VIBRANT ACADEMY ORGANIC CHEMISTRY

Class Test-4
(India) Private Limited Target IIT JEE 2024
CLASS : XII (MEGA)
Topic : Aldehyde Ketone Carboxylic Acid & its Derivatives
Single Choice Question :
1. Which of the following compounds show positive tollen test
O O
(a) (b) (c) NaI
H C OH
OH
NH3 Cl
(d) (e)
OH
OH
O OR
(f) (g) (h) OR
OR OH
OCH3
S S OH
(i) (j) H
H
(A) 3 (B) 4
(C) 5 (D) 6

2. Examine the structural formulas of following compounds

and find out number of compounds which show higher
rate of nucleophilic addition than
O
H3C C H

O H O H O H

:OCH3 Cl NO2
:

O H O H O H

:N(CH3)2 :OH C N
:

(A) 3 (B) 4
(C) 5 (D) 6

Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 0744-3507788 (www.vibrantacademy.com) [1]
3. Consider the following reactions and identify how many
reactions can give carbonyl compounds as major product.
Ph O3 KMnO4/OH
(a) (b)
Ph Me2S OH
OH
(c) KMnO4 (d) KMnO4/OH
OH
OH
O PhMgBr
(e) (f) CrO3
O Dil. Acetone

O O

Cl Cl
(g) (h)
AlCl3 AlCl3

(A) 3 (B) 4
(C) 5 (D) 6

4. Of the following carbonyl compounds, how many would

give aldol condensation reaction.
O O
O
, C CH3 , C H ,
H3C C CH3

O
CH3 O
H
H3C C H
H , , ,
CH3 O
O

O
O
H H
O , Ph
H O
(A) 3 (B) 4
(C) 5 (D) 6

Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 0744-3507788 (www.vibrantacademy.com) [2]
5. Examine the structural formulas of compounds given below
and identify number of compounds which show positive
iodoform test.

O O O O
, , , ,
H
O
O O
, C CH3 , ,
O
O
O O
,
Ph Ph
(A) 3 (B) 4
(C) 5 (D) 7

6. Find out number of substrates those cannot undergo

Cannizzaro's reaction.
O O O
, , ,
H C H Ph C H H 3C C H
O
O O O
C CH3 , , ,
H C C H H3C C H

O O O O
, , O C H
Ph C C Ph Ph C C H
O
(A) 3 (B) 4
(C) 5 (D) 6

7. Find the number of reactions in which aldehyde is obtained

as one of the product.
O
H2 -Pd (i) SnCl2 /HCl
(a) CH3 C Cl (b) CH 3 C  N
BaSO4 –
  

(ii) H3O

CH3 CH +
(i) CrO2Cl2 NH H3O
(c) (ii) H2O
(d)

O
C
(e) Cl (i) DIBALH (f) CH3– CH2– OH
Cu

(ii) H2O

OH
PCC Dry
(g) (h) (CH3COO)2 Ca + (HCOO)2 Ca
CH2Cl2 distillation

(i) CH3MgCl + CH3C  N

H3O
(A) 7 (B) 9
(C) 11 (D) 13

Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 0744-3507788 (www.vibrantacademy.com) [3]
8. Identify that compounds that give Cannizaro reaction
H O O
(a) H (b) (c) CH3

O
H D H3C

O CHO
(d) (e)
H 3C CH3

O O
H3C O CHO
(f) (g) (h)

O
O
(i) OHC CHO (j) (k)
H 3C CH3

O CH3

(l) CH3 (m)

H3C CH3
H3C O
CH3
H3C
(n)
CH3
O
(A) 3 (B) 4
(C) 5 (D) 6

9. How many aldehydes, ketones (including stereoisomers)

are possible of molecular formula C8H8O2 (benzene
derivatives only) that are capable to give fehling's test
positive.
(A) 3 (B) 4
(C) 5 (D) 6

10. x = number of reaction in which final product is aldehyde

DIBAL–H LiAlH 4
(a) Ph – C  N (b) Ph – C  N
–78ºC, H2O
O O
H2
(c) (d) Ph – C – O – Et DIBAL–H
Pd-BaSO4
Ph Cl
O
DIBAL–H aq. KOH
(e) (f) CH3 – CHCl2
Ph OH
(A) 3 (B) 4
(C) 5 (D) 6

Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 0744-3507788 (www.vibrantacademy.com) [4]
11. Count the number of reactions in which ketone is
formed as final product.
O

H2SO4 OH
(1) (2) 
OH OH
O

CCH
N
BH3:THF
(3) (4) H3O
H2O2/HO

NH
(5) H 3O

O O
(6) + H2SO4
O

OH
HIO4
(7) or
OH Pb(OAc)4

(8) CH3MgBr + CH3 OCH3

(1 mole)
(A) 3 (B) 4
(C) 5 (D) 6

Video solution by M S Chouhan (MSC sir)

Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 0744-3507788 (www.vibrantacademy.com) [5]