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Concentration of Solutions
Concentration of Solutions
SOLUTIONS
GENERAL CHEMISTRY 2
QUARTER 3 – LESSON 7
Use different ways of expressing concentration of solutions:
• percent by mass,
• mole fraction,
• molarity,
• molality,
• percent by volume, and
• ppm
PRETEST
ITEM NO. 1
• There are ways on how to A. The moles of solute present in the
express the concentration of solution.
a solution, one of which is B. The volume of solution (in liters)
mole fraction, which of the containing the solute.
following are needed to C. The volume of solution (in liters)
containing the solvent.
calculate the mole fraction?
D. The number of moles of each
component present in the solution.
D. The number of moles of each component
present in the solution.
3
PRETEST
D. Mole
4
PRETEST
ITEM NO. 3
•What is the unit of A. mol/kg
molarity? B. mol
C. mol/L
D. none of the above
C. mol/L
5
PRETEST
ITEM NO. 5
•What is the molarity of a A. 0.182
solution with 5.0 g CaCl2 B. 0.00182
in 250 mL solution? C. 20
D. 0.0022
A. 0.182
7
What is a Solution?
A solution is a homogeneous mixture of
one or more solutes dissolved in a solvent.
MOLARITY
is a useful way to describe solution
concentrations for reactions that are
carried out in solution.
MOLE FRACTIONS
are used not only to describe gas
concentrations
but also, to determine the vapor pressures
of mixtures of similar liquids.
10
Concentration
of a Solution
• is a macroscopic property,
• represents the amount of solute
dissolved in a unit amount of
solvent or of solution, and
• can be expressed in a variety of
ways (qualitatively and
quantitatively). 11
Qualitative Expressions of Concentration
A solution can be qualitatively
described as :
DILUTE → CONCENTRATED
DILUTE: a solution that contains a small proportion of solute
relative to solvent
CONCENTRATED: a solution that contains a large proportion 12
of solute relative to solvent.
Semi-Quantitative
Expressions of
Concentration
I. II. III.
Percent by Mass Mole Fraction Molarity
IV. V. VI.
Molality Percent by Volume Parts per million
14
I. PERCENT BY MASS
*+,, ./ ,.01&"
30g !"#$"%& () *+,, =
*+,, ./ ,.01&2.%
×455
SAMPLE Solution:
PROBLEM 1 %&'' 06 '0-12304 = 30 7 +&,- + 105 7 06 9&2:;
%&'' 06 '0-12304 = 135 7
A sample of 30
grams (g) of sodium
chloride (NaCl) is 30 " +&,-
dissolved in 105 % #$ %&'' = ×100
135 "'0-12304
grams of water.
What is the percent
by mass of NaCl in % %& '()) = ++. ++ %
the solution?
16
II. MOLE FRACTION
Ratio of the number of mole of one component to the total
number of moles in a solution.
It is represented by a capital letter X.
!"#$% %"#'($
<0-: =;&>2304 ? @0-12: A =
!"#$% %"#'()"*
%0-:' '0-B:42
<0-: =;&>2304 ? @0-B:42 C =
%0-:' '0-12304
41%#:; 06 %0-:' '0-12304 = 41%#:; 06 %0-:' '0-12: + 41%#:; 06 %0-:' '0-B:42
<0-: =;&>2304 06 '0-12: + <0-: =;&>2304 06 '0-B:42 = 1
?+ + ?, = 1
17
SAMPLE PROBLEM 2
A solution is made by dissolving 1.25 g of Na2SO4 in 65.0 g water. Calculate
the mole fraction of the solute and the solvent.
! "#$%& =g!Na
Given: mass of solute=1.25 2SO4+
(#&)$* !(#&,*!$
; mass of solvent = 65.0 g water
Required: mole fraction
!(#&)$- #! = !.%2014 + !321
Solution:
!(#&)$-#! = 0.0018 + 3.61 = 3.61 ;#&
,1"#2*$ "' 1"#3$,*
!"#$ &'()*+", (.) =
,1"#2*+",
0.0088 7"#
.1"#2*$ = = ;. ;;<=
3.62 7"#
3.61 7"#
.1"#3$,* = = ;. ??@
3.62 7"#
Check your answer: !"#$%&' + !"#$*'+& = 1
0.0024 + 0.997 = 0.999 ≈ 1
19
III. MOLARITY (M)
Ratio of the number of moles of solute per liter of solution.
The unit of molarity is mol/L
%0-:' 06 '0-12:
<0-&;32$(<) =
-32:; 06 '0-12304
21
Given:
Molarity, M = 0.5 M H2SO4 ;
liter of solution (volume) = 100 mL
SAMPLE
PROBLEM 4 Required: moles of solute, n
Calculate the
Solution:
number of
moles of solute *.0", (%) ./ ,.01&" = 02&"#, ./ ,.01&2.% ×:.0+#2&)(:)
in each of
100mL of 0.5 M 1, 0.5 +#$
of H2SO4. !"#$ %&' = 100+, × × = 1. 12 345
1000+, ,
22
IV. MOLALITY (m)
The number of moles of solute per kilogram of solvent.
The unit of molality is mol/kg.
%0-:' 06 '0-12:
<0-&-32$(%) =
%&'' 06 '0-B:42 (F7)
24
SAMPLE PROBLEM 6
The density of a 2.45 M aqueous solution of methanol (CH3OH) is 0.976 g/mL.
What is the molality of the solution? The molar mass of methanol is 32.04 g.
Given:
Density (CH3OH) = 0.976 g/mL ; Molarity = 2.45 M ; m, mass (CH3OH) =32.04 g
Required: molality, m
Solution: assume 1L soln, so the number of moles (CH3OH) is 2.45 mol
B0-1%: 06 '0-12:
Y:;>:42 #$ B0-1%: = ×100
B0-1%: 06 '0-12304
27
Given:
Volume of solvent = 120.6 mL;
Volume of solute = 4.94 mL
% -. /01234 = >. ?@ %
28
VI. PARTS PER MILLION (ppm)
The number of units of mass of a chemical or contaminant
per million units of total mass.
Parts per million is mathematically expressed as:
*+,, ./ ,.01&" 7.01*" ./ ,.01&"
;;* (*⁄*) = ×45! ;;* (7⁄7) = ×45!
*+,, ./ ,.01&2.% 7.01*" ./ ,.01&2.%
or
*+,, ./ ,.01&"(=)
;;* (*⁄7) = ×45!
7.01*" ./ ,.01&2.% (*>)
A 'C )DEFGH
A BB' =
A I )DEJ
29
Given:
Concentration of solution = 1.24 g/L
SAMPLE
Required: ppm
PROBLEM 8
30
Given:
% by mass solute = 0.000077%
Required: ppm
SAMPLE
PROBLEM 9 Solution:
<&'' 06 '0-12: = % #$ %&'' '0-12:
What is the <&'' 06 '0-4 100
concentration
in ppm of a 0.000077 % 0.00000077 7 '0-12:
solution that is = =
100 % 7 '0-4
0.000077% by
mass solute? 0.00000077 7 '0-12:
ZZ% = ×1000000 = ]. ^^ __H
7 '0-4
31
BIG IMAGE
32
LET’S DO THIS
1. A solution is prepared by
dissolving 5.02 g of KNO3 in
95.0 g of water. Calculate the
percent by mass of the solute.
% by mass of KNO3 = 5.02 %
33
LET’S DO THIS
2. A solution is prepared by
dissolving 5.02 g of KNO3 in
95.0 g of water. Calculate the
Mole Fraction:
mole fraction of the solute and X solute(KNO3) = 0.0094
X solvent(H2O) = 0.9906
the solvent.
34
LET’S DO THIS
35
LET’S DO THIS
36
LET’S DO THIS
5. A solution is made by
adding 50 mL of ethanol
to 180 mL of water.
Calculate the percent by
% by mass of ethanol = 21.74 %
volume of ethanol.
37
LET’S DO THIS
6. A solution is prepared
by dissolving 6.08 g of
NaCl in 115 g of water.
Calculate the
Parts per million=50,215 ppm
concentration of the
solution in ppm.
38
SUMMARY
Concentration refers to the amount of solute present in a given amount of solvent.
DEFINITION FORMULA
1. Percent by %&'' )* ')+,-.
mass of solute per 100 g of solution % #$ %&'' = ×233
mass %&'' )* ')+,-/)0