Solutions to JEE Super-50 Test-03 18-March

Given mass
1. CO2 (g) + C(s) ⟶ 2CO(g) = no. of moles
Initial 1L 0 0 M olecular mass

Final volume (1 x) L 2x 2
Final volume = 1 – x + x + 2x = 1.4 L = × 56
3
∴ x = 0.4 L
∴ Volume of CO = 2x = 2 × 0.4 = 0.8 L
=37.3 g
Volume of CO2 = (1 – x) = 1 – 0.4 = 0.6 L
7. 500
mole of NH 3 = 6.02 x 1023 molecules
2. 1 molecule contains = 6 O atoms, 22.4 × 10
3

0.3 mole molecules contains = 6 × 0.3 moles O atoms 23

100 6.02 × 10
= 1.8 moles O atoms mole of CO2 = molecules
3
22.4 × 10 5
3. The balanced reaction of Zn and HCl is given below:
Zn + 2HCl → ZnCl2 + H 2 (g) 8. 1 mole of any substance contains a fixed number of
We know, 1 mole of any gas produces 22400 mL at STP. particles that is equal to Avagadro's number.
1.12
⇒ Number of moles of 1.12 mL of H 2 gas at STP = 9.
22400

From the balanced reaction, we can say,

1 mole of H 2 gas is produced by 1 mole of Zn
1.12 1.12
⇒ mole of H 2 gas is produced by mole of 10. The reaction taking place can be represented by the
22400 22400
Zn. equation:
1.12 CaCl2 + 2Ag+ ⟶ 2AgCl + Ca 2+
⇒ Mass of Zn required = × 65 g
22400 From the above euqtion;
⇒ Mass of Zn required = 32.5 × 10–4 g 1
moles of CaCl2 needed = × moles of AgCl formed
⇒ Option (C) is CORRECT. 2

Given, mass of AgCl formed = 143.5 g

4. Let's assume the atomic mass of B = y g mol–1 mass 14.35
And the atomic mass of A = x g mol–1 ⇒ moles of AgCl formed = = = 0.1
M. W. 143.5

⇒ Molar mass of B2 A3 = (2y + 3x) g mol–1 1

⇒ moles of CaCl2 needed = × 0.1 = 0.05
⇒ Molar mass of B2 A = (2y + x) g mol–1 2

mass of CaCl2 needed =moles of CaCl2 needed × M.W. of

0.05 moles of B2 A3 weighs = 9 gm
CaCl2
⇒ 0.05 × (2y + 3x) = 9
⇒ 2y + 3x = 180 ....(1) ⇒ mass of CaCl2 needed =0.05 × 111 = 5.55 g
0.1 mole of B2 A weighs = 10 gm
11. 4 4 4
⇒ 0.1 × (2y + x) = 10 l = 2 = 16, m = 2 = 16, n = 2 = 16,

⇒ 2y + x = 100 ....(2) ⇒ 2l − m − n = 0

Substracting equation (2) from (1), we get, 12. A : x ∈ (−3, 1) B : x ∈ (−∞, −1] ∪ [3, ∞)
2x = 80
⇒ x = 40 B = A = (−∞, −3) ∪ [3, ∞) = R − (−3, 3)
And, y = 30
13. Given n(A) = m and n(B) = n
x= 40
⇒{ } Let R : A → B
y= 30

⇒ Option (B) is CORRECT. We know A × B will have mn ordered pairs.

Each subset of A × B will be a relation.
5. 4HNO3 (l) + 3KCl(s) → Cl2 (g) + NOCl(g) + 2H 2 O(g) + Now, the number of subsets of set consisting of mn
3KNO3 (s) element is 2mn
Hence the total number of possible relations are 2mn
110 g of KNO3 ⇒ moles of KNO3 =
110
∴ = 1.089 mol
101

As, 4 mole of HNO3 produces 3 mol of KNO3 .

Hence, the moles of HNO3 required to produce 1.089
4 14. A − B = A − (A ∩ B) is correct.
moles of KNO3 = × 1.089 = 1.452 mol
3 A = (A ∩ B) ∪ (A − B) is correct.
Hence, the mass of HNO3 required is 1.452 × 63 = 91.5 g
(approx.)

6. Now, By using stochiometry

n1 18/18
=
2 3

2
n1 =
3

K Venkanna Junior College: Tarnaka, Secunderbad

 Solutions to JEE Super-50 Test-03 18-March

= n(P ) − n(P ∩ (M ∪ C)) = n(P ) − n((P ∪ M ) ∪ (P ∩ C))

= n(P ) − n(P ∩ M ) − n(P ∩ C) + n(P ∪ M ∩ C)

= 24 − 12 − 7 + 4 = 9
′ ′
n(C ∩ M ∩ P ) = n(C ) − n(C ∩ P ) − n(C ∩ M) + n(C ∩ P ∩ M)

= 19 − 7 − 9 + 4 = 23 − 16 = 7.
Hence the number of student studying exactly one subject=
6 + 9 + 7 = 22

Alternatively we can understand the same question using

Venn-Diagram

(3) is false.
∴ (1) and (2) are true.

15. Going with option (B)

It is given {x : x is a real number and x2 + 1 = 0}

Since x2 + 1 = 0, gives x2 = −1 ⇒ x = ±i
⇒ x is not real but x is real (given)
∴ No value of x is possible.

16. A = {1, 2, 3, 4} & R = ((2, 2), (3, 3), (4, 4), (1, 2))

Now
∵ (1, 1) ∉ R so R is not reflexive
Also
∵ (1, 2) ∈ R but (2, 1) ∉ R so
R is not symmetric.
Hence total number of student studying exactly one
Also, there is no two elements for whom transitivity fails, so
subject is the one present in shaded area
R is transitive.
i.e 6 + 9 + 7 = 22
17. For R to be reflexive ⇒ xRx
⇒ 3x + αx = 7x ⇒ (3 + α)x = 7K
19. A = {1, 2, 4}
⇒ 3 + α = 7λ ⇒ α = 7λ − 3 = 7N + 4, K, λ, N ∈ I
B = {2, 3}
∴ when α divided by 7, remainder is 4.
A × B{(1, 2), (1, 3), (2, 2), (2, 3), (4, 2), (4, 3)}
R to be symmetric xRy ⇒ yRx

3x + αy = 7N1 , 3y + αx = 7N2
20. Given that in a battle let total persons fought n(U ) = 100
⇒ (3 + α)(x + y) = 7(N1 + N2 ) = 7N3
70% of the combatants lost one eye ⇒ n(A) = 70
Which holds when 3 + a is multiple of 7
80% of the combatants lost an ear ⇒ n(B) = 80
∴ α = 7N + 4 (as did earlier)
75% of the combatants lost an arm ⇒ n(C) = 75
R to be transitive
xRy & yRz ⇒ xRz. 85% of the combatants lost a leg ⇒ n(D) = 85

3x + αy = 7N1 & 3y + αz = 7N2 and

Let the number of combatants who lost all four limbs are
3x + αz = 7N3 n(A ∩ B ∩ C ∩ D) = x (given)
∴ 3x + 7N2 − 3y = 7N3 c c c c
x = n( A ∩ B ∩ C ∩ D ) = n( U ) − [ n( A ) ∪ n( B ) ∪ n( C ) ∪ n( D ) ] . . . . . ( i)

∴ 7N1 − αy + 7N2 − 3y = 7N3

(where n(P ) is the number of elements in the
c

∴ 7(N1 + N2 ) − (3 + α)y = 7N3 complement set of set P )

∴ (3 + α)y = 7N for the minimum value of x
Which is true again when 3 + α divisible by 7,
c c c c c c c c
[n(A ) ∪ n(B ) ∪ n(C ) ∪ n(D )] = [n(A ) + n(B ) + n(C ) + n(D )]

i.e. when a divided by 7, remainder is 4. put in equation (i)

c c c c
xmin = n(A ∩ B ∩ C ∩ D) = n(U ) − [n(A ) + n(B ) + n(C ) + n(D )] . . . . . (ii)
18. Let the student studying maths be representes as M
,physics as P and chemistry as C Now,
c
Now given : n(M ) = 23, n(P ) = 24, n(C) = 19 n(A ) = n(U ) − n(A) = 100 − 70 = 30
c
n(M ∩ P ) = 12, n(M ∩ C) = 9, n(P ∩ C) = 7 and n(B ) = n(U ) − n(B) = 100 − 80 = 20
c
n(M ∩ P ∩ C) = 4 n(C ) = n(U ) − n(C) = 100 − 75 = 25
c
n(D ) = n(U ) − n(D) = 100 − 85 = 15
We have to find
put all these values in the equation (ii)
′ ′ ′ ′ ′ ′
n(M ∩ P ∩ C ) or n(P ∩ M ∩ C ) or n(C ∩ M ∩ P )

Now n(M ∩ P
′ ′
∩ C ) = n(M ∩ (P ∪ C) )
′
xmin = 100 − (30 + 20 + 25 + 15))

= n(M ) − n(M ∩ (P ∪ C)) xmin = 100 − 90

= n(M ) − n[(M ∩ P ) ∪ (M ∩ C)] xmin = 10

= n(M ) − n(M − P ) − n(M ∩ C ) + n(M ∩ P ∩ C )

21. 3v1 v2 v3
= 23 − 12 − 9 + 4 = 27 − 21 = 6 Average speed =
′ ′ ′ v1 v2 + v2 v3 + v1 v3
n(P ∩ M ∩ C ) = n(P ∩ (M ∪ C) )

K Venkanna Junior College: Tarnaka, Secunderbad

 Solutions to JEE Super-50 Test-03 18-March

3 × v × 2v × 3v 18 1
2
= = v ∴ x1 = αt (∵ u = 0)
2 2 2 1
2v + 6v + 3v 11 2

and velocity at t = t1 s, is v = αt1

22. d dv
Slope of v2 vs x graph is 2
(v ) = 2v After t1 s, body is travelling with constant deceleration till
dx dx
velocity of body becomes zero, for t2 s.
dv
v is equal to acceleration of the particle. 1
dx ∴ x2 = βt
2
2
(∵ uf = 0 and visulise reverse
2
Slope = 2a ...(1) phenomenon for t2 s. i.e body started from rest with
From graph, slope = tan 45° = 1 ...(2) constant deceleration β for t2 . In original case and later
∴ 2a = 1 case distance travelled is same.)
1 Further, applying 1st equation of kinematics in 2nd interval,
⇒a= = 0.5 m/s2 . we get v = βt2 .
2

23. A boy reaches the airport and finds that the escalator is not
t1 β
working. He walks up the stationary escalator in time t 1 . If ∴ υ = αt1 = βt2 ⇒ =
he remains stationary on the moving escalator, the t2 α

escalator takes him up in time t 2 . We have to find the time αt

2
x1
taken by him to walk up on the moving escalator.
1
and =
2
x2 βt
2
Let l be the length of escalator, v 1 be the velocity of the boy
x1 β t1 β
w.r.t the escalator and v 2 be the velocity of the escalator. ⇒ = (∵ = )
Now, velocity of the boy w.r.t. the escalator is, x2 α t2 α
−−→ −−→ −−
→
v = v
b,e
−v , where the subscripts b, e and g
b,g e,g x1 β t1
⇒ = =
represent the boy, the escalator and the ground x2 α t2
respectively.
We can simply write it as v = v − v as the motion b,e b,g e,g 27. Given,
here is one-dimensional. The acceleration of the particle is varying with respect to
⇒v =v +v b,g b,e e,g
time according to the equation, a = 2t + 5.
We know that the acceleration is the rate of change of
In the first case, v b,g = v 1 + 0 = v 1 as the escalator is dv
velocity a = .
not moving. dt
The distance covered in the ground frame is l. dv

l
⇒ = 2t + 5 .
⇒ t1 = . dt
v1 ⇒ dv = (2t + 5)dt .
In the seond case, v b,g = 0 + v2 = v2 as the boy is not Let, the velocity of the particle is v at t = 5 sec. So, on
moving. integrating on both sides we can write
v 5
l
⇒ t2 = . ∫ dv = ∫ (2t + 5)dt .
v2 0 0

Let t be the time taken by the boy to walk up on the moving 5 5

⇒v = [t ]
2
+ 5[t]
escalator. 0 0

In this case, v b,g = v 1 + v 2 . ⇒v = 25 + 25 = 50 m/s.

In this case too, the distance covered in the ground frame 28. Given that a train is moving with uniform velocity on a
is l. straight track. Consider velocity of train w.r.t ground is,
l →
⇒t =
V = a î + b ĵ m/s.
T ,G
v1 + v2
l A boy moving at 4 km/h due east observes that the train is
⇒t=
l
+
l
moving due North. i.e. VA,G = 4^
i.
t t
1 2
→ → →
t1 t2
⇒t = . Velocity of train w.r.t person A is V T ,A = V T ,G −V A,G

t1 + t2
→
⇒V T ,A
= a î + b ĵ − 4 î = (a − 4) î + b ĵ
24. → → →
v b,g = v b,r + v r,g
As train appears to be moving along North, component
→ → →
⇒ v b,r = v b,g − v r,g along East direction should be zero.
→
⇒ v b,r = 9 ^
i + 12 ^
j a − 4 = 0

⇒a = 4
25. a
S th = u+ (2n − 1)
n
2
u = 0 and a = g (cost.)
S
n
th ∝ (2n − 1) (here n = 1, 2, 3 ......)
D1 : D2 : D3 : . . . . . . . . . . . . = 1 : 3 : 5 : . . . . . . . . . . . .

26. Given, body has started from rest and travelling for t1 s,
with constant acceleration α.

K Venkanna Junior College: Tarnaka, Secunderbad

 Solutions to JEE Super-50 Test-03 18-March

As the train appears to be moving towards North-East,

component along North direction should be equal
to component along East direction. i.e b + 1 = 4.
⇒b = 4 − 1 = 3

→
ˆ ˆ
∴ V T /G
= 4 i + 3j

→
⇒ |V km/hr.
2 2
T ,B
| = √3 + 4 = 5

29. Distance 40
Another boy moving at 1 km/h due South claims that the v= = = 5 ms–1
Time 8
train is moving towards North-East. i.e. VB,G = 1(−^
j) .

→ → → 30. R 100
Velocity of train w.r.t person A is, V T ,B = V T ,G −V B,G
R = ux T ⇒u x = = = 20 m/s
T 5
→
⇒V T ,B
ˆ ˆ ˆ ˆ ˆ
= a i + b j − 1(−j ) = a i + (b + 1) j

K Venkanna Junior College: Tarnaka, Secunderbad