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Natural Gas Drying
Natural Gas Drying
Natural Gas Drying
part of Aker
Troll A
1. Introduction/motivation
2. Industrial examples
3. Theory drying
• Dehydration
4. Summary
snøhvit
Refinery and
petrochemicals
Pipe line
Sleipner Troll
1: Off shore to land, pipe line demands 3: LNG composition demands
2: Export pipe line, demands 4: Condensate composition
demands
Typical [1] Saturated 0-15 0-3 0-30 0-5 75-99 1-15 1-10 0-1
Background:
•Troll is located in the north part of the North Sea, about 65 km west of Kolsnes
• Ocean depth is above 300 meter
• The field is divided into Troll east and Troll west
• 2/3 of the recoverable gas reserve is located in the east
* Monoethylene Glycol (MEG) also called ethylene glycol (EG)
Slide 11 © 2008 Aker Solutions part of Aker
Troll
Dehydration system
MEG
(Pressure, BARG)
<Temperature, Celcius>
Lean gas to pipeline
(68.5) compressors
Turboexpander
Inlet gas <-11.7>
Suction drum (78.4) <-0.7>
separator
Feed gas from
slug catchers (90) (89.5) Dewpoint
<5> <-5.1> separator
(69.4)<-20.2> (67)
<-21>
(69)<-20.2>
Condensate
and Glycol
Q Q
Kristin is a high pressure field (900 in the well, choke sea bottom to 350 bar)
Ocean depth is about 350 meters
Gas is transported to Kårstø
Economic choice of technology; takes advantage of high well pressure and existing single phase
pipe-line to Kårstø
Full processing offshore to meet existing pipe-line spec (105 cricondenbar) inlet pipeline pressure
211 bar and 50 degrees Celsius
Gas is delivered at Kårstø at 100 bar
Slide 13 © 2008 Aker Solutions part of Aker
Kristin
Liquid separation system
To Dehydration system
Pres
<26> s
3st stage incre ure
(25) recompressor asing
<30>
(7)
Inlet wet 2st stage <30>
gas Inlet <112> recompressor (1.7)
separator (87)
1st stage
<120> recompressor
(26)
2nd stage
<Temperature, Celcius>
separator
(Pressure, BarA) <74>
pre (2.15)
red ssu
uc re 3rd stage
tio
n separator To condensate
storage
To separator
Q Q
Kristin is a high pressure field (900 in the well, choke sea bottom to 350 bar)
Ocean depth is about 350 meters
Gas is transported to Kårstø
Economic choice of technology; takes advantage of high well pressure and existing single phase
pipe-line to Kårstø
Full processing offshore to meet existing pipe-line spec (105 cricondenbar) inlet pipeline pressure
211 bar and 50 degrees Celsius
Gas is delivered at Kårstø at 100 bar
Slide 16 © 2008 Aker Solutions part of Aker
Kristin
De-hydration (TEG) system
Feed from
pipeline Slug Inlet CO2 De- Mercury
catcher separation Removal hydration Removal
To
pipeline MEG Condensate Natural gas LNG
Recovery treatment liquefaction storage
Condensate LPG
Fractionation
storage storage
Example of
Molecular sieves (pressure, barA)
<Temp, Celsius >
Hot Oil
• Absorption and refrigeration with hydrate inhibition is the most common dehydration
process used to meet pipeline sales specifications
• Adsorption processes are used to obtain very low water contents required in low
temperature processes, for example LNG
• TEG is most common in absorption systems
• MEG is most common in glycol injection systems
3. Non corrosive
Vapor pressure MEG DEG TEG T4EG
4. Low affinity for hydrocarbons and 25 C
acid gases
5. Thermal stability
Basic glycol properties
6. Easy regeneration
7. Low viscosity
8. Low vapor pressure at the contact
temperature
9. Low tendency to foam
Slide 25 © 2008 Aker Solutions part of Aker
Absorption Basic glycol dehydration unit
Dehydration
Simplified flow diagram for a glycol dehydration unit. from the GPSA Engineering Data Book, 11th
ed.
■ Absorber internal
One, two pass trays
● Tray Maximize
Reactor
■ Bubble cap Contact area
■ Valve and time
■ Sieve Gas/glycol
● Packing
■ Berl Saddle, Raschig Ring……
Bearl Saddle
Sieve tray
Bubble Cap tray
Slide 27 © 2008 Aker Solutions part of Aker
Absorption
Dehydration Absorber design
Design parameters
w Yb
flo
in gas
Bottom of gas phase
■ Working pressure e
P lin tower
■ Choice of absorbent Yt O Yb*
li n e
EQ Y* EQ mol frac.
Design procedure ol f lo w Water gas phase
Yt* Glyc
■ Mass balance circulate enough glycol to Mol fraction water
absorb the water in the gas
in glycol
■ Gas rate tank diameter (flooding)
Principal sketch assuming:
■ Equilibrium analysis number of equilibrium
stages • Mass transfer are controlled by
■ Real analysis, have to take into account the resistance on the gas side
reaction kinetic and contact time between
glycol and gas. Gives number of actual trays • Straight operation and equilibrium
■ Dryer glycol higher concentration lines of mol fraction water in the gas
differences higher reaction kinetic phase
higher efficiency more expensive and
No. of EQ stages
■
heavier glycol regeneration system
Higher glycol circulation rate higher
concentration differences higher reaction No. of actual stages
kinetic higher efficiency higher pressure
drop more expensive and heavier pumps
Slide 28 © 2008 Aker Solutions part of Aker
Absorption
Dehydration Glycol dehydration unit
Working principle
Heat
Water Re boiler
Exchanger
TEG unit
Heat
A; Stripping gas
■ Recharging of towers present no problems ■ Overheating of solutions may produce both low
and high boiling decomposition products
■ Materials that would cause fouling of some ■ The resultant sludge may collect on heating
solid adsorbents can be tolerated in the surfaces, causing some loss in efficiency, or, in
contactor severe cases, complete flow stoppage
■ When both oxygen and hydrogen sulfide is
present, corrosion may become a problem
because of the formation of acid material in the
glycol solution
■ Liquids such as water, light hydrocarbons or
lubrication oils in inlet gas may require
installation of an efficient separator ahead of
the absorber. Highly mineralized water entering
the system with inlet gas may, over long
periods crystallize and fill the re-boiler with solid
salts
■ Foaming of solution may occur with a resultant
carry-over of liquid. The addition of a small
quantity of antifoam compound usually
remedies this problem
Natural
gas
Pressure [Bar]
70
4-5 Dewpoint separator
5-6 Gas-gas heat exchanger 50
6-7 Compression
30
Temperature [C]
Lean gas to pipeline
Turboexpander
compressors
Suction drum
Dehydrated
6 Phase envelope based Troll, dehydrated gas
3 7
gas
Dewpoint
1 2 separator
4
5
Turbo expander process for
NGL extraction
Condensate
and Glycol
Slide 37 © 2008 Aker Solutions part of Aker
Dehydration by
cooling NGL
Joule Thompson cycle
recovery (Troll gas)
110
1 Feed gas Path turbo expander
Feed gas phase envelope
1-2 Gas-gas heat exchanger Path joule thompson 90
2-3 Suction drum
Pressure [Bar]
3-4 Valve expander 70
Condensate
and Glycol
Slide 38 © 2008 Aker Solutions part of Aker
Dehydration by
adsorption
Example of sorbents:
■ Silica gel (Gel type)
Outlet gas water content down to 10 ppm (v/v) and dew point -60 C can be achieved
Regenerated between 120 and 200 C
It adsorbs hydrocarbons, which are desorbed during regeneration
Silica gel is destroyed by free water which causes the granules to burst, and react with bases
■ Activated alumina Al2O3
Outlet gas water content <1 ppm (v/v), outlet dew point -73 C can be achieved
Heavy hydrocarbons are adsobed but can not be desorbed during regeneration
■ Molecular sieves (zeolites)
Outlet gas water content down to 0.03 ppm (v/v) , outlet dew point -100 C
Water is adsorbed in a micro porous structure
The presence of carbonyl sulfide (COS) and carbon disulfide (CS2) should be avoided
The adsorbent must be replaced frequently (about every three year)
The water content in the feed must be low
Slide 41 © 2008 Aker Solutions part of Aker
Dehydration
By sorption Principal sketch
Adsorbent system
Operation
Molecular sieves
Regeneration gas
Process gas
http://www.uop.com/objects/96%20MolecularSieves.pdf
Slide 42 © 2008 Aker Solutions part of Aker
Dehydration
by sorption Adsorption Dry gas
Concentration profiles
Active
Zone
Mass transfer
Zone
Equilibrium
Zone
Wet gas
Variation of adsorption zones with time and height Schematic view of reactor bed with adsorption zones
Fossil fuel
CO2
Combustion Flue gas N2 ,O2
Air separation
Energy CO2
Air
Fossil fuel
Gasification/ CO2
H2, CO2 H2 Combustion N2 ,O2 , H2O
Air/O2 Steam reforming separation
Capture
Current Emerging Current Emerging Current Emerging Current Emerging
technologies
* From IPCC special report on Carbon Dioxide Capture and Storage, 2005
Slide 48 © 2008 Aker Solutions part of Aker
Selcetion of CO2 capture technology
http://www.uop.com/gasprocessing/6010.html
Acid gas
Water
Make Up
Water Wash
Pumps
Regen. Acid Gas
Feedgas Reflux Condenser
(CW)
Amine Drum
Feed
Absorber Carbon
Gas
Filter
KO Drum (Lean Sol)
HP Lean
Pump
Lean Sol. Reflux
Cooler Pump
(CW) Flash gas
Amine
Regen-
erator
LP Lean
Pump Regen.
Reboiler
(LPS)
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