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CHIMEC 5165

MSDS for A-Polymer (51-PK-008-Z-001,


51-PK-013-Z-009)
MATERIAL SAFETY DATA SHEET

Trade Name CHIMEC 5165

Revision Date: 20/04/2017

This MSDS complies with Regulations (EC) 1907/2006 (REACH), 1272/2008 (CLP) and their amendments, GHS Document.

Product Code 1146/2

1 Identification of the substance/mixture and of


the company/undertaking
1.1. Product identifier : CHIMEC 5165
1.2. Relevant identified uses of : flocculant product.
the substance or mixture and
uses advised against

Identified Use Exposure Scenario Title Applicable Use Applicable Use


Descriptors Descriptors
(PROC or PC) (ERC)

flocculant product. Form ulation & (re)packing of substances and m ixtures P ROC01 ERC02
Use in Oil and Gas field drilling and production operations P ROC02 ERC04
W ater treatm ent chem icals P ROC03 ERC07
"Use in laboratories P ROC04 ERC08a
P ROC05 ERC08d
P ROC08a ERC09a
P ROC08b ERC09b
P ROC09
P ROC15

1.3. Details of the supplier of the : CHIMEC S.p.A. - Via Ardeatina Km 22,500
safety data sheet 00040 S. Palomba - Pomezia (ROMA)
Tel. +39.06.918251
e-mail: infosds@chimec.it
1.4. Emergency telephone : -Chimec 06.918251 (lun/ven 8:30-13:00, 14:00-17:30)
number

2 Hazards identification

2.1. Classification of the :


substance or mixture
Regulation (CE) Nr. 1272/2008 :
Risk category :

H-statements : based on the data in our possession, the product is not classified as hazardous according to Regulation (EC)
1272/2008 (CLP Regulation), Regulation (EC) 1907/2006 (REACH Regulation), and subsequent amendments
and supplements.
Important hazards : the product produces no hazard of irritation or toxicity: however, avoid contact with eyes and handle in
accordance with good industrial hygiene and safety procedures.
2.2. Label elements :
Regulation (CE) Nr. 1272/2008 :
Pictograms :

Warning :

- Contains : none.

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Trade Name CHIMEC 5165

H-statements : based on the data in our possession, the product is not classified as hazardous according to Regulation (EC)
1272/2008 (CLP Regulation), Regulation (EC) 1907/2006 (REACH Regulation), and subsequent amendments and
supplements.
P-statements :

2.3. Other hazards : none.

3 Composition / information on ingredients

3.2 Mixtures Cas Nr. Regulation (CE) Nr. 1272/2008 Conc. [%]
Hazardous component(s) EC / Index Nr.
Reach Nr.

no dangerous com ponent is


present at sufficient concentration
to require a hazard classification
for health in accordance with EU
Directives.

4 First-aid measures

4.1. Description of first aid :


measures
Inhalation : remove the exposed person from contaminated area; keep warm and in fresh air.

: if victim has trouble breathing, transport to medical care and give supplemental oxygen.

: in case of loss of consciousness, give artificial respiration.


- Skin contact : take off immediately all contaminated clothing.

: wash thoroughly with soapy water.


- Eye contact : wash with plenty of water,for at least 15 minutes, keeping the lids well open.
- Ingestion : keep the injured person warm and at rest.

: rinse the mouth with clean water; give plenty of water, seek medical advice.

: do not give anything by mouth to an unconscious or convulsing person.

: do not induce vomiting.

: if aspiration is suspected (during spontaneous vomiting,for instance),seek medical advice urgently.


4.2. Most important symptoms : Symptoms: Symptoms and most important known effects are described on the label and/or in the section 11.
and effects, both acute and
delayed
: Hazards: if handled in a proper manner and in accordance to the intended uses, risks are not expected.
4.3. Indication of any immediate : seek medical advice.
medical attention and special
treatment needed
: Treatment: for the symptomatic treatment (decontamination, vital functions) specific antidotes are not known.

5 Fire - fighting measures

5.1. Extinguishing media :


- Suitable : carbon dioxide, dry chemicals, foam, water spray ( or fog).
- Not suitable : in case of large fire, water may be ineffective
5.2. Special hazards arising from : as a water solution, the fire is highly improbable.
the substance or mixture
5.3. Advice for firefighters : fire fighters and others who may be exposed to the products of combustion, should be equipped with NIOSH
approved positive pressure self-contained breathing apparatus and full protective clothing.
: when exposed to flames or high temperatures encountered during fire conditions, sealed containers may rupture
because of the build up of internal pressure: cool containers with water and remove.
: the contaminated water used for extinguishing must be disposed of in accordance with local legislation.

6 Accidental release measures

6.1. Personal precautions, : spilled material becomes very slippery when wet.
protective equipment and
emergency procedures
: isolate the dangerous area, wear protective clothing. Remove all sources of ignition and contain the spill with inert
materials.
6.2. Environmental precautions : the product is water soluble.

: if spilled product is going into water courses or drain and soil or vegetation are contaminated, advise legal
authority and take measures to minimize effects on the aquatic environment.
: avoid dispersion of large quantities of product in sewers or waterways.

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Trade Name CHIMEC 5165

6.3. Methods and material for : then collect in suitable containers and dispose of or burn at approved site.
containment and cleaning up
6.4. Reference to other sections : Information on exposure/personal protective controls and disposal considerations are shown in sections
8 and 13.

7 Handling and storage

7.1. Precautions for safe handling : avoid contact with skin and eyes.

: handle the product near emergency washing and eye wash bottles.

: in processes where airborne particulates may be generated, mechanical ventilation or localized


aspiration must be provided.
: avoid producing or diffusing dust into the air.
7.2. Conditions for safe storage, : store in well closed boxes.
including any incompatibilities
: store in a fresh and well-ventilated place, away from incompatible substances.

: store away from all sources of ignition (heat sources, sparks and open flames).
7.3. Specific end use(s) : none.
Suitable storage materials : stainless steel, teflon and fluorinated polymers, high density polyethylene, polypropylene,
(literature data) polyurethanes and poly- methyl methacrylates.
Not suitable storage materials : avoid contact with ordinary steel.
(literature data)

8 Exposure controls / personal protection

8.1. Control parameters : there are no exposure standards for the substances in this product with a recommended or
acknowledged OEL value.
TLV (mg/m3) : ---
TLV (ref. to solvent) (mg/m3) : ---
8.2. Exposure controls :
- Respiratory protection : none under normal conditions.

: ensure good ventilation.

: antidust mask may be desirable when emptying bags.


- Skin protection : protective gloves in neoprene or latex, approved for protection against chemical substances (EC seal -
Directives 89/686 and 93/68).
- Eye protection : goggles or face shield with safety glasses.
- Others : appropriated protective clothing.

: eyewash bottle with clean water.


Industrial hygiene : ventilate thoroughly the working place.

: do not eat or drink when handling this product.

: remove all contaminated clothing and remove protective clothing when the work is completed.

: handle in accordance with good industrial hygiene and safety procedures.


Frequency and duration of use : Covers frequency up to: daily yearly use
Operational conditions and risk : Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at
management measures openings
: Prevent environmental discharge consistent with regulatory requirements.

9 Physical and chemical properties

9.1. Information on basic physical :


and chemical properties
Physical state at 20°C : solid.
Colour : off-white.

: product color variations do not affect its performance


Odour : characteristic.
Change in physical state -760 :
mm Hg
Freezing point (°C) : n.d.
Boiling point (°C) : n.d.
Pour point (ASTM D97) (°C) : n.d.
Density at 20°C (gr/cm3) : not applicable.
Viscosity at 20°C (cP) : ca. 600 (5 g/l)
Soluble in : water.
pH value (concentrated product) : n.d.
Flash point (ASTM D 93) (°C) : none.
Auto-ignition temperature (°C) : n.d.

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Trade Name CHIMEC 5165

Explosion limits :
- Lower (% vol) : n.d.
- Upper (% vol) : n.d.
Thermal decomposition (°C) : no decomposition under normal conditions of use.
9.2. Other information : The physical and chemical properties reported in this document are not to be considered Technical
Specifications, and therefore they do not constitute a contractual obligation.

10 Stability and reactivity

10.1. Reactivity :
On combustion forms : may produce carbon oxides.

: nitrous gases (NOx) and hydrogen chloride vapours.


10.2. Chemical stability : The product is stable if the handling and storage requirements/indications are observed.
10.3. Possibility of hazardous : none to our knowledge.
reactions
10.4. Conditions to avoid : extremely high temperatures.
10.5. Incompatible materials : avoid contact with strong oxidizers.
10.6. Hazardous decomposition : no hazardous decomposition products.
products

11 Toxicological information

Rat oral LD50 (mg/kg) : > 5000


Inhalation : no significant signs or symptoms indicative of any health hazard are expected to occur.
Dermal toxicity : no significant signs or symptoms indicative of any health hazard are expected to occur.
Ingestion : no significant signs or symptoms indicative of any health hazard are expected to occur.
Corrosivity / Irritating capacity :
- skin : not irritant.
- eyes : not irritant.
Sensitization : no evidence of this effect is shown.
Carcinogenicity : no evidence of this effect is shown.
Mutagenicity : no evidence of this effect is shown.
Teragenicity : no evidence of this effect is shown.

12 Ecological information

12.1. Toxicity : utilize in accordance with good working practice and avoid to disperse the product in the environment.
96 Hour-LC50-fish (mg/l) : n.d.
12.2. Persistence and : the product is rapidly eliminated from the aquatic medium through irreversible adsorption onto
degradability suspended matter and dissolved organics.
Biodegradation (%) : readily degradable.
12.3. Bioaccumulative potential : the product has been shown to present no bioaccumulation hazard in aquatic plants or fish.
12.4. Mobility in soil : with a correct disposal in biological treatment system, are not expected problems for the degradation
activity of activated sludge.
12.5. Results of PBT and vPvB : The product does not meet the PBT classification requirement (persistent, bioaccumulative/toxic) and
assessment vPvB (very persistent/very bioaccumulative
12.6. Other adverse effects : the product does not affect the depletion of the ozone layer and the formation of atmospheric ozone,
and its potential impact on global warming is negligible.
AOX : the product does not contain organic halons.
WGK class (Germany) : 0 - no hazardous.

13 Disposal considerations

13.1. Waste treatment methods : dispose in a safe manner in accordance with local/national regulations.

: do not dispose in a sink, drain or in the immediate environment.

: of the methods of disposal currently available, it is recommended that an alternative be selected


according to the following order of preference, based upon environmental acceptability:
: 1 - recycle or rework if at all feasible;
2 - incinerate at an authorized facility;
3 - treat at an acceptable waste treatment facility.
Disposal of packaging : dirty containers of product must be recycled or disposed by an authorized facility.

14 Transportation information

- ADR/RID/IATA : not dangerous goods

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Trade Name CHIMEC 5165

14.1. UN number :
14.2. UN proper shipping name :
Contains : none.
14.3. Transport hazard class(es) :
Risk Label(s) :
Subsidiary Risk Label(s) :
14.4 Packing group :
Danger identification number :
(upper)
Substance identification number :
(lower)
Tremcard type :
Tunnel restriction code :
- IMO-IMDG : not dangerous goods
14.1. UN number :
14.2. UN proper shipping name :
Contains : none.
IMO class :
Risk Label :
Subsidiary Risk Label :
14.4 Packing group :
Emergency Schedule (EmS) :

15 Regulatory information

15.1. Safety, health and : refer to relevant international/national regulations for specific actions that should be taken or specific
environmental provisions applicable
regulations/legislation specific for
the substance or mixture
15.2. Chemical safety : a Chemical Safety Assessment has been carried out
assessment

16 Other information

Further information : This Safety Data Sheet contains an Exposure Scenario in an integrated form. Contents of the Exposure
Scenario consist with sections 1.2, 6, 7, 8, 9, 12, 15 and 16 of this Safety Data Sheet
Sources of key data used : N.Irving SAX - Dangerous properties of Industrial Materials ( Sixth edition) - Edited by Van Nostrand
Reinhold Company - 1984
: TLV - Threshold Limit Values for Chemical Substances in Work Environment - Adopted by ACGIH

: A.D.R. - European Agreement concerning the international carriage of Dangerous Goods by Road -
United Nation Publication
: Karel VERSCHUEREN - Handbook of Environmental data on organic chemicals
Information for medical staff :
Revised chapters : The chapters indicated by " ********** " have been modified with the present version of this MSDS.

ST1 - 1146/2 02/07/2003 - 1

The information reported on this MSDS results from our present state of knowledge on safety regulations and is not to be considered as a
guarantee of any specific product property.

CHIMEC cannot be held responsible for any injury or damage deriving from the improper application of the product.

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