NIST Chemistry WebBook, SRD 69

Monoethanolamine
Formula: C2H7NO
Molecular weight: 61.0831
IUPAC Standard InChI: InChI=1S/C2H7NO/c3-1-2-4/h4H,1-3H2

IUPAC Standard InChIKey: HZAXFHJVJLSVMW-UHFFFAOYSA-N

CAS Registry Number: 141-43-5
Chemical structure:

This structure is also available as a 2d Mol file or as a computed 3d SD file

The 3d structure may be viewed using Java or Javascript.
Other names: Ethanol, 2-amino-; β-Aminoethanol; β-Aminoethyl alcohol; β-
Hydroxyethylamine; Aminoethanol; Colamine; Ethanolamine; Ethylolamine; Glycinol; MEA;
Olamine; Thiofaco M-50; 2-Amino-1-Ethanol; 2-Aminoethan-1-ol; 2-Aminoethanol; 2-
Hydroxyethanamine; 2-Hydroxyethylamine; NH2CH2CH2OH; β-Ethanolamine; Aethanolamin;
2-Aminoaethanol; 2-Aminoetanolo; Etanolamina; Kolamin; Monoaethanolamin; UN 2491;
USAF EK-1597; 2-Ethanolamine; 1-Amino-2-hydroxyethane; 2-Aminoethyl alcohol
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Information on this page:
Phase change data
References
Notes
Other data available:
Condensed phase thermochemistry data
Reaction thermochemistry data
Henry's Law data
Gas phase ion energetics data
Ion clustering data
IR Spectrum
Mass spectrum (electron ionization)
Gas Chromatography
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Phase change data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:

BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment

Weast and
Tboil 443.2 K N/A BS
Grasselli, 1989
Buckingham and
Tboil 444. K N/A BS
Donaghy, 1982
Anderson and
Tboil 444.15 K N/A Shimanskaya, Uncertainty assigned by TRC = 1.5 K; TRC
1969
Tboil 444.0 K N/A Lecat, 1947 Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
McDonald,
Tfus 283.46 K N/A Shrader, et al., Uncertainty assigned by TRC = 0.05 K; TRC
1959
Quantity Value Units Method Reference Comment
Teja and
Tc 671.4 K N/A Uncertainty assigned by TRC = 1.5 K; TRC
Rosenthal, 1991
Uncertainty assigned by TRC = 50. K; Tc >
Anselme and Teja,
Tc 670. K N/A 670 K, which was observed with
1990
decomposition; TRC
Quantity Value Units Method Reference Comment
 Teja and
Pc 80.30 bar N/A Uncertainty assigned by TRC = 0.40 bar; TRC
Rosenthal, 1991
Quantity Value Units Method Reference Comment
ΔvapH° 58. ± 3. kJ/mol AVG N/A Average of 9 values; Individual data points

Enthalpy of vaporization
ΔvapH Temperature
Method Reference Comment
(kJ/mol) (K)
Kim, Svendsen, et al.,
55.9 372. EB Based on data from 357. - 435. K.; AC
2008
Stephenson and
61.7 325. A Based on data from 310. - 444. K.; AC
Malanowski, 1987
McDonald, Shrader,
54.7 394. N/A Based on data from 379. - 443. K.; AC
et al., 1959, 2
Matthews, Sumner, et Based on data from 338. - 443. K. See
58.9 353. N/A
al., 1950 also Boublik, Fried, et al., 1984.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)

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Temperature
A B C Reference Comment
(K)
Matthews, Sumner, et Coefficents calculated by NIST
338.6 - 444.1 4.29252 1408.873 -116.093
al., 1950, 2 from author's data.

In addition to the Thermodynamics Research Center (TRC) data

available from this site, much more physical and chemical
property data is available from the following TRC products:

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compounds.
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compounds, binary mixtures and chemical reactions
SRSD 2 – Web Thermo Tables (WTT), "lite" edition
SRSD 3 – Web Thermo Tables (WTT), professional edition
 SRD 147 – Ionic Liquids Database
SRD 156 – Clathrate Hydrate Physical Property Database

References
Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989

CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s).,
CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Buckingham and Donaghy, 1982

Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and
Hall, New York, 1982, 1. [all data]

Anderson and Shimanskaya, 1969

Anderson, A.A.; Shimanskaya, M.V., Gas-Liquid Chromatography of some Aliphatic and Heterocyclic
Polyfunctional Amines: II. Solution Thermodyn. of Amines in Fix. Phas., Latv. PSR Zinat. Akad. Vestis,
Kim. Ser., 1969, No. 5, 527. [all data]

Lecat, 1947
Lecat, M., Orthobaric Azeotropes of Sulfides, Bull. Cl. Sci., Acad. R. Belg., 1947, 33, 160-82. [all data]

McDonald, Shrader, et al., 1959

McDonald, R.A.; Shrader, S.A.; Stull, D.R., Vapor Pressures and Freezing Points of 30 Organics, J. Chem.
Eng. Data, 1959, 4, 311. [all data]

Teja and Rosenthal, 1991

Teja, A.S.; Rosenthal, D.J., The critical pressures and temperatures of ten substances using a low
residence time flow apparatus in Experimental Results for Phase Equilibria and Pure Component
Properties, DIPPR DATA Series No. 1, 1991. [all data]

Anselme and Teja, 1990

Anselme, M.J.; Teja, A.S., The critical properties of rapidly reacting substances, AIChE Symp. Ser.,
1990, 86, 279, 128-32. [all data]

Kim, Svendsen, et al., 2008

Kim, Inna; Svendsen, Hallvard F.; Børresen, Eli, Ebulliometric Determination of Vapor-Liquid Equilibria
for Pure Water, Monoethanolamine, N -Methyldiethanolamine, 3-(Methylamino)-propylamine, and Their
Binary and Ternary Solutions, J. Chem. Eng. Data, 2008, 53, 11, 2521-2531,
https://doi.org/10.1021/je800290k . [all data]