PRODUCT: METHYLTIN MERCAPTIDE YR-181 Date: May 12, 2017

SAFETY DATA SHEET

SECTION 1 - PRODUCT IDENTIFCATION

Product Name: METHYLTIN MERCAPTIDE Company:

CODE: YR-181 YUNTINIC RESOURCES, INC.
DOT Name: NOT APPLICABLE 2050 PIONEER COURT, SAN MATEO, CA 94403
Tel: 267-303-4760 Fax: 650-312-9286
Synonyms: YT-181; YR-141; PVC HEAT STABILIZER E-MAIL: STEVE@YUNTINIC.COM

Chemical Family: PVC HEAT STABILIZERS; ALKYL TIN Emergency Telephone No.:
& ORGANOTIN COMPOUNDS USA – CHEMTREC: 1-800-424-9300
Chemical Formula: MIXTURE OF MONO & DI AKYLTIN MERCAPTIDES Outside USA/Canada: 1-703-527-3887

CAS Number: SEE SECTION 3 Revision Date: October 18, 2017

Recommended Use: HEAT STABILIZER FOR PVC

SECTION 2 - HAZARD IDENTIFICATION

LABELLING:

STATE / FORM OF THE SUBSTANCE: TRANSPARENT LIQUID (@ 20 °C)

ODOR: SULPHUROUS

SIGNAL WORD: WARNING

HAZARD STATEMENTS:

HEALTH HAZARDS:
ACUTE TOXICITY - ORAL: ACUTE TOXICITY CATEGORY 4; H302: HARMFUL IF SWALLOWED.
ACUTE TOXICITY - DERMAL: ACUTE TOXICITY CATEGORY 4; H312: HARMFUL IN CONTACT WITH SKIN.
SKIN SENSITIZATION: SKIN SENSITIZATION CATEGORY 1; H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
REPRODUCTIVE TOXICITY: CATEGORY 2; H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN
CHILD.
GERM CELL MUTAGENICITY: CATEGORY 2; H341: SUSPECTED OF CAUSING GENETIC DEFECTS.
SPECIFIC TARGET ORGAN TOXICITY – SINGLE: STOT SINGLE EXPOSURE CATEGORY 3; H335: MAY CAUSE
RESPIRATORY IRRITATION (AFFECTED ORGANS: RESPIRATORY SYSTEM; ROUTE OF EXPOSURE:
INHALATION).
SPECIFIC TARGET ORGAN TOXICITY – REPEATED: STOT REPEATED EXPOSURE CATEGORY 2; H373: MAY
CAUSE DAMAGE TO ORGANS (AFFECTED ORGANS: NERVOUS SYSTEM; ROUTE OF EXPOSURE: ORAL).
ENVIRONMENTAL HAZARDS - CHRONIC: CATEGORY 3; H412: HARMFUL TO AQUATIC LIFE WITH LONG
LASTING EFFECTS.

PRECAUTIONARY STATEMENTS:

PREVENTION:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202: DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P272: CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280: WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING. WEAR PROTECTIVE
GLOVES/CLOTHING AND EYE/FACE PROTECTION.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.

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PRODUCT: METHYLTIN MERCAPTIDE YR-181 Date: May 12, 2017

RESPONSE:
P302 + P352+ P303 + P361 + P353: IF ON SKIN (OR HAIR): WASH WITH PLENTY OF SOAP AND WATER. TAKE OFF
IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/SHOWER.
P304 + P340: IF INHALED: REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P305 + P351 + P338: IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT
LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P308+P313: IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P333 + P313: IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.

STORAGE:
P405: STORE LOCKED UP.
P404 + P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.

DISPOSAL:
P501: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATION.

SECTION 3 - COMPOSITION

COMPONENT CAS NO. % PEL/TLV

3
DIMETHYLTIN BIS (2-ETHYLHEXYL 57583-35-4 90-10 0.1 mg/m OSHA & ACGIH TWA AS Sn
3
MERCAPTOACETATE) 0.2 mg/m ACGIH STEL* AS Sn
[DANGER OF SKIN ABSORPTION]
3
METHYLTIN TRIS (2-ETHYLHEXYL 57583-34-3 10-90 0.1 mg/m OSHA & ACGIH TWA AS Sn
3
MERCAPTOACETATE) 0.2 mg/m ACGIH STEL* AS Sn
[DANGER OF SKIN ABSORPTION]

2-ETHYLHEXYL THIOGLYCOLATE 7659-86-1 1-5

*SHORT TERM EXPOSURE LIMIT

SECTION 4 - FIRST AID MEASURES

SKIN: REMOVE ALL CONTAMINATED CLOTHING AND SHOES. WASH WITH SOAP AND PLENTY OF
WATER. IF IRRITATION OCCURS AND PERSISTS, SEEK MEDICAL ATTENTION. WASH
CONTAMINATED CLOTHING BEFORE REUSE. DO NOT TAKE CLOTHING HOME TO BE
LAUNDERED.

EYES: FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS,
SEEK MEDICAL ATTENTION.

INHALATION: MOVE TO FRESH AIR. BEGIN RESCUE BREATHING IF REQUIRED, AND SEEK MEDICAL
ATTENTION.

INGESTION: DRINK 1 OR 2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS

PERSON. GET IMMEDIATE MEDICAL ATTENTION. INDUCE VOMITING ONLY UNDER THE
DIRECTION OF MEDICAL PERSONNEL.

NOTE TO PHYSICIANS: MAY CAUSE SENSITIZATION TO SUSCEPTIBLE PERSONS.

SECTION 5 - FIRE FIGHTING MEASURES

FLASH POINT (°C):

FOR METHYLTIN TRIS (2-ETHYLHEXYL MERCAPTOACETATE): 140 ± 2 (CLOSED CUP)
FOR DIMETHYLTIN BIS (2-ETHYLHEXYL MERCAPTOACETATE): 156 ± 2 (CLOSED CUP)

FLAMMABILITY (AUTOIGNITION TEMPERATURE °C):

FOR METHYLTIN TRIS (2-ETHYLHEXYL MERCAPTOACETATE): 252 ± 5
FOR DIMETHYLTIN BIS (2-ETHYLHEXYL MERCAPTOACETATE): 238 ± 5

EXTINGUISHING MEDIA: WATER: (X – as spray) FOAM: (X) CO2: (X) DRY CHEMICAL: (X)

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PRODUCT: METHYLTIN MERCAPTIDE YR-181 Date: May 12, 2017

SPECIAL FIRE FIGHTING PROCEDURES:
COMBUSTIBLE LIQUID – PRODUCT WILL BURN AT ELEVATED
TEMPERATURES. FIREFIGHTERS MUST WEAR SELF-CONTAINED
BREATHING APPARATUS AND FULL PROTECTIVE GEAR. HARMFUL AND
IRRITATING FUMES CAN BE EVOLVED (CARBON OXIDES, SULFUR
OXIDES AND HYDROCARBONS).

UNUSUAL FIRE & EXPLOSION HAZARDS: CONTAINERS EXPOSED TO INTENSE HEAT UNDER FIRE CONDITIONS
MAY RUPTURE DUE TO FUME GENERATION AND / OR PRESSURE
BUILD-UP. USE WATER SPRAY TO COOL UNOPENED CONTAINERS.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE OF SPILL OR LEAK:

KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK. MATERIAL CAN CREATE SLIPPERY CONDITIONS. VENTILATE SPILL
AREA AND ELIMINATE ALL SOURCES OF IGNITION. WEARING FULL PROTECTIVE EQUIPMENT, INCLUDING SELF CONTAINED
BREATHING APPARATUS WHEN ENTERING AREAS OF UNKNOWN AIRBORNE CONCENTRATION (SEE SECTION 8), STOP
SOURCE OF LEAK OR SPILL. CONTAIN SPILL AND COVER WITH SAND, DRY CHEMICAL ABSORBENT OR OTHER INERT
MATERIAL. USING NON-SPARKING UTENSILS, SCOOP OR SHOVEL MATERIAL (INCLUDING ANY CONTAMINATED SOIL) INTO
CLEAN, DRY CONTAINERS FOR PROPER DISPOSAL. DO NOT RELEASE TO SEWER SYSTEMS, NATURAL BODIES OF WATER, OR
THE ENVIRONMENT.

SECTION 7 - HANDLING & STORAGE

FOR INDUSTRIAL USE ONLY

HANDLING & STORAGE INFORMATION: USE PROTECTIVE EQUIPMENT WHEN HANDLING (SEE SECTION 8). PROPERLY GROUND
ALL HANDLING AND PROCESSING EQUIPMENT. AVOID BREATHING MISTS AND VAPORS. AVOID SKIN AND EYE CONTACT.
AVOID PROLONGED OR REPEATED OVEREXPOSURE. DO NOT INGEST. WASH THOROUGHLY AFTER HANDLING AND CLEAN
CONTAMINATED CLOTHING. KEEP CONTAINER SEALED WHEN NOT IN USE. STORE IN A COOL, DRY, WELL-VENTILATED AREA
AWAY FROM HIGH HEAT AND IGNITION SOURCES. IF MATERIAL IS TRANSFERRED TO OTHER CONTAINERS, USE ONLY
PLASTIC, STAINLESS STEEL OR GLASS CONTAINERS – DO NOT USE STANDARD IRON DRUMS.

OTHER PRECAUTIONS: DO NOT EAT, DRINK OR SMOKE WHILE USING MATERIAL. AVOID CONTACT WITH ACIDS AND STRONG
OXIDIZING AGENTS.

SECTION 8 - EXPOSURE CONTROLS & PERSONAL PROTECTION

THRESHOLD LIMIT VALUE: 0.1 mg/m3 - 8 HOUR TIME WEIGHTED AVERAGE (TWA) AS TIN (Sn)
OSHA PEL: 0.1 mg/m3 TWA AS Sn
ACGIH TLV: 0.1 mg/m3 TWA AS Sn; 0.2 mg/m3 STEL AS Sn
PRIMARY ROUTES OF EXPOSURE: SKIN, EYES, INHALATION, INGESTION
RESPIRATORY EQUIPMENT: USE NIOSH APPROVED DUST / VAPOR RESPIRATOR OR SELF-CONTAINED BREATHING
APPARATUS IN ACCORDANCE WITH 29 CFR 1910.134
PROTECTIVE GLOVES: CHEMICAL RESISTANT GLOVES
EYE PROTECTION: CHEMICAL GOGGLES
VENTILATION: LOCAL EXHAUST OR PROCESS ENCLOSURES TO MINIMIZE AIRBORNE CONCENTRATIONS
OTHER PROTECTIVE EQUIPMENT: COVERALLS, LABCOAT, BOOTS, ACCESS TO EYEWASH FOUNTAIN AND SAFETY SHOWER

SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES

BOILING POINT (°C): >220 DENSITY (g/m3): 1.17

MELTING POINT (°C): <-60 °C FREEZING POINT (°C): <-50 °C
VAPOR PRESSURE (mm Hg): ~ 0.5 (@ 20 °C) PERCENT VOLATILE (BY WT.): NOT KNOWN
VAPOR DENSITY (AIR=1): ~ 4.5 EVAPORATION RATE: NOT KNOWN
SOLUBILITY IN WATER: INSOLUBLE pH (% IN WATER): NOT KNOWN
ODOR THRESHOLD: NOT KNOWN
APPEARANCE & ODOR: CLEAR TO LIGHT YELLOW LIQUID; MILD SULPHUROUS ODOR

SECTION 10 - STABILITY & REACTIVITY

STABILITY: STABLE AT AMBIENT TEMERATURE

INCOMPATIBILITY: ACIDS AND STRONG OXIDIZING AGENTS.

HAZARDOUS DECOMPOSITION PRODUCTS: THERMAL DECOMPOSITION/COMBUSTION CAN YIELD TOXIC FUMES OF SO OR TIN OXIDE
X
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR

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PRODUCT: METHYLTIN MERCAPTIDE YR-181 Date: May 12, 2017

CONDITIONS TO AVOID: EXTREMES OF TEMPERATURE AND DIRECT SUNLIGHT; OPEN STORAGE; HIGH HEAT, SPARK,
FLAME, IGNITION SOURCES; CONTACT WITH ACIDS; CONTACT WITH WATER / MOISTURE - HYDROLYZES IN WATER /
MOISTURE, DIMINISHING ITS PERFORMANCE

SECTION 11 - TOXICOLOGICAL INFORMATION

METHYLTIN TRIS (2-ETHYLHEXYL MERCAPTOACETATE):

ORAL LD50 BODY WEIGHT (RAT): 0.88 g/kg.
DERMAL LD 50 (RABBIT): 2.15 g/kg (in male) AND 1.0 g/kg (in female).
INHALATION LC50 (RAT): 240 mg/L/h.
DERMAL IRRITATION (RABBIT): PRIMARY IRRITATION INDEX OF 0.25 (METHOD: OECD 404).
EYE IRRITATION (RABBIT): CAUSED CONJUNCTIVAL IRRITATION WHICH CLEARED BY 48 HOURS.

DIMETHYLTIN BIS (2-ETHYLHEXYL MERCAPTOACETATE):

ORAL LD50 BODY WEIGHT (RAT): 1.15 g/kg.
DERMAL LD 50 (RABBIT): >1.05g/kg (both sexes).
DERMAL IRRITATION (RABBIT): PRIMARY IRRITATION INDEX OF 1.75 (METHOD: OECD 404)

LISTED CARCINOGEN: NONE ( ) OSHA ( ) NTP ( ) IARC ( ) OTHER (X**)

** ACGIH —A4: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN

SECTION 12 - ECOLOGICAL INFORMATION

ACUTE TOXICITY: MAY BE HARMFUL TO AQUATIC ORGANISMS WITH LONGTERM EFFECTS:

METHYLTIN TRIS (2-ETHYLHEXYL MERCAPTOACETATE):

MICROORGANISMS EC50 (3-HRS) >1,000 mg/L (METHOD: OECD 209).
FRESHWATER ALGAE (SCENEDESMUS SUBSPICATUS) EC50 (72-HRS): >1.8 mg/L
(METHOD: OECD 201).
ZEBRA FISH (BRACHYDANIO RERIO) EC50 (96 HRS): >6 mg/L (METHOD: OECD 203).

DIMETHYLTIN BIS (2-ETHYLHEXYL MERCAPTOACETATE):

FRESHWATER ALGAE (SELENASTRUM CAPRICORNUTUM) EC50 (72-HRS): 270 mg/L BASED ON
GROWTH RATE (METHOD: OECD 201).
AQUATIC INVERTEBRATES (DAPHNIA MAGNA) EC50 (48-HRS): 32 mg/L (METHOD: OECD 202).
FATHEAD MINNOWS (PIMEPHALES PROMELAS) EC50 (96-HRS): >1,000 mg/L (METHOD OECD 203).

BIODEGRADATION: DUE TO MICROBIAL ACTIVITY, ORGANOTIN COMPOUNDS USED AS STABILIZERS ARE GENERALLY
NOT PERSISTENT IN THE ENVIRONMENT. ORGANOTIN STABILIZERS EVENTUALLY DEGRADE INTO
INORGANIC TIN. BIOLOGICAL DEGRADATION OF METHYLTIN COMPOUNDS SHOWED HALF LIVES
BETWEEN A FEW DAYS TO SEVERAL WEEKS AND DECREASED WITH HIGHER TEMPERATURES.

SECTION 13 - DISPOSAL CONSIDERATIONS

WASTE DISPOSAL INFORMATION:

RECLAIM OR RECYCLE ANY USABLE MATERIAL. DISPOSE OF WASTE VIA LICENSED WASTEHAULER IN AN EPA
APPROVED LANDFILL OR INCINERATE. FOLLOW ALL FEDERAL, STATE AND LOCAL REGULATIONS.
RCRA HAZARDOUS WASTE: NO (X) YES ( ) RCRA # : ( )
CERCLA: NO (X) YES ( ) RQ ( )
FOR STATE OF CALIFORNIA: THIS PRODUCT CONTAINS ONE OR MORE SUBSTANCES THAT ARE LISTED AS A
HAZARDOUS WASTE.

FOLLOW ALL LOCAL, STATE AND FEDERAL INFORMATION AND REGULATIONS

SECTION 14 - TRANSPORT INFORMATION

DOT REGULATED: YES: ( ) NO: (X*) RQ: ( )

*THOUGH AN ORGANOTIN COMPOUND, THIS PRODUCT DOES NOT MEET THE DEFINITION OF THE 6.1 HAZARD CLASS.

IF REGULATED, PROPER SHIPPING NAME: NOT APPLICABLE HAZARD CLASS: ( )

IDENTIFICATION NO.: ( ) PACKING GROUP: ( ) LABEL REQUIRED: ( )

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PRODUCT: METHYLTIN MERCAPTIDE YR-181 Date: May 12, 2017

IMDG (FOR 2-ETHYLHEXYL THIOGLYCOLATE):

UN NUMBER: 3082; PROPER SHIPPING NAME: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.; HAZARD CLASS: 9; PACKING GROUP III (MINOR DANGER).

EMERGENCY RESPONSE GUIDE (ERG) NO.: 171

SECTION 15 - REGULATORY INFORMATION

TSCA: LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY.
DSL/NDSL: LISTED ON THE CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST.
EINECS/ELINCS: LISTED ON THE EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST
OF NOTIFIED CHEMICAL SUBSTANCES.
IECSC: LISTED ON THE CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES.
ENCS: LISTED ON THE JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES.

SARA TITLE III, SECT. 313: LISTED ( ) NOT LISTED (X)

SECTION 16 - OTHER INFORMATION

NATIONAL FIRE PROTECTION ASSOCIATION (NFPA):

HEALTH HAZARDS: 2
FLAMMABILITY: 1
INSTABILITY: 0
PHYSICAL AND CHEMICAL PROPERTIES: -

HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS):

HEALTH HAZARDS: 2 (CHRONIC HEALTH HAZARD)

FLAMMABILITY: 1
PHYSICAL HAZARDS: 0
PERSONAL PROTECTION: X

IN ACCORDANCE WITH GOOD PRACTICES OF PERSONAL HYGIENE, HANDLE WITH DUE CARE AND AVOID ANY
UNNECESSARY CONTACT WITH THIS PRODUCT. USE RECOMMENDED PERSONAL PROTECTION WHEN HANDLING (SEE
SECTION 8).

THIS INFORMATION IS BEING SUPPLIED TO YOU UNDER OSHA "RIGHT TO KNOW” REGULATION 29 CFR 1910.1200 AND IS
OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS PRODUCT SPECIFICATION. THE INFORMATION IS BELIEVED TO
BE TRUE AND ACCURATE. NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THIS DATA, THE
HAZARD CONNECTED WITH USE OF THE MATERIAL, OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF, IS
MADE. YUNTINIC RESOPURCES, INC. AND ITS SUPPLIERS ASSUME NO RESPONSIBILITY FOR DAMAGE OR INJURY FROM
THE USE OF THE PRODUCT DESCRIBED HEREIN.

OUR PRODUCTS ARE INTENDED FOR SALE ONLY TO INDUSTRIAL AND COMMERCIAL CUSTOMERS. THE CUSTOMER IS
RESPONSIBLE FOR DETERMINING WHETHER PRODUCTS AND THE INFORMATION IN THIS DOCUMENT ARE APPROPRIATE
FOR CUSTOMER'S USE AND FOR ENSURING THAT CUSTOMER'S WORKPLACE AND DISPOSAL PRACTICES ARE IN
COMPLIANCE WITH APPLICABLE LAWS AND OTHER GOVERNMENT ENACTMENTS.

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