Mis disculpas por la confusión.

Aquí está el orden corregido:

**Ejercitación N1 - Estequiometría**

1. What is the concentration, in mol dm−3, of 20.0 g of NaOH (Mr = 40.0) in 500.0 cm3?
A. 0.250
B. 0.500
C. 1.00
D. 4.00

2. What is the sum of the integer coefficients when propene undergoes complete combustion?
__C3H6 (g) + __O2 (g) → __CO2 (g) + __H2O (l)
A. 11
B. 17
C. 21
D. 23

3. A student determined the percentage of the active ingredient magnesium hydroxide, Mg(OH)2, in a
1.24 g antacid tablet. The antacid tablet was added to 50.00 cm3 of 0.100 mol dm−3 sulfuric acid, which
was in excess.
a. Formulate the equation for the reaction of H2SO4 with Mg(OH)2.
b. The excess sulfuric acid required 20.80 cm3 of 0.1133 mol dm−3 NaOH for neutralization.
c. Calculate the amount of excess acid present.
d. Calculate the amount of H2SO4 that reacted with Mg(OH)2.
e. Determine the mass of Mg(OH)2 in the antacid tablet.
**f. Calculate the percentage by mass of magnesium hydroxide in the 1.24 g antacid tablet to three
significant figures.**

4. What is the coefficient of HCl (aq) when the equation is balanced using the smallest possible whole
numbers?
__CuO(s) + __HCl (aq) → __CuCl2 (aq) + __H2O (l)
A. 1
B. 2
C. 3
D. 4

5. Chlorine undergoes many reactions. 2.67 g of manganese(IV) oxide was added to 200.0 cm3 of 2.00
mol dm-3 HCl.
MnO2 (s) + 4HCl (aq) → Cl2 (g) + 2H2O (l) + MnCl2 (aq)
Chlorine gas reacts with water to produce hypochlorous acid and hydrochloric acid.
Cl2 (g) + H2O (l) ⇌ HClO (aq) + HCl (aq)
**a. State the full electron configuration of the chlorine atom.**
b(i). State, giving a reason, whether the chlorine atom or the chloride ion has a larger radius.

6. Iron (II) sulfide reacts with hydrochloric acid to form hydrogen sulfide, H2S.
**a(i). Draw the Lewis (electron dot) structure of hydrogen sulfide.**
a(ii). Predict the shape of the hydrogen sulfide molecule.
a(iii). State the formula of its conjugate base.
b(i). Saturated aqueous hydrogen sulfide has a concentration of 0.10 mol dm−3 and a pH of 4.0.
Demonstrate whether it is a strong or weak acid.
b(ii). Calculate the hydroxide ion concentration in saturated aqueous hydrogen sulfide.
 b(iii). A gaseous sample of nitrogen, contaminated only with hydrogen sulfide, was reacted with excess
sodium hydroxide solution at constant temperature. The volume of the gas changed from 550 cm3 to 525
cm3. Determine the mole percentage of hydrogen sulfide in the sample, stating one assumption you
made.

7. Explain why Si has a smaller atomic radius than Al.

a(i). Explain the decrease in radius from Na to Na+.

8. **(Manten

8. State the condensed electron configurations for Cr and Cr3+.

[2]

9. Describe metallic bonding and how it contributes to electrical conductivity.

[3]

10. Deduce the Lewis (electron dot) structure and molecular geometry of sulfur dichloride, SCl2.
[2]

11. Suggest, giving reasons, the relative volatilities of SCl2 and H2O.
[3]

12. Consider the following equilibrium reaction:

2SO2 (g) + O2 (g) ⇌ 2SO3 (g)
State and explain how the equilibrium would be affected by increasing the volume of the reaction
container at a constant temperature.
[2]

13. Dinitrogen monoxide, N2O, causes depletion of ozone in the stratosphere.

a. Outline why ozone in the stratosphere is important.
[1]
b. State one analytical technique that could be used to determine the ratio of 14N:15N.
[1]
c(i). A sample of gas was enriched to contain 2% by mass of 15N with the remainder being 14N.
Calculate the relative molecular mass of the resulting N2O.
[2]
c(ii). Predict, giving two reasons, how the first ionization energy of 15N compares with that of 14N.
[2]
c(iii). Suggest why it is surprising that dinitrogen monoxide dissolves in water to give a neutral solution.

14. What is the ground state electron configuration of an atom of chromium, Cr (Z = 24)?
A. [Ar]3d6
B. [Ar]4s23d4
C. [Ar]4s13d5
D. [Ar]4s24p4

15. Lewis (electron dot) structures are useful models.

Draw the Lewis (electron dot) structures of PF3 and PF4+ and use the VSEPR theory to deduce the
molecular geometry of each species.
[4]
a. Predict with a reason, whether the molecule PF3 is polar or non-polar.
16. What is the formula of ammonium phosphate?
A. (NH3)3PO4
B. (NH4)3PO4
C. (NH4)2PO4
D. (NH3)2PO3

17. What is the IUPAC name of NiCO3?

A. nickel(II) carbonate
B. nickel carbonate
C. nickel(I) carbonate
D. nitrogen(I) carbonate

18. What is the enthalpy change of the reaction, in kJ?

2C (graphite) + O2 (g) → 2CO (g)
A. −394 − 283
B. 2(−394) + 2(−283)

19. Hydrogen gas can be formed industrially by the reaction of natural gas with steam.
CH4(g) + H2O(g) → 3H2(g) + CO(g)
Determine the enthalpy change, ΔH, for the reaction, in kJ, using section 11 of the data booklet