PRINCIPLES RELATED TO

PRACTICAL CHEMISTRY
(OC & PC)
1. Match the following column I with column II and choose the correct option from the codes given below :
Column-I (Distinguish) Column-II (By reagent)
(A) Phenol and Methanol (P) HCl + anhyd. ZnCl2
(B) Methanol and ethanol (Q) Sodium metal
(C) Ethanol and butan-2-ol (R) Iodoform test

(D) Methanol and diethyl ether (S) Bromine water

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(1) A-R, B-S, C-P, D-Q (2) A-P, B-R, C-S, D-Q (3) A-S, B-R, C-P, D-Q (4) A-S, B-P, C-R, D-Q
LrEHk I dk feyku LrEHk II ds lkFk dhft, rFkk fn;s x;s dwVksa ls lgh fodYi pqfu,:
LrEHk-I (foHksfnr) LrEHk-II (vfHkdeZd }kjk)
(A) QhukWy rFkk esFksukWy (P) HCl + ZnCl2
(B) esFksukWy rFkk ,sFksukWy (Q) lksfM;e /kkrq
(C) ,sFksukWy rFkk C;wVsu-2-vkWy (R) vk;MksQkWeZ VsLV
(D) esFksukWy rFkk Mkb,sfFky bZFkj (S) czksehu ty
(1) A-R, B-S, C-P, D-Q (2) A-P, B-R, C-S, D-Q (3) A-S, B-R, C-P, D-Q (4) A-S, B-P, C-R, D-Q
2. Assertion : Acetaldehyde given red ppt. when treated with Fehling's or Benedict's solution.
Reason : The red ppt formed is due to CuO formed.
(1) Both assertion and reason are true (2) Assertion is true but reason is false
(3) Assertion is false but reason is true (4) Both assertion and reason are false
dFku : ,slhVSfYMgkbM dks Qsfyax ;k csusfMDV foy;u ds lkFk mipkfjr djus ij ;g yky vo{ksi nsrh gSA
dkj.k : CuO cuus ds dkj.k yky vi{ksi fufeZr gksrk gSA
(1) dFku rFkk dkj.k nksuksa lgh gSA (2) dFku lgh gS ijUrq dkj.k xyr gSA
(3) dFku xyr gS ijUrq dkj.k lgh gSA (4) dFku rFkk dkj.k nksuksa xyr gSA
3. Which of the following statement is Incorrect ?
(1) By burning the given compound in flame, we can identify whether the given compound is alphatic or aromatic
(2) Phenol and ethanol can be distinguished by NaHCO3 test
(3) Phenol and carboxylic acid cannot be distinguished by litmus paper
(4) Acetaldehyde and acetone cannot be distinguished by sodium bisulphite test
fuEu esa ls dkSulk dFku lgh ugha gS ?
(1) fn;s x;s ;kSfxd dks Tokyk esa tykdj] ge fn;s x;s ;kSfxd dks fd og ,sysQsfVd gS ;k ,sjksesfVd igpku ldrs gSA
(2) QhukWy rFkk ,sFksukWy dks NaHCO3 ijh{k.k }kjk foHksfnr dj ldrs gSA
(3) QhukWy rFkk dkcksZfDlfyd vEy dks fyVel i= ds }kjk foHksfnr ugha dj ldrs gSA
(4) ,slhVSfYMgkbM rFkk ,slhVksu dks lksfM;e ckblYQkbV ijh{k.k }kjk foHksfnr ugha dj ldrs gSA
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4. Statement-I : Benzaldehyde and acetophenone can be distinguished by Fehling solution.
Statement-II : Ketones does not show Fehling test.
(1) Both I and II are true (2) I is true but II is false
(3) I is false but II is true (4) Both I and II are false
dFku-I : cSUtSfYMgkbM rFkk ,slhVksQhukWu dks Qsfyax foy;u }kjk foHksfnr dj ldrs gSA
dFku-II : dhVksu Qsfyax ijh{k.k ugha n'kkZrs gSaA
(1) I rFkk II nksuksa lR; gS (2) I lgh gS ijUrq II xyr gS
(3) I xyr gS ijUrq II lgh gS (4) I rFkk II nksuksa xyr gS
5. Match the following column I with column II and choose the correct option form the codes given below :

Column-I (Distinguish) Column-II (By reagent)

(A) Acetaldehye and Acetone (P) DNP test

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(B) 2-pentanone and 3-pentanone (Q) Ethanol + conc H2SO4 /∆

(C) Phenol and Cyclohexanone (R) Iodoform test

(D) Phenol and Acetic acid (S) Tollens reagent

(1) A-R, B-S, C-P, D-Q (2) A-S, B-R, C-P, D-Q (3) A-S, B-P, C-R, D-Q (4) A-R, B-Q, C-S, D-P
LrEHk I dk feyku LrEHk II ds lkFk dhft, rFkk fn;s x;s dwVksa ls lgh fodYi pqfu,:
LrEHk-I (foHksfnr) LrEHk-II (vfHkdeZd }kjk)

(A) ,slhVSfYMgkbM rFkk ,slhVksu (P) DNP ijh{k.k

(B) 2-isaVsukWu rFkk 3-isaVsukWu (Q) ,sFksuksy + lkUnz H2SO4 /∆

(C) QhukWy rFkk lkbDyksgsDlsu (R) vk;MksQkWeZ ijh{k.k

(D) QhukWy rFkk ,sflfVd vEy (S) VkWysu vfHkdeZd

(1) A-R, B-S, C-P, D-Q (2) A-S, B-R, C-P, D-Q (3) A-S, B-P, C-R, D-Q (4) A-R, B-Q, C-S, D-P
6. Aniline and ethanamine can be distinguished by :
(1) CHCl3/KOH (2) Mustard oil test
(3) Hinsberg test (4) NaNO2/HCl followed by β-napthol
,sfuyhu rFkk ,sFksusehu dks fuEu esa ls fdlds }kjk foHksfnr dj ldrs gS:
(1) CHCl3/KOH (2) eLVMZ vk;y ijh{k.k
(3) fgUlcxZ ifj{k.k (4) NaNO2/HCl ds ckn β-us¶FkkWy ls
7. Phenol and Benzoic acid can be distinguish by :
(1) Litmus test (2) Burning (3) NaOH (4) NaHCO3
QhukWy rFkk csUtksbd vEy dks fuEu esa fdlds }kjk foHksfnr dj ldrs gS:a
(1) fyVel ijh{k.k (2) tykdj (3) NaOH (4) NaHCO3
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8. Which of the following is incorrect statement ?
(1) Methyl amine and dimethyl amine can be distinguished by adding Ph-SO2Cl followed by dilute alkali.
(2) Benzene diazonium chloride reacts with aniline in weakly acidic medium to given an yellow dye called as
aniline-yellow
(3) Dimethyl amine and trimethyl amine can be distinguished by carbylamine test
(4) Primary and secondary aliphatic amine can be distinguished by NaNO2/HCl followed by cerric ammonium
nitrate
fuEu esa ls dkSulk dFku lgh ugha gS?
(1) esfFky ,sehu rFkk MkbesfFky ,sehu dks Ph-SO2Cl feykus ds i'pkr ruq {kkj }kjk foHksfnr dj ldrs gS
(2) csathu Mkb,stksfu;e DyksjkbM nqcZy vEyh; ek/;e esa ,sfuyhu ds lkFk fØ;k djds ,d ihyk jatd tks fd
,sfuyhu izhr dgykrk gS nsrh gS
(3) MkbesfFky ,sehu rFkk VªkbesfFky,sehu dks dkfcZy ,sehu ijh{k.k }kjk foHksfnr dj ldrs gSA
(4) izkFkfed rFkk f}rh;d ,sysQsfVd ,sehu dks NaNO2/HCl ds i'pkr lsfjd veksfu;e ukbVªsV }kjk foHksfnr dj
ldrs gSa

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9. Assertion : In the test of halogen, first he sodium extract is treated with nitric acid and then treated with
AgNO3.
Reason : AgCN is white ppt and Ag2S is black ppt.
(1) Both assertion and reason are correct and reason is the correct explanation of assertion
(2) Both assertion and reason are correct but reason is not the correct explanation of assertion
(3) Assertion is true but reason is false
(4) Assertion is false but reason is true
dFku : gSykstu ds ijh{k.k esa] igys lksfM;e Nfur dks ukbfVªd vEy ds lkFk mipkfjr djds rc blds ckn
AgNO3 ls mipkfjr djrs gSA
dkj.k : AgCN lQsn vo{ksi gS rFkk Ag2S dkyk vo{ksi gS
(1) dFku rFkk dkj.k nksuksa lgh gS rFkk dkj.k] dFku dh lgh O;k[;k gSA
(2) dFku rFkk dkj.k nksuksa lgh gS ijUrq dkj.k] dFku dh lgh O;k[;k ugha gSA
(3) dFku lgh gS ijUrq dkj.k xyr gSA
(4) dFku xyr gS ijUrq dkj.k lgh gSA
10. Which of the following incorrect ?
(1) Colloidal sol of starch is example of lyophilic sol.
(2) Colloidal sol of egg albumin is prepared by mixing egg white into water directly.
(3) Ferric hydroxide sol is prepared by direct mixing of it with water.
(4) Ferric hydroxide sol is lyophobic sol.
fuEu eas ls dkSulk vlR; gS?
(1) LVkpZ dk dksyk;Mh lksy nzOkLusgh lksy dk mnkgj.k gS
(2) v.Ms dh tnhZ dk dksyk;Mh lksy] v.Ms dh lQsnh dks ty esa lh/ks feykdj cuk;k tkrk gS
(3) Qsfjd gkbMªksDlkbM lksy dks bls ty esa lh/ks feykdj cuk;k tkrk gSA
(4) Qsfjd gkbMªksDlkbM lksy nzOkfojks/kh lksy gSA
11. The process of conversion of freshly prepared precipitate in colloid by shaking with an electrolyte is known as :
(1) dialysis (2) peptization (3) coagulation (4) tindal effect
fo|qr vi?kV~; ds lkFk feykdj dksyk;M esa rktk cuk;s x;s vo{ksi ds ifjorZu dh fof/k dgykrh gS :
(1) viksgu (2) isIVhdj.k (3) Ldanu (4) fV.MYk izHkko
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12.
dil.H2SO4
H2S H2S
H2S gas Rubber tube

Iron sulphide
dil. H2SO4

water Beaker

As2O3 solution

In above exp what is the colour of solution in beaker and what is the charge on colloidal particles.
(1) Yellow, positive (2) Yellow, negative
(3) Red, positive (4) Red, negative
mijksDr iz;ksx esa] chdj eas foy;u dk jax D;k gS rFkk dksyk;Mh d.kks ij vkos'k D;k gSA
(1) ihyk] /kukRed (2) ihyk] _.kkRed

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(3) yky] /kukRed (4) yky, _.kkRed
13. What happened when egg albumin sol is prepared in hot water ?
(1) Sol is more stable in it (2) It solidifies in hot water
(3) It take lesser time to prepare (4) Its surface tension increases
D;k gksrk gS] tc v.M+s dh tnhZ dks xeZ ikuh esa cuk;k tkrk gS ?
(1) lksy bleas vf/kd LFkk;h gksrk gS (2) ;g xeZ ty esa Bksl gks tkrk gS
(3) fuekZ.k eas de le; ysrk gS (4) bldk i`"B ruko c<+rk gS
14. FeCl3 + 3H2O () → Fe(OH)3 (aq) + 3HCl (aq) in the preparation of lyophobic sol of Fe(OH)3, HCl is removed

by :
(1) Dialysis (2) Peptization (3) Coagulation (4) Tindal effect
FeCl3 + 3H2O () → Fe(OH)3 (aq) + 3HCl (aq), Fe(OH)3 ds nzOkfojks/kh lksy ds fuekZ.k eas] HCl dks dSls gVk;k

tkrk gSA
(1) viksgu (2) isIVhdj.k (3) Ldanu (4) fV.MYk izHkko
15. For reaction of iodide ion with H2O2 at room temperature, what will be the order of reaction concerning iodide
ion ?
(1) Second order reaction (2) Zero order reaction
(3) Third order reaction (4) First order reaction
dejs ds rki ij vk;ksMkbZM vk;u dh H2O2 ds lkFk vfHkfØ;k ds fy,] vk;ksMkbM vk;u ds lUnHkZ eas vfHkfØ;k dh
dksfV D;k gksxh
(1) f}rh;d dksfV vfHkfØ;k (2) 'kwU; dksfV vfHkfØ;k
(3) r`rh;d dksfV vfHkfØ;k (4) izFke dksfV vfHkfØ;k
16. What is the colour of the starch iodine complex formed ?
(1) Yellow (2) Blue (3) Green (4) Red
fufeZr LVkpZ vk;ksMhu ladqy dk jax D;k gS ?
(1) ihyk (2) uhyk (3) gjk (4) yky
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17. Which of the following is correct ?
(1) CuSO4(s) + 5H2O() → CuSO4.5H2O (s) the heat of reaction is enthalpy of solution at constant pressure &
temperature.
(2) CuSO4(s) + H2O (Excess) → CuSO4(aq) the heat of reaction is enthalpy of solution at constant pressure &
temperature.
(3) CuSO4.5H2O(s) → CuSO4(s) + 5H2O is exothermic process.
(4) Enthalpy of solution is always negative.
fuEu eas ls dkSulk lgh gS?
(1) CuSO4(s) + 5H2O() → CuSO4.5H2O (s) vfHkfØ;k dh Å"ek] fLFkj nkc o rki ij foy;u dh ,UFksYih gksrh gSA

(2) CuSO4(s) + H2O (Excess) → CuSO4(aq) vfHkfØ;k dh Å"ek] fLFkj nkc o rki ij foy;u dh ,UFksYih gksrh gSA
(3) CuSO4.5H2O(s) → CuSO4(s) + 5H2O Å"ek{ksih izØe gSA
(4) foy;u dh ,UFksYih lnSo _.kkRed gksrh gSA
18. The heat of solution of anhydrous CuSO4 and CuSO4.5H2O are –15.89 Kcal mol–1 and 2.80 Kcal mol–1

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respectively, What will be heat of hydration of anhydrous CuSO4 ?
futZy CuSO4 rFkk CuSO4.5H2O foy;u dh Å"ek Øe'k%–15.89 Kcal mol–1 rFkk 2.80 Kcal mol–1 futZYk CuSO4 eas
ty;kstu dh Å"ek gksxh ?
(1) –18.69 Kcal (2) 18.69 Kcal (3) –28.96 Kcal (4) 28.96 Kcal
19. Which of the following is correct ?
(1) The value of enthalpy of neutralization of all acid and base is equal to 13700 cal.
(2) When one gram equivalent of acid is completely neutralized by one gram equivalent of base the heat
released is 13700 cal.
(3) The value of enthalpy of neutralization of all strong acid and strong base is equal to 13700 cal.
(4) when one gram equivalent of strong acid is completely neutralized by one gram equivalent of strong base the
heat released is 13700 cal.
fuEUk eas ls dkSulk lR; gS ?
(1) lHkh vEy o {kkjks ds mnklhuhdj.k dh ,UFksYih dk eku 13700 ds cjkcj gksrk gSA
(2) vEy dk ,d xzke rqY;kad {kkj ds ,d xzke rqY;kad ls iw.kZr;k mnklhuhd`r gksrk gS] fu"dkflr Å"ek 13700 cal gSA
(3) lHkh izcy vEYk rFkk izcy {kkjks ds mnklhuhdj.k dh ,UFksYIkh dk eku 13700 cal ds cjkcj gksrk gSA
(4) izcy vEy dk ,d xzke rqY;kad izcy {kkj ds ,d xzke rqY;kad }kjk iw.kZr;k mnklhuhd`r gksrk gS] fu"dkflr
Å"ek dk eku 13700 cal gSA
20. The heat of neutralization of a strong acid and a strong alkali is 57.0 kJ equivalent–1. The heat released when
0.5 mole of HNO3 solution is mixed with 0.2 mole of KOH is :
(1) 57.0 kJ (2) 11.4 kJ (3) 28.5 kJ (4) 34.9 kJ
,d izcy vEy rFkk ,d izcy {kkj ds mnklhuhdj.k dh Å"ek 57.0 kJ equivalent–1 gSA 0.5 eksy HNO3 foy;u dks
0.2 eksy KOH ds lkFk fefJr djus ij mRlftZr Å"ek gS :
(1) 57.0 kJ (2) 11.4 kJ (3) 28.5 kJ (4) 34.9 kJ

ANSWER KEY : (PRINCIPLES RELATED TO PRACTICAL CHEMISTRY) OC & PC

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. 3 2 2 3 2 4 4 3 2 3 2 2 2 1 4 2 2 2 4 2
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