HAZOP Worksheets

Project Title: Production of Nitric Acid

Group No.: Group 3
Date: 18/Mar/2024
Drawing No. and P-0006 (SHEET 14 OF 18, Rev.0) P-0006 (SHEET 15 OF 18, Rev.0) P-0006 (SHEET 16 OF 18, Rev.0)
Node No.: 1 Person-in-charged: Tan Chun Kiat Team Shummmmmm
Node Upstream Pump P-500 to downstream Heat Exchanger E-500 and Oxido-Adsorption Column R-500 outlet.
Design Intent: To promote the adsorption of nitrogen dioxide gas with water and oxidation of nitric oxid in formation of nitric acid. Water is pumped and heated to the desired pressure and temperature in the pump and heat exchanger .
Design Design Pressure: 1497 kPa (Pump P-500), 1497 kPa (Heat Exchanger E-500), 1430 kPa (Oxido-Adsorption Column R-500); Design Temperature: 30℃ (Pump P-500), 72℃ (Heat Exchanger E-500), 72℃ (Oxido-Adsorption Column R-500)
Operating Operating Pressure: 101.3 kPa (Inlet) / 1050 kPa (Outlet) (Pump P-500), 1050 kPa (Heat Exchanger E-500), 1000 kPa (Oxido-Adsorption Column R-500); Operating Temperature: 25℃ (Pump P-500), 25℃ (Inlet)/ 60℃(Outlet) (Heat Exchanger E-500), 60℃
condition: (Oxido-Adsorption Column R-500)
Guideword/ Party
Item Possible Causes Consequences Safeguards Recommendations
Deviation Responsible
1 1 1 No flow 1. SDV-501 malfunction closed 1.1. No Flow to P-500, leading to break 1.1.1. Low-Low Flow Alarm and Trip System (FZALL501) is provided. 1. Consider to remove V-410 drain valve. Consultant
down of P-500 due to pump minimum 1.1.2. SDV-502 is provided. 2. Investigate the effect of more tail gas in the tail gas
flow. 1.1.3. PM-503 is provided. treatment and provide adequate protection if required.
1.2. No Flow of water leading to 1.1.4. I-503 is provided. 3. Add Reverse Valve at R-500 water inlet stream.
potential high temperature in E-500. 1.1.5. Low Flow Controller Alarm FICAL-503 is provided.
1.3. Loss of production due to no flow of 1.2.1. High-High Temperature Alarm and Trip System (TZAHH503) is
water flowing into R-500. provided.
1.4. No Flow of water to R-500, leading to 1.2.2. SDV-503 is provided.
potential high pressure in R-500. 1.2.3. V-408 drain valve is provided.
1.2.4. Low Temperature Controller (TICL-504) is provided.
1.3.1. Low-Low Level Alarm and Trip System (LZALL506) is provided.
1.3.2. SDV-508 is provided.
1.3.3. Low Level Controller (LICL-506) is provided.
1.4.1. High-high Pressure Alarm and Trip System (PZAHH504) is provided.
1.4.2. SDV-504 is provided.
1.4.3. PSV-500 is provided.
1.4.4. V-432 vent valve is provided.
1.4.5. High Pressure Controller (PICH-505) is provided.

1 1 2 2. FV-501 malfunction closed Refer to item no. 1.1.1. Refer to item no. 1.1.1. Refer to recommendation No Flow above (1,2,3) Consultant
1 1 3 3. M-503 malfunction Refer to item no flow above (1.2) Refer to item no flow above (1.2.1) 4. Consider to add Low-Low Flow Alarm and Trip System Consultant
Refer to item no flow above (1.3) Refer to item no flow above (1.2.2) (FZALL502) at P-500 pump outlet to shutdown SDV-501
Refer to item no flow above (1.4) Refer to item no flow above (1.2.3) and SDV-502.
Refer to item no flow above (1.2.4) 5. Install backup pump.
Refer to item no flow above (1.3.1)
Refer to item no flow above (1.3.2)
Refer to item no flow above (1.3.3)
Refer to item no flow above (1.4.1)
Refer to item no flow above (1.4.2)
Refer to item no flow above (1.4.3)
Refer to item no flow above (1.4.4)
Refer to item no flow above (1.4.5)
1 1 4 4. V-525 malfunction closed Refer to item no. 1.1.3. Refer to item no. 1.1.3. 6. Consider to place V-525 check valve after V-404 drain Consultant
valve.
7. Consider to add High-high Flow Alarm and Trip
System (FZAHH501) at P-500 inlet to shut down SDV-501
and SDV-502.
1 1 5 5. SDV-502 malfunction closed Refer to item no. 1.1.3. Refer to item no. 1.1.3. Refer to recommendation No Flow above (1,2,3) Consultant
1 1 6 6. SDV-503 malfunction closed 6.1. Potential loss of heating leading to 6.2.1. Low-Low Temperature Alarm and Trip System (TZALL505) is provided. 8. Consider to add Low-Low Temperature Alarm and Consultant
low temperature of E-500. 6.2.2. SDV-505 is provided. Trip System (TZALL503) at E-500 to alert operator.
6.2. Less temperature water inlet of R- 6.2.3. V-422 drain valve is provided.
500, leading to decrease reaction rate. 6.2.4. Low Temperature Controller Alarm (TICAL-507) is provided.

1 1 7 7. SDV-504 malfunction closed 7.1. No Flow of gas leading to potential
low temperature in R-500.
7.2. Loss of production due to no flow of
process gas into R-500.
7.3. No Flow of process gas to R-500,
leading to potential low pressure in R-
500.
7.1.1. Low Temperature Controller Alarm (TICAL-507) is provided. 9. Consider changing philosophy of Low-Low Pressure Consultant
Refer to item no flow above (6.2.1) Alarm and Trip System (PZALL504) to also shut down
Refer to item no flow above (6.2.2) SDV-506 which prevents flooding of R-500.
Refer to item no flow above (6.2.3)
7.3.1. Low-low Pressure Alarm and Trip System (PZALL504) is provided.
7.3.2. SDV-507 is provided.
7.3.3. Low Pressure Controller (PICL-505) is provided.

1 1 8 8. V-526 malfunction closed Refer to item no flow above (1.1.7) Refer to item no flow above (1.1.7) N/A Consultant

1 1 9 9. SDV-505 malfunction closed 9.1. No flow of coolant leads to potential
loss of cooling, possible thermal runaway
and leading to decrease of reaction rate.
9.2. More vapour is generated due to
high temperature, leading to high
pressure in R-500.
1 1 10 10. SDV-506 malfunction closed 10.1. No Flow of water leading to
potential low temperature in R-500.
Refer to item no flow above (1.3)
Refer to item no flow above (1.4)
1 2 1 More Flow 1. FV-501 malfunction stuck opened 1.1. More water flow to P-500, leading to
break down of P-500 due to pump
maximum flow.
1.2. More water flow leading to potential
low temperature in E-500.
1.3. More water flow to R-500, lead to
potential flooding and damage of tray in
R-500.
1.4. More water flow to R-500, leading to
potential low pressure in R-500.
1.5. More water flow of low temperature
water to R-500, leading to low
temperature in R-500.
1 2 2 2. FV-502 malfunction stuck opened Refer to item more flow above (1.1)
HAZOP Worksheets
9.1.1. High-High Temperature Alarm and Trip System (TZAHH505) is Refer to recommendation No Flow above (2) Consultant
provided.
9.1.2. SDV-504 is provided.
9.1.3. SDV-506 is provided.
9.1.4. V-420 Drain Valve is provided.
9.1.5. High Temperature Controller Alarm (TICAH-507) is provided.
Refer to item no flow above (1.4.1)
Refer to item no flow above (1.4.2)
Refer to item no flow above (1.4.3)
Refer to item no flow above (1.4.4)
Refer to item no flow above (1.4.5)
Refer to item no flow above (6.2.1) Refer to recommendation No Flow above (2) Consultant
Refer to item no flow above (6.2.2)
Refer to item no flow above (6.2.3)
Refer to item no flow above (6.2.4)
Refer to item no flow above (1.3.1)
Refer to item no flow above (1.3.2)
Refer to item no flow above (1.3.3)
Refer to item no flow above (1.4.1)
Refer to item no flow above (1.4.2)
Refer to item no flow above (1.4.3)
Refer to item no flow above (1.4.4)
Refer to item no flow above (1.4.5)
1.1.1. High-High Flow Alarm and Trip System (FZAHH502) is provided. Refer to No Flow above (7) Consultant
1.1.2. SDV-501 is provided. Refer to No Flow above (8)
1.1.3. SDV-502 is provided. 10. Consider to add Alarm at Flow Indicator Controller
1.1.4. V-398 Drain Valve is provided. (FIC-501) to alert operator.
1.1.5. PM-503 is provided.
1.1.6. I-503 is provided.
1.1.7. High Flow Controller (FICH-502) is provided.
1.1.8. High Flow Controller Alarm (FICAH-503) is provided.
1.2.1. V-407 Drain Valve is provided.
1.2.2. Low Temperature Controller (TICL-504) is provided.
1.3.1. High-High Level Alarm and Trip System (LZAHH506) is provided.
1.3.2. SDV-506 is provided.
1.3.3. V-420 Drain Valve is provided.
1.3.4. High Level Controller (LICH-506) is provided.
1.4.1. Low-Low Pressure Alarm and Trip System (PZALL504) is provided.
1.4.2. SDV-507 is provided.
1.4.3. Low Pressure Controller (PICL-505) is provided.
1.5.1. Low-Low Temperatur Alarm and Trip System (TZALL505) is provided.
1.5.2. SDV-505 is provided.
1.5.3. V-422 Drain Valve is provided.
1.5.4. Low Temperature Controller Alarm (TICAL-507) is provided.
Refer to item more flow above (1.1.1) N/A Consultant
Refer to item more flow above (1.1.2)
Refer to item more flow above (1.1.3)
Refer to item more flow above (1.1.4)
Refer to item more flow above (1.1.5)
Refer to item more flow above (1.1.6)
Refer to item more flow above (1.1.7)
Refer to item more flow above (1.1.8)

1 2 3 3. TV-504 malfunction stuck opened 3.1 More Flow of utility stream from E-
500, leading to potential high
temperature of E-500.
3.2 More Flow of utility stream from E-
500, leading to potential high
temperature of R-500 due to high
temperature water stream.
3.3 More vapour is generated due to high
temperature, leading to high pressure in
R-500.
1 2 4 4. PV-505 malfunction stuck opened 4.1 More flow from R-500, leading to
potential low pressure in R-500.
4.2 Low Pressure of R-500, leading to
potential reverse flow of bottom liquid
outlet stream.
4.3 Reverse Flow of bottom liquid outlet
stream, leading to potential high level in
R-500.
1 2 5 5. LV-506 malfunction stuck opened 5.1 More flow from R-500, leading to
potential low level in R-500.
5.2 Low level in R-500, leading to
potential high pressure in R-500.
1 2 6 6. TV-507 malfunction stuck opened 6.1 More Flow of utility stream from R-
500, leading to potential low
temperature of R-500.
6.2 Low temperature of R-500, leading to
decrease of reaction rate.
1 3 1 Less Flow 1. FV-501 malfunction partially closed 1.1. Less Flow to P-500, leading to break
down of P-500 due to pump minimum
flow.
1.2. Less Flow of water leading to
potential high temperature in E-500.
1.3. Loss of production due to less flow
of water flowing into R-500.
1.4. Less Flow to R-500, leading to
potential high pressure in R-500.
1.5. Less water flow to R-500, leading to
high temperature in R-500.
HAZOP Worksheets
3.1.1. High-High Temperature Alarm and Trip System (TZAHH503) is 11. Consider to remove V-424 vent valve. Consultant
provided. Refer to recommendation No Flow above (2)
3.1.2. SDV-503 is provided.
3.1.3. V-408 drain valve is provided.
3.2.1. High-High Temperature Alarm and Trip System (TZAHH505) is
provided.
3.2.2. SDV-504 is provided.
3.2.3. SDV-506 is provided.
3.2.4. V-420 drain valve is provided.
3.2.5. High Temperature Controller Alarm (TICAH-507) is provided.
3.3.1. High-High Pressure Alarm and Trip System (PZAHH504) is provided.
3.3.2. SDV-504 is provided.
3.3.3. PSV-500 is provided.
3.3.4. V-432 vent valve is provided.
3.3.5. High Pressure Controller (PICH-505) is provided.
Refer to item more flow above (1.4.1) 12. Consider to install check valve at the bottom liquid Consultant
Refer to item more flow above (1.4.2) outlet of R-500 to prevent reverse flow before V-425
Refer to item more flow above (1.4.3) Drain Valve.
4.3.1. V-425 drain valve is provided.
Refer to item more flow above (1.3.1)
Refer to item more flow above (1.3.2)
Refer to item more flow above (1.3.3)
Refer to item more flow above (1.3.4)
5.1.1. Low-Low Level Alarm and Trip System (LZALL506) is provided. N/A Consultant
5.1.2. SDV-508 is provided.
5.1.3. High Flow Indicator and Alarm (FIAH-508) is provided.
5.1.4. Low Level Controller (LICL-506) is provided.
Refer to item more flow above (3.3.1)
Refer to item more flow above (3.3.2)
Refer to item more flow above (3.3.3)
Refer to item more flow above (3.3.4)
Refer to item more flow above (3.3.5)
Refer to item more flow above (1.5.1) N/A Consultant
Refer to item more flow above (1.5.2)
Refer to item more flow above (1.5.3)
Refer to item more flow above (1.5.4)
1.1.1. Low-Low Flow Alarm and Trip System (FZALL501) is provided. Refer to recommendations No Flow above (1, 2,3). Consultant
1.1.2. SDV-502 is provided.
1.1.3. PM-503 is provided.
1.1.4. I-503 is provided.
1.1.5. Low Flow Controller (FICL-502) is provided.
1.1.6. Low Flow Controller Alarm (FICAL-503) is provided.
1.2.1. High-High Temperature Alarm and Trip System (TZAHH503) is
provided.
1.2.2. SDV-503 is provided.
1.2.3. V-408 drain valve is provided.
1.2.4. High Temperature Controller (TICH-504) is provided.
1.3.1. Low-Low Level Alarm and Trip System (LZALL506) is provided.
1.3.2. SDV-508 is provided.
1.3.3. Low Level Controller (LICL-506) is provided.
1.4.1. High-high Pressure Alarm and Trip System (PZAHH504) is provided.
1.4.2. PSV-500 is provided.
1.4.3. V-432 vent valve is provided.
1.4.4. SDV-504 is provided.
1.4.5. High Pressure Controller (PICH-505) is provided.
1.5.1. High-High Temperature Alarm and Trip System (TZAHH505) is
provided.
1.5.2. SDV-504 is provided.
1.5.3. SDV-506 is provided.
1.5.4. V-420 Drain Valve is provided.
1.5.5. High Temperature Controller Alarm (TICAH-507) is provided.

1 3 2 2. FV-502 malfunction partially closed Refer to item less flow above (1.1)
1 3 3 3. M-503 malfunction Refer to item less flow above (1.2)
Refer to item less flow above (1.3)
Refer to item less flow above (1.4)
Refer to item less flow above (1.5)
1 3 4 4. TV-504 malfunction partially closed 4.1 Less Flow of utility stream from E-
500, leading to potential low
temperature of E-500.
4.2 Less Flow of hot water utility stream
from E-500, leading to potential low
temperature of R-500.
1 3 5 5. PV-505 malfunction partially closed 5.1 Less top outlet flow from R-500,
leading to potential high pressure in R-
500.
1 3 6 6. LV-506 malfunction partially closed 6.1 Less Flow from R-500, leading to
potential high level in R-500.
6.2 High level in R-500, leading to
potential low pressure in R-500.
1 3 7 7. TV-507 malfunction partially closed 7.1 Less Flow of utility stream from R-
500, leading to potential high
temperature of R-500.
1 4 1 Reverse Flow 1. V-525 malfunction closed 1.1. More water accumulation at outlet
of P-500 will flow back through the
recycle stream leading to damaged
pump.
1 4 2 2. TV-504 malfunction closed 2.1. Reverse Flow to E-500, leading to
potential low temperature of E-500.
2.2. No Flow of Hot water utility stream
from E-500, leading to potential low
temperature of R-500.
1 4 3 3. SDV-506 malfunction closed 3.1. Reverse Flow to E-500, leading to
potential high temperature in tube side
of E-500.
HAZOP Worksheets
Refer to item less flow above (1.1.1) N/A Consultant
Refer to item less flow above (1.1.2)
Refer to item less flow above (1.1.3)
Refer to item less flow above (1.1.4)
Refer to item less flow above (1.1.5)
Refer to item less flow above (1.1.6)
Refer to item less flow above (1.2.1) Refer to recommendations No Flow above (4, 5). Consultant
Refer to item less flow above (1.2.2)
Refer to item less flow above (1.2.3)
Refer to item less flow above (1.2.4)
Refer to item less flow above (1.3.1)
Refer to item less flow above (1.3.2)
Refer to item less flow above (1.3.3)
Refer to item less flow above (1.4.1)
Refer to item less flow above (1.4.2)
Refer to item less flow above (1.4.3)
Refer to item less flow above (1.4.4)
Refer to item less flow above (1.4.5)
Refer to item less flow above (1.5.1)
Refer to item less flow above (1.5.2)
Refer to item less flow above (1.5.3)
Refer to item less flow above (1.5.4)
Refer to item less flow above (1.5.5)
4.2.1. Low-Low Temperature Alarm and Trip System (TZALL505) is provided. Refer to recommendation No Flow above (8). Consultant
4.2.2. SDV-505 is provided.
4.2.3. V-422 drain valve is provided.
4.2.4. Low Temperature Controller Alarm (TICAL-507) is provided.
Refer to item less flow above (1.4.1) N/A Consultant
Refer to item less flow above (1.4.2)
Refer to item less flow above (1.4.3)
Refer to item less flow above (1.4.4)
Refer to item less flow above (1.4.5)
6.1.1. High-High Level Alarm and Trip System (LZAHH506) is provided. N/A Consultant
6.1.2. SDV-506 is provided.
6.1.3. V-425 drain valve is provided.
6.1.4. Low Flow Indicator and Alarm (FIAL-508) is provided.
6.1.5. High Level Controller (LICH-506) is provided.
6.2.1. Low-Low Pressure Alarm and Trip System (PZALL504) is provided.
6.2.2. SDV-507 is provided.
6.2.3. Low Pressure Controller (PICL-505) is provided.
Refer to item less flow above (1.2.1) N/A Consultant
Refer to item less flow above (1.2.2)
Refer to item less flow above (1.2.3)
Refer to item less flow above (1.2.4)
1.1.1. PM-503 is provided. Refer to recommendation No Flow above (6, 7) Consultant
1.1.2. I-503 is provided.
1.1.3. Drain valve of P-500 is provided.
1.1.4. V-398 drain valve is provided.
2.1.1. V-414 bypass valve is provided. Refer to recommendation No Flow above (8) Consultant
2.2.1. Low-Low Temperature Alarm and Trip System (TZALL505) is provided.
2.2.2. SDV-505 is provided.
2.2.3. V-422 drain valve is provided.
2.2.4. Low Temperature Controller Alarm (TICAL-507) is provided.
3.1.1. High Temperature Controller (TICH-504) is provided. 13. Consider to install a reverse valve at E-500 stream Consultant
3.1.2. V-417 drain valve is provided. outlet.
14. Consider to add Alarm at Temperature Indicator
Controller (TIC-504) to alert operator.
15. Consider to install a Temperature Emergency Trip
System at tube side of E-500.

1 4 4 4. PV-505 malfunction closed. 4.1 Reverse Flow to R-500, leading to
potential high pressure in R-500.
4.2 High Pressure of R-500, leading to
potential reverse flow of inlet water
stream.
4.3 Reverse flow of R-500 inlet water
stream to E-500, leading to potential high
temperature of E-500.
1 4 5 5. SDV-507 malfunction closed Refer to item no. 1.4.4
1 4 6 6. TV-507 malfunction closed 6.1. Reverse Flow to R-500, leading to
potential high temperature in R-500.
1 4 7 7. LV-506 malfunction closed 7.1. Reverse Flow to R-500, leading to
potential high level in R-500
7.2. High level in R-500, leading to
potential low pressure in R-500.
1 4 8 8. SDV-508 malfunction closed Refer to item no. 1.4.7
1 5 1 High Pressure 1. SDV-501 malfunction closed 1.1. No Flow to P-500, leading to break
down of P-500 due to pump minimum
flow.
1.2. No Flow of water leading to
potential high temperature in E-500.
1.3. Loss of production due to no flow of
water flowing into R-500.
1.4. No Flow of water to R-500, leading to
potential high pressure in R-500.
1 5 2 2. FV-501 malfunction closed Refer to item no. 1.5.1.
HAZOP Worksheets
4.1.1. High-High Pressure Alarm and Trip System (PZAHH504) is provided. Refer to recommendation No Flow above (3) Consultant
4.1.2. SDV-504 is provided. 16. Consider to install reverse valve at top vapor stream
4.1.3. PSV-500 is provided. outlet of R-500 for protection purpose before V-432.
4.1.4. V-432 Vent Valve is provided.
4.1.5. High Pressure Controller (PICH-505) is provided.
4.3.1. High-High-High Temperature Alarm and Trip System (TZAHH503) is
provided.
4.3.2. SDV-503 is provided.
4.3.3. V-417 Drain Valve is provided.
4.3.4. High Temperature Controller (TICH-504) is provided.
Refer to item no. 1.4.4 Refer to recommendation No Flow above (3) Consultant
Refer to recommendation Reverse Flow above (16).
Refer to item reversed flow above (4.3.1) 17. Consider to install reverse valve at utility stream Consultant
Refer to item reversed flow above (4.3.2) outlet of R-500 for protection purpose before V-439.
Refer to item reversed flow above (4.3.3)
Refer to item reversed flow above (4.3.4)
7.1.1. High-High Level Alarm and Trip System (LZAHH506) is provided. Refer to recommendation More Flow above (12) Consultant
7.1.2. SDV-506 is provided.
7.1.3. V-425 drain valve is provided.
7.1.4. Low Flow Alarm (FIAL-508) is provided.
7.1.5. High Level Controller (LICH-506) is provided.
7.2.1. Low-Low Pressure Alarm and Trip System (PZALL504) is provided.
7.2.2. SDV-507 is provided.
7.2.3. Low Pressure Controller (PICL-505) is provided.
Refer to item no. 1.4.7 Refer to recommendation More Flow above (12) Consultant
1.1.1. Low-Low Flow Alarm and Trip System (FZALL501) is provided. Refer to recommendation No Flow above (1, 2, 3). Consultant
1.1.2. SDV-502 is provided.
1.1.3. PM-503 is provided.
1.1.4. I-503 is provided.
1.1.5. Low Flow Controller Alarm (FICAL-503) is provided.
1.2.1. High-High Temperature Alarm and Trip System (TZAHH503) is
provided.
1.2.2. SDV-503 is provided.
1.2.3. V-408 drain valve is provided.
1.2.4. Low Temperature Controller (TICL-504) is provided.
1.3.1. Low-Low Level Alarm and Trip System (LZALL506) is provided.
1.3.2. SDV-508 is provided.
1.3.3. Low Level Controller (LICL-506) is provided.
1.4.1. High-high Pressure Alarm and Trip System (PZAHH504) is provided.
1.4.2. SDV-504 is provided.
1.4.3. PSV-500 is provided.
1.4.4. V-432 vent valve is provided.
1.4.5. High Pressure Controller (PICH-505) is provided.
Refer to item no. 1.5.1. Refer to recommendation No Flow above (1, 2, 3). Consultant

1 5 3 3. FV-501 malfunction partially closed 3.1. Less Flow to P-500, leading to break
down of P-500 due to pump minimum
flow.
3.2. Less Flow of water leading to
potential high temperature in E-500.
3.3. Loss of production due to less flow
of water flowing into R-500.
3.4. Less Flow to R-500, leading to
potential high pressure in R-500.
3.5. Less water flow of high temperature
water to R-500, leading to high
temperature in R-500.
1 5 4 4. M-503 malfunction Refer to item high pressure above (1.2)
Refer to item high pressure above (1.3)
Refer to item high pressure above (1.4)
Refer to item high pressure above (3.2)
Refer to item high pressure above (3.3)
Refer to item high pressure above (3.4)
Refer to item high pressure above (3.5)
1 5 5 5. V-525 malfunction closed Refer to item high pressure above (1.2)
Refer to item high pressure above (1.3)
Refer to item high pressure above (1.4)
5.1. More water accumulation at outlet
of P-500 will flow back through the
recycle stream leading to damaged
pump.
HAZOP Worksheets
Refer to item high pressure above 1.1.1. Refer to recommendation No Flow above (1, 2, 3). Consultant
Refer to item high pressure above 1.1.2.
Refer to item high pressure above 1.1.3.
Refer to item high pressure above 1.1.4.
3.1.1. Low Flow Controller (FICL-502) is provided.
3.1.2. High Flow Controller Alarm (FICAL-503) is provided.
Refer to item high pressure above 1.2.1.
Refer to item high pressure above 1.2.2.
Refer to item high pressure above 1.2.3.
3.2.1. High Temperature Controller (TICH-504) is provided.
Refer to item high pressure above 1.3.1.
Refer to item high pressure above 1.3.2.
Refer to item high pressure above 1.3.3.
Refer to item high pressure above 1.4.1.
Refer to item high pressure above 1.4.2.
Refer to item high pressure above 1.4.3.
Refer to item high pressure above 1.4.4.
Refer to item high pressure above 1.4.5.
3.5.1. High-High Temperature Alarm and Trip System (TZAHH505) is
provided.
3.5.2. SDV-504 is provided.
3.5.3. SDV-506 is provided.
3.5.4. V-420 Drain Valve is provided.
3.5.5. High Temperature Controller Alarm (TICAH-507) is provided.
Refer to item high pressure above (1.2.1) Refer to recommendation No Flow above (4, 5). Consultant
Refer to item high pressure above (1.2.2)
Refer to item high pressure above (1.2.3)
Refer to item high pressure above (1.2.4)
Refer to item high pressure above (1.3.1)
Refer to item high pressure above (1.3.2)
Refer to item high pressure above (1.3.3)
Refer to item high pressure above (1.4.1)
Refer to item high pressure above (1.4.2)
Refer to item high pressure above (1.4.3)
Refer to item high pressure above (1.4.4)
Refer to item high pressure above (1.4.5)
Refer to item high pressure above (3.2.1)
Refer to item high pressure above (3.5.1)
Refer to item high pressure above (3.5.2)
Refer to item high pressure above (3.5.3)
Refer to item high pressure above (3.5.4)
Refer to item high pressure above (3.5.5)
Refer to item high pressure above (1.2.1) Refer to recommendation No Flow above (6, 7) Consultant
Refer to item high pressure above (1.2.2)
Refer to item high pressure above (1.2.3)
Refer to item high pressure above (1.2.4)
Refer to item high pressure above (1.3.1)
Refer to item high pressure above (1.3.2)
Refer to item high pressure above (1.3.3)
Refer to item high pressure above (1.4.1)
Refer to item high pressure above (1.4.2)
Refer to item high pressure above (1.4.3)
Refer to item high pressure above (1.4.4)
Refer to item high pressure above (1.4.5)
5.1.1. PM-501 is provided
5.1.2. I-503 is provided
5.1.3. Drain valve of P-500 is provided.
5.1.4. V-398 drain valve is provided.

1 5 6 6. SDV-502 malfunction closed Refer to item high pressure above (1.2)
Refer to item high pressure above (1.3)
Refer to item high pressure above (1.4)
1 5 7 7. TV-504 malfunction stuck opened 7.1 More Flow of utility stream from E-
500, leading to potential high
temperature of E-500.
7.2 More Flow of utility stream from E-
500, leading to potential high
temperature of R-500 due to high
temperature water stream.
7.3 More vapour is generated due to high
temperature, leading to high pressure in
R-500.
1 5 8 8. SDV-505 malfunction closed 9.1. No flow of coolant leads to potential
loss of cooling, possible thermal runaway
and leading to decrease of reaction rate.
Refer to item high pressure above (7.3)
1 5 9 9. SDV-506 malfunction closed 9.1. No Flow of water leading to
potential low temperature in R-500.
Refer to item high pressure above (1.3)
Refer to item high pressure above (1.4)
1 5 10 10. PV-505 malfunction closed 11.1 Reverse Flow to R-500 and No Flow
from R-500, leading to potential high
pressure in R-500.
11.2 High Pressure of R-500, leading to
potential reverse flow of inlet water
stream.
11.3 Reverse flow of R-500 inlet water
stream to E-500, leading to potential high
temperature of E-500.
1 5 11 11. SDV-507 malfunction closed Refer to item no. 1.5.10.
1 5 12 12. PV-505 malfunction partially 12.1 Less top outlet flow from R-500,
closed leading to potential high pressure in R-
500.
HAZOP Worksheets
Refer to item high pressure above (1.2.1) Refer to recommendation No Flow above (1, 2, 3) Consultant
Refer to item high pressure above (1.2.2)
Refer to item high pressure above (1.2.3)
Refer to item high pressure above (1.2.4)
Refer to item high pressure above (1.3.1)
Refer to item high pressure above (1.3.2)
Refer to item high pressure above (1.3.3)
Refer to item high pressure above (1.4.1)
Refer to item high pressure above (1.4.2)
Refer to item high pressure above (1.4.3)
Refer to item high pressure above (1.4.4)
Refer to item high pressure above (1.4.5)
7.1.1. High-High Temperature Alarm and Trip System (TZAHH503) is Refer to recommendation No Flow above (2) Consultant
provided. Refer to recommendation More Flow above (11)
7.1.2. SDV-503 is provided.
7.1.3. V-408 drain valve is provided.
7.2.1. High-High Temperature Alarm and Trip System (TZAHH505) is
provided.
7.2.2. SDV-504 is provided.
7.2.3. SDV-506 is provided.
7.2.4. V-420 drain valve is provided.
7.2.5. High Temperature Controller Alarm (TICAH-507) is provided.
Refer to item high pressure above (1.4.1)
Refer to item high pressure above (1.4.2)
Refer to item high pressure above (1.4.3)
Refer to item high pressure above (1.4.4)
Refer to item high pressure above (1.4.5)
9.1.1. High-High Temperature Alarm and Trip System (TZAHH505) is Refer to recommendation No Flow above (2) Consultant
provided.
9.1.2. SDV-504 is provided.
9.1.3. SDV-506 is provided.
9.1.4. V-420 Drain Valve is provided
9.1.5. High Temperature Controller Alarm (TICAH-507) is provided.
Refer to item high pressure above (1.4.1)
Refer to item high pressure above (1.4.2)
Refer to item high pressure above (1.4.3)
Refer to item high pressure above (1.4.4)
Refer to item high pressure above (1.4.5)
9.1.1. Low-Low Temperature Alarm and Trip System (TZALL505) is provided. Refer to recommendation No Flow above (2) Consultant
9.1.2. SDV-505 is provided.
9.1.3. V-422 drain valve is provided.
Refer to item high pressure above (1.3.1)
Refer to item high pressure above (1.3.2)
Refer to item high pressure above (1.3.3)
Refer to item high pressure above (1.4.1)
Refer to item high pressure above (1.4.2)
Refer to item high pressure above (1.4.3)
Refer to item high pressure above (1.4.4)
Refer to item high pressure above (1.4.5)
Refer to item high pressure above (1.4.1) Refer to recommendation No Flow above (3) Consultant
Refer to item high pressure above (1.4.2) Refer to recommendation Reverse Flow above (16)
Refer to item high pressure above (1.4.3)
Refer to item high pressure above (1.4.4)
11.3.1. High-High-High Temperature Alarm and Trip System (TZAHH505) is
provided.
11.3.2. SDV-504 is provided.
11.3.3. SDV-506 is provided.
11.3.4. V-439 Drain Valve is provided.
Refer to item no. 1.5.10. Refer to recommendation No Flow above (3) Consultant
Refer to recommendation Reverse Flow above (16)
Refer to item high pressure above (1.4.1) N/A Consultant
Refer to item high pressure above (1.4.2)
Refer to item high pressure above (1.4.3)
Refer to item high pressure above (1.4.4)
Refer to item high pressure above (1.4.5)

1 5 13 13. LV-506 malfunction stuck opened 13.1 More flow from R-500, leading to
potential low level in R-500.
13.2 Low level in R-500, leading to
potential high pressure in R-500.
1 6 1 Low Pressure 1. FV-501 malfunction stuck opened 1.1. More water flow to P-500, leading to
break down of P-500 due to pump
maximum flow.
1.2. More water flow leading to potential
low temperature in E-500.
1.3. More water flow to R-500, lead to
potential flooding and damage of tray in
R-500.
1.4. More water flow to R-500, leading to
potential low pressure in R-500.
1.5. More water flow of low temperature
water to R-500, leading to low
temperature in R-500.
1 6 2 2. M-503 malfunction 2.1. Low pressure in P-500 outlet,
leading to less flowrate of water and
potential high temperature to E-500.
2.2. Loss of production due to less flow
of water flowing into R-500.
2.3. Less Water Flow to R-500, leading to
potential high pressure in R-500.
2.4. Less water flow of high temperature
water to R-500, leading to high
temperature in R-500.
1 6 3 3. SDV-504 malfunction closed 3.1. No Flow of gas leading to potential
low temperature in R-500.
3.2. Loss of production due to no flow of
process gas into R-500.
3.3. No Flow of process gas to R-500,
leading to potential low pressure in R-
500.
1 6 4 4. V-526 malfunction closed Refer to item no. 1.6.4
HAZOP Worksheets
5.1.1. High Flow Indicator and Alarm (FIAH-508) is provided. N/A Consultant
Refer to item high pressure above (1.3.1)
Refer to item high pressure above (1.3.2)
Refer to item high pressure above (1.3.3)
Refer to item high pressure above (1.4.1)
Refer to item high pressure above (1.4.2)
Refer to item high pressure above (1.4.3)
Refer to item high pressure above (1.4.4)
Refer to item high pressure above (1.4.5)
1.1.1. High-High Flow Alarm and Trip System (FZAHH502) is provided. Refer to recommendation No Flow above (7,8) Consultant
1.1.2. SDV-501 is provided. Refer to recommendation More Flow above (10)
1.1.3. SDV-502 is provided.
1.1.4. V-398 Drain Valve is provided.
1.1.5. PM-503 is provided.
1.1.6. I-503 is provided.
1.1.7. High Flow Controller (FICH-502) is provided.
1.1.8. High Flow Controller Alarm (FICAH-503) is provided.
1.2.1. V-407 Drain Valve is provided.
1.2.2. Low Temperature Controller (TICL-504) is provided.
1.3.1. High-High Level Alarm and Trip System (LZAHH506) is provided.
1.3.2. SDV-506 is provided.
1.3.3. V-420 Drain Valve is provided.
1.3.4. High Level Controller (LIC-506) is provided.
1.4.1. Low-Low Pressure Alarm and Trip System (PZALL504) is provided.
1.4.2. SDV-507 is provided.
1.4.3. Low Pressure Controller (PICL-505) is provided.
1.5.1. Low-Low Temperatur Alarm and Trip System (TZALL505) is provided.
1.5.2. SDV-505 is provided.
1.5.3. V-422 Drain Valve is provided.
1.5.4. Low Temperature Controller Alarm (TICAL-507) is provided.
2.1.1. High-High Temperature Alarm and Trip System (TZAHH503) is Refer to recommendations No Flow above (4, 5). Consultant
provided.
2.1.2. SDV-503 is provided.
2.1.3. V-408 drain valve is provided.
2.1.4. High Temperature Controller (TICH504) is provided.
2.2.1. Low-Low Level Alarm and Trip System (LZALL506) is provided.
2.2.2. SDV-508 is provided.
2.2.3. Low Level Controller (LICL-506) is provided.
2.3.1. High-high Pressure Alarm and Trip System (PZAHH504) is provided.
2.3.2. PSV-500 is provided.
2.3.3. V-432 vent valve is provided.
2.3.4. SDV-504 is provided.
2.3.5. High Pressure Controller (PICH-505) is provided.
2.4.1. High-High Temperature Alarm and Trip System (TZAHH505) is
provided.
2.4.2. SDV-504 is provided.
2.4.3. SDV-506 is provided.
2.4.4. V-420 Drain Valve is provided.
2.4.5. High Temperature Controller Alarm (TICAH-507) is provided.
3.1.1. Low Temperature Controller Alarm (TICAL-507) is provided. Refer to recommendation No Flow above (9). Consultant
3.2.1. Low-Low Temperature Alarm and Trip System (TZALL505) is provided.
3.2.2. SDV-505 is provided.
3.2.3. V-422 drain valve is provided.
3.3.1. Low-low Pressure Alarm and Trip System (PZALL504) is provided.
3.3.2. SDV-507 is provided.
3.3.3. Low Pressure Controller (PICL-505) is provided.
Refer to item no. 1.6.4 Refer to recommendation No Flow above (9). Consultant

1 6 5 5. PV-505 malfuntion stuck opened 5.1 More vapor flow exit from R-500,
leading to potential low pressure in R-
500.
5.2 Low Pressure of R-500, leading to
potential reverse flow of bottom liquid
outlet stream.
5.3. Reverse Flow of bottom liquid outlet
stream, leading to potential high level in
R-500.
1 6 6 6. LV-506 malfunction closed 6.1. Reverse Flow to R-500 and No Outlet
Flow from R-500, leading to potential
high level in R-500
6.2. High level in R-500, leading to
potential low pressure in R-500.
1 6 7 7. LV-506 malfunction partially closed 7.1 Less Flow from R-500, leading to
potential high level in R-500.
7.2 High level in R-500, leading to
potential low pressure in R-500.
1 6 8 8. SDV-508 malfunction closed Refer to item no. 1.6.6
1 7 1 High Temperature 1. SDV-501 malfunction closed 1.1. No Flow to P-500, leading to break
down of P-500 due to pump minimum
flow.
1.2. No Flow of water leading to
potential high temperature in E-500.
1.3. Loss of production due to no flow of
water flowing into R-500.
1.4. No Flow of water to R-500, leading to
potential high pressure in R-500.
1 7 2 2. FV-501 malfunction closed Refer to item no. 1.7.1.
1 7 3 3. FV-501 malfunction partially closed 3.1. Less Flow to P-500, leading to break
down of P-500 due to pump minimum
flow.
3.2. Less Flow of water leading to
potential high temperature in E-500.
3.3. Loss of production due to less flow
of water flowing into R-500.
3.4. Less Flow to R-500, leading to
potential high pressure in R-500.
3.5. Less water flow of high temperature
water to R-500, leading to high
temperature in R-500.
HAZOP Worksheets
5.1.1. Low-Low Pressure Alarm and Trip System (PZALL504) is provided. Refer to recommendation No Flow above (2). Consultant
5.1.2. SDV-507 is provided. Refer to recommendation More Flow above (12).
5.1.3. Low Pressure Controller (PICL-505) is provided.
Refer to low pressure above (1.3.1).
Refer to low pressure above (1.3.2).
Refer to low pressure above (1.3.3).
5.3.1. V-425 drian valve is provided.
6.1.1. High-High Level Alarm and Trip System (LZAHH506) is provided. Refer to recommendation More Flow above (12). Consultant
6.1.2. SDV-506 is provided.
6.1.3. V-425 drain valve is provided.
6.1.4. Low Flow Alarm (FIAL-508) is provided.
6.1.5. High Level Controller (LICH-506) is provided.
Refer to item low pressure above (5.1.1).
Refer to item low pressure above (5.1.2).
Refer to item low pressure above (5.1.3).
Refer to item no. 1.6.6 Refer to recommendation More Flow above (12). Consultant
Refer to item no. 1.6.6 Refer to recommendation More Flow above (12). Consultant
1.1.1. Low-Low Flow Alarm and Trip System (FZALL501) is provided. Refer to recommendation No Flow above (1, 2, 3) Consultant
1.1.2. SDV-502 is provided.
1.1.3. PM-503 is provided.
1.1.4. I-503 is provided.
1.1.5. Low Flow Controller Alarm (FICAL-503) is provided.
1.2.1. High-High Temperature Alarm and Trip System (TZAHH503) is
provided.
1.2.2. SDV-503 is provided.
1.2.3. V-408 drain valve is provided.
1.2.4. Low Temperature Controller (TICL-504) is provided.
1.3.1. Low-Low Level Alarm and Trip System (LZALL506) is provided.
1.3.2. SDV-508 is provided.
1.3.3. Low Level Controller (LICL-506) is provided.
1.4.1. High-high Pressure Alarm and Trip System (PZAHH504) is provided.
1.4.2. SDV-504 is provided.
1.4.3. PSV-500 is provided.
1.4.4. V-432 vent valve is provided.
1.4.5. High Pressure Controller (PICH-505) is provided.
Refer to item no. 1.7.1. Refer to recommendation No Flow above (1, 2, 3) Consultant
Refer to item high temperature above (1.1.1). Refer to recommendation No Flow above (1, 2, 3) Consultant
Refer to item high temperature above (1.1.2).
Refer to item high temperature above (1.1.3).
Refer to item high temperature above (1.1.4).
Refer to item high temperature above (1.1.5).
3.1.1. High Flow Controller Alarm (FICAL-503) is provided.
Refer to item high temperature above (1.2.1).
Refer to item high temperature above (1.2.2).
Refer to item high temperature above (1.2.3).
Refer to item high temperature above (1.2.4).
Refer to item high temperature above (1.3.1).
Refer to item high temperature above (1.3.2).
Refer to item high temperature above (1.3.3).
Refer to item high temperature above (1.4.1).
Refer to item high temperature above (1.4.2).
Refer to item high temperature above (1.4.3).
Refer to item high temperature above (1.4.4).
Refer to item high temperature above (1.4.5).
3.5.1. High-High Temperature Alarm and Trip System (TZAHH505) is
provided.
3.5.2. SDV-504 is provided.
3.5.3. SDV-506 is provided.
3.5.4. V-420 Drain Valve is provided.
3.5.5. High Temperature Controller Alarm (TICAH-507) is provided.

1 7 4 4. M-503 malfunction 4.1. No Flow and less flow of water
leading to potential high temperature in
E-500.
4.2. Loss of production due to no flow of
water flowing into R-500.
4.3. No Flow and less flow of water to R-
500, leading to potential high pressure in
R-500.
4.4. Less water flow of high temperature
water to R-500, leading to high
temperature in R-500.
1 7 5 5. V-525 malfunction closed Refer to item high temperature above
(1.2)
Refer to item high temperature above
(1.3)
Refer to item high temperature above
(1.4)
1 7 6 6. SDV-502 malfunction closed Refer to item no. 1.7.5
1 7 7 7. TV-504 malfunction stuck opened 7.1 More Flow of utility stream from E-
500, leading to potential high
temperature of E-500.
7.2 More Flow of utility stream from E-
500, leading to potential high
temperature of R-500 due to high
temperature water stream.
7.3 More vapour is generated due to high
temperature, leading to high pressure in
R-500.
1 7 8 8. SDV-505 malfunction closed 8.1. No flow of coolant leads to potential
loss of cooling, possible thermal
runaway of R-500 and leading to
decrease of reaction rate.
8.2. More vapour is generated due to
high temperature, leading to high
pressure in R-500.
1 7 9 9. SDV-506 malfunction closed 9.1. Reverse Flow to E-500, leading to
potential high temperature in tube side
of E-500.
HAZOP Worksheets
Refer to item high temperature above (1.2.1). Refer to recommendation No Flow above (4, 5) Consultant
Refer to item high temperature above (1.2.2).
Refer to item high temperature above (1.2.3).
Refer to item high temperature above (1.2.4).
4.1.1. High Temperature Controller (TICH-504) is provided.
Refer to item high temperature above (1.3.1).
Refer to item high temperature above (1.3.2).
Refer to item high temperature above (1.3.3).
Refer to item high temperature above (1.4.1).
Refer to item high temperature above (1.4.2).
Refer to item high temperature above (1.4.3).
Refer to item high temperature above (1.4.4).
Refer to item high temperature above (1.4.5).
4.4.1. High-High Temperature Alarm and Trip System (TZAHH505) is
provided.
4.4.2. SDV-504 is provided.
4.4.3. SDV-506 is provided.
4.4.4. V-420 Drain Valve is provided.
4.4.5. High Temperature Controller Alarm (TICAH-507) is provided.
Refer to item high temperature above (1.2.1). Refer to recommendation No Flow above (6, 7) Consultant
Refer to item high temperature above (1.2.2).
Refer to item high temperature above (1.2.3).
Refer to item high temperature above (1.2.4).
Refer to item high temperature above (1.3.1).
Refer to item high temperature above (1.3.2).
Refer to item high temperature above (1.3.3).
Refer to item high temperature above (1.4.1).
Refer to item high temperature above (1.4.2).
Refer to item high temperature above (1.4.3).
Refer to item high temperature above (1.4.4).
Refer to item high temperature above (1.4.5).
Refer to item no. 1.7.5 Refer to recommendation No Flow above (1, 2, 3) Consultant
Refer to item high temperature above (1.2.1). Refer to recommendation No Flow above (2) Consultant
Refer to item high temperature above (1.2.2). Refer to recommendation More Flow above (11)
Refer to item high temperature above (1.2.3).
Refer to item high temperature above (3.5.1).
Refer to item high temperature above (3.5.2).
Refer to item high temperature above (3.5.3).
Refer to item high temperature above (3.5.4).
Refer to item high temperature above (3.5.5).
Refer to item high temperature above (1.4.1).
Refer to item high temperature above (1.4.2).
Refer to item high temperature above (1.4.3).
Refer to item high temperature above (1.4.4).
Refer to item high temperature above (1.4.5).
Refer to item high temperature above (4.4.1). Refer to recommendation No Flow above (2) Consultant
Refer to item high temperature above (4.4.2).
Refer to item high temperature above (4.4.3).
Refer to item high temperature above (4.4.4).
Refer to item high temperature above (4.4.5).
Refer to item high temperature above (1.4.1)
Refer to item high temperature above (1.4.2)
Refer to item high temperature above (1.4.3)
Refer to item high temperature above (1.4.4)
Refer to item high temperature above (1.4.5)
9.1.1. High Temperature Controller (TICH-504) is provided. Refer to recommendation Reverse Flow above (13, 14, Consultant
9.1.2. V-417 drain valve is provided. 15)

1 7 10 10. PV-505 malfunction closed 10.1 Reverse Flow to R-500 and No
Outlet Flow of R-500, leading to potential
high pressure in R-500.
10.2 High Pressure of R-500, leading to
potential reverse flow of inlet water
stream.
10.3 Reverse flow of R-500 inlet water
stream to E-500, leading to potential high
temperature of E-500.
1 7 11 11. SDV-507 malfunction closed Refer to item no. 1.7.10
1 7 12 12. TV-507 malfunction closed 12.1. Reverse Flow of coolant to R-500, Refer to item high temperature above (10.3.1)
leading to potential high temperature in Refer to item high temperature above (10.3.2)
R-500. Refer to item high temperature above (10.3.3)
Refer to item high temperature above (10.3.4)
1 7 13 13. TV-507 malfunction partially 13.1 Less Flow of utility stream from R-
closed 500, leading to potential high
temperature of R-500.
1 8 1 Low Temperature 1. FV-501 malfunction stuck opened 1.1. More water flow to P-500, leading to
break down of P-500 due to pump
maximum flow.
1.2. More water flow leading to potential
low temperature in E-500.
1.3. More water flow to R-500, lead to
potential flooding and damage of tray in
R-500.
1.4. More water flow to R-500, leading to
potential low pressure in R-500.
1.5. More water flow of low temperature
water to R-500, leading to low
temperature in R-500.
1 8 2 2. SDV-503 malfunction closed 2.1. Potential loss of heating leading to
potential low temperature of E-500.
2.2. Less temperature water inlet of R-
500, leading to decrease reaction rate.
1 8 3 3. TV-504 malfunction closed 3.1. Reverse Flow to E-500, leading to
potential low temperature of E-500.
3.2. No Flow of Hot water utility stream
from E-500, leading to potential low
temperature of R-500.
1 8 4 4. TV-504 malfunction partially closed 4.1. Less Flow of utility stream from E-
500, leading to potential low
temperature of E-500.
4.2. Less Flow of hot water utility stream
from E-500, leading to potential low
temperature of R-500.
HAZOP Worksheets
Refer to item high temperature above (1.4.1). Refer to recommendation No Flow above (3) Consultant
Refer to item high temperature above (1.4.2). Refer to recommendation Reverse Flow above (16)
Refer to item high temperature above (1.4.3).
Refer to item high temperature above (1.4.4).
Refer to item high temperature above (1.4.5).
10.3.1. High-High-High Temperature Alarm and Trip System (TZAHH503) is
provided.
10.3.2. SDV-503 is provided.
10.3.3. V-417 Drain Valve is provided.
10.3.4. High Temperature Controller (TICH-504) is provided.
Refer to item no. 1.7.10 Refer to recommendation No Flow above (3) Consultant
Refer to recommendation Reverse Flow above (16).
Refer to recommendation Reverse Flow above (17). Consultant
Refer to item high temperature above (1.2.1) N/A Consultant
Refer to item high temperature above (1.2.2)
Refer to item high temperature above (1.2.3)
Refer to item high temperature above (10.3.4)
1.1.1. High-High Flow Alarm and Trip System (FZAHH502) is provided. Refer to recommendation No Flow above (7,8) Consultant
1.1.2. SDV-501 is provided. Refer to recommendation More Flow above (10)
1.1.3. SDV-502 is provided.
1.1.4. V-398 Drain Valve is provided.
1.1.5. PM-503 is provided.
1.1.6. I-503 is provided.
1.1.7. High Flow Controller (FICH502) is provided.
1.1.8. High Flow Controller Alarm (FICAH503) is provided.
1.2.1. V-407 Drain Valve is provided.
1.2.2. Low Temperature Controller (TICL-504) is provided.
1.3.1. High-High Level Alarm and Trip System (LZAHH506) is provided.
1.3.2. SDV-506 is provided.
1.3.3. V-420 Drain Valve is provided.
1.3.4. High Level Controller (LIC-506) is provided.
1.4.1. Low-Low Pressure Alarm and Trip System (PZALL504) is provided.
1.4.2. SDV-507 is provided.
1.4.3. Low Pressure Controller (PICL-505) is provided.
1.5.1. Low-Low Temperatur Alarm and Trip System (TZALL505) is provided.
1.5.2. SDV-505 is provided.
1.5.3. V-422 Drain Valve is provided.
1.5.4. Low Temperature Controller Alarm (TICAL-507) is provided.
Refer to item Low temperature above (1.5.1) Refer to recommendation No Flow above (8). Consultant
Refer to item Low temperature above (1.5.2)
Refer to item Low temperature above (1.5.3)
Refer to item Low temperature above (1.5.4)
3.1.1. V-414 bypass valve is provided. Refer to recommendation No Flow above (8) Consultant
Refer to item Low temperature above (1.5.1)
Refer to item Low temperature above (1.5.2)
Refer to item Low temperature above (1.5.3)
Refer to item Low temperature above (1.5.4)
Refer to item Low temperature above (3.1.1) Refer to recommendation No Flow above (8). Consultant
Refer to item Low temperature above (1.5.1)
Refer to item Low temperature above (1.5.2)
Refer to item Low temperature above (1.5.3)
Refer to item Low temperature above (1.5.4)

1 8 5 5. SDV-504 malfunction closed 5.1. No Flow of gas leading to potential
low temperature in R-500.
5.2. Loss of production due to no flow of
process gas into R-500.
5.3. No Flow of process gas to R-500,
leading to potential low pressure in R-
500.
1 8 6 6. V-526 malfunction closed Refer to item no. 1.8.5
1 8 7 7. SDV-506 malfunction closed 7.1. No Flow of water leading to
potential low temperature in R-500.
Refer to item low temperature above
(5.2)
Refer to item low temperature above
(5.3)
1 8 8 8. TV-507 malfunction stuck opened 8.1. More Flow of utility stream from R-
500, leading to potential low
temperature of R-500.
8.2 Low temperature of R-500 leading to
decrease of reaction rate.
1 9 1 No Level 1. SDV-501 malfunction closed 1.1. No Flow to P-500, leading to break
down of P-500 due to pump minimum
flow.
1.2. No Flow of water leading to
potential high temperature in E-500.
1.3. Loss of production due to no flow of
water flowing into R-500, under no level
in R-500.
1.4. No Flow of water to R-500, leading to
potential high pressure in R-500.
1 9 2 2. FV-501 malfunction closed Refer to item no. 1.9.1.
1 9 3 3. M-503 malfunction closed Refer to item no level above (1.2)
Refer to item no level above (1.3)
Refer to item no level above (1.4)
1 9 4 4. V-525 malfunction closed Refer to item no. 1.9.3.
1 9 5 5. SDV-502 malfunction closed Refer to item no. 1.9.3.
HAZOP Worksheets
Refer to item Low temperature above (1.5.1) Refer to recommendation No Flow above (9). Consultant
Refer to item Low temperature above (1.5.2)
Refer to item Low temperature above (1.5.3)
Refer to item Low temperature above (1.5.4)
5.3.1. Low-low Pressure Alarm and Trip System (PZALL504) is provided.
5.3.2. SDV-507 is provided.
5.3.3. Low Pressure Controller (PICL-505) is provided.
Refer to item no. 1.8.5 Refer to recommendation No Flow above (9). Consultant
7.1.1. Low-Low Temperature Alarm and Trip System (TZALL505) is provided. Refer to recommendation No Flow above (2) Consultant
7.1.2. SDV-505 is provided.
7.1.3. V-422 drain valve is provided.
7.1.4. Low Temperature Controller Alarm (TICAL-507) is provided.
7.1.5. Low-Low Level Alarm and Trip System (LZALL506) is provided.
7.1.6. SDV-508 is provided.
7.1.7. Low Level Controller (LICL-506) is provided.
7.1.8. High-high Pressure Alarm and Trip System (PZAHH504) is provided.
7.1.9. SDV-504 is provided.
7.1.10. PSV-500 is provided.
7.1.11. V-432 vent valve is provided.
7.1.12. High Pressure Controller (PICH-505) is provided.
Refer to item Low temperature flow above (7.1.1) N/A Consultant
Refer to item Low temperature flow above (7.1.2)
Refer to item Low temperature flow above (7.1.3)
Refer to item Low temperature flow above (7.1.4)
1.1.1. Low-Low Flow Alarm and Trip System (FZALL501) is provided. Refer to recommendation No Flow above (1,2,3) Consultant
1.1.2. SDV-502 is provided.
1.1.3. PM-503 is provided.
1.1.4. I-503 is provided.
1.1.5. Low Flow Controller Alarm FICAL-503 is provided.
1.2.1. High-High Temperature Alarm and Trip System (TZAHH503) is
provided.
1.2.2. SDV-503 is provided.
1.2.3. V-408 drain valve is provided.
1.2.4. Low Temperature Controller (TICL-504) is provided.
1.3.1. Low-Low Level Alarm and Trip System (LZALL506) is provided.
1.3.2. SDV-508 is provided.
1.3.3. Low Level Controller (LICL-506) is provided.
1.4.1. High-high Pressure Alarm and Trip System (PZAHH504) is provided.
1.4.2. SDV-504 is provided.
1.4.3. PSV-500 is provided.
1.4.4. V-432 vent valve is provided.
1.4.5. High Pressure Controller (PICH-505) is provided.
Refer to item no. 1.9.1. Refer to recommendation No Flow above (1,2,3) Consultant
Refer to item no level above (1.2.1) Refer to recommendation No Flow above (4,5) Consultant
Refer to item no level above (1.2.2)
Refer to item no level above (1.2.3)
Refer to item no level above (1.2.4)
Refer to item no level above (1.3.1)
Refer to item no level above (1.3.2)
Refer to item no level above (1.3.3)
Refer to item no level above (1.4.1)
Refer to item no level above (1.4.2)
Refer to item no level above (1.4.3)
Refer to item no level above (1.4.4)
Refer to item no level above (1.4.5)
Refer to item no. 1.9.3 Refer to recommendation No Flow above (6, 7) Consultant
Refer to item no. 1.9.3 Refer to recommendation No Flow above (1,2,3) Consultant

1 9 6 6. SDV-506 malfunction closed 6.1 No Flow of water leading to potential
low temperature in R-500.
Refer to item no level above (1.3)
Refer to item no level above (1.4)
1 10 1 High Level 1. FV-501 malfunction stuck opened 1.1. More water flow to P-500, leading to
break down of P-500 due to pump
maximum flow.
1.2. More water flow leading to potential
low temperature in E-500.
1.3. More water flow to R-500, lead to
potential flooding and damage of tray in
R-500.
1.4. More water flow to R-500, leading to
potential low pressure in R-500.
1.5. More water flow of low temperature
water to R-500, leading to low
temperature in R-500.
1 10 2 2. PV-505 malfunction stuck opened 2.1. More flow from R-500, leading to
potential low pressure in R-500.
2.2. Low Pressure of R-500, leading to
potential reverse flow of bottom liquid
outlet stream.
2.3 Reverse Flow of bottom liquid outlet
stream, leading to potential high level in
R-500.
1 10 3 3. LV-506 malfunction partially closed 3.1. Less Flow from R-500, leading to
potential high level in R-500.
3.2. High level in R-500, leading to
potential low pressure in R-500.
1 10 4 4. LV-506 malfunction closed 4.1. Reverse Flow to R-500, leading to
potential high level in R-500
4.2. High level in R-500, leading to
potential low pressure in R-500.
1 10 5 5. SDV-508 malfunction closed Refer to item no. 1.10.4
HAZOP Worksheets
6.1.1. Low-Low Temperature Alarm and Trip System (TZALL505) is provided. Refer to recommendation No Flow above (2) Consultant
6.1.2. SDV-505 is provided.
6.1.3. V-422 drain valve is provided.
6.1.4. Low Temperature Controller Alarm (TICAL-507) is provided.
Refer to item no level above (1.3.1)
Refer to item no level above (1.3.2)
Refer to item no level above (1.3.3)
Refer to item no level above (1.4.1)
Refer to item no level above (1.4.2)
Refer to item no level above (1.4.3)
Refer to item no level above (1.4.4)
Refer to item no level above (1.4.5)
1.1.1. High-High Flow Alarm and Trip System (FZAHH502) is provided. Refer to recommendation No Flow above (7,8) Consultant
1.1.2. SDV-501 is provided. Refer to recommendation More Flow above (10)
1.1.3. SDV-502 is provided.
1.1.4. V-398 Drain Valve is provided.
1.1.5. PM-503 is provided.
1.1.6. I-503 is provided.
1.1.7. High Flow Controller (FICH-502) is provided.
1.1.8. High Flow Controller Alarm (FICAH-503) is provided.
1.2.1. V-407 Drain Valve is provided.
1.2.2. Low Temperature Controller (TICL-504) is provided.
1.3.1. High-High Level Alarm and Trip System (LZAHH506) is provided.
1.3.2. SDV-506 is provided.
1.3.3. V-420 Drain Valve is provided.
1.3.4. High Level Controller (LIC-506) is provided.
1.4.1. Low-Low Pressure Alarm and Trip System (PZALL504) is provided.
1.4.2. SDV-507 is provided.
1.4.3. Low Pressure Controller (PICL-505) is provided.
1.5.1. Low-Low Temperatur Alarm and Trip System (TZALL505) is provided.
1.5.2. SDV-505 is provided.
1.5.3. V-422 Drain Valve is provided.
1.5.4. Low Temperature Controller Alarm (TICAL-507) is provided.
Refer to item high level above (1.4.1) Refer to recommendation No Flow above (2). Consultant
Refer to item high level above (1.4.2) Refer to recommendation More Flow above (12).
Refer to item high level above (1.4.3)
2.3.1. V-425 drain valve is provided.
Refer to item high level above (1.3.1)
Refer to item high level above (1.3.2)
Refer to item high level above (1.3.3)
Refer to item high level above (1.3.4)
3.1.1. High-High Level Alarm and Trip System (LZAHH506) is provided. N/A Consultant
3.1.2. SDV-506 is provided.
3.1.3. V-425 drain valve is provided.
3.1.4. Low Flow Indicator Alarm (FIAL-508) is provided.
3.1.5. High Level Controller (LICH-506) is provided.
3.2.1. Low-Low Pressure Alarm and Trip System (PZALL504) is provided.
3.2.2. SDV-507 is provided.
3.2.3. Low Pressure Controller (PICL-505) is provided.
Refer to item high level above (3.1.1) Refer to recommendation More Flow above (12). Consultant
Refer to item high level above (3.1.2)
Refer to item high level above (3.1.3)
Refer to item high level above (3.1.4)
Refer to item high level above (3.1.5)
Refer to item high level above (3.2.1)
Refer to item high level above (3.2.2)
Refer to item high level above (3.2.3)
Refer to item no. 1.10.4 Refer to recommendation More Flow above (12). Consultant

1 11 1 Low Level 1. FV-501 malfunction partially closed 1.1. Less Flow to P-500, leading to break
down of P-500 due to pump minimum
flow.
1.2. Less Flow of water leading to
potential high temperature in E-500.
1.3. Under low level condition,leading to
loss of production due to less flow of
water flowing into R-500.
1.4. Less Flow to R-500, leading to
potential high pressure in R-500.
1.5. Less water flow of high temperature
water to R-500, leading to high
temperature in R-500.
1 11 2 2. M-503 malfunction partially closed Refer to item low level above (1.2)
Refer to item low level above (1.3)
Refer to item low level above (1.4)
Refer to item low level above (1.5)
1 11 3 3. LV-506 malfunction stuck opened 3.1 More flow from R-500, leading to
potential low level in R-500.
3.2 Low level in R-500, leading to high
pressure in R-500.
HAZOP Worksheets
1.1.1. Low-Low Flow Alarm and Trip System (FZALL501) is provided. Refer to recommendations No Flow above (1, 2,3). Consultant
1.1.2. SDV-502 is provided.
1.1.3. PM-503 is provided.
1.1.4. I-503 is provided.
1.1.5. Low Flow Controller (FICL-502) is provided.
1.1.6. Low Flow Controller Alarm (FICAL-503) is provided.
1.2.1. High-High Temperature Alarm and Trip System (TZAHH503) is
provided.
1.2.2. SDV-503 is provided.
1.2.3. V-408 drain valve is provided.
1.2.4. High Temperature Controller (TICH-504) is provided.
1.3.1. Low-Low Level Alarm and Trip System (LZALL506) is provided.
1.3.2. SDV-508 is provided.
1.3.3. Low Level Controller (LICL-506) is provided.
1.4.1. High-high Pressure Alarm and Trip System (PZAHH504) is provided.
1.4.2. PSV-500 is provided.
1.4.3. V-432 vent valve is provided.
1.4.4. SDV-504 is provided.
1.4.5. High Pressure Controller (PICH-505) is provided.
1.5.1. High-High Temperature Alarm and Trip System (TZAHH505) is
provided.
1.5.2. SDV-504 is provided.
1.5.3. SDV-506 is provided.
1.5.4. V-420 Drain Valve is provided.
1.5.5. High Temperature Controller Alarm (TICAH-507) is provided.
Refer to item low level above (1.2.1) Refer to recommendations No Flow above (4, 5). Consultant
Refer to item low level above (1.2.2)
Refer to item low level above (1.2.3)
Refer to item low level above (1.2.4)
Refer to item low level above (1.3.1)
Refer to item low level above (1.3.2)
Refer to item low level above (1.3.3)
Refer to item low level above (1.4.1)
Refer to item low level above (1.4.2)
Refer to item low level above (1.4.3)
Refer to item low level above (1.4.4)
Refer to item low level above (1.4.5)
Refer to item low level above (1.5.1)
Refer to item low level above (1.5.2)
Refer to item low level above (1.5.3)
Refer to item low level above (1.5.4)
Refer to item low level above (1.5.5)
3.1.1. Low-Low Level Alarm and Trip System (LZALL506) is provided. N/A Consultant
3.1.2. SDV-508 is provided.
3.1.3. High Flow Indicator and Alarm (FIAH-508) is provided.
3.1.4. Low Level Controller (LICL-506) is provided.
3.2.1. High-High Pressure Alarm and Trip System (PZAHH504) is provided.
3.2.2. SDV-504 is provided.
3.2.3. PSV-500 is provided.
3.2.4. V-432 vent valve is provided.
3.2.5. High Pressure Controller (PICH-505) is provided.