CBSE+2 CHEMISTRY CDF MATERIAL

2. ELECTRO
CHEMISTRY
GALNANICCELL
The cellwhich converts chemical energy to clectric energy is called
a) Galvanicor Voltaic cell b)Photo cell
c) Pimary oell d) Secondary cell
Galvanic or Voltaic cell redox reaction is

a) Mg(s) +2Ag* ’ Mg" +2Ag(s)

d)All
3. The example for Galvanic or Voltaic cell is
a) Primary cell b) Secondary cell
c) Photo cell d) Daniel cell
4 The cellnotation of Daniel (Galvanic) cell is

5 EMF ofthe cell is calculated by

a) E = Eet-Eich (or)E = Eanode Eeahode

b) El =Eot -Ej (or)E.el =Eanode Eanode

c) E =Eir -Ea (orE =Poahd -Eanok

d) Eell = Eich -Eriehr (or)E = Ea
cathode -Ecathode

SINGLE ELECTRODE POTENTIAL

6.
A metal(or) non-metal in contact with the solution ofits ions tends to develop electric potential at
the metal ion (or) non-metalnon-metal ion interface is called
a) Single electrode potential b) Reduction potential
c) Cellpotential d) Halfcell
BLECTRODE POTENTIAL
1.
The potential difference developed between the electrode and the electrolyte is called
a) Standered electrode potential b) Electrode potential
c)Cell electro motive force d) Cell Potential

NARAYANA GROUP Page No. [90]

RSE2

Sngle clatnxie otential is Measuedbyconbining with CHEMISTRY

a) Standerd platinum eloctroxde b)
)Standard lhydnogen clectrode d)
Standered
mecury electrode
Standered aurum clectrode
ELECTROCHEMICALSERIES
9
Arangement of different metals in theincreasing order of reduction
a)Galvanic cell
c) Secondary cell
b) Primary cell potentials knowna
is
d) Electrochemical series
10. High reduction potential metal ions
undergo and act as
a) Oxidation, Anode
b) Reduction, Cathode
c) Reduction, Anode
d) Oxidation,Cathode
11. Low reduction potential
metal ions (high negativevalue) undergo
a) Oxidation, Anode and act as
b) Reduction, Cathode
c) Reduction, Anode
d) Oxidation, Cathode
12,
K*IK=-2.93V, Ag*IAg =0.80V , Hg* Hg =
0.79V ,
Mg*/Mg = -2.37V, Cr /
Cr=-0.74V
Arrange these metals in their increasing order of
a) K*K> Mg* | Mg > reducing power.
Cr* ICr> Hg* | Hg > Ag* / Ag
b) Hg* > Ag*I Ag /Mg >
Cr* / Cr > K* IK> Mg
c) Mg > Cr* /Cr> Hg* >
Ag*IAg IK* IK> Mg?*
d) Mg > Cr* ICr >
K*TK> Mg* > Hg*> Ag* I Ag
NERNST EQUATION
13. The Nernst equation for
metals is represented by
a) A,G=-4FEcd)

b) E- E t 0.059 log
M" (or) E=E 0.059
n
log C
c) A,Go =-RT In K

d) E = E 0.059
log| M(or) E= E 0.059
-log C
n

NARAYANAGROUP PageNo.191/
 CHEMISTRY CDF MATERIAL
CBSE+2

The Nernstcquationfor non-metals is represented by

14
AG=-RT'ln R
a)
0.059 0.059
b)E=E
+. logM" ](or)E=En + -logC

0.059 0.059
log C

energychangeeiin the Galvanic cell (AG) and electrode potential ofthe cell ( Eel ) are
5 Gibb's
relatedas

a) AG=-nE(oel)

b) 4,G =-RTIn K
0.059 0.059
log M(or)E =E -log C
c) E= Pll n

0.059 0.059
log4 (or)E =Exa -log C
) E= El

reaction(A,G") and standred electrode potiential of

16. StandardGibb's energy change ofthe
the cell (E) are related as

a) A,G =-nFEd
b) 4,G =-RT In. K

c) AG=-nfFE,lcel)
0.059
0.059
log[M(or)E=E -log C
d) E=Et n
n

type aA+ bB cC+dD

For the general electro chemical reaction of the
where. K is the concentrationequilibrium constant.
4,G= RT inK
istheconcentrationequilibrium Constant.
b) A,G =-RT In K where, K,
constant.
c) 4,G =-RTIn k where, K, isthe equilibrium
constant.
)A,G = RT n K K, istheequilibrium Page No. [92]
NARAYANA GROUP
CBSE+2
8. Single electrode potential is measured by combining with
a) Standered platinum electrode b) Standeered
CHEMISTRY
mecury
c) Standard hydrogen clectrode d) Standered
aurum clecctlecriorodede
ELECTROCHEMICALSERIES
9. Arangement of different metalsin theincreasing order of reduction
a) Galvanic cell b) Primary cell Dotentials is knowna8
c) Secondary cell d) Electrochemical series
10. High reduction potential metal ions underg0 and act as
a)Oxidation, Anode b) Reduction, Cathode
c) Reduction, Anode d) Oxidation, Cathode
11. Low reduction potential metal ions (high negative value) undergo
and act as
a) Oxidation, Anode b) Reduction, Cathode
c) Reduction,Anode d) Oxidation, Cathode
12.
K*IK=-2.93V, Ag*lAg =0.80V, Hg /Hg =0.79V,
Mg* /Mg =-2.37V, Cr* / Cr=-0.74V
Arrange these metals in their increasing order of reducing power.
a) K* /K>Mg²* |Mg > Cr ICr >
Hg* |Hg > Ag*IAg
b) Hg* > Ag*IAg / Mg > C* /Cr > K* /K>
Mg?*
c) Mg > Cr/Cr > Hg* > Ag*lAg | K*
IK> Mg
d) Mg> Cr* /Cr > K* /K> Mg*>
Hg* > Ag*l Ag
NERNST EQUATION
13. The Nernst equation for metals isrepresented by
a) A,G=4FE(cel)
0.059
b) E = Eel t log[M(or)E =F O0S log C
n

c) A,G=-RT In K
0.059 0.059
d) E = E log[M](or) E=E n
-log C

NARAYANA GROUP Page No. [91]

CBSE+2
CHEMISTRY CDF MATERIAL
The
i Nermstequationforrnon-metals is represented by

A,G°=-RTIn K
a)
0.059 0.059
log M(or)E =E -logC

c)4,G=
0.059 0.059
log[4](or)E=E -log C

Gibb'senergy changeintheGalvanic cell (AG) andi electrode potential of the cell (E ) are
relatedas

a) AG=-nfE
K
b) A,G =-RTIn
0.059 0.059
E +
c) E= Paell log[M ](or)E- E, -log C

0.059 0.059
d) E=E log4 ](or)E=El -log C

I6 Standard Gibb's energy change of the reaction (4,G") and standred electrode potiential of
the cell (E) are related as

a) 4,G' =-nFE
b) 4,G =-RT ln K

c) AG=-nFEcel)
0.059 0.059
d) E=E+ log M" (or)E-E + -logC

l. For the general electrochemical reaction ofthe type aA+bBcC+dD

equilibrium constant.
a) A,G = RT In K_ where, K, is the concentration
concentrationequilibrium constant.
0) A,G" =-RT In Kwhere, Kis the

C) 4,G =-RT In Kwhere, K. is the equilibriumconstant.

) 4,G' =RT In K Kis the equilibrium constant.
NARAYANA GROÚP Page No. [92]
CBSE+2
CONDUCTANCE OFELECTROLYTIC SOLUTION CHEMISTRY
I8. Carbon black, graphite and organic polymers are
a) Nonconductors b) Electrolytic conductors
c) Electrical conductors d) Insulaters
19. Equation used to calculate resistance (R) is

a) G= b) G'= A
c)KC
R A

20. Equation usedto calculate specific conductance (K)=

d)
G
R
21. The formulae used to calculate the conductance is G=

a)G G
A b) R

1
R

22. The formulae used to calculate specific resistance (p) =

RA
a G
A c) R
d)
23. Units ofcell constant

a) ohmCm-l b) Cm'(or)m
c) mho'.Cm-mol-! d) mol.m
24. Units of specific conductance (K)
a) ohmCm
b) mho.Cm
C) ohm'm' (or)S.m
d)All
Page
No.
NARAYANAGROUP
 CHEMISTRY CDP MATERIAS.
CBSE+2
Molarconductivity
25.

where, K is expressed in Sm andconcentration Cin mol m

a)

K where, K is expressed in Sm and concentration C in mol m2

b)

K where. Kis expressed in Sn and concentration C in molm-!

c) C
K
where, Kis expressed in Sm and concentration Cin mol

6 Units ofmolar conductivity

a) ohm'.Cm-! b) mho.Cm
-1
c) ohm'.Cm'.mol' (or)S.Cm'mol-! d) Sm
27. 1Sm'mol!
b)10+S cm²mol!
a) 104S m' mol-!
c) 10°S m²mol! d) 10-4Scm² mol!

28. 1S cm'mol!
a) 10+S m²mol! b) 104S cm²mol!
d) 10-4S cm²mol!
c) 10»S mmol!

29. ^(Scm mol)=

a
K(S.cm')
1000(L.m)x molarity(mol.L')

K(Scm')
b)
1000(L.m')xmolarity(mol.I")

C
K(Scm')
1000(L.m)xmolarity(mol.L)
K(S.cm')
1000(Lm) xmolarity(mol.L)

Page No. (94]

NARAYANA GROÚP
CBSE+2 CHEMISTRY CDF MNTEXIAN
30. Cell constant (G]=
a) Conductivity /resistance b) Conductivity +resistance
c) Conductivity -resistance d) Conductivity xresistance
31. What is theeffect ofdilution, on
conductivity molar conductivity of asolution
a) Decreases, Increases
b) Increases, Decreases
c) Increases, Increases
d) Decreases, Decreases
32. Limiting molar conductivities of anelectrolyte is equalto thesum of
anion and the cation of the electrolyte the individual
a) Faraday's first law
c) Faraday's second law
is called
b) Kohlrausch law
d) None of these
contributionofte
33.
Anelectrolyteon dissociation gives V,cations and Vanions then its limiting
(a2) molar conductivibvi
a) (v,2 +v_a)(a and 2° are
the limiting molar
conductivities of the cation and cation )
b)(v,2 +v2)(a and 2° are the limiting
molar conductivities of theanion and )
c) (v.2, anion
+v_2)(a and 2 are thelimiting molar
d) (v,2 +v_2) and 2 conductivities of thecation and anion)
are thelimiting molar
34.
For strong conductivities of the anion and cation )
electrolytes, molar conductivity a m

a)
|where = limiting molar conductivity. C=
solution. concentration of the electrolytic
b)(-AC)where a, limiting molar conductivity.
c)(Am-AC) where a =limitingmolar C=concentration ofthe electrolytic solution.
conductivity.C=concentration oftheelectrolyticsoluton.
where =limiting molar
solution.,
conductivity, C= concentration of the electrolytic
35. Ratio between molar
conductivity and limiting molar conductivity is called
a) Degree ofassociation
b) Degree of association and dissociation
c) Dissociation constant
d) Degree of
dissociation
CBSE+2 CHEMISTRY CDF MATERIAL

36 Dissociation constant offweak acidic clectrolyte K

CA:
b) -4C?

c) d) None of these

ELECTROLYTIC CELLAND ELECTROLYSIS

17 The amount of anysubstance that is deposited or liberated at an electrode is directly propor
tional to quantity of electricity passed through the electrolyte
a) Kohlrausch law b) Faraday's first law
c) Faraday's second law d) None of these

38. Faraday's first law mathematical forn(w)=

a) Z/it(or)Z IQ (Z = electrochemical equivalent)
b)( Zir)or (2zo) (Z =electrochemical equivalent)
c) (Zit)or (zo) (Z =atomic number)
d) Z/it(or)Z /Q(Z= atomic mumber)
39. Chemical equivalent weight=
a) Valencyl Atomic mass b) Atomic number / Valency
c)Atomic mass / valency d)Valency/Atomic number
40. One Faraday is equal to
a) 96500. b) 96500 c.mol
c) 96500 c d) 96500 c.mol!

41. How much charge required for 1mol of MnO, to Mn?

a) 4F b)5F c) 2F d) 10F
42. Quantity of current in coloumbs
a) W= Zit b) ZQ
c)Q=Current (inamp) xtime(in seconds) Q=It d) None of these
43. The amounts of diferentsubstances liberated by the same quantity ofelectricity passing through the
electrolytic solution are proportional to their chemical equivalent weights is
a) Faraday's second law b) Faraday's first law

NARAYANA GROUP Page No. (96]

 CBSE+2
C)Rohlrausch
law d) None ofthese CHEMISTRY
44. Faraday's second law mathematical fon:

a) E b)
W
E, W E

c) d) W,
W E, E,
45. When an aqueous solution of sodiumn chloride electrolyses the
and at anode is gases liberated at
cath
a) C1,, H, b)CI,CI
c) H,H, d) H,CI,
BATTERIES
46. In a dry cell the space between the electrodes is filled by
moist paste is
a) NH,Cl and ZnCl, b) CuSo, and ZnCl,
c) ZnSo, and ZnCl, d) H,So, and ZnCl,
47. Dry cell and Mercury cell the cell potential is
approximately
a) 3.0V, 4.00 V b) 2.5 V, 2.70V
c) 1.5V,1.35 V d) 1.5 V, 2.35 V
48. cells can be recharged.
a) Primary b) Secondary
c) Both 1&2 d) None of these
49. Lead storage battery and Nickel-Cadmium cell cells.
a) Secondary b) Primary
c) Both1&2 d) Fuel cells
50. Lead storage battery recharged is anode and is cathode.
a) Carbon rod, Zinc cup
b) lead (Pb); lead dioxide (PbO,)
c) Oxizition, Hydrogen
d) Zinc-mercury amalgam, paste of Hgo and carbon
51. In lead storage battery solution used as
a) 38% ofH.SO
Electrolyte
 51) a 41) b
31) a
21) d 11) a 1)a CBSE+2

52) a 42) c 32) b

22) a 12) a 2)d

53) c 43) a 33) c 23) b 13) b 3)d

54) d 44) c 34) a 24) d 14) d 4)a

55) a
45) d 35) d 25) a 15) a 5)c
KEY
56) d 46) a 36) a
26) c 16) a 6)a

57) a 47) c 37) b 27) b

17) b 7)b
CHEMISTRY
MATERIN CDF
58) a 48) b
38) b 28) a 18) c
8)c

59) c 49) a 39) c 29) c

19) d 9)d

S0)b 40) d 30) d 20)a 10)6