24/30 4. Twostudents plan to investigate equll [oucny (aq) + 6H20() = outoxy(ea) + 4Creq) yelow lu . 4.1 at room temperaturg ibrium 41.1 shown, equilibrium 4.4 ‘The students are supplied wit the equlbrum mixture in equilibrium (2) got CuCi() is weighed to make 100 cm’ solution of 105 mol dof the equim misting (i) Calculate the value of x in two decimal places. we coves PeL mol 2 in wer ' oes Ht fre fede, |e (35 81D 2 ender) ‘con (0-275 rol 0.05 Py a 2 onl Ba oh (il) The xg of CuCt(e) calulated in (a) i added into a beaker. Describe how the student should make 100 om® solution of 0.05 mol dm of the ‘equilibrium mixture. — — Give the name and size of any key apparatus which should be used and describe how the student should ensure the volume is exactly 100 cm. \Wte your answer using a seris of numbered steps Vat 0 34 0F Gatle ba. lode? beaker. olirselee Th using..Ashiled,. oat. sos : HL Transher Ye... eletrr ba. Woden? relumetare Mask and..add... dbited.ssale.up. fe te, maak, FO Shake the roumebcc Ooch wx (ii) Suggest what the student should do to avoid the solution prepared in (a() exceed the 400 cm® volume. Ue a tides herd, Ark. 2 Biker Hoe mark otele okey af he mack woth te : foal. Wie adapter ppeti * \eees en vielen 1s clon t dy reach the mrnele Vv _23-2naprinilca}heisryPSIOPo 3 fester 20 cn oe ns tet eas 20? emir 80 The om stetnet 20" 6 ‘The students use col a The students use colorimety to cbserve how the colour of the eal minture changes 1 absorbance the gfe * The colorimeter is set up so that the greater th ater the concentration of [Cu(HiOh"(ag). + Tea ebsotance sto ze +The absorbance is recorded every 30 seconds The students plot the graph in Fig 1. rom the resus ofthe experiment 50°C 90°C Absorbance watt Time/s ty 7 Fig. 1.1 G Mr wileals, howe Fae 10°C using Fig. 1.1 and collision theory. yeti te Yat afl 50 sfepen.snelol Sabectls Phan. in the diferent intial rates at 60 °C and gore hea (Expl (a) _Predit the sign of AH forthe forward reaction in equitiblum 14. Give your reesorng wed toe we Identify the piece of apparatus that should be used to maintain the temperature of the ON Betmebal sede sob bh. za.2unapreimscacremistyPSOP uy4 (6) The students investigate how addlion of aqueous siver nitrate, AGNOs(aa), ana cequibriom position in equilibrium 1.4 The graph in Fig. 1.2 shows the changes inthe equltrium concentrations of [CUCM Cr eng [Cu(Hs0) after addition of the AGNOs(aq) ‘The AgNO;(aq) is added at time = Concentration () dently 2 controled variable nts investigation TPA coe . . ~“) (ii) Explain why the Cr concentration drops sharply at time = t ut, Papo been. gl. (iil) What is observed by the students at time = f. Blan. seat. wih tt abil fk _-2un2prelin\zcaCheristyPSIOP5 : (iv) Using Fig. 1.2, explain the changes in concentration of [oucn)*, OF ard foot ators =f Refer to equllsrium 1.4 in your answer. Aha ds, alle... pina Aptast ee thom dytle eax. tera. a. hep. oe ; Qentfalen ae cbthe, edudicte dn hen Sat 6 be eg Chere ete. oat ee 4 [ART he seperti. LA Toe / i (Total: 15) U a es a £ wnereat Lmnark, J Wool ae AND incase C(7 by AK6 ‘Ammonia gas is produced Becording to the reaction 2.1 shown, Feaction 24 SHx(9) + Nala) = 2NHsiQ) now as KA student calculated the Ky using the pate, 28 In reaction 2.1 mixture at eqallosins (9) The hydrogen gas “sed in reaction 2.4 is obtained when zine reacts with hydrochloric acid, Hei(aq), ‘The student uses the folowing ‘method Step 1 Accurately weigh 1.00 Q0f zine foi, 92.00 mol dm 2:20 mol den SteP 3 Add the zinc flo the So em of HCi(aq) in the fas, Step 2 Add 50 cm? conical fa 50 en HCi(aq) to @ conical flask, SY SRTREIAEG thot pps an ties etn seertn noc ‘ns essa the veune of yep ans ware ae uel du Sings 0 Auhl, /, fe v 1 Ht ai by Som? of 2.00 rrolden? fig. 24 6 (il) The student wears chemicaly resistant gloves. ‘Suggest why. Ne anced /cetresine . @ zs 24n2ProimC2Cbeniety PSF(2) The 4 and temperature, (nk) of eaction 2 areinadby mathematical relator shown (R= Gas constant in J mot" K"! and 4H is enthalpy change in J mot). ‘equation 2.1 (Table 2.1 shows the values of Kyat ferent temperatures for an equilibrium mixture in reaction 2.1, Complete Table 2.1 by adding the missing values of + ‘and In Kp. . Table 2.4 [Temperature Tak | 400 [500 [600 700 oo x10? | 5.06108 wo ee | 414 10% Taoo~ | 50x 10% | 18910" | 148% 10" | 1.14 *10% | 250%107 | 4.9 0xt97?[+67*10"? 145x007 p26 41077 jd “ | 195 log V| e.g We Yar, @ [ é Moe TE X® (ii) Temperature 400 K is obtained from the measured Femperatuire value of 127 in °C- v Determine the percentage error of the measured temperature of 127 °C: ‘Show your working Sat change 0-s¥2, 0-5 Le iy Tey TiO-7E7 7-127 lee agcizet crepes 000m (il) Plotagraphto show the relationship ofin Kp against +. using the axes provided on the ridin page 8. & Use 2 cross (x) to plot each data pont. Draw a tne of best it ® (iv) _ Use your graph to determine the gradient ofthe ine of best ft. State the coordinates of both points you used in your calculaTon, These must be selected from your line of best fit . 4 coordinates 1A: 2MO3 60... coordinates 2... BER 2, (00 W t-te reais et 2.26405 [-2¢~e-3 = Govvo gradient1h rod Af angreph 10x19 is 20x40 40% 10° tins as (¥) there's an anomalous point onthe graph, suggest one reason to explain the anomalous point. Assume there was no erin detaining Ky. Hel, ik aims.fa value for the (wi) Use the gradient determined in (b)(Wv) and equation 2.1 to calculate a val enthalpy change, in kJ mol”, for reaction 2.1, AH. Give your answer to three significant figures. $v), use the value 70000. I you were unable o determine a value forthe gradient in (BN), This isnot the comeet valu, a oy = - wagon! bowo= - + 1 fn Kp against. + (vil) Explain how AS could be calculated ees a gran of 7 sry 23-241a2Preliiscaicnemishy