SRI CHAITANYA IIT ACADEMY, INDIA 06-04-2024_Sr.

C-120_Jee-Mains_ WTM-28_KEY & Sol’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur – Hyderabad
Sec: Sr. C-120 Jee Main Date: 06-04-24
Time: 09.30Am to 12.30Noon WTM-28 Max. Marks: 300

KEY SHEET
PHYSICS
1) 1 2) 4 3) 4 4) 2 5) 4
6) 1 7) 4 8) 3 9) 3 10) 1
11) 4 12) 4 13) 1 14) 4 15) 4
16) 3 17) 4 18) 4 19) 4 20) 1
21) 2 22) 136 23) 4 24) 2 25) 4
26) 753 27) 4 28) 1 29) 2791 30) 40

CHEMISTRY
31) 2 32) 2 33) 2 34) 3 35) 2
36) 4 37) 2 38) 3 39) 1 40) 3
41) 2 42) 1 43) 4 44) 2 45) 3
46) 2 47) 2 48) 1 49) 2 50) 4
51) 1 52) 9 53) 4 54) 3 55) 8
56) 49 57) 7 58) 0 59) 4 60) 5

MATHEMATICS
61) 4 62) 3 63) 1 64) 3 65) 2
66) 2 67) 1 68) 1 69) 3 70) 1
71) 4 72) 1 73) 2 74) 4 75) 4
76) 3 77) 3 78) 1 79) 4 80) 4
81) 1 82) 26 83) 7 84) 400 85) 1
86) 8 87) 4 88) 72 89) 1 90) 25
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SOLUTIONS
PHYSICS
1. Out of the rays given UV rays have maximum frequency hence are most effective for
emission of electrons from a metallic surface
2. Stopping potential does not depend on intensity or power of light used. KEmax depends on
frequency or wavelength of incident light.
3. The beam of electron due to its very small size show both diffraction and interference.
Davisson and Germer were the first to prove this through their famous experiment
12.27
4.  electron  A
V
5. Photoelectric saturation current is independent of frequency. It only depends on intensity of
light.
6. E  h
E  6.63  1034  6  1014  3.978  1019 J
P  ETotal per second  2  103 W
P
Noof photons 
Energyof each photon
2  103
 19
 5.03  1015 photon / sec
3.978  10
h h h
7.   v
p mv m
v1 m1  2 4 2 8
 .   
v2 m2 1 1  1
8. Incident frequency is less than threshold frequency.
9. Stopping potential is independent of intensity but depends on frequency & nature of emitter
material
10. From Einstein’s photo electric equation
hc hc 2hc
KE   .......1 KE /2   ....... 2 From (1) & (2) 
 /2 3
11. As stopping potential is independent of intensity. So there will be no change in the curve
hc hc hc hc
12. Using Equation   KEmax     .....1 3KEmax   ..... 2
  500 200

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hc
KEmax 3 200  
 2 by 1   Putting hc  1237.5 , therefore, work function
KEmax 1 hc  
500
  0.976  1019 J
hc hc  1 1  1237  120
13. KEmax  E  o KEmax    1237      1.5 eV  2.4  1019 J
 o  260 380  380  260
h
14. de-Broglie wavelength     2 m : 3m  1:1
p
15. Both UV rays and infrared rays have wave length less than 109 A
16. KE1  E  W  3  0.5  2.5eV KE2  E  W  4  1.5  2.5eV
KE3  E  W  5  2.5  2.5eV KE1 : KE2 : KE3  1:1:1
hc hc
17. W      3100A
 W
18. Conceptual
1 0.2  0.2
19. saturation curernt  2   18  2mA
r 0.6  0.6
20. As  increases saturation current also increases.
h h
21.   0  x 1 PE  E0 TE  2 E0
mv 2mk
h
KE  2 E0  E0  E0 1  x  1 PE  0
2mE0
2
h 1  
TE  2 E0 KE  2 E0 2   2  1  2
2m  2 E0  2   2
1.23nm 1.23 136
22.  V  81 V   109  1.36 A  A  x  136
V 81 100
23. KEmax  eV0  4eV
60
24. P  10W E in1sec 10 J E used   10  6
100
hc 6.63  1034  3  108 6.63  3
Energy used to take out 1 photon =    1017
 590  109 590
6
No. of Photons   1.77  1019  2
6.63  3
 1017
590
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25. mc  2mmoc 2 mv  2  1.67  10 27  9.1  1031  3  108

h 6.62  1034
mv  1.654  1020 kgm / s de-Broglie wavelength     20
 4  10 14
mv 1.654  10
 P4
hf 1 2 hf 7.43
26. K .E   mv   v  105  v  743  103 m / s
 2  100
KE of Photon hf 2hc
27.   4
KE of electron 1 mv 2 mv 2
2
9 h 6.63  1034
28.   663  10 ,   60    9
 10 27
 6.63  10
1
Force excerted  n  2  P cos   1  1019  2  1027   1  108 N
2
hc 1 WN t  W 5460  2.3
29. W W  t  N N   2790.66A  2791 A
  Wt  N Wt 4.5
1 2 hc 2hc 2hc
30. mv  mv 2    ph 
2  ph  ph mv2
h h
De-Broglie wavelength  p  
p mv
 ph 2hc / mv 2 2c 5 c c  ph
  vc    20  2  20  40
p h / mv v 100 20 v p

CHEMISTRY
31.  H 2 SO4  2  H 
SO2  2 H 2O 
SO2 gas is used as a bleaching agent. Its bleaching action is temporary due to its reducing
action.
32. H 2O  H 2Te  H 2 Se  H 2 S BP of H2O is due to H-bonding.
CO excess CO
33. 2  CaCO 
Lime water  3 
2  Soluble Ca HCO
3 2
SO excess SO
2  CaSO 
Lime water  3  3 2
2  Soluble Ca HSO

34. Cyclic trimer of SO3

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35. 2O3 
 3O2
2vol 3vol
9
3vol ?  4.5
2
O3  1.5
36. Bond order H 2O2  1 Bond length order is H 2O2  O3  O2
O2  2
37. SO2 is an anhydride of sulphurous acid
38. Oxidation state of Sulphur in S8 = Zero, Valency = 2

39. 3O2  2O3 ; H  142 kJ mol 1.

40.  Paramagnetic O3 
O2   Diamagnetic
41.
 n,
 Ar 3d 8.
n  2(lowest)
42. Zn,Cd and Hg have d10 completely filled electronic configuration. Hence their metallic
bonding is weak and so they are soft metals.
43. Conceptual
44. Conceptual
45. Interstitial compounds are chemically inert
46.  n  1 d 5ns 2
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47. Mn2 is stable than Mn3 due to d 5 configuration.

In aqueous solution Co2 is more stable than Co3
48. Pt(78)=  Xe  4 f 14 5d 9 6 s1
49. A)  2  5.92 BM B) E 0  Mn  Fe
Mn M 3 / M 2
C) Conceptual D) E 0  0.26V Negative SRP so displaces H 2 from Acids.
Cr 3 / Cr 2
50. Due to 3d10 configuration , Zn is not considered as transition element.
51. Ozone does not oxidise KMnO4
52. 2 I 2  9O3 
 I 4O9  9O2 Dry I 2 Is oxidised to yellow I 4O9
8
53. Atomicity of O2  2 Atomicity of sulphur = 8  Ratio  4
2
54. CO  Neutral CuO  Basic CrO3 , Mn2O7 , SO2  Acidic
55. S , Se, Te 
 Octa -atomic

56. Fe(26)   Ar  4 s 2 3d 6
n4
  n  n  2  BM
 4  4  2
 4.9
 49  101
57. Unpaired d-electrons: Coloured/paramagnetic
No unpaired d-electrons: Colourless/diamagnetic
10
58. (46) Pd   Kr  4d 5s 0 , n  0
59. Bronze - Cu  Sn
Brass - Cu  Zn
German Silver - Cu  Ni  Zn
60. They have ESRp o
 ve
Cu, Ag , Au , Hg , Pt

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MATHEMATICS
61.  ,  are the roots x 2  ax  b  0       a,   b
 ,  are the roots x 2  ax  b  0       a,   b
               

 
  2           2             2  a   b,  2    b

  2  a  b   2  a  b 

  b  b b  b  2b.2b  4b 2
62. For real roots we get q 4  4 p 2  0  q 2  2 p
If p  1  q  2,3, 4,5
p  2  q  2,3,4,5
p  3  q  3, 4,5
p  4  q  3, 4,5
p  5  q  4,5
Total number of different possibilities = 16
63. Now a  b  c, b  c  a, c  a  b.....etc.,
a 2  b 2  2 ab  c 2 ......1 b 2  c 2  2bc  a 2 ...... 2
x 2  a 2  2ca  b 2 ...... 3 1   2   3 we get
a 2  b2  c 2
  2........ 4  using AM  GM
ab  bc  ca
a2  b2 b2  c 2 c2  a 2
 ab  bc  ca
2 2 2
2 2 2 a 2  b2  c2 a 2  b2  c2
a  b  c  ab  bc  ca  1..... 5 1 2
ab  bc  ca ab  bc  ca
64. In triangle PQR , P  Q  R  180, R  90
P Q  P Q b c
P  Q  90    45  tan     1   1
2 2  2 2 a a
 b  a  c cab

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65.

2 x 4  11x3  44 x 2  76 x  48 2
x  2x  1 x  13 x  19
4 3 2
x  2x  x
  
13x 3  45 x 2  76 x  48
13x 3  26 x 2  13x
  
 19 x 2  63x  48
 19 x 2  38 x  19
  
25 x  67
Quotient is x 2  13x  19
66. Suppose the roots are imaginary. Then
1 1
   and        2  1
 
Which is not possible. The roots are real, so

 p2  q   0, b2  ac   0
Hence, statement 1 is correct.
Also, 2b / a     and   c / a ,     2 p,   q
If   1, then
  q  c  qa (which is not possible)
Also,
2b 2b
 1   2 p   b  ap (which is not possible)
a a
Hence, statement 2 is correct, but it is not correct explanation of statement 1
2 
 1 1 1  1 1 1 1 1 1
67. 2         2  2  2
            
2   1 9 2  2
      2    2
 4 4
1 1 1 1 2
Now           1
   2 2

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2
  2   2   2         2        4  2  1  6


  3   3   3  3        .  2   2   2       
  3   3   3  3   2  6   1  3 2   2  7  6  8

68.  
Since, one root of the quadratic equation a 2  5a  3 x 2   3a  1 x  2  0 is twice as large
as other, then let their roots be  and 2 .

   2  
 3a  1  3  
 3a  1

a 2  5a  3  a 2  5a  3  
2 2
And   .2   2 2 
 a2  5a  3  a2  5a  3
 3a  1 2 1
  3a  1  9  a

 2
9 a  5a  3

 a 2
 5a  3 
2 2

 5a  3

26 2
 45a  6a  27  1  a  
39 3
2 4 6 sin 2 x
69. We have, sin x  sin x  sin x  ..... 
2
 tan 2 x
1  sin x

2
So, exp    
sin 2 x  sin 2n x  .... ln 2  exp tan 2 x.ln 2  2tan x 
Now the roots of the equation x 2  9 x  8  0 are 1 and 8
2 2
2tan x  1 and 2tan x  8  tan 2 x  0.3
As x lies in first quadrant so only possibility is tan x  3 .
2

 1  tan x   2 2  3 
70. Let the roots of x 2  6 x  a  0 be  ,4 and that of x2  cx  6  0 be  and 3
   4  6 and 4  a and    3  c and 3  6
a 4
   a  8  x2  6x  8  0   x  4 x  2  0  x  2,4
6 3
And x 2  cx  6  0  22  2c  6  0  c  5  x2  5x  6  0
 x  2,3 Hence, common root is 2.

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2  28 2  6i 1 3 
71. Given, x 2  2 x  2  0 x    2  i
2 2 2 2 
i i
1 3 
  2  i  2e 3 &   2e 3
 2 2 
i14  i 2   i 2 
14 7 14
  2 e 3  128 e 3  ,   128  e 3 
   
   
 2 
14  14  128 2i  sin    128 3i
 3
 x 2  8 x  15, x  3 or x  5
2 
72. x  8 x  15   Case 1: x  3 or x  5
2

  x  8 x  15 ,  3 x5

x 2  8 x  15  2 x  7  0  x  5  3 Case 2: 3  x  5, x 2  8 x  15  2 x  7  0  x  4
Hence difference = 1  3
 1 2 
 5 5
73. 2
Given expression is x   5  3
log 3 5 log 3  x  3 3 log 3 5  3 
5 5
log 3 3  1  0
   
 
log3 5 log3 5. log3 5. log5 3 log3 5. log5 3 log5 3 log5 3
Take, 3 3 3  3 log3 5  5
2/3
 log5 3
3
3 log 5 3log3 5 3  log 3 2  3log3 5
3 5   5 log5 3
2/3

After putting the value, the equation is x 2  5 x  3  0 and roots are  & 
2     10 10 4 4
sum of roots =   product of roots = 
 3 3  3
10 4
Equation =x2  x   0 3x 2  10 x  4  0
3 3
1 1
74. Let 3   x  3   x  3 4 x  1  x
1 1
4 4
1 x
3
4  ....
2
 3 3 3 
4  x    12  x  3   3  rejected
 2 2 2

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75. We have f  x   x 2  2bx  2c 2 and g  x   x 2  2cx  b 2 ,  x  R 

2 2
 f  x   x  b  2c 2  b 2 and g  x     x  c   b 2  c 2
Now, f min  2c 2  b2 and g max  b2  c 2
Given; min f  x   max g  x   2c 2  b2  b2  c 2  c 2  2b2
c c c
 c  b 2
b
 2  2
b

b
  2,  
76.

d
 roots satisfy its equation  product of routs  
a
   1   1   As f    0 f  1  1  b  c  0  c  b  1
As  ,  ,   c,    1  c  c  1   1      1
      b    1  b  1
      b,      0 b  0 Now, x3  1  0

  1,   w,   w2 3b3  6c3  9 3  18 3  24 3  57

77. x 2  bx  1  0 [common root]

b 1 b 1
x2  x  b  0 x Put x  in equation
b 1 b 1
2
 b 1  b 1 2 2
     b  0   b  1   b  1 b  1  b  b  1  0
 b 1  b 1

 
 b 2  1  2b  b2  1  b b2  2b  1  0  2b 2  2b  b3  2b 2  b  0  b3  3b  0

 
 b b2  3  0  b2  3  b   3i  b  9
4

2 9
78. Let 9 tan x  P   P  10  P 2  10 P  9  0   P  9  P  1  0  P  1,9
P
2 2    
9tan x  1 or 9tan x  9 tan 2 x  0 or tan 2 x  1 x  0,   x    , 
4  2 2
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    
  tan 2  0   tan 2    tan 2   
 12   12 
2 2 2
 0  2  tan15   2 2  3     
   2 7  4 3 Then, 14  8 3  14   192
79. a  b  2c, c  d  2a  a  c  b  d
a & c satisfy (1) & (2) equation respectively a 2  2ac  5d  0& c 2  2ac  5b  0 on adding
2
both equations  a  c  2ac  5  b  d   0

 a  c 2  5 a  c  150  0 (as ab.cd  5d  5b ) a  c  15  a  b  c  d  30

80. ax2  2bx  5  0,
If  and  are roots of equations, then sum of roots
2b b 5 b2 5
2     and product of roots   2   
a a a a2 a
 b 2  5a  a  0
For x2  2bx  10  0;     2b and   10
b
and   10  is also root of x 2  2bx  10  0  b2  2ab 2  10a 2  0
a
1 5
By eqn. (i)  5a  10a 2  10a 2  0  20 a 2  5a  a  and b 2 
4 4
 2  20 and  2  5; Now,  2   2  5  20  25

81.
10

10 8
a10  2a8     2   

8

 
8  2  2  8  2  2     
6a9 6 9  9  
6  9  9  
 is root of x2  6x  2  0   2  2  6 
 Also,  is root of x2  6x  2  0   2  2  6 
  6    6  
8 8
6     9 9
  1
6    
9 9
6     9 9

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q r
82. Given,  and  are roots of px 2  qx  r  0, p  0     ,   .......1
p p
1 1  
Since, p, q and r are in A.P  2q  p  r........ 2 Also,   4  4
  
q 4r
     4    q  4r
p p
On putting the value of q in Equation (2) we get  2  4r   p  r  p  9r
q 4r 4r 4 r r 1 2 2
Now,        And               4
p p 9r 9 p 9r 9
16 4 16  36 2 52 2
             13
81 9 81 81 9
 x   x   x  31
83. Given          x
 2   3   5  30
31
Clearly LHS is integer so RHS also must be integer x  k (an integer)
30
So, x should be multiple of 30 So, possible values can be 0,30,60, ……990
84. Given x 2  18 x  30  2 x 2  18 x  45...... 1
Let x 2  18 x  30  y when y  0  y  2 y  15  y 2  4  y  15
Or y 2  4 y  60  0  y  10, 6 If y  10  x 2  18 x  30  10
i.e x 2  18 x  20  0..... 2 If y  6  x 2  18 x  30  60.... 3
(this is rejected because it gives imaginary roots)  from x 2  18 x  20  0
Products of the roots x1x2  20
2 1
85. Given x  2  2 3  2 3 , On cubing both sides, we get
2 1 2 1
 x  23  4  2  3.2 3.2 3  2 3  2 3   x  23  6  6 x  2  x3  6x2  6 x  2
 
86. Let t be the root of the given cubic where t can take values a, b, c hence
t 3  t 2  333t  1002  0 or t 3  1002  333t  t 2
  t 3   1002  333 t   t 2  3006  333 t  

  t 2  2 t1t2 
but  t  1 ;  t1t2  333  a3  b3  c3  3006  1000  2006

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87   2 2
Given equation p 2  q 2 x2  2q  p  r  x  q 2  r 2  0  px  q    qx  r  .... i 
Here,
x2  2 x  8  0
x2  4 x  2 x  8  0
 x  4  x  2   0
x  4, 2.
From (i),
q r
x ,
p q
Put
x  4
q r
q     4
p q
q  4 p , r  4 q
r  16 p
Take square both sides,
q 2  16 p 2 r 2  256 p 2
q2  r 2 16 p 2  256 p 2
   272.
p2 p2
1 2
88.    0,     7 and  
7
 1 1 1  1 
Now,            3     
     
 
0  3             0
  
 
      3
 
89.

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x 2  12 x   x  31  0
  x  x 2  11x  31  0  x 2  11x  31  1
 x 2  11x  30  0
x   5,6  , take x  5
x2  12 x  5  31  0  x2  12 x  36  0
x  6 but x   5,6   Nosolution,So m  0

Now
x2  5 x  2  4  0
x  2 x  2
x 2  5 x  14  0 x2  5 x  6  0
 x  7  x  2   0  x  3 x  2   0
x  7, 2
x  7, 2, 3  n  3
 m 2  mm  n2  n2  9
x 2  ax  b
90. Let y 
x2  2x  3

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 x2 1  y   x  a  2 y   b  3 y  0
x R  D0
  
 a 2  4 y 2  4ay  4 b  3 y  by  3 y 2  0 
 8 y 2  4 y  a  3  b  a 2  4b  0
 8 y 2  4 y  a  3  b  4b  a 2  0 .....1
Now compare with  y  5 y  4  0 {as the range is  5,4  }
y 2  y  20  0 ..... 2
8 4  a  3  b 4b  a 2
 
1 1 20
 2  a  3 b
 5 ab .... 3
And 160  a 2  4  a  5

a 2  4a  140  0
 a  14 a  10  0
a  14; a  10  rejected
a  14; b9
 a 2  b 2  2ab  196  81  2 14 9  25

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