Post-Lab 6 Copper Cycle-Problems

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nwabuisi (upn64) – Post-lab 6 Copper Cycle – lyon – (50555) 1

This print-out should have 25 questions. 5. −2; +9


Multiple-choice questions may continue on
the next column or page – find all choices 6. +2; +7
before answering.
7. 0; +1
001 10.0 points
In a reaction, the substance undergoing oxi- 8. +2; +9
dation serves as the
9. +2; −1
1. oxidizing agent.
004 10.0 points
2. reducing agent. Given the oxidation-reduction half-reactions

3. electron acceptor. Al(s) → Al3+ (aq)


Cu2+ (aq) → Cu(s)
4. proton donor. what is the overall balanced reaction equa-
tion?
002 10.0 points
The question below is referring to experiment 1. 2 Al3+ (aq) + 3 Cu2+ (s) →
6, The Cycle of Copper Reactions. 3 Cu(s) + 2 Al(s)
It is necessary to perform the first reaction
under the hood because... 2. 3 Al(s) + Cu2+ (aq) →
Al3+ (aq) + 2 Cu(s)
1. the copper metal is susceptible to oxida-
tion from the atmosphere. 3. 2 Al(s) + 3 Cu2+ (aq) →
2 Al3+ (aq) + 3 Cu(s)
2. the moisture in the atmosphere reacts
violently with the nitric acid. 4. 3 Al(s) + 2 Cu2+ (aq) →
3 Al3+ (aq) + 2 Cu(s)
3. the nitric acid is highly corrosive and may
cause the resulting copper solution to bump. 5. Al(s) + Cu2+ (aq) → Al3+ (aq) + Cu(s)
4. the nitrogen dioxide gas generated in the 005 10.0 points
reaction is toxic. Consider the process in which HClO3 is con-
verted to HClO2 . The oxidation state of oxy-
003 10.0 points gen remains −2, and the oxidation state of H
In the redox conversion of Ni2+ to NiO4 − , remains +1. Select the correct statement.
the oxidation number of Ni goes from (−2, 0,
+2) to (−1, +1, +7, +9). Recall that the 1. Cl is oxidized and gains electrons.
oxidation number of oxygen is typically −2.
2. Cl neither gains nor loses electrons in this
1. 0; +7 reaction.
2. 0; +9 3. Cl is reduced and loses electrons.
3. −2; +7 4. Cl is reduced and gains electrons.
4. −2; +1 5. Cl is oxidized and loses electrons.
nwabuisi (upn64) – Post-lab 6 Copper Cycle – lyon – (50555) 2
006 10.0 points
Consider the metals in the following reactions. 2. precipitation

2 Mg + O2 → 2 MgO 3. acid-base

CuO + H2 → Cu + H2 O 4. All of the choices are correct.

009 10.0 points


Ag+ + Cl− → AgCl Which of the following is a reduction reaction?
Which of the following is true?
1. 2 Br− (aq) → Br2 (g) + 2 e−
1. Magnesium is reduced; copper and silver
are neither oxidized nor reduced. 2. Cu(s) → Cu+2 + 2 e−

2. Magnesium is oxidized; copper and silver 3. C(s) + O2 (g) → CO2 (g)


are reduced.
4. Zn+2 (aq) + 2 e− → Zn(s)
3. Magnesium is oxidized, copper is reduced,
and silver is neither oxidized nor reduced. 5. C2 H6 (g) → C2 H4 (g) + H2 (g)

4. Magnesium and silver are oxidized; cop- 010 10.0 points


per is reduced. Given the oxidation-reduction reaction

007 10.0 points


Give the oxidation numbers for copper in the Mg(s) + Sn2+ (aq) → Mg2+ (aq) + Sn(s) ,
compound Cu2 O and for Mo in the compound
what is the oxidation half-reaction?
Mo2 O2−
7 , where oxygen maintains an oxida-
tion number of −2.
1. Sn2+ (aq) → Sn(s)
1. 0; −2
2. Mg(s) → Mg2+ (aq)
2. +2; +7
3. Mg(s) + Sn2+ (aq) → Mg2+ (aq) + Sn(s)
3. +1; +12
4. Sn2+ (aq) → Mg2+ (aq)
4. 0; 0
5. Mg(s) → Sn(s)
5. +1; +6
011 10.0 points
6. +2; +6 In the reaction
Cu(s) + 4 HNO3 (aq) →
7. +1; +1 Cu(NO3 )2 (aq) + 2 NO2 (g) + 2 H2 O ,
what is the oxidizing agent?
008 10.0 points
Classify the reaction 1. HNO3
HNO3 (aq) + NaOH(aq) →
H2 O(ℓ) + NaNO3 (aq) . 2. NO2

1. oxidation reduction 3. This is not a redox reaction.


nwabuisi (upn64) – Post-lab 6 Copper Cycle – lyon – (50555) 3

4. Cu(NO3 )2 016 10.0 points


Which reaction is both a redox and a decom-
5. Cu position reaction?

012 10.0 points 1. Br2 + 2 I− → I2 + 2 Br−


When added to water, which one of the fol-
lowing would produce a base? 2. 2 KClO3 → 2 KCl + 3 O2

1. Cl2 3. BaCO3 → BaO + CO2

2. SO3 4. NH3 + HCl → NH4 Cl

3. CO2 5. Zn + 2 HCl → ZnCl2 + H2

4. Na2 O 017 10.0 points

013 10.0 points


Balance the reaction
Al + H2 SO4 → Al2 (SO4 )3 + H2 .
What is the coefficient of H2 SO4 in the bal-
anced equation?

014 10.0 points


In the reaction
Ni + 2 H+ + 2 Cl− −→ NiCl2 + H2 ,
which species is reduced?

1. Ni

2. NiCl2

3. H2

4. H+
018 10.0 points
Which elements are oxidized and which ele-
015 10.0 points ments are reduced in the synthesis of hydro-
The question below is referring to experiment
gen from coal in the reaction
6, The Cycle of Copper Reactions.
The percent yield at the end of the experi- H2 O(g) + C(s) −→ H2 (g) + CO(g) ?
ment should represent the mass of pure cop-
per recovered, not copper plus any remaining
contaminants. 1. Neither is oxidized nor reduced because
this is not a Redox reaction.
1. True
2. Carbon is oxidized and oxygen is re-
2. False duced.
nwabuisi (upn64) – Post-lab 6 Copper Cycle – lyon – (50555) 4
3. Low
3. Carbon is oxidized and hydrogen is re-
duced. 022 (part 3 of 5) 10.0 points
An excess of sulfuric acid is added in step 8.
4. Hydrogen is oxidized and carbon is re-
duced. 1. Low

5. Hydrogen is oxidized and oxygen is re- 2. High


duced.
3. No effect
019 10.0 points
What is the reducing agent in the reaction 023 (part 4 of 5) 10.0 points
Some unreacted aluminum remains with the
Ca + 2 HBr → CaBr2 + 2 H2 ? product at the end of the experiment.

1. Br− 1. No effect

2. H+ 2. Low

3. Ca 3. High

4. HBr 024 (part 5 of 5) 10.0 points


The copper is not completely dried before
5. This is not a redox reaction. weighing.

020 (part 1 of 5) 10.0 points 1. No effect


Before answering the questions below, recall
the definition of the percent recovery of cop- 2. Low
per in experiment 6.
Describe whether the error introduced by 3. High
each of the following five problems would re-
sult in a high, low or no affect on the percent 025 10.0 points
recovery of the original copper sample. What type of reaction is
Insufficient NaOH is added in Step 3. AgNO3 (aq) + NH4 Cl(aq) →
NH4 NO3 (aq) + AgCl(s) ?
1. High
1. redox
2. Low
2. single displacement
3. No effect
3. precipitation
021 (part 2 of 5) 10.0 points
Some solid is lost during the decanting process 4. decomposition
in step 5.

1. High

2. No effect

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