07 12 16 - SR - IIT IZ CO SPARK - RPTA 13 - 2015 - P1 - Q.P

RPTA-13
NARAYANA IIT ACADEMY

INDIA
Sec: Sr.IIT-IZ-CO-SPARK Date: 07-12-16
Time:09.00 AM to 12.00 Noon Max. Marks:264
Name of the Student: ___________________ H.T. NO:

PAPER-I
07-12-16_Sr.IIT-IZ-CO-SPARK_RPTA-13_Weekend Syllabus
MATHS:
TRIGONOMETRY:TRIGONOMETRY UPTO TRANSFORMATIONS, GENERAL SOLUTIONS
PHYSICS:
E M I & AC : Magnetic flux calculation, Faraday’s laws Lenz’s law, Motional EMF, Induced
electric filed ,Self and mutual induction, L-R,C-R,L-C-R circuits, L-C Oscillations with D-C source,
LCR series circuit with AC , resonance: Quality factor, Power in AC circuits, Wattless current.
CHEMISTRY:
Atomic Structure, Stoichiometry Surface Chemistry

Narayana IIT Academy 07-12-16_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2015_P1)_RPTA-13_Q.Paper
JEE-ADVANCE-2015-P1-Model
Time: 3:00 Hours IMPORTANT INSTRUCTIONS Max Marks: 264
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 9 – 18) Questions with Multiple Correct Choice 4 -2 10 40
Matrix Matching
Sec – III(Q.N : 19 – 20) (+2/-1 for every match) 2 -1 2 16
Total 20 88
CHEMISTRY:
Matrix Matching
Total 20 88
MATHEMATICS:
Matrix Matching
Total 20 88
Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 2

PHYSICS Max Marks : 88
SECTION – I
(INTEGER ANSWER TYPE )
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
1. Two concentric and coplanar circular coils have radii a and b(>>a)as shown in figure.
Resistance of the inner coil is R. Current in the outer coil is increased from 0 to i, then
0i 2
the total charge circulating the inner coil is . Find the value of x = ?
xRb
2. A triangular wire frame (each side = 2m) is placed in a region of time variant
magnetic field having dB/dt = 3 T/s. The magnetic field is perpendicular to the plane
of the triangle. The base of the triangle AB has a resistance 1  while the other two
sides have resistance 2 each. The magnitude of potential difference between the
x
points A and B will be (volts). Find x = ?
10

3. In an RLC series circuit shown in figure, the readings of voltmeters V1 and V2 are 100 V
and 120 V, respectively. The source voltage is 130 V. For this situation the power factor
x
of the circuit is . the find x=?
13
V2
V1
~
V
4. A long straight wire is arranged along the symmetry axis of a toroidal coil of rectangular
cross-section, whose dimensions are given in the figure. The number of turns on the coil
is N, and relative permeability of the surrounding medium is unity. If the current
i  im cos t flows along the straight wire, then the amplitude of the emf induced in this
0 him N
coil, is : ln . Find x = ?
x


5. A uniform magnetic field B fills a cylindrical volumes of radius R. A metal rod CD of
length l is placed inside the cylinder along a chord of the circular cross-section as shown
in the figure. If the magnitude of magnetic field increases in the direction of field at a
1 dB 12
constant rate dB/dt, then the magnitude of the EMF induced in the rod is R2  .
x dt 4
Find x = ?
6. The time constant of an inductive coil is 2 10 3 second. When 90 resistance is added
in series, the time constant reduces to 0.5 103 second. If inductance of the coil is
n 10 2 Henry. Find n?
7. A rod of mass m  2 kg and length l  3m rotates about an axis passing through one end
O and perpendicular to its length. The other end of rod A, slides without friction on a
circular conducting rail (negligible resistance). A resistor R is connected to the rod and
rail as shown. The whole set up lies in horizontal plane with uniform magnetic field B

directed in to the plane of ring. The rod is given an angular speed 0 and released. The
total heat generated in the resistor R is 27 J. Find the value of 0 in rad/s.
8. A uniform disc of radius r and mass m is charged uniformly with the charge q. This
disc is placed flat on a rough horizontal surface having coefficient of friction  . A
uniform magnetic field is present in a circular region (a > r) but varying as kt3 as
shown in figure. Find the time in second after which the disc begins to rotate.
(Given r = 1 m, m = 18 kg, q = 1C,  = 0.1, K = 4, g = 10 m/s2)
Disc
B
a
r

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
9. Figure shown plane figure made of a conductor located in a magnetic field along the
inward normal to the plane of the figure. The magnetic field starts diminishing. Then the
induced current
A) at point P is clockwise
B) at point Q is anticlockwise
C) at point Q is clockwise
D) at point R is zero
10 Two circular coils P & Q are fixed coaxially & carry currents I1 and I2 respectively

A) if I2 = 0 & P moves towards Q, a current in the same direction as I1 is induced in Q

B) if I1 = 0 & Q moves towards P, a current in the opposite direction to that of I2 is
induced in P.
C) when I1  0 and I2  0 are in the same direction then the two coils tend to move
apart .
D) when I1  0 and I2  0 are in opposite directions then the coils tends to move apart.
11. AB and CD are smooth parallel rails, separated by a distance l, and inclined to the
horizontal at an angle . A uniform magnetic field of magnitude B, directed vertically
upwards, exists in the region. EF is a conductor of mass m, carrying a current i. For EF
to be in equilibrium,
B F D
C  B
l
E

A
A) i must flow from E to F B) Bil = mg tan 
C) Bil = mg sin  D) Bil = mg
12. For L – R circuit, the time constant is equal to
A) twice the ratio of the energy stored in the magnetic field to the rate of the dissipation
of energy in the resistance.
B) the ratio of the energy stored in the magnetic field to the rate of dissipation of energy
in the resistance.
C) half of the ratio of the energy stored in the magnetic field to the rate of dissipation of
energy in the resistance.
D) square of the ratio of the energy stored in the magnetic field to the rate of dissipation
energy in the resistance.
13. An inductor L, a resistance R and two identical bulbs B1 and B2 are connected to a
battery through a switch S as shown in the figure. The resistance of coil having
inductance L is also R. Which of the following statement gives the correct description of
the happenings when the switch S is closed?
A) The bulb B2 lights up earlier than B1 and finally both the bulbs shine equally bright.
B) B1 light up earlier and finally both the bulbs acquire equal brightness.
C) B2 lights up earlier and finally B1 shines brighter than B2.
D) B1 and B2 light up together with equal brightness all the time.

14. Two different coils have self inductance 8mH and 2mH. The current in one coil is
increased at a constant rate. The current in the second coil is also increased at the same
constant. At a certain instant of time, the power given to the two coils is the same. At
that time the current, the induced voltage and the energy stored in the first coil are I1, V1
and W1 respectively. Corresponding values for the second coil at the same instant are I2,
v2 and W2 respectively. Then:
I1 1 I W V 1
A)  B) 1  4 C) 2  4 D) 2 
I2 4 I2 W1 V1 4
15. For an LCR series circuit phasors of current i and applied voltage v = v0 sin t are
shown in diagram at t = 0. Which of the following is/are correct

A) At t  , instantaneous power supplied by source is negative
2
2
B) From t > 0 to t  average power supplied by source is positive
3
5
C) At t  , instantaneous power supplied by source is negative
6
D) If  is increased slightly, angle between the two phasors decreases.
16. In the circuit shown, the switch S is closed at t  0 and i1 and i2 are the instantaneous
currents.
L R
C R
s

A) i1 is maximum at t   and i2 is maximum at t  0

L
B) i1  i2 is independent of time , if R 2 
C
C) i1 and i2 are equal only at one instant from 0  t  
D) i1 and i2 never be equal
17. The given arrangement carries a capacitor with capacitance 40mF and two inductors

L1  25 H and L2  100 H If the capacitor initially carries a charge of 10mC, then
A) The maximum current through the inductor L1 when key k1 is closed is 20 mA
B) The maximum current through the inductor L2 when only key k2 is closed is 5 mA
C) The maximum current through inductor L2 when both the keys are closed is
D) Time period of oscillation of charge is minimum when both the keys are closed
18. A capacitor of capacitance C with upper plate M and lower plate N is connected to two
parallel, horizontal rails of good conductor. A metallic rod PQ is acted upon by a
constant horizontal force F, so that the rod can slide smoothly on the rails. A uniform
vertical magnetic field acts into the plane of the rails. During the motion of the rod,
A) The charge on plate M is positive and the charge value keep on increasing.
B) The charge on plate M is positive and the charge value remains constant
C) The charge on plate N is negative and the charge value keep on increasing.
D) The current flowing through the rod remains constant
SECTION - III
(MATRIX MATCHING ANSWER TYPE)
This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and four statements (P, Q, R and
S) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. For
example, if for a given question, statement B matches with the statements given in Q and R, then for the particular question darken the
bubbles corresponding to Q and R in the OMR sheet. For each correct matching will be awarded +2 marks ONLY and 0 if not
attempted and -1 in all other cases.
19. In column I, the variation of current i with time t is given in the figure. In Column II,
root mean square current irms and average current are given. Match the following
columns and select the correct option from the codes given below .
Column -I Column –II
i0
A) p) irms 
3
B) q) Average current for positive half cycle is i0

i0
C) r) Average current for positive half cycle is
2
D) s) Full cycle average current is zero .

20. Apply Kirchhoff’s laws to the circuit given below .

Given
i1  10e2 t Amp From aO
i2  4 Amp From cO
VC  3e2 t Volt
C  2F , L  4 H , R1  2, R2  3 
Now match the following columns and select the correct option from the codes given
below .
Column -I Column -II
A) Current through inductor p) increases with time
B) Magnitude of potential drop across inductor q) decreases with time
C) Magnitude of potential difference r) may become 3(in S.I) at
some time between points a and c
D) Magnitude of potential difference between s) may become zero at some
points c and d time

CHEMISTRY Max Marks : 88
SECTION – I
2 4
21. In  PtCl4  ,  Fe  CN 6  and VO  acac 2  complexes, sum of magnitude of magnetic
quantum number for d-orbitals involved in the hybridization is

22. Degeneracy of 2nd exicited state of Li2+ ion is x, and degeneracy of 4th exicited state of
Li+ ion is y then x/y is
23. 20 mL of M/60 solution of KBrO3 was added to a definite volume of SeO32 solution. The
bromine evolved was removed by boiling and excess of KBrO3 was back titrated with
5.1 mL of M/25 solution of NaAsO2. The reactions are given below. (Atomic mass of
K = 39, Br = 80, As = 75, Na = 23, O = 16, Se = 79)
(a) SeO23  BrO3  H  SeO42  Br2  H2O
(b) AsO2  BrO3  H2O  AsO43  Br  H

If the amount (in milligrams) of SeO32 in solution is 12x, the value of x is

24. A solution contains Na2CO3 and NaHCO3. 10ml of the solution required 2.5 ml of
0.1M H2SO 4 for neutralization using phenolphthalein as indicator. Methyl orange is
then added when a further 2.5 ml of 0.2 M H2 SO4 was required. The amount of
NaHCO3 (grams) in 1 litre of the solution is nearer to integer x. Then the value of x is
25. On addition of 1 ml of 10% solution of NaCl to 10ml red gold sol in presence of 0.025 g
of the starch, the coagulation is just prevented. The gold number of starch is x 2 . Then
the value of x is
x 
26. Graph between log   and log P is a straight line at 450 with intercept OA as shown.
m 
 x 
Hence,   at a pressure of 2 atm is:
 m 
450
x A
log   log 2
m 
O log P

27. A 1.10 g sample of copper ore is dissolved and Cu2+ formed are titrated with excess of
KI. The liberated iodine requires 12.12 ml of 0.10 N Na2S2O3 solution for titration. The
% of copper by mass in sample is...
28. If the percentage of water of crystallization in MgSO4 .xH 2O is 13%. What is the value of
x is
SECTION – II
29. Which of the following is /are incorrect?
A) Formation of micelles takes place when temperature is below Kraft Temperature (Tk)
and concentration is above critical micelle concentration (CMC)
B) A colloid of Fe(OH)3 is prepared by adding a little excess of NaOH in FeCl3 solution
the particles of this sol will migrate towards cathode during electrophoresis
C)  is the best colligative property to characterise the colloidal particles among the
colligative properties
D) Mg(OH)2 attains blue colour when precipitated in presence of 4-(4-nitrophenyl azo )
resorcinol

30. Which of the following is /are correct?
A) As n decreases, deBroglie’s wavelength of an electron in Bohr’s orbit increases
B) As n increases, orbit frequency decreases
C) An atomic orbital wave function  represents the state of an electron in an atom
D) If the velocity of the electron is suddenly increased by 2 times, the electron is
knocked out of atom.
31. Which of the following statement is/are correct?
A) When Fe SCN2 oxidizes into Fe3 , SO24, CO23 and NO3
Molecular weight
Eq.wt.of Fe SCN2 
33
K 2Cr2O 7  xH 2SO 4  ySO 2  K 2SO 4  Cr2 SO 4 3  zH 2O ;
B)
Then the value of x  y  z is 5
C) CO is estimated by iodimetric titration
D) equivalent weight of K2Cr2O 7 in dichromate titration is 49

32. Which of the following statement is/are correct?
A) Greater electro kinetic potential represents lesser stability to the lyophobic sol
B) The refractive indices of the dispersed phase and the dispersion medium differ
greatly in magnitude to observe Tyndall effect.
C) Butter and cream are examples of w/o type emulsions
D) The diameter of the dispersed particles is not much smaller than the wavelength of
the light used to observe Tyndall effect.
33. Which of the following statement is/are incorrect?
A) According to adsorption theory of catalysis, adsorption produces heat which
increases the rate of reaction
B) Positive catalyst accelerates reaction by bringing down the activation energy
C) A catalyst does not take part in the reaction mechanism
D) A catalyst changes heat of the reaction
34. Among the following incorrect statement is
A) A surfactant can acts as an emulsifier
B) Micellization of soap is exothermic process
C) In the micellization of soap entropy increases
D) As number of carbons increases in the alkyl group of surfactant, its kraft temperature
decreases
35. Mg  HNO3  Mg  NO3 2  NH 4 NO3  H 2O
Correct statements regarding this reaction is / are

A) 4g atoms of Mg oxidised by 10 mole of HNO3
B) 4 g atoms of Mg oxidised by 1 mole of HNO3
C) 1 mole of HNO3 reduced by 0.4 g atoms of Mg
D) 1 mole of HNO3 reduced by 96 g of Mg
36. Choose the correct statement(s)
A) the shape of an atomic orbital depends upon azimuthal quantum number
B) The orientation of an atomic orbital depends up on the magnetic quantum number
C) The energy of an electron in an atomic orbital of multi- electron atom depends
principal quantum number only
D) The number of degenerate atomic orbitals of one type depends upon the value of
azimuthal quantum number
37. Intramolecular redox reactions but not disproportionation reactions is/are
 
A)  NH 4 2 Cr2O7   B) NH 4 NO3  
 
C) 2KClO3   D) PCl5  

38. Which of the following expression is/are correct for energy of an electron in the nth
orbit of H-like species
 me2 KZ 2
A) 2 0 n 2h 2
 RH .ch.Z 2
B) n2 (RH= Rydberg’s constant for H-atom)
4 2 me 2 K 2 Z 2 1
C) 2 2
nh (K= 4 0 )
 e4 .Z 2
D) 32 2 02 2 n2 (  reduced mass )
SECTION - III
39. Match the following
Column – I Column – II
(A) Al(OH)3 Sol (p) Negativity charged colloidal
particle

(B) As2S3 sol (q) Positivity charged colloidal
particles
(C) Gold Sol (r) Lyophilic Sol
(D) Starch (s) Lyophobic Sol

(T) Macromolecular sol
40. Match the following:
B.E. – Binding energy
I.E. – Ionization energy
Column I Column II
(A) B.E. of He  atom in an excited state (P) required/emitted energy in
Infrared region
(B) Electron jumps from 6th exited state to 3rd (Q) 3.4 eV
Orbit in H-sample
(C) electron jumps from 5th orbit to ground (R) 13.6eV
State in H-sample
(D) series limit of Balmer series in H-atom (S) 10 Spectral lines observed
(T) Required/emitted energy in U.V
region

MATHS Max Marks : 88
SECTION – I
41. Number of solution(s) of x   0,   , satisfying the equations
 log 3
tan x  
log 3 3 3  log tan x 3  1 is/are________
42. Find the number of integral values of b for which the equation
2
 3sin x  4 cos x    b2  b  5  3sin x  4 cos x   b3  3b 2  2b  6   0 , has real solutions.
43. If m = sin x +cos x + tan x + cot x + sec x + cosec x
n=sin x + cos x – tanx – cot x – sec x – cosec x .
Then the value of (m+n-2) (m-n)=______
(x, is an acute angle)
44. Number of solutions of the equation
    
cos 2 
 4
 

sin x  2 cos 2 x   tan 2  x  tan 2 x   1  0, x   2 , 2  is………..
 4 

  101x 
2sin 50 x sin   
n cos 2rx k
45. If    4 2 
then value of n is k. what is the value of   ,
r 1     x  12 
sin rx   sin  
 4 2
where [.] denotes greatest integer function………..
46. Let P   4 tan10  4 tan 20  4 tan 30  .....  4 tan10 0  , Q   tan 20  tan 40  tan 6 0  .....  tan 200  and
R  1  tan10 1  tan10 1  tan 20 1  tan 20  ...... 1  tan10 0 1  tan10 0  . If P  QR then find

the value of ……….
128
47. Number of values of  in [0, 2  ] for which the expression
tan  x     tan x  tan  x   

y is independent of x……
tan  x    tan x tan  x   
48. Number of solutions of the equations cos 4 2 x  2sin 2 2 x  17  sin x  cos x 8 ,  0  x  2 
is…….

SECTION – II
x x
49. Consider y  4sin 2 x  3cos 2 x  24sin  24 cos where x  0,  2  then .
2 2
A) minimum value of y is 4  24 2
B) maximum value of y is -21
C) maximum value of y is 4  2
D) minimum value of y is 4
50. If p  sin  A  B  sin  C  D 
q  sin  B  C  sin  A  D 
r  sin  C  A  sin  B  D 
Then, which of the following is/are always true?

A) p  q  r  pqr
B) p 2  q 2  r 2  pq  qr  rp
C) p  q  r  0
D) p3  q3  r 3  3 pqr  0

51. Consider the following statements

i) If 0  A   6 then A sec A 
3 3
 
ii) If 0  A, B  then A cos ecA  B cos ecB 
4 2
 
iii) If 0  A, B, C  then A cot A  B cot B  C cot C 
3 3
Which of the following is/are true?
A) Statement (i) true B) statement (ii) true.
C) both statement (i) & (ii) true. D) both statement (i) & (iii) true
52. For each non-negative integer “n” function, “f” defined by
 2  n 4 
f n  x   sin n x  sin n  x    sin  x   then which of the following are true?
 3   3 
27 3
A) f 6  x    sin 2 3x B) sin 3x. f n  x   3 f n 1  x   4 f n3  x 
32 16
15
C) f5  x   sin 3x D) sin 3x. f n  x   4 f n 3  x   3 f n3  x 
16
53. If  ,  and  are connected by the relation
2 tan 2  tan 2  tan 2   tan 2  tan 2   tan 2  tan 2   tan 2  tan 2   1 then,
A) sin 2   sin 2   sin 2   1 B) cos 2   cos2   cos2   2

C) cos 2  cos 2  cos 2  1 D) cos     cos       cos 2 
n n
54. Let n f n  x   sin x  cos x, x  N . Then
A) f n  x  is a periodic function with well defined period for all n  N .
B) f n  x  is a periodic function with well defined period for all n  2 .

1
C) f 4  x   f 6  x  
12
1
D) f8  x   f10  x  
40
1
55. Let f  x   cos  a1  x   1 2 cos  a2  x   1 2 cos  a3  x   ....  cos  an  x 
2 2n 1
Where a1 , a2 , a3 ,.....an  R.
If f  x1   f  x2   0 then x1  x2 can be equal to
A)  B)  2 C) 2 D) 3
sin  cos  sin 
56. Consider f    cos  sin  cos  then,
cos  sin  sin 
A) f    0 has exactly two solutions in  0,   .

B) f    0 has exactly three solutions in  0,   .
C) maximum value of f   .  cos   sin  1  sin 2  is 1
 f   
D) lt   1
 0 1  sin 2
 
57. The system of equations tan x  a cot x, tan 2 x  b cos y
A) Cannot have a solution if a  0
B) cannot have a solution if a  1
C) Cannot have a solution if 2 a  b 1  a 
D) has a solution for all a & b
58. For, x, y,  0, 2  the equation 2  sin x  sin y   2cos  x  y   3 has a solution then
which of the following is/are true
x y
A) value of sin   can be equal to 1
 2 
x y 1
B) value of cos   can be equal to
 2  2
C) number of ordered pairs  x, y  is 2
D) number of ordered pairs  x, y  is 3

SECTION - III
59. Matching
Column-I Column-II
A) The value of P) -2
2 0 2 0 2 0 2 0 2 0 2 0
sin 12  sin 21  sin 39  sin 48  sin 9  sin 18  ___
B) Sum of all the solutions of the equation Q) 1
  1 
sin   log 3     0 in  0, 2  is k then the value of 2k-8
  x 
is
C) The angles of a convex pentagon are 1 , 2 ,3 ,4 , 5 R) 0
1   2   3   4   5  then the value of
cos 1   2  cos 1   2   3  cos 3   4  5   0, 
  
cos 3   4   5  cos  4   5 
….  cos 4  5   0 
D) 8
S) 2
the value of  tan rA tan  r  1 A  8  _____ where
r 1
A  360

60.
Column-I Column-II
A) Number of solution(s) of the equation P) 9
2 x  9 (1  cos x ), is / are
B) If x   200 , 50  and Q) 11
f  x   tan  500  x   cos  500  x   cot  500  x  then
global maximum value f(x) is k, then the value of

 k 2  ,where [.] denotes greatest integer function
C) If maximum value of the expression R) 10

2 2 2 2
sin x  2a  2a  1  cos x is k. Then sum of the
digits of the number  k  7  , is

8
D)   S) 12
Let ao  2  3  6 & bo  cot   then the value of
 24 
4
bo  ao  4 , is equal to

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RPTA-13

NARAYANA IIT ACADEMY

Name of the Student: ___________________ H.T. NO:

TRIGONOMETRY:TRIGONOMETRY UPTO TRANSFORMATIONS, GENERAL SOLUTIONS

Atomic Structure, Stoichiometry Surface Chemistry

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 2

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 3

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 4

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 5

(Given r = 1 m, m = 18 kg, q = 1C,  = 0.1, K = 4, g = 10 m/s2)

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 6

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 7

A) if I2 = 0 & P moves towards Q, a current in the same direction as I1 is induced in Q

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 9

A) i1 is maximum at t   and i2 is maximum at t  0

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 11

B) q) Average current for positive half cycle is i0

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 13

D) s) Full cycle average current is zero .

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 14

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 15

quantum number for d-orbitals involved in the hybridization is

K = 39, Br = 80, As = 75, Na = 23, O = 16, Se = 79)

(a) SeO23  BrO3  H  SeO42  Br2  H2O

(b) AsO2  BrO3  H2O  AsO43  Br  H

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 16

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 17

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 18

Then the value of x  y  z is 5

C) CO is estimated by iodimetric titration

D) equivalent weight of K2Cr2O 7 in dichromate titration is 49

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 19

32. Which of the following statement is/are correct?

Correct statements regarding this reaction is / are

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 21

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 22

(C) Gold Sol (r) Lyophilic Sol

(D) Starch (s) Lyophobic Sol

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 23

43. If m = sin x +cos x + tan x + cot x + sec x + cosec x

n=sin x + cos x – tanx – cot x – sec x – cosec x .

Then the value of (m+n-2) (m-n)=______

(x, is an acute angle)

44. Number of solutions of the equation

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 24

where [.] denotes greatest integer function………..

47. Number of values of  in [0, 2  ] for which the expression

tan  x     tan x  tan  x   

48. Number of solutions of the equations cos 4 2 x  2sin 2 2 x  17  sin x  cos x 8 ,  0  x  2 

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 25

Then, which of the following is/are always true?

Sr.IIT-IZ-CO-SPARK_Adv_Q.P space for rough work Page 26

A) sin 2   sin 2   sin 2   1 B) cos 2   cos2   cos2   2

A) f n  x  is a periodic function with well defined period for all n  N .

B) f n  x  is a periodic function with well defined period for all n  2 .

A) f    0 has exactly two solutions in  0,   .

A) Cannot have a solution if a  0

B) cannot have a solution if a  1

C) Cannot have a solution if 2 a  b 1  a 

D) has a solution for all a & b

which of the following is/are true

C) number of ordered pairs  x, y  is 2

D) number of ordered pairs  x, y  is 3