MCQS:

1. The unit of equilibrium constant Kc for the reaction N2 + O2 ↔ 2NO is :

(a) mole-1 dm3 (b) mole-2 dm3 (c) mole dm-1 (d) none of these
2. The relationship between Kpand Kcis given by :
P
(a) Kc = Kp (P)Δn(b) Kc = Kp( )Δn(c)Kp= kc( RT )Δn (d)Kp= kc( RT )-Δn
N
3. _______ is used as catalyst in Haber’s process for NH3 gas manufacture .
(a) Iron (b) Carbon (c) Copper (d) Silver
4. In modern Haber process Plants, the temperature maintained during the process is :
(a) 670 - 770 K ( 4000C - 5000C) (b) 270 – 370 K (0 0C - 1000C )
0 0
(b) 370 – 470 K (100 C - 200 C) (d) 570 – 600 K (300 0C - 3800C)
5. The PH of human blood;
(a) 8.1 (b) 7.53 (c) 7.63 (d) 7.35
6. The term PH was introduced by;
(a) Henderson (b) Sorenson (c) Goldsmith (d) Thomson
7. The PH of 10-4 mol dm-3 of an aquous solution of Ba(OH)2 is;
(a) 4.5 (b) 6.4 (c) 7.5 (d) 10.5
8. The PH of gastric juice is;
(a) 2.0 (b) 3.0 (c) 3.5 (d) 5.6
9. The nature of an aquous solution of ammonia (NH3) is:
(a) Amphotaric (b) Neutral (c) Acidic (d) Basic
10. The value of Kw at 25 oC is :
(a) 0.11 ×10-14 (b) 0.30 ×10-14 (c) 1 ×10-14 (d) 3 ×10-14
11. pH of soft drinks at 25 oC is about:
(a) 3.0 (b) 11.0 (c) 1.0 (d) 7.0
12. Which salt dissolved in water forms a solution with the pH greater than 7:
(a) NaCl (b) CuSO4 (c) Na2CO3 (d) NH4Cl
13. Ionization of Hydrogen sulphide gas is suppressed by :
(a) KCl (b) NaCl (c) HCl (d) KClO3
14. pH of buffer can be calculated by using:
(a) Moseley’s equation (b) Henderson’s equation
(c) Dc-Broglie’s equation (d) Bohr’s equation

15. The pH mixtureof CH3COONa and CH3COOH is :

(a) 7 (b) >7 (c) <7 (d) 1
S.Q

1) Differentiate between reversible and irreversible reactions. Give examples.

2) What do you understand by chemical equilibrium ?
3) Why the equilibrium constant value has its units for some of the reversible reactions , but has not units for some other
reactions?
4) Derive equilibrium constant expression for the dissociation of PCl5 .
5) Write two applications of equilibrium constant.
6) Give the statement of Le Chatlier’s principle.
7) How does a catalyst affect a reversible reaction?
8) How ammonia is synthesized by Haber’s process. Also give the optimum conditions for reaction.
9) Increasing pressure increases the oxidation of SO2 to SO3 .Explain why?
10) What is an ionic product of water? Give its value at room temperature.
11) Define pH and pOH .
12) Define pOH of a solution and give an example.
13) Calculate pH of 10-4 mol/dm3of Ba (OH)2
14) Calculate the pH of 10-3 mol dm-3 HCl.
15) Define pKa and pKb.
16) Prove that pKa + pKb = 14
17) Define common ion effect.Give two examples .
18) Why HCl is added before passing H2S gas in qualitative analysis of 2nd group basic radicals.
19) What are buffer solution ?How are they prepared?
20) What are the applications of buffer?
21) What are buffer solution? How an acidic buffer is prepared?
22) How does the buffer act?
23) Give the two applications of the solubility product.