1. The end product in the following sequence of reaction is ;
HC CH ⎯⎯ ⎯⎯ ⎯→ A ⎯⎯ 1%HgSO 4 ⎯⎯→ B ⎯⎯ CH 3 MgX ⎯→ [O ] 14.On reductive ozonolysis yields. 20 % H 2 SO 4 (a) 6-oxoheptanal (b) 6-oxoheptanoic acid (a) Acetic acid (b) Isopropyl alcohol (c) 6-hydroxyheptanal (d) 3-hydroxypentanal (c) Acetone (d) Ethanol 15. An alkene of molecular formula C9 H18 on ozonolysis gives 2,2 2. Compound which gives acetone on ozonolysis: (a) CH 3 − CH = CH − CH 3 (b) (CH 3 )2 C = C(CH 3 )2 dimethyl propanal & 2-butanon, then the alkene is. (a) 2, 2, 4-trimethyl –3-hexene (b) 2, 2, 6-trimethyl-3-hexene (c) C6 H5 CH = CH 2 (d) CH 3CH = CH 2 (c) 2, 3, 4-trimethyl-2-hexene (d) 2, 2, 4-trimethyl-2-hexene 3. Which one of the following compounds is prepared in the (e) 2, 2dimethyl-2-heptene laboratory from benzene by a substitution reaction; (a) Glyoxal (b) Cyclohexane 16. (c) Acetophenone (d) Hexabromo cyclohexane CH 3 COCl ⎯⎯⎯→ CH 3 CHO + HCl ; 2H Pd / BaSO 4 4. The above reaction is called (a) Reimer-Tiemann reaction (b) Cannizzaro reaction (c) Rosenmund reaction (d) Reformatsky reaction Relationship between products (Q) and (S) is ? (a) Positional isomer (b) Chain isomer 5. The oxidation of toluene to benzaldehyde by chromyl chloride is called; (c) Stereoisomer (d) Functional isomer (a) Cannizzaro reaction (b) Wurtz reaction 17. Correct order of reactivity of following compound towards (c) Etard reaction (d) Reimer-Tiemann reaction Grignard reagent : 6. From which of the following tertiary butyl alcohol is obtained by the action of methyl magnesium iodide; (a) HCHO (b) CH 3 CHO (c) CH 3 COCH 3 (d) CO 2 (a) I > II > III (b) II > I > III CH 3 − CH 2 − C CH ⎯⎯→ R (c) II > III > I (d) I > III > II H 2O 7. Butanone, R is. O ++ || (a) Hg (b) KMnO 4 (c) KClO 3 (d) K2Cr2O7 18. Ph − C− OH ⎯⎯⎯2 →(A) ⎯⎯→ SOCl H 2 (B) 8. Dry heating of calcium acetate gives. Pd− BaSO 4 (a) Acetaldehyde (b) Ethane Product (B) is . (c) Acetic acid (d) Acetone O || 9. Acetophenone is prepared by the reaction of which of the (a) Ph − C− H (b) Ph − CH 2 − OH following in the presence of AlCl 3 catalyst; (a) Phenol and acetic acid (c) Ph − CH 2 − Cl (d) Ph − CH = CH 2
19. (A) ⎯⎯⎯4 →(B) ⎯⎯⎯4 →
(b) Benzene and acetone HgSO LiAlH (C) dil. H 2SO 4 (c) Benzene and acetyl chloride racemic mixture
(d) Phenol and acetone reactant (A) is ;
10. On heating calcium acetate and calcium formate, the product (a) CH 3 − C CH (b) HC CH formed is? (a) CH 3COCH 3 (b) CH 3CHO (c) CH 3 − C C − CH 3 (d) Ph − CH = CH 2
(c) HCHO + CaCO 3 (d) CH 3CHO + CaCO 3
11. Which of the following compound gives a ketone with Grignard reagent; (a) Formaldehyde (b) Ethyl alcohol (c) Methyl cyanide (d) Methyl iodided 12. Methyl ethyl ketone is prepared by the oxidation of; (a) 2-propanol (b) 1-butanol (c) 2-butanol (d) t-butyl alcohol 13. Benzaldehyde can be prepared by oxidation of toluene by; (a) Acidic KMnO 4 (b) K2Cr2O7 (c) CrO2 Cl 2 (d) All of these