HW11P1

clear
syms V
Pr=1.78;
Tr=1.35;
Vmc=203;
Right=Tr*8/3;
Vm=solve(Right == (Pr+(3*(Vmc)^2)/(V^2))*(V/Vmc-1/3),V);
Vm=vpa(Vm(3:3))

Vm =

298.14895244334940793770917518852

P2
clear
syms V U
P=276.4;
T=480;
R=0.08206;
a=1.378;
b=0.03183;
aR=17.16;
bR=0.0221;
Vm=solve(P == ((R*T)/(V-b))-(a/(V^2)),V);
Vm=vpa(Vm(3:3))
Vm2=solve(P == ((R*T)/(U-b))-(a/(U*(U+b)*sqrt(T))),U);
Vm2=vpa(Vm2(3:3))

Vm =

0.1478796605824042387361834982334

Vm2 =

0.17343135687795581382765237080919

P3

clear
syms x
X=solve(0 == (-0.00000000152*(x^3))+0.00000314*(x^2)-0.000884*x-
0.009,x);
X=vpa(X(2:2))
X =

348.5660853626280233877155101225
P4

clear
syms V U W
P=10;
Tc=304.2;
Tb=1040;
Ti=1388;
R=0.08206;
a=3.640;
b=0.04267;
Vm=solve(V == ((R*Tc/(P))*(1+(b-(a/(R*Tc))/V))),V);
Vm=vpa(Vm(2:2))
Vm2=solve(U == ((R*Tb/(P))*(1+(b-(a/(R*Tb)))/U)),U);
Vm2=vpa(Vm2(2:2))
Vm3=solve(W == ((R*Ti/(P))*(1+(b-(a/(R*Ti)))/W)),W);
Vm3=vpa(Vm3(2:2))

Vm =

2.4544806227404577322660528368829

Vm2 =

8.5342582817059022458438779864356

Vm3 =

11.400629884807486072447256608844

diary off
 0.08205
T 273.15 R 8
P Vm Z
22.390 0.99894
1 5 5
0.92664
100 0.2077 7
0.91370
200 0.1024 9
0.96233
300 0.0719 9
1.05112
400 0.0589 2
500 0.0518 1.15552
1.26884
600 0.0474 2
1.38662
700 0.0444 5
1.50262
800 0.0421 3
1.61817
900 0.0403 5
1.73551
1000 0.0389 1

1.8

1.6 f(x) = − 1.5223556986E-09 x³ + 0.0000031405391518 x² − 0.0008843695757 x

+ 0.9908201576991
R² = 0.998887508042868
1.4

1.2

0.8

0.6

0.4

0.2

0
0 200 400 600 800 1000 1200