PHYSICAL CHEMISTRY FORMULA REVISION BASIC CONCEPTS AVERAGE ATOMIC MASS = aiXi + a2X2 + asX3 +... SCE ee Tg eo Cen Cuts 100 eet no. of moles, n = —2ivenmass _ Ww Pre ie n= _Ne-of particles _ iM OTE ee Coe Ayre el had en Tr en? Ce Ce eid rye al Pen MEG a ee) rf oe euler COU OR eee oa eae is Lea) Lae) ea TES TCT) el ACR EAC . EAE ACLS) ny ry ai . Ce ee Ee eee TOE Ee maul odSalted el ak aA+bB>cC Cee Re Toe rs sees ATOMIC STRUCTURE PLANK’S QUANTUM THEORY Lit role ar rm PHOTO ELECTRIC EFFECT . KEmax B= + KEms : i eee a 1 v De BROGLIE’S HYPOTHESIS Ce Weald mvr = 2h en eae Pad n? a ee reo any a r4 1 bh Af ier OLE a ae ene or wel Or eee CEE Sa oaELM re Com Cae acted from nz to ni: [(n2 - mi)(n2 - ma + 1))/2 HEISENBERG'S UNCERTAINTY PRINCIPLE rw Nad zt QUANTUM MODEL Pe a ea EO ea radial nodes = n-1-1 Oo Cres URLs SEC CRSO Lg THERMODYNAMICS TERMODYNAMIC PROCESS OE a reversible PO eee Pea PC ee Ge) adiabatic > Q=0 ae RR AU rd AU=qtw oo eo ew Cielt Ne NS ie Cees Cr Ser CS - ws Cee Oye Ce ya Ce ea Coe an oars ey wal INVES eet Cee) vecon’s rati avs Ew NEw Ue ee ras Eee) CT) ICTs ae ed Perc ee vee monoatomic | sr/2 | sr/2 | 5/3 ed Ce) a eh BC Ca Peer? cla a WORK DONE dW = -P..dV for isobaric errs eee aed Cae ae Sa ea ae 2h) ane SA ea OY) Le SEL Us a eee Caer ECU ee Ae ACE) ee CO Wrey = 2.3nRT log(V2/Vi) Wrev = (P2V2 - Pai) NU 2.3nRT log(P,/P2) 7 iS %) Weer = -Pe(V2 - Vi) Wire = (P2V2 - PaVa) ra AgRELATION BETWEEN AH AND AU aXe eng => AU = qp- PAV => qp = AU + PAV aera A = OH = AU + An,RT Lb el Prev PE Ora ea a eA 8) ALO ee ALCL) 2nd LAW OF THERMODYNAMICS ASuniv 2 0 PUTTS 14a tg ea a eeu aCe Lt AG —> -ve —> spont. Xceed 0 —> equilibrium AG = AG° + 2.303 RT logQ at eq. AG = 0; Q=Keq AG? = -2.303 RT logK oqCHEMICAL EQUILIBRIUM ea ola te vale) | aA+bB~cC+dD Pea ae Prat Peete aLfee Ro La ig aa Do Celt [a NG 14 | ity = Sk." 2303r | TT DEGREE OF DISSOCIATION CR a os Py eee Fry ° eq: 3-2x 2-x 2x a: 2x/2 x/2 ora Kt > product stable LS eC LLG Bae on Per a1 ei circ Ce ei oe for endo: AH=+ve>Tt > KT PEA aC ee OC Lied Pea O Rect fn = no. of moles of product for unit PaerrriIONIC EQUILIBRIUM PORE oo er] POH = - log[OH-] Pee eae or) CUE) RNC aCe Bets 5 : a eae PH=>IPK,-logC] a (CBE L ad eas ec cag Coa CR Oe eT ea) ee CROC CD Lae Cm ey ol et Lae eos STU) ett ae aN WB &SB COR CL Bea hone bad [H*] = -C2 t [C2? + 4KaiCa OR ae WTB) Fy fy Rta lee aL ARES Na Ea VR Red ya ee) ea a) WA + WB Ky mus ae sCharat ar a acs Ca cm c pH=7+ Sau Ts] Peta Sau eet] Cee a Ges ee Lugs tet aod Erte hag Pre hig [eo | Pea es Pease CORAL Berar Pe ear) Trees)SOLUTIONS lS ae eae Ce a ae rer) aay = ao Le eas ee Sed Eee PONE a a dicts Dede Thad ORO Ce Tg => PL= PRxAt PEXs en CTO Mt Cl a ty Relative Lowering in VP Cre eeic eee e eaamic tae) Sat tld eka Ces eed eee ee reno cA EL Pre ee RL er eer Ca Le Co AT, = Kym Lake TeVAN'T HOFF FACTOR Pye ob: cp Cerra abnormal molar mass —_ calculated CP i=1+ (n-Na Peer CO Ra ec 7 BAUS) eee Oe et ere a ee AT, =iK,m Nea an Cs ELECTROCHEMISTRY ELECTROCHEMICAL CELL i Zn —> Zn** + 2e- Cu?* + 2e°—> Cu perry eer AG? = -nFE® PX eee NERNST EQUATION aA(aq) + bB(g) > cC(aq) + dD(s) at eq, Ecey = O and Q = Ka, Pe ed ee nod ee ny n Pe Pe SO rn roFARADAY’S LAW ae PLT Re WY) Wee Ear 2) BACHE Ee ae as CELL CHARACTERISTICS Penne ot ohm conductivity, K = a es 7 G* —> cell constant Pear a) ery ake Cea ai _ Ce Oa aa Lea iy VARIATION OF MOLAR CONDUCTIVITY Am = Am? - AVE KOHLRAUSCH LAW ea nN tay ce AxBy —> xAY* + yBX = K, ee oo) 5 _ a a “ Le oe Cree Oren aCHEMICAL KINETICS UTNE ee) eit Venlo) | ed) eter) SCRE) CCT) Pea CRE. CC IC] ir en nC LV Ren! eee ery Loi Le dO) m=an=b Seong BOCs Bre tra INTEGRATED RATE EQUATIONS PC ast a a ts Cre . 5 cJ roy rls coy ci c eee) pee ete a a te hes aaa aa les = a cee cy ry a oi o oyINTEGRATED RATE EQUATIONS Gas phase first order reactions A—>B+C or Cd a ARRHENIUS EQUATION ane ary i ee oe a Ee Se ee ink took esulssaabeep pocorn aha a ' Cr e_ 7 ron