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Additional Content - Chemistry
Additional Content - Chemistry
Additional Content - Chemistry
Chemistry
1. Consider the given reactions 6. A gas has smell like rotten egg and turns lead acetate
paper black. The gas is
(1) NO2
(2) H2S
(3) CO2
Products (A) and (B) can be differentiated using
(4) SO3
(1) Na
(2) 2, 4-DNA 7. If a gas turns lime water milky and when added to
(3) Tollens' reagent acidified K2Cr2O7 solution, it turns green then the gas is
(4) NaHSO3 (1) SO2
(2) H2S
2. Which of the following ions corresponds to zero group?
(3) HCl
(1) Pb2+
(4) NO2
(2) Cu2+
8. Which of the following will not give positive test with
(3) NH+
4
CHCl3/KOH?
(4) Mg2+
(3) CuBO2
(4)
(4) CuO
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10. Which compound gives positive iodoform test? 17. Given below are two statements
(1) Pentan-2-one Statement I : The point at which just an adequate
reagent is added to react completely with a substance is
(2) Pentan-3-one
known as equivalence point.
(3) Benzaldehyde Statement II : The point where colour change occurs in
(4) Isobutyl alcohol the system is the end point.
In the light of above statements choose the correct option.
11. In a reaction, MnO – ion is converted to Mn2+. The
4 (1) Both the statements I and II are correct
number of equivalents of KMnO4 present in 250 mL of (2) Both the statements I and II are incorrect
0.04 M KMnO4 solution is (3) Statement I is incorrect and statement II is correct
(1) 0.02 (4) Statement I is correct and statement II in incorrect
(2) 0.05
18. Phenolphthalein is an example of
(3) 0.04
(1) Strong acid indicator
(4) 0.07
(2) Weak acid indicator
12. In the salt solution ‘A’, KI followed by freshly prepared (3) Strong base indicator
starch solution is added and acidification with acetic acid (4) Weak base indicator
gives blue colour. The salt ‘A’ contains
19. How many moles of FeSO4 is completely oxidised by 2.5
(1) Cl–
mole of KMnO4 in acidic medium?
(2) CO
2–
3
(1) 2.5
(3) Br– (2) 12.5
(4) (3) 10
–
NO2
(4) 5
13. Which of the following indicators is most suitable for weak
acid vs strong base titration? 20. Methyl orange indicator is used in the acid-base titration
(1) Methyl orange whose pH range lies between____.
(2) Methyl Red (1) 3-4.5
(3) Phenolphthalein (2) 1-3
(4) Bromophenol blue (3) 7-11
(4) 11-14
14. Which of the following statements is/are correct for the
test of Br– ions? 21. Which of the following statements is/are correct for the
(a) Starch paper turns yellow when comes in contact with test of I– ions?
bromine vapours (a) Addition of MnO2 to the iodide salt intensifies the
(b) Evolution of brown fumes on heating the bromide salt evolution of violet vapours.
with conc. sulphuric acid (b) Iodine vapours turn starch paper blue
(c) Acidified sodium carbonate extract of bromide salt with
(c) Acidified sodium carbonate extract of iodide salt forms
AgNO3 gives brown precipitate.
yellow precipitate with AgNO3.
(d) Brown ring test is a confirmatory test for Br– ions (d) The precipitate formed is highly soluble in ammonium
(1) a only hydroxide.
(2) b and d only (1) a only
(3) a and b only (2) b and d only
(4) a, b, c and d (3) a, b and c
(4) a, b, c and d
15. The following reaction is performed for the detection of
NO ions
−
3
22. The correct statement among the following is
FeSO4 + NO → Product (1) Formic acid gives positive Tollen's test
Choose the correct statement Ethanol and propanone can be distinguished by
(2)
(1) Colour of the complex compound formed is violet iodoform test
(2) Oxidation number of 'Fe' in complex is +3 (3) Propan-1-ol turns blue litmus red
(4) Propane reacts with bromine water.
(3) The complex formed is [Fe(H2O)5NO]2+
(4) Colour of the complex product is yellow 23. The incorrect statement among the following is
Carboxylic acid reacts with NaHCO3 and produces
16. n-factor of KMnO4 is strongly basic medium is (1)
effervescence due to formation of CO2
(1) +3 (2) Schiff test is given by both aldehyde and ketone
(2) +5
2,4-DNP test can be given by both aldehyde and
(3) +1 (3)
ketone
(4) +2 (4) Propene decolorizes bromine water
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24. Titration of oxalic acid vs KMnO4 is type of 30. Consider the following statements.
Statement-A: Ethene and ethyne can be distinguished
(1) Precipitation titration
by bromine water.
(2) Redox titration Statement-B: Benedict’s solution is more stable than,
(3) Acid base titration Fehling’s solution.
(4) Complexometric titration In light of above two statements mark the correct option.
(1) Both statements A and B are correct
25. KMnO4 in redox titration with oxalic acid acts as:
(2) Both statements A and B are incorrect
(a) Strong oxidising agent
(3) Statement A is correct and statement B is incorrect
(b) Self indicator
(c) Strong reducing agent (4) Statement A is incorrect and statement B is correct
(1) Only (a) 31. The solution of compounds which turn blue litmus red
(2) Only (c) among the following are
(3) Both (a) and (b)
(4) Both (b) and (c)
(1) a(i), b(ii), c(iii), d(iv) 33. All of the following are white precipitates, except
(2) a(iv), b(iii), c(ii), d(i) (1) Ca(COO)2
(3) a(ii), b(i), c(iv), d(iii) (2) Mg(NH4)PO4
(4) a(iii), b(ii), c(i), d(iv) (3) PbSO4
27. Consider the following statements. (4) BaCrO4
Statement-A: Benzene does not decolorize bromine
water. 34. Consider the following statements:
Statement-B: Phenol decolourizes bromine water. Statement-I: Aqueous solution of ZnCl2 reacts with
In light of above two statements mark the correct option. NaOH solution to form white precipitate of Zn(OH)2.
(1) Both statements A and B are correct Statement-II: Zn(OH)2 is soluble in excess of NaOH
(2) Both statements A and B are incorrect solution on heating.
(3) Statement A is correct and statement B is incorrect In the light of above statements choose the correct option.
(4) Statement A is incorrect and statement B is correct (1) Both statement I and statement II are true
(2) Statement I is true but statement II is false
28. n-factor of KMnO4 in acidic medium is
(3) Statement I is false but statement II is true
(1) +3 (4) Both statement I and statement II are false
(2) +5
(3) +2
(4) +1
29. A reagent of known concentration in the titration is known
as
(1) Saturated solution
(2) Titrand
(3) Titrant
(4) Concentrate
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35. Given below are two statements : one is labelled as 39. On addition of group reagent to the original solution
Assertion (A) and the other is labelled as Reason (R). various basic radicals precipitates in the form of their
Assertion (A): Yellow coloured precipitate of lead respective salts. Match the given radicals (column-I) with
chromate is soluble in hot sodium hydroxide solution. their respective salt (column-II) in the form of which they
Reason (R): PbCrO4 ions react with hot sodium precipitate.
hydroxide solution to form Pb(OH)2. Column-I (Basic Column-II (Precipitates
In the light of the above statements, choose the most radical) as)
appropriate answer from the options given below. a. Pb2+ (Group-I) (i) Carbonate
Both (A) and (R) are correct and (R) is the correct
(1) b. Al3+ (Group-II) (ii) Sulphide
explanation of (A)
Both (A) and (R) are correct but (R) is not the correct c. Zn2+ (Group-III) (iii) Hydroxide
(2)
explanation of (A)
(3) (A) is correct but (R) is incorrect d. Ca2+ (Group-IV) (iv) Chloride
(4) (A) is incorrect but (R) is correct Select the correct option.
36. During the identification of basic radical in a salt, when its (1) a(iv), b(iii), c(i), d(ii)
small amount was treated with a few drops of sodium (2) a(iii), b(ii), c(iv), d(i)
hydroxide then a gas ‘X’ with characteristic odour is (3) a(iii), b(iv), c(ii), d(i)
evolved. Gas ‘X’ reacts with Nessler’s reagent to form a
brown coloured precipitate. The basic radical belongs to (4) a(iv), b(iii), c(ii), d(i)
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44. Sodium nitroprusside when added to sodium fusion 50. During the reaction of ferric chloride with NaSCN; blood
extract, it gives violet colour confirms the presence of red colour is appeared due to formation of
(1) Nitrogen (1) Fe(CN)3
(2) Chlorine (2) Fe(SCN)3
(3) Sulphur
(3) Fe(SCN)2
(4) Bromine
(4) [Fe(CN)6]4–
45. Mohr’s salt is
(1) Hexagonal crystal 51. Which of the following compound will produce
(2) Trigonal crystal effervescence with sodium bicarbonate?
(3) Monoclinic crystal (1) CH3CH2OH
(4) Triclinic crystal
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55. The major product (P) in the reaction given below is 59. Consider the following statements
Statement I : Acetylation of aniline is carried out in the
presence of weak base than amine
Statement II : During acetylation of amine, base like
pyridine removes HCl so formed and shift the equilibrium
towards forward direction
Choose the correct option
(1) Both statement I and statement II are correct
(1) (2) Both statement I and statement II are incorrect
(3) Statement I is incorrect but statement II is correct
(4) Statement I is correct but statement II is incorrect
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Additional Content
65. Iodoform reaction is given by 68. Given below are two statements: one is labelled as
assertion (A) and the other is labelled as reason (R).
Assertion (A) : Activating effect of –NHCOCH3 group in
a. b.
acetanilide is less than that of amino group in aniline.
Reason (R) : In acetanilide, the lone pair of electrons on
(CH3)2CH – CH2 – nitrogen is less available for donation to benzene ring by
c. d. resonance.
OH
In the light of above statements choose the correct
Choose the correct option. answer.
(1) a, b and c only Both (A) and (R) are true and (R) is the correct
(1)
explanation of (A)
(2) b, c and d only
(2) (A) is true but (R) is false
(3) a and b only
(3) (A) is false but (R) is true
(4) a, b, c and d
Both (A) and (R) are true but (R) is not the correct
(4)
66. Consider the following reaction explanation (A)
69. Identify the correct statement for the below reaction
(1)
(1)
(3)
(2) S2–
(3)
–
NO
2
(4) Cl–
71. CrO
2–
+ 2H
+
+ 2H2 O2 → (A) + 3H2 O
4
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72. Consider the following reaction 76. Which of the following statements are not correct?
a. Colloidal solution is a homogenous mixture
b. Egg albumin, starch and gum are lyophilic sol
c. Lyophillic sol are less stable than lyophobic sol
d. Lyophillic sol are called reversible sol
(4) –
x = √2y
(4)
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solvent
−
(2)H2 O2 / HO ⎝ ⎠
(3) Red
84. Enthalpy of hydration of 1 mole of CuSO4 (anhydrous) is (4) Black
–78.1 kJ. If 1 mole of anhydrous CuSO4 is dissolved in 91. Group-III reagent which is generally used for group
excess of water, – 66.4 kJ heat is evolved. Then heat analysis is
change when 1 mole of CuSO4·5H2O dissolved in water
(1) NH4OH + NH4NO3
will be
(1) +11.7 kJ (2) NH4Cl + (NH4)2CO3
liberation of iodine, the colour appeared will be Here, 20 mL of 0.1 M KMnO4 is equivalent to
(1) Blue
(1) 120 mL of 0.25 M H2C2O4
(2) Yellow
(2) 150 mL of 0.10 M H2C2O4
(3) Orange
(4) Red (3) 25 mL of 0.20 M H2C2O4
(4) 50 mL of 0.20 M H2C2O4
86. Which among the following will form negatively charged
colloid? 93. Which of the following is a group-I cation?
(1) 100 ml, 0.1 M AgNO3 + 100 ml, 0.1 M KI (1) Zn2+
(2) 50 ml, 0.2 M AgNO3 + 50 ml, 0.2 M KI
(2) NH
+
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96. The metal ion that imparts apple green colour to the flame 98. If enthalpy of neutralization of CH3COOH by NaOH is –
test is 49.86 kJ/mol then enthalpy of ionization of CH3COOH is
(1) Cu2+ (1) 7.24 kJ/mol
(2) Sr2+ (2) –7.24 kJ/mol
(3) 10.54 kJ/mol
(3) Ba2+
(4) 5.86 kJ/mol
(4) Ca2+
99. Chromyl chloride test is given by
97. In the test for iodine, (1) PbCl2
Na2 S2 O3 + I2 → NaI + P
(Product) (2) AgCl
Product (P) will be (3) Hg2Cl2
(1) Na2S4O6 (4) NH4Cl
(2) Na2SO4
100. Nitrate is confirmed by brown ring test. The brown colour
(3) Na2S of the ring is due to formation of
(4) Na3ISO4 (1) Ferrous nitrite
(2) Nitroso ferrous sulphate
(3) Ferrous nitrate
(4) Ferric nitrite
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