YT CRASH COURSE DAY -03

GASEOUS STATE DPP - 01

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01. The atmospheric pressure on a certain day is 732 mm Hg. 08. Which of the following statement is false ?

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What is the pressure in kPa ? (1) The product of pressure and volume of fixed amount of
(1) 60 kPa (2) 80.6 kPa a gas is independent of temperature

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(3) 77.8 kPa (4) 97.6 kPa (2) Molecules of different gases have the same KE at a
02. Hydrogen bonding is a particularly strong type of ________ given temperature
interaction (3) The gas equation is not valid at high pressure and low

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(1) dipole-induced dipole temperature
(2) dipole-dipole (4) The gas constant per molecule is known as Boltzman
constant
(3) ion-dipole
09. If P, V and T represent pressure, volume and temperature
(4) instantaneous dipol-induced dipole of the gas, the correct representation of Boyle’s law is

as the only intermolecular forces ?

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03. Which of the following pairs exhibit only dispersion forces
(1) V 
1
T
(at constant P)
(1) HBr and H2S (2) NH3 and C6H6
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(3) Cl2 and CBr4 (4) I2 and NO 3 (2) PV  RT
04. Which of the following species are capable of hydrogen (3) V  1/ P (at constant T)
bonding among themselves (4) PV  nRT
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(1) H2S (2) C6H6

10. If V0 is the volume of a given mass of gas at 273 K at
(3) CH3OH (4) CH4
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constant pressure, then according to Charles’s law, the

05. Dispersion forces are weak attractive forces that are volume at 100C will be
important only over exteremely distances because they vary
as 2
(1) 10V0 (2) (V0  10)
(1) 1/d6 (2) 1/d4 273
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(3) 1/d7 (4) 1/d5 10 283

(3) V0  (4) V0
06. Which of the following interactions is not a part of the van 273 273
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der Waals forces ? 11. I, II, and III are three isotherms respectively at T1, T2 and
(1) Diple-dipole forces T3 as shown in the graph. Temperature will be in order
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(2) Dipole-induced dipole forces

(3) Dispersion forces
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(4) Ion-dipole forces

07. 300 ml of a gas at 27oC is cooled to –3oC at constant
pressure, volume is
(1) T1 = T2 = T3 (2) T1 < T2 < T3
(1) 540 ml (2) 135 ml
(3) T1 > T2 > T3 (4) T1 > T2 = T3
(3) 270 ml (4) 350 ml
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12. A certain sample of gas has a volume of 0.2 litre measured 18. Densities of two gases are in the ratio 1 : 2 and their
at 1 atm pressure and 00C. At the same pressure but at temperaures are in the ratio 2 : 1, then the ratio of their
2730C, its volume will be respective pressures is
(1) 0.4 litres (2) 0.8 litres (1) 1 : 1 (2) 1 : 2
(3) 27.8 litres (4) 55.6 litres (3) 2 : 1 (4) 4 : 1
13. A gas cylinder containing cooking gas can withstand a 19. If the pressure of a given mass of gas is reduced to half and
pressure of 14.9 atm. The pressure gauge of cylinder temperature is doubled simultaneously the volume will be
indicates 12 atm at 270C. Due to sudden fire in building the (1) Same as before (2) Twice as before
temperature starts rising. The temperature at which the

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(3) 1/4 the as before (4) None
cylinder will explode is
20. Pressure of a mixture of 4 g of O2 and 2 g of H2 confined in
(1) 42.50C (2) 67.80C

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a bulb of 1 litre at 0oC is
(3) 99.50C (4) 25.70C
(1) 25.184 atm (2) 31.205 atm
14. The product of PV is plotted against P at two temperatures
(3) 45.215 atm (4) 15.210 atm

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T1 and T2 and the result is shown int he figure. What is correct
about T1 and T2 ? 21. In the equation PV  nRT , which one cannot be the
numerical value of R
T2

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PV
(1) 8.31 × 107 erg K–1 mol–1
T1
(2) 8.31 × 107 dyne cm K–1 mol–1
P(bar)
(3) 8.31 JK–1 mol–1
(1) T1 > T2 (2) T2 > T1
(4) 8.31 atm. K–1 mol–1
(3) T1 = T2 (4) T1 + T2 = 1 A22. 120 g of an ideal gas of molecular weight 40 is confined to a
15. An open vessel containing air is heated from 300 K to 400
volume of 20 litre at 400 K, then the pressure of gas is
K. The fraction of air originally present which goes out of it
is at 400 K (1) 490 atm (2) 4.92 atm
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(1) 3/4 (2) 1/3 (3) 2236 atm (4) 22.4 atm
(3) 2/3 (4) 1/8 23. If two moles of an ideal gas at 546 K occupies a volume of
44.8 litres, the pressure must be
16. At the definite temperature the volume of a definite mass of
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gas is 10 L at 5 atm pressure, at the same temperature if the (1) 2 atm (2) 3 atm
pressure of the gas is decreased to 1 atm, the volume of the (3) 4 atm (4) 1 atm
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same gas becomes 24. Equal weights of methane and hydrogen are mixed in an empty
(1) 50 L (2) 2 L container at 25oC. The fraction of total pressure exerted by
(3) 5 L (4) 0.5L hydrogen is
17. If 20 cm gas at 1 atm is expanded to 50 cm3 at constant T,
3 (1) 1/2 (2) 8/9 (3) 16/19 (4) 1/9
then what is the final pressure 25. A cylinder is filled with a gaseous mixture containing equal
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masses of CO and N2. The partial pressure ratio is

1 1
(1) 20  (2) 50  (1) PN 2  PCO (2) PCO  0.875 PN 2
50 20
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1 1
(3) 1  50 (4) None of these (3) PCO  2 PN2 (4) PCO  PN 2
20 2
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ANSWER KEY

01. 4 02. 2 03. 3 04. 3 05. 3 06. 4 07. 3 08. 1 09. 3 10. 4
11. 3 12. 1 13. 3 14. 2 15. 2 16. 1 17. 1 18. 1 19. 4 20. 1
21. 4 22. 2 23. 1 24. 2 25. 1
YT CRASH COURSE DAY -03
GASEOUS STATE DPP - 02

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01. Under critical states of a gas for one mole of a gas, 06. Mark the correct statement

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compressibility factor is (1) Surface tension of a liquid increase with temperature
3 8 (2) Addition of chemicals reduces the surface tension of a

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(1) (2) liquid
8 3
(3) Stalagmometer is used for measuring viscosity of the
1
(3) 1 (4) liquid

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4
(4) Viscosity of the liquid does not depend on intermolecular
02. A temperature at which real gases obey the ideal gas laws forces
over a wide range of pressure is called
07. Association of molecules in water is due to
(1) Critical temperature
A (1) covalent bonding
(2) Inversion temperature
(2) hydroen bonding
(3) Boyle’s temperature
(3) ionic bonding
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(4) Kindling temperature (4) van der Waals forces
03. Which of the following characterises the critical point ? 08. Which of the following statements is wrong ?
(1) At the critical point both liquid and solid phase coexist (1) Evaporation is a sponataneous process
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(2) At the critical point solid, liquid and gas phase coexist (2) Evaporation is a surface phenomenon
(3) At the critical point liquid and gas phase coexist together (3) Vapour pressure decreases with increase of temperature
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(4) At the critical point liquid and gas phase have unequal (4) The vapour pressure of a solution is always less than the
density vapour pressure of a pure solvent.
04. NH3 is liquefied more easily than N2. Hence 09. Which of the following expressions regarding the unit of
coefficient of viscosity is not true ?
(1) a of NH3 = to a of N2
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(1) dyne cm–2 sec

(2) a of NH3 > a of N2
(2) dyne cm2 sec–1
(3) a of NH3 < a of N2
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(3) Nm–2 sec

(4) None
(4) 1 poise = 10–1 Nm–2 sec
05. A real gas at a very high pressure occupies
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10. The boiling point of water, ethyl alcohol and diethyl ether
(1) more volume than that of an ideal gas under identical
are 100 o C, 78.5 oC and 34.6 o C respectively. The
conditions
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intermolecular forces will be in the order of

(2) less volume than that of an ideal gas under identical
(1) water > ethyl alcohol > diethyl ether
conditions
(2) ethyl > alcohol > water > diethyl ether
(3) same volume than that of an ideal gas under identical
conditions (3) diethyl > ethyl alcohol > water
(4) can’t predict (4) diethyl ether > water > ethyl alcohol
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11. The rise of a liquid in a capillary tube is due to
(1) viscosity (2) osmosis
(3) diffusion (4) surface tension (3) (4)
12. With increase in temperature, the fluidity of liquids
(1) increases (2) decreases 17. A mixture of N2 and Ar gases in a cylinder contains 7g of
(3) remains constant (4) may icnrease or decrease N2 and 8g of Ar. If the total pressure of the mixture of gases
in the cylinder is 27 bar, the partial pressure of N2 is [Use
13. Viscosity of a liquid is increased by
atomic masses (in g mol–1) N = 14, Ar = 40]

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(1) increase in temperature
(1) 18 bar (2) 9 bar
(2) decrease in molecular size

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(3) 12 bar (4) 15 bar
(3) increase in molecular size
18. A gas at 350 K and 15 bar has molar volume 20 percent
(3) none of the above

14. Which of the following statements is correct if the
intermolecular forces in liquids A, B and C are in the order
A<B<C?
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smaller than that for an ideal gas under the same conditions.
The correct option about the gas and its compressibility
factor (Z) is

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(1) Z > 1 and attractive forces are dominant
(1) B evaporates mroe readily than A (2) Z > 1 and repulsive forces are dominant
(2) B evaporates less readilty than C
(3) Z < 1 and attractive forces are dominant
(3) A and B avaporate at the same rate
(4) Z < 1 and repulsive forces are dominant
(4) A evaporates more readily than C
15. Water boils at lower temperature on high altitudes because
A19. Given van der Waals constant for NH3, H2, O2 and CO2
are respectively 4.17, 0.244, 1.36 and 3.59, which one of
the following gases is most easily liquefied ?
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(1) atmospheric pressure is low there
(2) atmospheric pressure is high there (1) NH3 (2) H2
(3) water is weakly hydrogen bonded there (3) O2 (4) CO2
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(4) water in pure form is found there 20. The correction factor ‘a’ to the ideal gas equation
corresponds to
16. Choose the correct option for graphical representation of
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Boyle’s law, which shows a graph of pressure vs. volume (1) density of the gas molecules
of a gas at different temperatures :
(2) volume of the gas molecules
(3) electric field present between the gas molecules
(4) forces of attraction between the gas molecules
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(1) (2)
A
K
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ANSWER KEY

01. 1 02. 3 03. 3 04. 2 05. 1 06. 2 07. 2 08. 3 09. 3 10. 1
11. 2 12. 1 13. 3 14. 4 15. 1 16. 2 17. 4 18. 3 19. 1 20. 4