Professional Documents
Culture Documents
Physical Science LP
Physical Science LP
Learning Competencies
1. To give evidence for and explain the formation of the light elements in the Big Bang theory.
2. To site evidences for and describe the formation of heavier elements during star formation and evolution.
3. To write the nuclear fusion reactions that take place in stars, which lead to the formation of new elements.
I. INTRODUCTION
Everything around us is matter, which is composed of varying combinations of any of the 118 elements identified to
be present in the universe, including our planet. These elements are later found to be composed of atoms- the
building blocks of matter. How these elements formed and existed is explained by physicists, chemists and
astronomers on the basis of cosmology and the nuclear reactions that occurred during the early existence of the
universe.
II. NUCLEAR REACTIONS
- processes in which a nucleus of an atom combines with another nucleus (nuclear fusion) or splits into smaller
nuclei
(Nuclear fission) resulting to the emission of large amounts of energy.
NUCLEAR FISSION – the splitting of a heavy nucleus into lighter nuclei. This reaction sustains nuclear power
plants and nuclear weapons
NUCLEAR FUSION - involves the combining of light nuclei to form a heavier nucleus. These reactions fuel the
stars as well as hydrogen or thermonuclear bombs. This type of nuclear reaction produces less radioactive
products and are thus safe than nuclear fission reactions. Moreover, fusion reaction generates less amounts of
nuclear waste products that must be disposed off properly.
RADIOACTIVITY – the release of energetic particles of an atom during nuclear fusion and fission. These energetic
particles or radioactive particles come in the form of the following:
2. 210
84��
206
82�� + _____
234 0
3. ____ 90�ℎ + 0ϒ
===================================================================================
III. COSMIC ORIGIN OF ELEMENTS - elements are formed from certain cosmological phenomena
A. Big Bang Nucleosynthesis or Primordial Nucleosynthesis – refers to the formation of the nuclei of light elements
after the Big Bang
Few seconds after the explosion of the singularity, the subatomic particles such as protons, neutrons and
electrons were formed. As the expanding universe cooled, the protons and neutrons started to fuse to form heavier
nuclei of deuterium (an isotope of hydrogen with one neutron and proton) and some into helium. Subsequent nuclear
fusion reactions followed resulting to the formation of other light elements and their isotopes.
Astronomers believed that minutes after the Big Bang, the cosmos was composed of approximately 75 %
hydrogen, 25 % helium and trace amounts of helium.
The following are the nuclear reactions that lead to the formation of light elements and their isotopes.
1
1� + 10� 2
1� + 00ϒ 2
1� + 21� 2�� + 0�
3 1
1
2
1� + 1�
3
2�� + 00ϒ 3
1� + 2
1�
4
2�� + 10�
2
1� + 2
1�
3
1� + 11� 3
2�� + 2
1�
4
2�� + 1
1�
B. Stellar Formation/Nucleosynthesis – formation of elements heavier than lithium like carbon, neon, oxygen, silicon,
etc. Depends on the mass of the star. Thru nuclear reactions, particularly nuclear fusion:
Small stars can merely transform hydrogen into helium
Medium sized stars ( like the sun ) transform the atoms of helium into carbon and oxygen
Massive stars undergo further nuclear reactions causing the nuclei oxygen and carbon to fuse to form
neon, sodium, magnesium, silicon and sulfur
* The nuclear reactions involved in the formation of each new
element happened in regions or layers called fusion shells. As
more elements were produced, more layers added up to the size
of the star until it becomes a red giant star.
a.) Nuclear Reactions in the Hydrogen Fusion shell
( Hydrogen Burning )
0
1� + +1�
1 1 2
1� + 1�
0
0ϒ
2 3
1� + 11� 2�� +
3 The Fusion Shells
2�� + 32�� 4
+ 11� + 11�
2��
b.) Helium Burning – occurs in the core of stars once the temperature reaches about 108 K. Includes the following
reactions:
4 4 8 16 4 20
2�� + 2�� 4�� 8� + 2�� 10�� + energy
8 4 12 20 4 24
4�� + 2�� 6� 10�� + 2�� 12�� + energy
12 4 16
6� + 2�� 8� + energy
c.) Carbon and Oxygen Burning – occurs at approximately 5 x 108 K. includes the following nuclear reactions:
12 12 24 12 12 20
6� + 6� 12�� + energy 6� + 6� 10�� + 42��
12 12 23
6� + 6� 11�� + 11� 20
10�� + energy 16
8� + 42��
16 16 28
8� + 8� 14�� + 42��
d.) Silicon Burning
The formation of silicon establishes the following reactions (through alpha decay) that leads to an inner core
that is iron and nickel rich.
2 I PHYSICAL SCIENCE 11 HumSS and ABM
28 4 32 44 4 48
14�� + 2�� 16� + energy 22�� + 2�� 24�� + energy
32 4 36 48 4 52
16� + 2�� 18�� + energy 24�� + 2�� 26�� + energy
36 4 40 52 4 56
18�� + 2�� 20�� + energy 26�� + 2�� 28�� + energy
40 4 44
20�� + 2�� 22�� + energy
C. Stellar Explosion/SUPERNOVA – the violent explosion of a red giant star releases a huge amount of nuclear energy
and thereby, producing, through neutron capture and beta decay, other elements heavier than iron.
1
0�
62 63
28�� + 28�� neutron capture
63 63 0 63
28�� 29�� + −1β beta decay of unstable 28��
1
0�
63 64
29�� + 29�� neutron capture
64 64
29�� 30�� + −10β beta decay of an unstable 64
29��
Rapid process ( r process ) - a series of neutron capture that occurred very fast in such a way that the seed
nucleus turned into a relatively heavier nucleus before beta decay took place.
- Exemplified in the formation of cobalt from iron
- 5626�� + 3 10� 59
26�� ; 59
26��
59
27�� + −10β
==================================================================================================
FORMATIVE ASSESSMENT 1b. Construct a concept map that shows the cosmic origin of elements
==================================================================================================
LESSON 2.
I. ATOMIC STRUCTURE and DISCOVERY – an element is a pure substance made up of only one kind of atom.
An atom is the basic unit of matter. The word atom came from the Greek word “atomos” that means
indivisible.
A. Greek Philosophers and Their Claims About Atoms
a. Leucippus and Democritus – believed that all things are made up of tiny indivisible and indestructible
particles called atoms.
b. Aristotle – all things can be divided infinitely; therefore, he claimed that there is no smallest part of
matter.
Experimentation in the field of alchemy – the practice of transforming common metals into gold- allowed the testing
of early Greek hypotheses of atoms which has been the bases of more accepted principles of atomic theory.
B. Dalton’s Atomic Theory (John Dalton, 1766-1844)
a. Atom is composed of small invisible particles called atoms.
b. Atoms of the same element is identical.
c. Compounds contain atoms of more than one element
d. In a compound, atoms of different elements always combine in the same proportion by mass.
Recall that an atom is made up of sub atomic particle like the proton, electron, and neutrons that are arranged inside
the atom. To illustrate, look at the timeline of the development of the atomic structure.
1. Eugen Goldstein (1850-1930) discovered positively charged subatomic particle as a component of anode
rays.
2. Ernest Rutherford (1871-1937) coined the term proton for the positively charged particle in an atom.
3. J.J Thomson (1856-1940) in his CRT (cathode ray tube) experiment discovered that an atom is also
composed of negatively charged particles called electrons.
4. James Chadwick (1932) discovered the neutral particles, which he called neutrons, located in the nucleus of
an atom.
The discovery of these sub atomic particles contributed to the arrangement of the elements in the modern periodic
table. If observed, the elements are arranged based on increasing atomic number. The number of protons determine the
atomic number (Z) of an element. Furthermore, the number of protons is equal to the number of electrons, except in an
ion form where the atom may donate or accept an electron. The difference between the number of protons and the
==================================================================================================
II. CHEMICAL REACTIONS
A. CHEMICAL REACTION – a process whereby 2 or more substances (ions, atoms, molecules, compound) chemically
combine to produce a substance/s which are entirely different from the substances that reacted.
Eg. Oxidation reactions, decomposition reactions, rusting of iron, photosynthesis, cellular respiration
- represented by a chemical equation
B.CHEMICAL EQUATION – makes use of the chemical symbol or formula of substances and other symbols to summarize
a chemical reaction
- composed of:
a. Reactant – found at the left side of a chemical equation, the starting materials
b. Product – found at the right side of a chemical equation, the end-result of the reaction
HCl + NaOH NaCl + H2 O
reactant products
C. Symbols to be used in Transforming a Chemical Reaction to a Chemical Equation
SYMBOL MEANING
+ - separates reactants or products ( if there are more than one reactant or product )
At the reactant side, it is read as chemically reacts
At the product side, it is read as and or plus
- separates the reactant from the products
It is read as yields or produces
- a solid substance or a precipitate is produced
- substance must be heated first before it is broken down into its component substance
2. DECOMPOSITION REACTION – takes place when a complex compound is broken down into its component
substances in the presence of heat or electricity; the opposite of combination reaction
- Takes the form :
AB A + B
Examples:
a.) the decomposition of a metallic carbonate
metallic carbonate metallic oxide + carbon dioxide
* Molybdenum ( V ) Carbonate is decomposed to
Mo2 ( CO3 )5 Mo2 O5 + 5CO2
RULE 2. If the metallic cation has 2 valence numbers, use the classical/traditional method and or stock method
to name the compound
CLASSICAL OR TRADITIONAL METHOD – If the lower valence number is used, the English name or Latin name of the
element will end in ous, if the higher valence number is used, the name will end in ic. The name of the cation ending in
ous or ic will be followed by the name of the non-metallic ion ending in ide.
STOCK SYSTEM- Name the metallic cation followed by the valence number written in Roman Numerals and enclosed in
parenthesis and the name of non-metallic anion will follow ending in ide.
Example Classical Method Stock System Example Classical Method Stock System
FeBr2 ferrous bromide iron (II) bromide Hg3P Mercurous Phosphide Mercury ( I ) Phosphide
FeBr3 ferric bromide iron (III) bromide Hg3P2 Mercuric Phosphide Mercury ( II ) Phosphide
Naming Ions Using the Stock System and Old System
Ion Stock System Old System
Fe 2+
Iron (II) Ferrous
Fe3+ Iron (III) Ferric
Cu +
Copper (I) Cuprous
Cu2+ Copper (II) Cupric
Sn 2+
Tin (II) Stannous
Sn4+ Tin (IV) Stannic
Pb 2+
Lead (II) Plumbous
Pb4+ Lead (IV) Plumbic
Hg +
Mercury (!) Mercurous
Hg2+ Mercury (II) Mercuric
Au +
Gold (I) Aurous
Au2+ Gold (III) Auric
Ni 2+
Nickel ( II ) Nickelous
Ni3+ Nickel ( III ) Nickelic
Co 2+
Cobalt ( II ) Cobaltous
Co3+ Cobalt ( III ) Cobaltic
Pt2+
Platinum ( II ) Platinous
Pt4+ Platinum ( IV ) Platinic
RULE 3. For metals with more than two oxidation states, use the stock method.
Example Name Example Name Example Name
CrO3 Chromium ( VI ) Oxide Mo3Sb5 Molybdenum ( V ) Antimonide TiC Titanium ( IV ) Carbide
B. Binary Covalent Compound – a compound composed of two non-metals
RULE. Use prefixes to indicate the numbers of atoms present *Mono is never used in the first element
Example Name Example Name Example Name
NO2 Nitrogen Dioxide P2O5 Diphosphorus Pentoxide N5Cl Pentanitrogen Monochloride
7 I PHYSICAL SCIENCE 11 HumSS and ABM
C. Binary acids – acids composed of hydrogen and a non-tal in aqueous solution; non-oxygen acids
RULE. Use the prefix hydro followed by the name of the anion ending in ic and the word acid added at the end
Example Name Example Name Example Name
HCl(aq) Hydrochloric Acid H2S(aq) Hydrosulfuric Acid H4C(aq) Hydrocarbonic Acid
D. Compounds composed of hydrogen and another non-metal
RULE. Name the cation, Hydrogen followed by the name of the non-metal ending in ide.
Example Name Example Name Example Name
HCl Hydrogen Chloride H2S Hydrogen Sulfide H4C Hydrogen Carbide
E. Ternary compounds - compounds composed of more than two elements: a monoatomic ion and a polyatomic ion or
the cation is polyatomic and the anion is a monoatomic ion or both the cation and anion are polyatomic ions.
RULE. Give first the name of the cation followed by the anion; if the anion is a monoatomic ion, the name should end in
ide.
Example Name Example Name Example Name
Al2(SO4)3 Aluminum Sulfate NH4NO3 Ammonium Nitrate ( H3O )2 Se Hydronium Selenide
F. Ternary acids/Oxyacids – composed of the Hydrogen ion and a polyatomic ion whose name ends in ate or ite.
RULE. If the polyatomic ion name ends in ite, drop ite and change it to ous. If the polyatomic ion name ends in ate, drop
ate and change it to ic and the word acid is added as the last name of the oxyacid.
Chemical Formula Polyatomic ion name Name of Compound
HClO2 Chlorite Chlorous Acid
HClO3 Chlorate Chloric Acid
H3PO3 Phosphite Phosphorous Acid
H3PO4 Phosphate Phosphoric Acid
H2SO3 Sulfite Sulfurous Acid
H2SO4 Sulfate Sulfuric Acid
I. Hydrates – compounds whereby attached to their solid structure are several molecules of water.
RULE. Name the compound ( follow the above rules in naming ) followed by the prefix ( 1 - mono; 2 – di; 3 – tri…etc. )
and the word hydrate.
Eg. a.) Al2(SO4)3.7H2O Aluminum Sulfate Pentahydrate b.) Pt3P4 . 4 H2O Platinic Phosphide Tetrahydrate
Platinum ( IV ) Phosphide Tetrahydrate
--------------------------------------------------------------------------------------------------------------------------------------------------------------
FORMATIVE ASSESSMENT 2c. Give the names of the following compounds. Use a ½ sheet of pad paper. (15 pts)
1.) Rf3P4 9.) Cl4C7
2.) NF6 10.) H2SnO2
3.) Rb4C 11.) I2S7
4.) H4As2O7 12.) H3P
5.) Mo2Se5 13.) H3P(aq)
6.) HMnO4 14.) H3BO3
7.) Sb2( S2O3 )5 15.) Pt3( AlO3 )2
8.) Y4 �� (��) 6
---------------------------------------------------------------------------------------------------------------------------------------------------------------
IV. WRITING THE CHEMICAL FORMULA OF AN INORGANIC COMPOUND
A. How to Write the Chemical Formulas of Inorganic Compounds
CHEMICAL FORMULA – a written representation of a compound.
- shows the atoms and the number of atoms of a certain element that composes a compound.
* Criss Cross Method – the method used to write the chemical formula of a certain inorganic compound.
Ions – charged atoms
Cation – a positively charged ion Anion – a negatively charged ion
Monoatomic Ion – composed of a single atom with a charge
Polyatomic Ion – composed of several ions/atoms that carry an overall charge
8 I PHYSICAL SCIENCE 11 HumSS and ABM
A list of Polyatomic Ions with their corresponding charges
Polyatomic ion Formula and Charge Polyatomic ion Formula and Charge
Ammonium NH4+ Permanganate MnO4-1
Hydronium H3O+ Thiocyanate SCN-1
Acetate C2H3O2- Bismuthate BiO4-3
Bicarbonate HCO3-1 Borate BO3-3
Chlorate ClO3-1 Sulfate SO4-2
Chlorite ClO2-1 Sulfite SO3-2
Carbonate CO3-2 Thiosulfate S2O3-2
Chromate CrO4-2 Phosphate PO4-3
Dichromate Cr2O7-2 Phosphite PO3-3
Oxalate C2O4-2 Aluminate AlO3-3
Stannate SnO3-2 Arsenite AsO3-3
Stannite SnO2-2 Bismuthate BiO4-3
Ferricyanide Fe ( CN )6-3 Silicate SiO4-4
Orthosilicate SiO4-4 Pyroarsenate As2O7-4
Pyrophosphate P2O7-4 Ferrocyanide Fe ( CN )6-4
NOTE: If the name ends in -ic, Stannic Antimonic NOTE: If the name ends in -ous, Antimonous
the higher valence electron Phosphide Nitrate the lower valence electron was Nitrate
was used. used Sb+3 NO3-1
Sn+4 P-3 Sb+5 NO3-1 Stannous Phosphide Sb( NO3 )3
Sn3P4 Sb( NO3 )5 Sn2 P-3
Sn3P2
NOTE: If, after the name of Technetium
the cation, a roman numeral (VI ) Nitride
enclosed in a parenthesis
follows, the roman numeral Tc+6 N-3
indicates the valence number Tc3N6 TcN2
used.
The number 6.02 X 10²³ particles is known as the Avogadro’s number, named after Amedeo Avogadro, an Italian
Scientist whose work led to the determination of this value (6.02214179 X 10²³). The reason Avogadro’s number is so
large is because the masses of atoms are so small.
Molar Mass
The atomic mass of an element is the weighted average value of the masses of the isotopes in a naturally occurring
sample of the element. The atomic masses of all elements can be found in the Periodic Table of Elements. The unit used
for the mass of atom is “amu” which stands for atomic mass unit
Atomic Masses of Some Elements
Element Atomic Weight Mass of One Atom Mass of One Mole
H 1.00 1.0 amu 1.0 g
C 12.01 12.0 amu 12.0 g
N 14.01 14.0 amu 14.0 g
O 16.00 16.0 amu 16.0 g
Al 26.98 27.0 amu 27.0 g
Cu 63.55 64.0 amu 64.0 g
* The formula mass of a substance is the sum of the atomic masses of all atoms indicated in the formula of a substance.
This formula can be that of an element (H₂, P, O₂, Ar) or of a molecular compound (NaCl, H₂O).
* Formula mass cannot be determined without considering the molar masses of the individual elements. The mass in
grams of one mole of substance is called molar mass. Each element has its own unique molar mass.
* Finding molar mass starts with units of grams per mole (g/mol). When calculating molar mass of a chemical compound,
it states how many grams are in one mole of that substance. The number of grams in the molar mass of an element is
10 I PHYSICAL SCIENCE 11 HumSS and ABM
the same as the atomic mass. Translating atomic masses into molar masses, the following dimensional analysis can be
used:
40.08 g Ca or 1 molCa
1 molCa 40.08 g Ca
1. A Chestnut compound is a mixture of copper sulfate (CuSO₄) and ammonium carbonate [(NH₄)₂ CO₃] used in
horticulture to prevent damping off in seedlings. Solve for the formula mass of the two substances used in the
preparation of this compound.
Formula Mass of CuSO₄ Formula Mass of (NH₄)₂ CO₃
Cu = 63.5 ɥ X 1 atom = 63.5 g/mol N= 14.01 ɥ X 2 atoms = 28.02 g/mol
S = 32.1 ɥ X 1 atom = 32.1 g/mol H=1.01 ɥ X 8 atoms=8.08 g/mol
O= 16.0 ɥ X 4 atoms= 64.0 g/ mol C=12.01 ɥ X 1 atom= 12.01 g/mol
TOTAL 159.6 g/mol O=16.0 ɥ X 3 atoms=48. 0 g/mol
TOTAL 96.11 g/mol
B. STOICHIOMETRIC CONVERSIONS
FOUR SIMPLE STEPS IN STOICHIOMETRY
1. Balance the equation.
2. Convert the units of a given substance to moles
3. Using the mole ratio, calculate the moles of a substance yielded by the reaction
4. Convert moles of the wanted substance to the desired units.
One mole of certain elements implies two things, namely: the molar mass of the element and the Avogadro’s number (N)
which is the same for all elements. Since the mole is used often in chemistry to quantify the number of atoms, molecules
and several other atoms, it is important to know the relationships that exist and how to move from one to another.
Mole to Mass
Sample problem: Johann Van Helmont was the first to prepare sulfuric acid by destructive distillation of ferrous sulfate
(1,600). This substance, which reacts violently with water, has recorded a melting point of -2 °C and boils at 327 °C.
Determine the mass in grams of 11.22 mol of sulfuric acid.
Solution: First, look up the atomic masses for hydrogen, sulfur, oxygen from the Periodic Table. The atomic mass is 1.01
for H; 32.07 for S; 16.00 for O. the formula mass of H₂SO₄ is:
H= 2 X 1.01= 2.02 g/mol
3. Use the balanced equation to set up the appropriate 0.20 mol of ��2 �3 X
3 ��� �� ����2
= 0.6 mol 0f BaCl2
1 ��� ����2 �3
mole ratios
4. If the problem is asking for the mass, convert the 0.6 mol 0f BaCl2 X
207 � �� ����2
= 124.2 g of BaCl2
1 ��� �� ����2
computed number of moles to grams
Therefore, 20 g ��2 �3 of reacted with 124.2 g of BaCl2
9�
= 11.88 �X 100
% YIELD = 75.76 %
==================================================================================================
=
FORMATIVE ASSESSMENT 2e.
A. Solve the molar mass of the given substance and convert the unit. Use a one whole sheet of pad paper.
1.) 34 g of Pb3 As4 to mol.
2.) 8 g of P2 S3 to number of particles
3.) 2.7 mol of �5 �12 to grams and number of particles
4.) 4.3 X 1020 particles of Silver (Ag) to number of moles and grams
Aside from household products, chemistry has been useful in explaining the contents and benefits of various personal
care products that enhance the appearance of the human body- cosmetic products. These products include lotions,
shampoos, shaving creams among others. Below are some of the common chemical components of some personal care
products.
Active Ingredients 2. 2.
Effects
----------------------------------------------------------------------------------------------------------------------------------------------------------------
LESSON 4. USES, PROPERTIES, MODE OF ACTION, OF PRODUCTS (FUEL, PERSONAL CARE AND HOUSEHOLD PRODUCTS)
AND PRECAUTIONS ON THE USE OF SUCH PRODUCTS.
Along with these benefits are the precautionary measures in handling every chemical used at home to maintain over all
health and safe environment. Below are some of the reminders that will help in using cleaning products and cosmetics:
1. Less or non-toxic alternatives should be used whenever possible.
2. Phosphate free laundry detergents and automatic dishwasher detergents should be used to reduce
contamination of the aquatic environment by high levels of dissolved plant nutrients which leads to algal blooms.
3. Use water-based products whenever possible.
4. Products should be used in well ventilated areas to avoid inhaling fumes.
5. Chemical products should be stored away from heat or possible sources of sparks.
6. Read and follow the proper use of chemical products carefully. Any hazards are indicated by pictograms and
statements while the relevant precautions, like wearing gloves or eye protection, are listed on the label.
7. Personal protective equipment, like protective gloves, aprons, and eye protection, should be used.
8. Different products should not be mixed with other unless the label directs the user to do so.
9. Special care should be taken when using caustic soda (sodium hydroxide). This can erupt when mixed with water.
Splashes in the eye can cause blindness.
10. Concentrates that contain bleach should never be mixed with any other chemical. These can react and
dangerous gas (chlorine) is released.
11. Pregnant women should avoid chemical exposure as much as possible. Some products are classified as toxic for
reproduction.
12. When taking chemical products to a civic amenity site for disposal, the containers should be carefully sealed and
clearly labelled with the name and active ingredient of the products.
----------------------------------------------------------------------------------------------------------------------------------------------------------------
FORMATIVE ASSESSMENT 4. In groups, identify the mode of action and properties of the following products.
1. Lipstick 4. Dishwashing liquid
2. Whitening soap 5. Bleach
3. Moisturizers/Lotion 6. Detergent
15 I PHYSICAL SCIENCE 11 HumSS and ABM
16 I PHYSICAL SCIENCE 11 HumSS and ABM