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LAKSHYA JEE AIR (2025)

Chemical Kinetics DPP-04

SINGLE CORRECT QUESTIONS t 0.875

4. The value of for n th order reaction is
1. In the series reaction t 0.50

A ⎯⎯
1
→ B ⎯⎯
k 2
→ C ⎯⎯
k
3
→ D , if k1  k 2  k 3 then
k (1) 2(2n −2) (2) 2(2n −2)−1

the rate determing step of the reaction is: 8 n −1 − 1

(3) (4) None of these
2 n −1 − 1
(1) A → B
(2) C → D 5. Decomposition of HI(g) on Gold surface is zero
(3) B → C order reaction. Initially few moles of H 2 are

(4) Any step present in container then which of the following

graph is correct?

2. Which of the following expressions is correct for

zero order and first order respectively [where a is (1) (2)
initial concentration]?
1
(1) t1/2  a; t1/2 
a
(2) t1/2  a; t1/2  a 0
(3) (4)
(3) t1/2  a 0 ; t1/2  a
1
(4) t1/2  a; t1/2 
a2
6. The following data pertain to reaction between A
3. Column I Column II and B
1 S. No [A] [B] Rate
P. Zero order reaction 1. t1/2 
[A]0 molL−1 molL−1 molL−1sec −1
Q. First order reaction 2. t100% = [A]0 / k I 1  10 −2 2  10 −2 2  10 −4
R. Second order 3. Involves at least
II 2  10 −2 2  10 −2 4  10 −4
reactions two reactants
III 2  10 −2 4  10 −2 8  10 −4
S. Pseudo 4. [A] = [A]0 e − kt
Which of the following inference(s) can be drawn
Unimolecular
from the above data?
reaction
(1) Rate constant of the reaction is 10 −4
Code:
P Q R S (2) Rate law of the reaction is k[A][B]
(1) 2 1 4 2 (3) Rate of reaction increases four times on
(2) 2 4 1 3 doubling the concentration of both the
(3) 2 1 3 4 reactant, Select the correct answer.
(4) 3 2 1 4 (1) a, b and c (2) a and b
(3) b and c (4) c alone
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7. If ' a ' is the initial concentration of the reactant, 12. A gaseous compound A reacts by three
the half-life period of the reaction of n th
order is independent first order processes (as shown in
inversely proportional to : figure) with rate constant 2  10 −3 , 3  10 −3 and
(1) a n −1 (2) a n 1.93  10 −3 sec −1 for products B, C and D
1− n n +1
(3) a (4) a respectively. If initially pure A was taken in a
closed container with P = 8 atm , then the partial
8. When ethyl acetate was hydrolysed in presence of
pressure of B (in atm) after 100 sec from starting
0.1M HCl , the rate constant was found to be
the experiment.
5.4  10 −5 s −1 . But in presence of 0.1M H 2SO 4 the

rate constant was found to be 6.25  10 −5 s −1 . Thus

it may be concluded that:
(1) H 2SO 4 furnishes more H + than HCl
(2) H 2SO 4 furnishes less H + than HCl
(1) 0.288
(3) both have the same strength
(2) 0.577
(4) will depend on concentration of ethyl acetate
(3) 1.154
9. In the presence of an acid, the initial concentration (4) none of these
of cane sugar was reduced from 0.20 to 0.10 molar
in 5 hours and from 0.2 to 0.05 molar in 10 hours. 13. A compound A dissociates by two parallel first
The reaction is of: order paths at certain temperature
(1) Zero order (2) First order (
k1 min −1
A(g) ⎯⎯ ⎯ ⎯→ 2B(g)
) k 1 = 6.93  10 −3 min −1
(3) Second order (4) Third order
(
k 2 min −1
A(g) ⎯⎯ ⎯ ⎯→ C(g)
) k 2 = 6.93  10 −3 min −1
10. For a particular reaction with initial concentration The reaction is started with 1 mole of pure ‘A’ in
of the reactants as a 1 and a 2 , the half-life period 1 litre closed container with initial pressure 2 atm.
are t1 and t 2 respectively. The order of the What is the pressure (in atm) developed in
reaction (n) is given by: container after 50 minutes from start of
log ( t 2 / t1 ) log ( t1 / t 2 ) experiment?
(1) n = 1 + (2) n =
log ( a 2 / a1 ) log ( a 2 / a 1 ) (1) 1.25
log ( t1 / t 2 )
(2) 0.75
(3) n = 1 + (4) none of these
log ( a 2 / a1 )
(3) 1.50
(4) 2.50

14. For given hypothetical elementary parallel reaction,

11. A decomposes as .
k1 1
Where =
The rate of appearance of B, taking 2M k2 2
concentration of A, is equal to:
Initially only 2 moles of A are present. The total
(1) 2  10 −3 Ms −1 no. of moles of A, B and C at the end of 75%
(2) 4  10 −3 Ms −1 reaction are:
−3 −1
(3) 8  10 Ms (1) 2 (2) 3
(4) None of these (3) 4 (4) 3.5
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kf
15. The reaction cis-X trans-X is first order in both
kb

directions. At 25 C , the equilibrium constant is

0.10 and the rate constant k f = 3  10 −4 s −1 . In an
experiment starting with the pure cis-form, how
long would it take for half of the equilibrium
amount of the trans-isomer to be formed?
(1) 150 sec (2) 200 sec
(3) 240 sec (4) 210 sec
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Answer Key
1. (2) 9. (2)
2. (2) 10. (3)
3. (2) 11. (3)
4. (3) 12. (3)
5. (2) 13. (4)
6. (3) 14. (4)
7. (1) 15. (4)
8. (1)

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