molecules into the mineral structure. The wide range of conditions found in different Note: this normally results in expansion, parts of the globe at present reflects the variety some clays expand as much as 60%, of natural processes that shape the Earth’s and by admitting water hasten the surface. These processes are Weathering, processes of solution, oxidation, Erosion, and Deposition. reduction and hydrolysis. 4. Hydrolysis - Hydrogen ions in percolating water replace mineral ❖ WEATHERING cations: no oxidation-reduction occurs. 5. Leaching – The migration of ions Weathering is the breaking down and changing produced by the above processes. Note: of rocks as a result of exposure to the the mobility of ions depends upon their environment. After rocks are weathered, they ionic potential: Ca, Mg, Na, K are easily are often eroded. And that process is erosion, leached by moving water, Fe is more which is the transportation of sediments that resistant, Si is difficult to leach and Al is have been broken down by weathering almost immobile. processes. The final part of the process is 6. Cation Exchange - Absorption onto deposition, which is the dropping off of the surface of negatively charged clay of sediments that have been weathered and positively charged cations in solution, eroded. especially Ca, H, K, Mg 7. Oxidation - is the combination of Land areas are continually being reduced and oxygen with a mineral to form oxides their shape modified by weathering and erosion, and hydroxides or any other reaction in and the general term for this is denudation. which the oxidation number of the Rocks exposed to the atmosphere undergo oxidized elements is increased weathering from atmospheric agents such as - Is the formation of rusts that occurs rain and frost. whenever Iron is exposed to oxygen. 8. Carbonation – is responsible for the formation of limestone caves. It occurs Main Types of Weathering: when water flows through the ground, it reacts with the different materials in the Chemical Weathering (decomposition) soil to create a very mild acid or - is the break-down of minerals into new carbonic acid. Carbonic acid is strong compounds by the action of chemical enough that if it encounters certain agents; acids in the air, in rain and in minerals or rocks it will eat away or river water, although they act slowly, dissolve that minerals or rocks. produce noticeable effects especially in soluble rocks. 1. Solution - is the dissociation of minerals into ions, greatly aided by the Chemical weathering is seen most readily in its presence of CO2 in the soil profile, solvent action on some rocks, notably which forms carbonic acid (H2CO3) with limestones and those rocks containing the percolating rainwater minerals Halite (NaCl), Anhydrite (CaSO4) and 2. Reduction - The release of oxygen Gypsum (CaSO4 2H2O). from a mineral to its surrounding In limestones the process depends on the environment: ions leave the mineral presence of feeble acids, derived from gases structure as the oxidation number of the such as CO2 and SO2 which enter into solution reduced elements is decreased. in percolating rainwater. The calcium carbonate of the limestone is slowly dissolved by rainwater weathering on these more resistant rocks can be containing carbon dioxide, and is held in solution clearly seen where deep weathering has as calcium bicarbonate. occurred and a thick cover of rotted material lies above the irregular surface which bounds the Underground caverns are opened out by solid rocks beneath the weathered zone bounds solution aided by the fall of loosened blocks of the solid rocks beneath the weathered zone. limestone from the cavern roof. Large systems of caves and solution channels are found in the French Pyrenees, the limestone plateau of FORMATION OF GRANITE TORS Kentucky, U.S.A., the Transvaal in S. Africa and elsewhere, most notably in S.E. Asia: China, The formation of granite tors is related to the Vietnam and New Guinea. The Karst area of frequency of jointing in the rocks; the tors are Istria in Yugoslavia and the Dalmatian coast of upstanding masses of solid granite, preserved the Adriatic has given the name karst where the spacing of joints is wider, in contrast topography to landforms which are to the adjacent rock; the latter has been more characteristic of chemically weathered easily and therefore more extensively denuded limestone; karst topography is developed most owing to the presence in it of closelyspaced spectacularly and most extensively in southern joints, which have resulted in more rapid China, where one-seventh of the country, i.e. weathering above the water-table (the broken 500000 km2 is karstic. line in the figure). Water circulating underground helps to extend In dry climates chemical weathering is channels and caverns by solution, particularly in superficial and much retarded by the lack of limestone formations; streams which once water, producing thin zones of weathered rock. flowed on the surface disappear down swallow In very dry climates mechanical processes are holes and open joints, and continue their the dominant weathering agents. journey by flowing along bedding planes and joints below ground. As water charged with calcium bicarbonate trickles over the walls and Mechanical Weathering (disintegration) drips from the roofs of caves, part of it - breaks down rocks into small particles evaporates and calcium carbonate is slowly re- by the action of temperature, by impact deposited as loss of carbon dioxide occurs. In from raindrops, and by abrasion from this way masses of stalactite, hanging from the mineral particles carried in the wind. roof or coating the walls of a cave, are formed, sometimes making slender columns where they 1. Mechanical Unloading have become united with stalagmites which - refers to the process of relieving or have been slowly built up from the floor of the reducing the pressure on rocks or cave, onto which water has dripped over a long geological structures. It can play a period of time. Sheet stalactite coats the walls of role in mechanical weathering by many caverns and may be coloured by traces of causing rocks to expand or fracture iron and lead compounds. due to the release of internal pressure. - When rocks are buried under layers Chemical weathering is not restricted to easily of sediment or overlying rocks, they soluble rocks but attacks all rock types. The experience immense pressure from most easily weathered are limestones; of the weight above. This pressure, greater resistance are sandstones and shales: known as lithostatic pressure, igneous rocks (excluding certain volcanic rocks can compact and consolidate the that weather rapidly) and quartzites are the rocks, making them more resistant most resistant. The effect of chemical to weathering. However, when the overlying pressure is removed, through their growth and chemical either due to erosion or other activities. geological processes, the rocks experience a decrease in pressure, 3. Wetting and Drying leading to mechanical unloading. - Wetting and drying contribute to the - The release of pressure can trigger a mechanical breakdown of rocks variety of mechanical weathering through the expansion and processes, including: contraction of minerals, the • Exfoliation: As the confining development of cracks, and the pressure is reduced, rocks may subsequent fragmentation of the expand and crack parallel to the rock. It is one of the several surface, resulting in the peeling or mechanisms that collectively shape flaking of outer layers. the Earth's surface through • Jointing: Mechanical unloading can mechanical weathering. cause rocks to fracture along pre- existing joints or create new When rocks or minerals absorb water, fractures, increasing the they can undergo various changes. susceptibility to further weathering. • Disintegration: In some cases, • Expansion: Water molecules can rocks subjected to mechanical enter the porous structure of rocks, unloading can disintegrate into causing them to swell and expand. smaller blocks or fragments due to This expansion can exert pressure the release of pressure and the on the surrounding mineral grains or subsequent expansion of minerals. rock matrix. However, it is during the drying phase that significant 2. Mechanical Unloading mechanical weathering occurs: - The impact on rocks and soil and • Shrinkage: As the water evaporates, abrasion by sand and weak rocks. the rocks or minerals shrink, This may further categorize as: potentially resulting in the formation of cracks and fractures. The • Abrasion involves the physical differential shrinkage between wearing down of rocks by the different minerals within a rock can frictional forces of wind, water, or also lead to internal stress and ice. These forces can exert further weakening. pressure on rocks, causing them to • Fragmentation: The repeated break apart or erode over time. For wetting and drying cycles can cause example, when water flows over the development and propagation of rocks, it can carry sediments that cracks, eventually resulting in the scrape against the rock's surface, physical fragmentation of rocks into leading to its gradual erosion. smaller pieces.
* Biological activity refers to the actions 4. Crystallization
of plants, animals, and microorganisms - Also known as salt crystal growth or that can contribute to the mechanical salt weathering, is a process of weathering of rocks. Burrowing animals mechanical weathering that occurs can physically disrupt rock structures, when dissolved salts in water plant roots can grow into cracks and crystallize within the pores and exert pressure, and microorganisms can cracks of rocks. It is particularly contribute to the breakdown of rocks significant in arid or semi-arid regions, coastal areas, or areas with Additionally, in volcanic environments, the saline groundwater. expansion of gases within magma or volcanic ash can generate significant pressure. This Here's how the process of crystallization pressure can fracture rocks, leading to their contributes to mechanical weathering: mechanical breakdown. • Water Infiltration: Water containing While "pneumatic loading" may not be a dissolved salts infiltrates into porous commonly used term in the field of geology, rocks or enters cracks and crevices. these examples highlight how air or gas • Evaporation: As the water evaporates pressure, in certain contexts, can contribute to due to high temperatures or low mechanical weathering processes such as humidity, the concentration of abrasion or fracturing. dissolved salts increases within the remaining water. • Salt Crystal Formation: As the Biological weathering (organic) concentration of dissolved salts reaches - refers to processes mediated by saturation, the salts begin to microorganisms, which can contribute to precipitate and form crystals within the the breakdown of rocks or can enhance pores and fractures of the rock. surface stabilization • Crystal Growth: As the crystals continue to grow, they exert pressure on the surrounding rock material. This pressure can be significant, especially if Weathering effects which are small in the crystals grow within confined themselves but noticeable in the aggregate can spaces or in areas where they have be attributed to plants and animals. Plants retain room for expansion. moisture and any rock surface on which they • Mechanical Disintegration: The growth grow is kept damp, thus promoting the solvent of salt crystals exerts pressure on the action of the water. rock, causing it to weaken and The chemical decay of rock is also aided by the eventually disintegrate. The expansion formation of vegetable humus, organic products of the crystals can widen existing derived from plants, and this is helped by the cracks or generate new fractures, action of bacteria and fungi. Organic acids are leading to the fragmentation and thereby added to percolating rain-water and breakdown of the rock. increase its solvent power. The mechanical break-up of rocks is hastened when the roots of plants penetrate into cracks and wedge apart 5. Pneumatic Loading the walls of the crack. - The impact of air or gas pressure on rocks. - For example, in regions with strong ❖ EROSION AND DEPOSITION winds, the force of moving air carrying sediment particles can cause abrasion and wear down rocks over time. Wind-driven sand Erosion occurs when pieces of rocks and soil, particles can act as abrasive agents, called sediments, are carried from one place to striking against exposed rock another surfaces and contributing to their Rivers, wind, moving ice and water waves are erosion and fragmentation. capable of loosening, dislodging and carrying particles of soil, sediment and larger pieces of rock. They are therefore described as the agents rock surface is easily recognized, and if of erosion. observed near but above an existing stream it marks a former course at a higher level
Deposition is the process of sediments, soils,
and minerals being dropped, or deposited, in a Valleys new place. Valleys A drainage system is initiated when, for Grains of sand are blown across the desert by example, a new land surface is formed by uplift strong winds, and they eventually land in a new of the sea floor. Streams begin to flow over it location. Over time, the sand builds up into a and excavate valleys, their courses mainly dune. directed by the general slope of the surface but also controlled by any irregularities which it may Sediments are carried by a river downstream. possess. But when the river enters the lake or ocean, the water slows down. In many instances present day lowland valleys have been shaped by the streams that occupy As the water slows down, the sediments settle them; these were most active during the out of the water. interglacial periods when their discharge was Fast-moving water is easily able to carry considerably greater than it is at present. Valleys sediments and pushed them downstream but in mountains and glaciated areas have been once it slows down, all those sediments start to modified by other agencies, such as the action settle out to the bottom of the lake of the ocean of avalanches, landslides and moving ice. In and over time the layers build up as sediments course of time a valley becomes deepened and are deposited. widened, and the river is extended by tributaries.
The area drained by a river and its tributaries is
The Work of Rivers called a catchment, or river basin. Stages of youth, maturity, and old age may be - the work of erosion performed by rivers distinguished in the history of a river, and results in the widening and deepening of their topographical forms characteristic of these valleys. The rate of erosion is greatly enhanced stages can be recognized in modern landscapes. in times of flood. Rivers are also agents of Thus there is the steep-sided valley of the transport, and carry much material in youthful stream; the broader valley and more suspension, to re-deposit part of it along their deeply dissected landscape of the mature river course further downstream, or in lakes, or in system; and the subdued topography of the times of flood as levees and over the flood plain; catchment of a river in old age. ultimately most of the eroded material reaches the sea.
Some matter is carried in solution and
contributes to the salinity of the oceans. The energy which is imparted to sediment moved by a stream, the finer particles in suspension and the coarser (including boulders) rolled along the bed during floods, performs work by abrading the channel of the river. Hollows known as pot- holes are often worn in the rock of a riverbed by the grinding action of pebbles which are swirled round by eddying water. Such a water-worn