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Thermal Energy
PV=C T=C
(V1,P1)
P (V1,P2)
V
Mathematical explanation:-
v2 V2
W =∫ ¿ W =∫ PdV
v1 V1
v1
c
W=∫ dv :- p=c/v
v
v 2
v1
1
W =ᴄ∫ dv
v
v 2
V2
W =ᴄln ( )
V1
Where PV=C
So,
&W=PVln V 2 /V 1
PV= n Rn T
n=m/M
m
&W = RnT
M
Rn
:- R=
M
V2
So W=mRTln
V1
This is the required equation of work done by isothermal process.
Work done in case of polytrophic process:-
v2
W.D=∫ CV ⁿdv
v1
1−n 1−n
P V V −P1 V 1 V 1
= 2 2 2
1−n
mR T 2−mR T 1
=
1−n
mR (T 2−T 1 )
= 1−n
This is the required work done in case of polytropic process
Volume is a state function so it will remain same in both process but the work is
not a state function it will be different in both cases temperature will same in
isothermal process but different polytropic process.