023 B. Tech.- VI (Chemical) Semester — VI Course Name : Instrumentation and Process Control Date: 27/02/2023 Course Code: 20CH310T Time: 2 hours ‘Time: 10:30 AM to 12:30 PM Max. Marks: 50 Tnstructions: 1. Donot write anything other than your roll number on question paper. 2. Assume suitable data wherever essential and mention it clearly. 3. Weng sport nits, nomen, and raving et kehechemats wherever required isan integral part of the answer. QNo. | Description Marks [COs | BTL il (a) What is Bourdon tube pressure gauge device? Highlight (with a figure) | [5] col |t it’s working principle with key advantages and disadvantages. (5) 2 “[{s} | co2 |3 (b) Describe the working of a Resistance temperature device (with a figure). 2 ‘The output ofa linear system is ¥(1) = 10 e* sin(4/), when the input is X(0) (Note: ¥() and X( are deviation variables) (a) Determine the transfer function of the system. (b) Determine the ultimate steady state response of the system to a unit step. (©) Find the response of the system to an 3 ] Figure 1 shows a stirred tank heater system. The liquid enters the tank wit flow rate of F; (m?/sec) and a temperature T; (°C), where it is heated with steam (having a flow rate of Fy). F and T are the flow rate and temperature of the leaving stream. The tank is considered to be well stirred. Apply the feedback control loop and draw/sketch a control scheme for any one of the following control objective, * To maintain the temperature of the outlet stream T at desired value T,. OR * To maintain the water level in the tank A at desired value hy. aa nlse input. | \ (5) | cos ]3 stem Figure 1: Stirred tank heater system Page 1 of 2Descruine the response of the syntem [nf] defined by the fellowing |(10] | CO} |3 (0) = ‘Consider a second order system given by the following transfer function. {io} | co2 4 ¥(s) 10 2 (3) = 3 "Fa 25715 A step change of magnitude 4 is introduced into the system. ‘Calculate the following. (a) Percent overshoot (b) Final value of y(t) (©) Maximum value of y(t) (@) Rise time (©) 5% sealing time (0) Period of oscillation (2) Natural period of oxillation | ‘Consider a tank system of cross sectional area A (= 2.5 mr), shown in Figure | [10] | CO3 | 2. The system is fed by a volumetric flow rate q(. A linear flow resistance R is attached to the outlet stream having a volumetric flowrate of qu(). The | second outlet stream from the tank is attached to a constant flow rate pump ‘which maintains the volumetric flow rate qz 2s constant. } | 9 | | R a 10 Ho | L=2m le ¥ a & Figure 2: Liquid level tank system | (a) Determine the transfer function for the system that relates the height of | [5] 3 | the liquid inthe tank h(9 tothe input volumetric flow rate q() forthe two | cases when Case 1: h() L (b) Comment whether the tank operates in a self-regulatory or @ non- regulatory mode for each case (Case 1 and Case 2). Support your | 2] 5 assertions by examining the response of tank system to a unit-step input. (c) ‘The tank operates at steady state height of 3 m with an inlet flow rate of 10 ‘m'imin, anda resistance of 1/5 min/m?, At t = 0, the inlet flow rate is | [3] 2 suddenly inereased by a unit-step function, Caleulate the water level inthe tank at ¢=2 min, Page 2 of 2Rott Ne. BE UOSS Pandit Deendayal Energy University End Semester Examination - May 2023 B. Tech VI (Chemical) Time: 3 hours ‘Max. Marks: 100 Time: 10 AM to 1:00 PM Instractions: ‘Do noe write anything other than your roll mumber on cvestion paper. Assume ‘No. | Description Explain (with figure) the working of any one direct and indirect level sensing | [10] device. dasa wherever esseatial and mention it clariy- 4 Consider the system represented by the block diagram constant 12 is twice that of the 11. Also, the response of by 45°. Given X(t) = 2sin ot . and t; = | min, ‘Write short notes (with neat diagrams) on any 2 of the following flow-measuring | [10] device. a) Venturi tube flow meter b) Orifice plate flow meter ©) Pitot tube flow meter 4) Rotameter “The open loop transfer function (Gox = GiGsP) ofthe system shown in Fig. i | [10] given below. Determine ifthe system is sable or unstable. Also, find ifthe response is oscillating or non-oscillating, answer. 2 ») Cals) “GENET a) Determine the input frequency (0). b) Determine the amplitude ofthe steady-state response 2. ©) Determine the overall response of the sy + Gout) = 20D ROG LL, c | 2) G9) = Sassy | Ae | cor | 4 | | | 1 ‘a logical reason to support your |: Schematic block diagram Fig. Shown in Fig.2.Thetime | [10] | CO2 |3 FY lags behind the input © Lresen | fen | _ | Fig. 2: Block diagram | stom (2 (0).noni)” [A eal PID controller has the pastor function, G(s) = 140.25 + 17(059).| 151 co4 Evaluate te frequency at ‘which the amplitude ratio ofthe controller is 1- 6 Plot Bode’s diagram for the system “whose overall transfer function is {15} | COS 5 2) OO) =GeEHErD +5) » (9 222 7] Fane « PID controller using the Ziegler Nichols Controller tuning method fora Troy | C06 system shown in Fig. 3. x ee cae ee Des = Fig.3 8 Construct the Routh array table for the system represented by the following | [10] COS characteristic equation, stash t6s?+4s¢ (14K) =0 ) Determine ifthe system is stable for K= b) Determine the value of K at which the system is marginally stable. Also, find the values of the roots on the imaginary axis. 9 Calculate the gain value Ke needed to produce continuous ‘oscillations in the | [10] C06 ‘control system shown in Fig. 1, where, Gy = Key H=1, Ga= 2Qstl)". a) n=2 by n= 10 | For the control system shown in Fig. 4, determine fio) | Co4 a) C(s/R(s) b) Cla) ©) Offset 4d) Whether the closed-loop response is oscillatory 4 1 c + R=Usae Roll No. WAXHOSS Pandit Deendayal Energy University Re-End Semester Examination — Oct 2023 B. Tech.- VI (Chemical Engineering) Semester - VI Course Name : Instrumentation and Process Control Date: 14/10/2023 Course Code: 20CH310T Time: 3 hours Time: 10 AM to 1:00 PM Max. Marks: 100 Instruetions: 1. Do not write anything other than your roll number on question paper. 2. Assume suitable data wherever essential and mention it clearly. 3. Writing appropriate units, nomenclature, and drawing net sketches/schematics wherever required i an integral part of the answer. Q.No. | Description Marks | COs 1 Explain (with figure) the working of any one direct and indirect level sensing | [10] cor device. 2 Describe the working of any one (with neat diagram) of the following flow- | [10] col measuring device. [3 Describe (with neat figure) the working of fio] cor | (a) Pressure swing thermometers | (b) Manometers 4 ‘A thermometer having a time constant of 0.2 min is at a steady-state temperature of | [5] co3 97°F. At time t = 0, the thermometer is placed in a temperature bath maintained at 110°F. Determine the time needed for the thermometer to read 107°P. | Consider the liquid-level systems shown in Fig. 1 in which two tanks are arranged so CO3 | that the outlet flow from the first tank is the inlet flow to the second tank. % Fig. 1: Liquid level tank system | a) Derive an expression for Hs)/Q(s) for the setup shown in Fig. 1 | fo) The time constants are f= 1 min and fy = 0.5 min, R:= 1. Evaluate the time- | [5] response of the level in tank 2 [# ()) if'a unitstep change is made in the inlet | flow rate to tank || Plot Bode’s diagram for the system whose overall transfer function is {10} | Cos 1 9 8 = GHesF ») 0) = SEH Consider a second order system given by the following transfer function, {to} | Cos 6 10 G(s) = 2-00 XQ) t+ 16544 A step change of magnitude 4 is introduced into the system. Caleulate the following, (a) Percent overshoot | (b) Final value of y(t) (© Maximum value of y(t) (@) Rise time (©) Period of oscillation g Construct the Routh array table for the system represented by the following | 10) | COS characteristic equation, st 453 46s? +45 + (14K) | Determine the value of K for which the system is stable. | 9 Using Ziegler Nichols table, calculate the gain value Kc needed to produce | [10] C06 continuous oscillations in the control system shown in Fig, 2, where, G)= Ke, H G:= UQs+1\Ss#). + R t G; G c H Fig.2 10 | Fora unit-step change in the set point R(S) for the control system shown in Fig. 3, | (10) | CO4 determine a) Y(sYR(s) | b) Steady state offset | r— 2 y | (Qst)Gst) | | | Fig. 3: Block diagram for the control systemRoll No. ZOPCHOSS. Pandit Deendayal Energy University Mid Semester Examination ~ March 2023 B.Tech. (Chemical) Semester -6 pate: 01/03/2023 . 10.30am- Course Name: Pharmaceutical Technologies saa .. Marks: Course Code: 20CH31ST Max. Marl Instructions: . Do not write anything other than your roll number on question paper. 5 Assume suitable data wherever essential and mention it clearly. 3 Weiting appropriate units, nomenclature, and drawing neat sketch required is an integral part of the answer 4, Answer all 5 questions, each carrying 10 Marks .es/schematics wherever 1 Explain distinguishing features of Pharmaceutical Industries (PI) from other industries. Explain ee iH C01 [10M] wy venture capital firms are hesitant to provide loans to PL faced in this gs via chemical synthesis route. Explain the challenges C02 [10M] (02 Explain production of any 3 dru route OR (202 Explain details of any 4 medications derived from animal origin along with their uses. Explain the CO? [10M] challenges faced in this mode of manufacture of medications, 1n4 basic components ofa successful formulation unit, Explain different drug formulation 203 Explai forms that are given to patients along with 2 examples of each COI [10M] oR 203 Define API and give the list of top API manufacturers in India and world. Explain the conesPt of CO1 [10M] contract manufacturing in PI Q04 Explain the concept of sterility and its need in Pl, Define and explain SAL Define and distinguish between aseptic, antiseptic and sterile and list agents/methods to achieve them, C03 [10M] (Q05 Explain different materials used in Membrane Sterilization (MS) and typical applications in which it is employed. Explain advantages and disadvantages of MS. C03 [10M] Page 1 of 1Roll No. AOPLHOSS: Pandit Deendayal Energy University End Semester-Exami ion - May,2023 B. Tech. (Chemical Engg.) ‘Semester. Date: 11/05/2023 Course Name: Pharmaceutical Technology Time: 10.00AM-1.00 NOON Course Code: 20CH31ST Max. Marks: 100 Instructions: 1. Do not write anything other than your roll aumber on question paper. 2. Assume suitable data wherever essential and mention it clearly. 3. Writing appropriate units, nomenclature, and drawing neat sketches/s required is an integral part of the answer. 4, Answer all 5 questions, each carrying 20 Marks chematics wherever Q01 a. Define API and Formulation along with their characteristics and examples. CO1 [10M] b. Explain role of particle size of raw materials in iquid dosage manufacturing COS [10M] (02 a. Explain in detail the concept and need of sterility in Pharmaceutical industries. CO3 [10M] C03 [10M] ». Explain Gas Sterilization method along with its merits and demerits. OR b. Explain Dry heat sterilization method with applications. How is it different from steam sieritizaion? Explain in derail. C03 [1004] (203 a. Explain role of pressurization and temperature control as design parameters in design of clean CO4 [10M] b. Pople chest issues that need to be addressed in design of clean facilities. CO4 [10M] Q04 a. Explain different solid dosage forms along with their examples. COS [10M] b. Explain various excipients used in semi-solid dosage forms. C05 [10M] OR b. Explain various commercial bases used for ointments and creams. COS [10M] Q05 a. Explain glass, plastics and metals as packaging materials used in Pharmaceutical industries along with their merits and demerits C06 [10M] b. Explain with a neat diagram one manufacturing process of tablets. C06 [10M] OR . Explain with a neat diagram one manufacturing process of capsules, C06 [10M] Page 1 of 1Roll No. 2A0G(HOSS Pandit Deendayal Energy University Re-Examination — October, 2023 B. Tech, (Chemical Engg.) Semester -6 12/10/2023 Course Name: Pharmaceutical Technology : 3.00PM-6.00 PM Course Code: 20CH315T Max. Marks: 100 Instructions: 1. Do not write anything other than your roll number on question paper. 2. Assume suitable data wherever essential and mention it clearly 3. Writing appropriate units, nomenclature, and drawing neat sketches/schematies, wherever required. is an integral part of the answer. 4. Answer all 5 questions, each carrying 20 Marks Q01 a. Explain in detail distinguishing characteristics of Pharmaceutical industries. CO1 [10M] b. Explain with examples drugs manufactured by isolation from animals C02 [10M] Q02 a. Explain in detail the need of sterility in Pharmaceutical industries C03 [10M] b. Explain Radiation sterilization method with applications. C03 [10M] OR = b. Explain Filtration sterilization method with applications. C03 [10M] Q03 a. Explain Air change rate as a design parameter for clean facilities C04 [10M] b. Explain Temperature control as a design parameter for clean facilities C4 [10M] Q04 a. Explain construction of HEPA filters as used in Pharmaceutical industries COs [10M] b. Explain characteristics and examples of Gelatine capsules COs [10M] OR b, Explain various forms of coated tablets along with applications COS [10M] Q05 a. Explain the need of quality control of packaging materials C06 [10M] b. Explain role of particle size in liquid dosage manufacturing C06 [10M] OR b. Explain critical role of uniformity in liquid dosage manufacturing C06 [10M] Page 1 of 1Roll No. 20 Hoss Pandit Deendayal Energy University Mid Semester Examination - February 2023 B. Tech.- VI (Chemical Engineering) Semester— VI Course Name : Piping Design Course Code: 20CH314T paboor Time: 10,30 to 12.30 PM. Bia’ Marks) Tnstruetions: 1. Do not write anything other than your roll number on question paper. 2. Assume suitable data wherever essential and mention it clearly. 3. Writing appropriate units, nomenclature, and drawing neat sketches/schematics wherever required is an integral part of the answer. Q.No. | Description Marks | COs | BTL 1 a) Illustrate the features covered in codes and standards of the piping | [5] col |4 system. Mention the individual components necessary to complete a piping system. b) To connect the various process and utility equipment contained within a process plant, itis necessary to use an assortment of piping components and pressure changers. Identify/write the name of the ‘components or schematics shown in the figure below. 15] | cor |1 @) ©) (®) Page 1 of 8What are the most commonly used valves in projects designed to | [8] ASME B31 codes. Explain the working functions of Gate valves, Globe valves and Check valves. | \ ™ | JL ‘A 6-cm-diameter horizontal water pipe expands gradually to a 9-cm- | [8] diameter pipe (Figure below). The walls of the expansion section are angled 10 from the axis. The average velocity and pressure of water before the expansion section are 7 m/s and 150 kPa, respectively. Determine the head loss in the expansion section and the pressure in the larger-diameter pipe. Assume a fully developed flow with ai = a2 = 1.06 and Ki = 0.133. 03 [3 a) Define cavitation. What are the effects of cavitation? Give the | [6] necessary precautions against cavitation. b) A centrifugal pump having outer diameter equal to two times the | (g] inner diameter and running at 1000 r.p.m works against a total head of 40 m. The velocity of flow through the impeller is constant and equal to 2.5 m/s. The vanes are set back at an angle of 40 at outlet. If the outer diameter of the impeller is 500 mm and width at outlet js 50 mm, determine: (i) vane angle at inlet, and (ii) work done by impeller on water per second. ce co4 1 co4 }3 Page 2 0f 3‘is and friction factor f. Im Ky=2 |The bathroom plumbing of building consists of 1.5-cm-diameter copper pipes with threaded connectors, as shown in figure below. (a) If | the gage pressure atthe inlet of the system is 200 kPa during a shower and the toilet reservoir is full (no flow in that branch), determine the flow rate of water through the shower head. (b) Determine the effect of flushing ofthe toilet on the flow rate through the shower head. Take the loss coefficients of the shower head and the reservoir to be 12 and 14, respectively. Write your answer in terms of volumetric flow rate V Shower head Ky=12 ® K-10 fully open K,=10 | Thilet reservoir with float K=14 9 Globe valve, (19) cO3 Page 3 of 3Course Name : Chemical Reaction Engineering II Course Code : 20CH311T Roll No. 2OPCHO SS Pandit Deendayal Energy University Mid Semester Exam B. Tech. Chemical Engineering ‘Semester - VI Instructions: ‘Do not write anything other than your roll number on question paper. ‘Write in clear handwriting. Poor handwriting will have negative marking. ‘Assume suitable data wherever essential and mention it clearly. Write all the answers sequentially Date: 28 Feb 2023 Time: 2.0 hours ‘Max. Marks: 50 ‘Writing appropriate units, nomenclature, and drawing neat sketches/schematics wherever required is an integral part of the answer. A residence time distribution study was performed on a recently procured reactor using a pulse tracer. ‘The results are tabulated as the concentration time data measured at ambient conditions. The sampling cele seater min (0.0] 1] 2]3]5]71 9 | 12] 15] 18 | 20 | 22 | 24 | 26 28 | 30 [2 {tc molm | 23 | 19 | 13 | 7.2 | 4.6 | 3.6] 28/23 |19[17|15[12]09|05 03 [01 a Cor r the RTD data provided above and answer the following a Construct the figures C(t) and E(t) as a function of time,(8) : b. Entimate the values for mean dence time and eterée (10) A ©. Considering second order reaction with k= 0.045 L/mol-min, Initial concentration Co can be taken as 2.2 mol/L. Determine the mean conversion for the reactor using segregation model. (5) 4. Find the number of tanks and Evaluate the conversion as per T-I-S model (5) ©. Considering the open-open system dispersion mode! - Develop the set of equations need to be solved for polymath solution (5) £ What is the relation between Bodenstein number and Peclet number? (2) 18 | co1 17 | coz 65) a Enlist the essential properties (minimum five) of a catalyst? Define the following, terms — Turn over frequency and Active Sites os | co @ External and internal mass transfer can change the course of reaction kinetics — How it can be avoided — Appraise when the reaction becomes independent of both the mass transfer steps — Explain in detail 0s | cos Explain in brief about dissociative and non-dissociated adsorption — Derive the final isotherm equation for any one case. 05 | cos Page of 15 -Timited reaction is being carried out in (The ease of divide and be conquered) A mass transferlimied reaction is z |! reactors of equal volume and packing, connete in seriesas shown in below figure Currently 26% conversion is being achieved (case 1) with this arangement. Engineers, suggested that the reactors be separated (case 2) and flow rate be divided equally among each of two react decrease the pressure drop and hence the pumping requirements. Estimate the new conversion ‘and comment on the arrangement. las 4k (anda athe react Langthofractory fn ceo 1 and case 2 respectively) 3B) (ys ««(@) (z=) in) = Be 10 iy ‘Attempt the following (with neat sketch) 43) Define Internal Effectiveness factor and its significance in designing of reactor (5 marks) b)_ Derive the relationship between Internal Effectiveness factor and Thiele modulus for first order reaction (10 marks) ©) Plot qualitative plots and explain (5 marks) 1) Effectiveness factor Vs Thiele modulus, 2) Effectiveness factor Vs Reaction O-der 3) Effectiveness factor Vs Epsilon (efiect of Volume) 4) Effectiveness factor Vs Thiele modulus (effect of Temperature) The first order system A — B was carried out over tw different sized pellets. The pelle Wee contained in a spinning basket reactor that was operated at sufficiently high rotation speeds thet extemal mass transfer resistance was negligible. The results of two experimental runs mde under identical conditions are given in below table, Estimate the following 4) Estimate the Thicle modulus and effectiveness factor fr each pellet (10 marks) b) Estimate the particle radius to reach the effectiveness factor 19 98% (10 marks) Reactor Data Measured rate Pellet Radius mol/g cat. see 3 Runi ‘O01 Run 2 15 0.007 10% = 3x coth, ~ 1) 10 All the Best. Page 2 of 2Course Name: Chemical Reaction Engineering 11 Roll No. ZOBCHOS' Pandit Deendayal Energy University End Semester Examination- May 2023 Programme Name Semester -< VI> Course Code: 20CH311T Max. Marks: 100 Tastruetions: Do not write anything other than your roll number on question paper. Time: 3 hour (10:00 AM to 01:00 PM 2 Assume suituble data wherever essential and mention it clearly 3. Welting appropriate unis, nomensatur, and drawing neat sketchesschemates wherever required ian integral par of 4__Assume appropriate data if ot provided PARTI GU Marks) & Description Ma [C] BTL ° rs | 0 "| 3) Prove that mean residence time for an idea reactors equal to spacetime sf iis co 1) Construct the RTD profile forthe following cases of PFR and CSTR in parallel, ()t»> tu ‘ (©) te <14 (6) t= (tt the space tne for PFR and MFR accordingly) st | Compare the relative diz of () PFR (i) CSTR and (i) LFR Tora mean conversion oF 86% | 9 | > |g Consider the reaction tobe frst order iveversible with te constant of Imi" 3 | Developa rte aw assuming a surfacefnited reaton in the eacton of two noxious automotTe exhaust pris 90 and NO-cued-ou-ove a topper cata 9 form snvronmestly scceptable produc, N: and CO, co+s == co-s Adsorption vows == wea] Atom ele NO-S+COS ==? CO:+N-S+S) Surface Reaction NS#N'S = NrS] ration Ne-S —> Not PARTI 0 Maris) Ge Description Ma | C] BTL ° ts | 0 1] For the ease of Diflsion tough a film on @-a cals (witout eaclony” atempr te | 20°] 4 | folowing (wth net sketch) 3) From the mole balance derive a mathematical modelo extimate the mass rans fx (forthe ext of fasion trough lm to actly patel” (15 mars) »)_Is concentration profile sina or expon=nial erss the film, Discuss (5 mark) 2 | Ung Flation for Woz derived in Question 1; Caleulate the mass transfer fox of reactant A] 10] #3 10. single calyst pli Iem in diameter suspe ded ina large body of liquid. The reactants present inthe dilate concentrations and the reaction is considered to take place instantaneously At the exer surface (ie, Cas = 0). Te blk cnecrvation ofthe reactant is 1.0, and he Hiuid velocity i 0.1 ms The kinematic viscesy is 104 ms, and the gud diusivty of Ais 10" mis, Use the singe pace corlaon Sh= 2+ 0.6 Re!? Sel" Pager ef2as Roll No. AOBCHDSS” Pandit Deendayal Energy University (Formerly Pandit Deendayal Petroleum University) Mid Semester Examination B. Tech, (Chemical Engineering) 1 eat Date: 07/03/2023 Course Name : Elective ~ Polymer Science & Technology Tine: 10130 9. 1:30 pm Course Code ? 20CH317T be Instructions: LW 2, 3. 1@) 1) 2¢@a) 2(b) Tremot write anything other than your rll number on question paper. pone auitble data wherever essential and ‘mention it clearly. ating appropriate units, nomenclature, and idravsing neat sketches of the answer. sfechematics wherever required is an integral part Give the mechanism and kinetics of Copolymerization. Derive the ‘copolymer equation in terms 16 CO3 sive immer concentration and monomer mole fraction. pefine various average molecular weight used In polymer fractionation. 04 CO3 Define and explain following polymerization techniques with significance of each. 12 CO3 (a) ‘Solution Polymerization (b) ‘Suspension Polymerization (Emulsion Polymerization Give the outline for following petrochemicals useful for manufacturing polymers: oy Propylene 12 Col 2) Styrene @) Phosgene @) Toluene Diisocyanate piscuss significance of glass transition temperature and melting point of polymer. o4 col ‘Write short notes on following: 18 CO2 (a) Give the importance and significance of polymer science ° {b) Short note on Polymer waste disposal and its remedies {@)__ Give comparison between polymers and metals. OR Describe in detail the production of Pol prod ly vinyl chloride (PVC) with the help of a neat 18 co2 flow sheet. Also highlight important properties: of PVC with its major: application. eee Page 1 of 2tll a | Iss we oon? Roll aver sid yaiver ~voN 0) & Explain wet spinning process of fibers in detall with a neat and clean diagram. (01) co; 7. What is adaitive? Why itis used in polymers? Write a detailed note on classification of (09) Co: additives, 8 _biscuss the various methods used to measure average molecular ‘weight of polymers. (09) Cos ° Attempt any two from the following: (09) COs Compare various methods of spinning used for fibers 'b. Give comparison between injection blow molding and extrusion blow molding. © Give comparison between addition and condensation polymerization Page 2 of 2Roll No.QoRCHOSS Pandit Deendayal Energy University ) (Formerly Pandit Deendayal Petroleum Unive End Semester Examination B. Tech, (Chemical Engineering) Semester - VI Date: 16/05/2023 Course Name : Elective - Polymer Science & Technology Time: 10:00 to 01:00 pm Course Code : 20CH317T Max. Marks: 100 Instructions: 1. Donot write anything other than your roll number on question paper. 2. Assume suitable data wherever essential and mention it clearly. ae 3. Writing appropriate units, nomenclature, and drawing neat sketches/schematics wherever required is an integral part of the answer. 1, Given below is the molecular weight distribution for polypropylene sample. (16) C06 Molecular Weight Range (g/mol) Xi Wi 8,000-16,000 0.05 0.02 16,000-24,000 0.16 0.10 24,000-32,000 0.24 0.20 32,000-40,000 0.28 0.30 40,000-48,000 0.20 0.27 48,000-56,000 0.07 Ol Find out following for the given sample: | (a) The number-average molecular weight (b) The weight-average molecular weight (©) The degree of polymerization 2. Describe in detail the production of Styrene Butadiene Rubber (SBR) with the help ofaneat (16) COS | and clean flow sheet. Also highlight important properties of SBR & its major application. OR Describe in detail the manufacture of Polypropylene (PP) with the help of a neat and clean (16) COs flow sheet. Also highlight important properties of PP with its application. 5, Discuss in detail about various polymer characterization techniques. (09) co3 4, Whatisvulcanlation of rubber? Compare properties of vulcanized rubber with unvulcanized (99) cy “rubber. 5, What is injection molding? Explain the entire Injection molding process with neat diagram. (16) COM Give specific applications of injection molding. OR 5. Discuss mechanism & kinetics of chain reaction polymerization. Also derive the formula for (16) CO rate of polymerization. Page 1 of 2