Sri ChaitanyaIIT Academy, India 08-07-2023_Jr.Super60_NUCLEUS BT_Jee-Main_WTM-04_Q.P. Sri ChaitanyaIIT Academy, India 08-07-2023_Jr.Super60_NUCLEUS BT_Jee-Main_WTM-04_Q.P.

CHEMISTRY Max Marks: 100 1) T3  T2  T1

(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be 2) T1  T2  T3
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
3) T1  T2  T3
31. Which is correct statement
1) The value of ionic product of water decreases with increase in temperature 4) Nothing could be predicted about temperature through given information

2) In pH scale , lower the pH value, weaker is the acid 36. For pure water at 25o C and 50o C the correct statement is
3) The ionization of acetic acid increase in presence of sodium acetate 1) pH 25o C  pH 50o C 2) pH 25o C  pH 50o C
4) The conjugate acid of hydride ion is H 2 3) pOH 50o C  pOH 25o C 4) pOH 25o C  pOH 50o C
32. In the equilibrium NH 4 HS( s )  NH 3( g )  H 2 S( g ) the forward reaction can be favoured by
37. The Kw of 0.01 M H 2 SO4 solution at 25o C is
1) Adding some more NH 4 HS
2) Adding some more NH 3 1) 104 2) 4 104 3) 4 1014 4) 1014
38. The pH of a weak monoprotic acid HA of 0.01N conc. is 4. The solution is diluted 100
3) Removing some NH 3 from the reaction mixture
times. Find the pH of the diluted solution.
4) Adding some more H 2 S
33. The correct Lewis acid order for boron halides is: 1) 3.5 2) 4.5 3) 5.0 4) 5.5
1) BI 3  BBr3  BCl3  BF3 2) BBr3  BCl3  BI 3  BF3 39. For the physical equilibrium
3) BF3  BCl3  BBr3  BI 3  4) BCl3  BF3  BBr3  BI 3  H 2O( s )  H 2O(l )
34. In a reaction A2 ( g )  4 B2 ( g )  2 AB4 ( g ); H  0 , the formation of AB4  g  will be
which of the following is true
favoured at
1) Low temperature and high pressure 2) High temperatue and low pressure 1) The pressure changes do not affect the equilibrium
3) Low temperature and low pressure 4) High temperature and high pressure 2) More of ice melts if pressure on the system is increased.
1 3) More of liquid freezes if pressure on the system is increased
35. The preparation of SO3 ( g ) by reaction SO2 ( g )  O2 ( g )  SO3 ( g ) is an exothermic
2
4) At low pressure, the nature of equilibrium changes to forward direction
reaction. If the preparation follows the following temperature-pressure relationship for
its % yield, then for temperatures T1 , T2 and T3 . The correct option is 40. Which of the following is the set of amphiprotic species?
1) H 2 PO2 , HPO42 , HCO3 2) H 2O , HPO32 , H 2 PO2

3) H 2 PO4 , H 2 PO3 , H 2O 4) NH 4 , H 3O  , HPO4

41. The following has no conjugate base
1) H 2 PO4 2) H 2 PO2 3) H 2 PO3 4) CH 3COOH

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 Sri ChaitanyaIIT Academy, India 08-07-2023_Jr.Super60_NUCLEUS BT_Jee-Main_WTM-04_Q.P. Sri ChaitanyaIIT Academy, India 08-07-2023_Jr.Super60_NUCLEUS BT_Jee-Main_WTM-04_Q.P.
42. Which of the following is neither a Lewis acid nor a Lewis base 50. At certain temperature H  ion concentration of pure water is 5  107 . The ionic product
1) HSO4 2) ZnCl2 3) NH 4 4) CH 3 of water at this temperature is ………. moles 2lit 2
43. Liquid NH 3 dissociates to a slight extent. At certain temperature, its self dissociation 1) 11014 2) 2.5  1013 3) 5 1014 4) 2.5  1010
constant K SDC ( NH 3 ) is 1030 . The No. of NH 4 ions present in pure liquid of 100CC (NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. If more than 5 questions attempted, First 5
Attempted questions will be considered. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest
volume is ( N A  6  1023 ) Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and if answer is from 10.5 and less than 11 round off is
11). Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

1) 1015 2) 6 108 3) 6 107 4) 6 106 51. An acid with molecular formula C7 H 6O3 forms three types of sodium salts. i.e.,

44.  
Calculate the ratio of [ HCOO ] &[ F ] in a mixture of 0.2 M HCOOH ( K a  2  10 ) & 4 C7 H 5O3 Na , C7 H 4O3 Na2 and C7 H 3O3 Na3 . The basicity of the acid is

0.1M HF ( K a  6.6  104 ) 52. At infinite dilution, the percentage ionisation for both strong and weak electrolytes is
53. The pH of solution obtained by mixing 500 ml of 0.15 M H 2 SO4 with 500 ml of 0.1 M
1) 1:6.6 2) 1:3.3 3) 2:3.3 4) 3.3:2
45. Identify the strongest base among the following if the K a values given are NaOH is
54. The pH value of 104 M NaOH
HSO4  1.2  102 ; H 2 PO4  6.3  108 ; HCO3  4.7  1011
55. The pH of a 0.1 M aqueous solution of a weak acid (HA) is 3. What is the percentage of
1) CO32 2) H 2 SO4 3) SO42 4) HPO42
degree of dissociation?
46. 4 gms of NaOH and 4.9 gms of H 2 SO4 are dissolved in water and made upto 250ml. The
56. What will be the pH of a 0.01 M H 3 PO4 solution having [ PO43 ]  105 M
pH of the resulting solution is
[ K a1  104 , K a2  106 , K a 3  108 ]
1) 7.0 2) 1.0 3) 2.0 4) 12.0
47. Find the [ S 2 ] in a saturated solution of 0.1 M H 2 S if the pH was adjusted to 2 by adding 57. When 1 ml of 0.1M HCl is added to 1 litre of water the pH of water becomes ________
58. The acid dissociation constants of H 2 S and HS  are 107 and 1013 respectively. The pH
HCl . product of K a1 & K a2 of H 2 S is 1.2  1021
of 0.1M H 2 S aqueous solution will be _______
1) 1.2 1010 2) 6 1018 3) 6 1012 4) 1.2 1018
59. The pH of 0.01 M aqueous solution of a weak acid if HA is 4. The pKa value of
48. K w value of water is 1013 M 2 at certain temperature . The sum of pH & pOH for a
the acid at 250 C is
neutral aqueous solution at this temperature is
60. The pH of a solution 4.3. The [OH  ] of the solution is 2 10 x . The value of x is
1) 7.0 2) 13.30 3) 14 4) 13
49. The degree of ionisation does not depends on? ___ at 250 C . (Antilog of 0.7 is 5)

1) Temperature 2) Current 3) Nature of solvent 4) Concentration

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