Section-II (CHEMISTRY)

Single Correct Type Questions

31. During the qualitative analysis of salt with cation
y2+, addition of a reagent (X) to alkaline solution
of the salt gives a rosy red precipitate. The
reagent (X) and the cation (y2+) present
respectively are:
(A) Dimethyglyoxime and Ni2+
(B) Dimethylglyoxime and Co2+
(C) Nessler’s reagent and Hg2+
(D) Nessler’s reagent and Ni2+
(A) Region - 4 (B) Region - 3
32. Few drops of a salt solution are shaken with (C) Region - 2 (D) Region – 1
chloroform and chlorine water. Chloroform layer
become violet, solution contains. 37. Which cation is detected by the flame test?
(A) NO 2– ion (A) Be2 (B) K+
(B) NO 3– ion (C) Mg2+ (D) Al3+
(C) Br– ion
(D) I– ion 38. Which of the following reaction (s) is relevant to
the microcosmic salt bead test?
33. Given below are two statements, which option is (A) Cr2O3 + 3B2O3  2Cr(BO2)3
correct? (B) CoO + ZnO  CoZnO2
Statement – I: Colourless cupric metaborates is (C) CoO + NaPO3  NaCoPO4
reduced to cuprous metaborates in a reducing (D) Al2(SO4)3 + 3Na2CO3  Al2O3 + 3Na2SO4 +
flame. 3CO2
Statement – II: Cuprous metaborates is obtained
by heating Boric anhydride and copper sulphate 39. Addition of solution of oxalate to an aqueous
in a oxidizing flame. solution of mixture of Ba2+, Sr2+ and Ca2+ will
(A) Statement (I) is true but statement (II) is precipitate
false. (A) Ca2+ (B) Ca2+ and Sr2+
2+ 2+
(C) Ba and Sr (D) All of these
(B) Statement (I) is false but statement (II) is
true.
40. NH 4 and K+ can be separated by:
(C) Both statement (I) and (II) are false.
(D) Both statement (I) and (II) are true. (A) HCl (B) HClO 4
(C) HNO3 (D) H 2SO 4
34. The reagent that distinguishes between silver and
lead salt is 41. [X] + dil.H2SO4  [Y];
(A) H2S gas in NH4OH Colourless gas with suffocating smell.
[Y] + K2Cr2O7 + H2SO4  Green solution
(B) dil. HCl solution added after this dissolved
So, [X] and [Y] are
in hot water.
(A) SO 32  and SO2 (B) Cl– and HCl
(C) NH4Cl (solid) + NH4OH (solution)
(D) (NH4)2CO3 (solid) + NH4OH (solution) (C) S2– and H2S (D) CO3–2 and CO2

35. The aqueous solution of salt gives white ppt with 42. FeCl3  Na 2S2O3  P   FeCl2  Na 2S4O6
BaCl2 solution, which is insoluble in acid and The compound ‘P’ in the question is:

base except conc. H 2SO 4 . The salt contains. (A) Na Fe S2O3   H2O 2  , pink colour

(A) Cl– (B) NO 3 (B) Na 2 Fe S2O3 2  , green colour

(C) I– (D) SO 2–
4 (C) Na  Fe S2O3 2  , violet colour

36. The combustion zone, which is hottest zone of (D)  Fe S2O3 2  Cl, red colour
Bunsen flame shown in the figure below is
[5]
43. Brown ring complex is unstable due to: NH4OH (excess)
3+
(A) Fe has +1 oxidation state which is unstable. 49. I. Fe + NH4OH Fe(OH)
3
Complex
(B) NO is odd electron species. NH OH (excess)
4
(C) CFSE of complex is very high. II.Cr3++ NH OH Cr(OH) Complex
4 3
(D) FeSO 4 is not a good absorber is NO.
Which of the following statement is correct?
44. In the test for iodine, I2 solution is treated with (A) In reaction I, complex formed is
sodium thiosulphate: 3
 Fe  NH3  
Na2S2O3 + I2  NaI +____  6
(A) Na2S4O6 (B) Na2SO4 (B) In reaction II, complex formed is
(C) Na2S (D) Na3ISO4 3
Cr  NH3  
 6

45. To avoid precipitation of hydroxides of Ni2+, (C) In reaction I, complex formation is not
Co2+ Zn2+ and Mn2+, along with those of Fe3+, possible
Al3+ and Cr3+, the third group solution should be (D) Both (B) and (C)
(A) Heated with few drops of conc. HNO3
(B) Treated with excess of NH4Cl 50. Match List-I with List-II:
(C) Concentrated by addition of NH 4 OH List-I List-II
(metal Ion)
(D) None of these (Group in Qualitative
Analysis)
46. Which of the following statement is correct?
(A) Fe3+ gives a deep green ppt. on adding 1. Mn2+ I. Group-III
K4[Fe(CN)6] solution 2. As3+ II. Group-IIA
(B) On boiling a solution having K+, Ca+2 and
3. Cu2+ III. Group-IV
HCO 3– we get a precipitate of K2[Ca(CO3)2]
(C) Manganese salts give a violet borax bead 4. Al3+ IV. Group-IIB
test in reducing flame
Choose the most appropriate answer from the
(D) From a mixed precipitate of AgCl and AgI
ammonia solution dissolves only AgCl options given below:
1 2 3 4
47. For the following Assertion and Reason, the (A) I II III IV
correct option is (B) III IV II I
Assertion (A): Salmon pink coloured complex (C) I IV II III
gives red colour solution on passing of moist (D) IV II III I
SO 2 .
Reason (R): Composition of red coloured Integer Type Questions
solution is unknown. 51. A + NH4SCN  Blood red colour The oxidation
(A) Both (A) and (R) are true and (R) is the number of metal ion of A is ____.
explanation for (A)
(B) Both (A) and (R) are false 52. The number of metals from the following which
(C) (A) is false and (R) is true give the Borax bead test is _____. Cr, Fe, Ni,
(D) Both (A) and (R) are true but (R) is not the Mn
explanation for (A)
53. Total number of iron atoms involve in a
molecule of Turnbull’s blue is ____.
48. Which of the following statements is incorrect?
(A) Fe3+ ion gives blood red colour with SCN– 54. To an aqueous solution containing ions such as
ion. Al3+, Zn2+,Ca2+,Fe3+,Ni2+,Ba2+ and Cu2+ was
(B) Fe2+ ion also gives blood red colour with added conc. HCl, followed by H2S.
SCN– ion. The total number of cations precipitated during
(C) On passing H2S into PbCl2 solution, a black this reaction is ___.
ppt of PbS is formed.
(D) Cupric ion react with excess of ammonia 55. Consider the sulphides HgS, PbS, CuS, Bi 2S3
solution to give deep blue colour of and CdS. Number of these sulphides insoluble in
[Cu(NH3)4]2+ ion. dil. HNO3 is ____.

[6]
56. Sodium sulphide react with sodium 58. How many of the following is/are preliminary
nitroprusside to form a purple coloured test for detecting ions?
compound. During the reaction, the change in (A) Borax bead test
oxidation state of iron is ___. (B) Flame test
(C) Brown ring test
57. An inorganic Compound ‘X’ on treatment with (D) Cobalt nitrate test
concentrated H2SO4 produces brown fumes and
gives dark brown ring with FeSO4 in presence of 59. Aqua regia is the mixture of conc.HCl and conc.
concentrated H2SO4. Also Compound ‘X’ give HNO3 in the ratio of X:Y, then the value of X+Y
black precipitate ‘Y’, when its solution in dilute is ____.
HCl is treated with H2S gas. The precipitate ‘Y’
on treatment with concentrated HNO3 followed 60. How many of the following hydroxides are
by excess of NH4OH further gives deep blue soluble in excess NaOH solution?
coloured solution. The total number of anions in Fe(OH)3, Al(OH)3, Cr(OH)3, Zn(OH)2
a molecule of compound ‘X’ is ___. Ni(OH)2, Mn(OH)2, Cu(OH)2

5
30
(A) (B) 
 6
  is 3 2
 1  i  (C) (D)
4 3
(B) 215 i
(C) –215 i (D) 65
66. If ,   0 and f (n)  n  n and
x2 2x  3 3x  4
3 1  f (1) 1  f (2)
62. If   2 x  3 3 x  4 4 x  5  Ax3  Bx 2  Cx  D 1  f (1) 1  f (2) 1  f (3)  K (1  ) 2 (1  ) 2 (  ) 2 ,
3x  5 5 x  8 10 x  17 1  f (2) 1  f (3) 1  f (4)
, then B + C is equal to
then K is equal to
(A) –1 (B) 1
(C) –3 (D) 9 (A) 1 (B) –1
1
(C)  (D)
z i 
63. Let z be a complex number such that 1
z  2i
5  2 2 
3
and z  . Then the value of z  3i is
2  1  sin 9  i cos 9 
67. The value of   is
(A) 10 (B)
7  1  sin 2  i cos 2 
2  9 9 
15
(C)
4
(D) 2 3 (A)
1
2
1 i 3  (B)
1
2
 3 i 
64. Let  and  be the roots of the equation (C) 
1
2
 3 i  (D) 
1
2

1 i 3 
x2 + x + 1 = 0. Then for in y  0 in R,
y 1  
 y  1 is equal to 2a ab ac
 1 y 68. If b  a 2b b  c  (a  b)(b  c)(c  a )  0 ,
(A) y(y2 – 1) (B) y(y2 – 3) c  a b  c 2c
(C) y3 (D) y3 – 1 then  is equal to
(A) a + b + c
65. Let (B) abc
    3  2i sin   (C) 4
A     ,   : is purely imaginary  .
  2  1  2i sin   (D) 1
Then the sum of the elements in A is
[7]