Which of The Following Compounds Will Show Cis Trans Isomerism

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Byju's Answer Standard XIII Chemistry Cis-Trans Nomenclature


Which of the ...

Question

Which of the following compounds will show cis -


trans isomerism?

A (CH3 )2 C = CHC2 H5

B H2 C = CCl2

C CH3 HC = CClCH3

D ClCH = CH2

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Solution

The correct option is C CH3 HC = CClCH3


Conditions for geometrical isomers:
1) Free rotation must be restricted.
2) Both the terminals must be attached with
different groups.
3) Terminals must not be in perpendicular planes.

a. (CH3 )2 C = CHC2 H5 has two methyl groups


attached to the same carbon of the double bond
so geometrical isomerism is not possible.

b. H2 C = CCl2 has two chlorine atoms attached to


the same carbon of the double bond so
geometrical isomerism is not possible.

c. CH3 HC = CClCH3 has different groups


attached to both carbons of the double bond so
geometrical isomerism is possible.

d. ClCH = CH2 has two hydrogen atoms attached


to the same carbon of the double bond so
geometrical isomerism is not possible.

Since all compounds have the same groups


attached to double bonded carbon atom except
in 2-chlorobut-2-ene, thus only 2-chlorobut-2-
ene exhibit cis-trans isomerism.

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Video Solution

NEET - Grade 12 - Chemistry -


Stereochemistry-1 - Session 01 - W08
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CHEMISTRY 01:50 Min | 61 Views

SIMILAR QUESTIONS

Q. Which of the following compounds will show


cis - trans isomerism?

Q. Which of the following compounds will exhibit


cis-trans isomerism?

Q. Which of the following compounds will not


show cis-trans-isomerism?

Q. Which of the following compounds will exihibit


cis trans isomerism:

Q. Which of the following compounds will exhibit


cis − trans (geometrical ) isomerism?

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