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Ahmadi 2016
Ahmadi 2016
To cite this article: Mohammad-Ali Ahmadi, Zainal Ahmad, Le Thi Kim Phung, Tomoaki
Kashiwao & Alireza Bahadori (2016) Experimental investigation the effect of nanoparticles on
micellization behavior of a surfactant: Application to EOR, Petroleum Science and Technology,
34:11-12, 1055-1061, DOI: 10.1080/10916466.2016.1148051
Article views: 19
ABSTRACT KEYWORDS
Chemical stimulation such as surfactant flooding in petroleum reservoirs Critical micelle
makes efforts to produce remained oil and improve sweep efficiency by means concentration; enhanced oil
of different phenomena such as lowering interfacial tension and wettability recovery; hydrophobic;
nanosilia; sugar based
alteration of reservoir rock. Implementing concentration of surfactant through
surfactant
surfactant flooding is one of the big challenges while interfacial tension
between surfactant solution and oil after certain concentration involves lit-
tle changes such as critical micelle concentration (CMC). This article highlights
the effect of nanosilica on CMC of Zyziphus Spina Christi, as sugar-based sur-
factant, in aqueous solutions for enhanced oil recovery and reservoir stimula-
tion purposes. A conductivity approach was selected to assess the CMC of the
introduced surfactant in aqueous solution at 25°C. The influence of nanosilica
concentrations on CMC variation of introduced surfactant is considered. It is
found that CMC of introduced surfactant decreased while the concentration
of the nanosilica increased. Results from this study can aim in optimum condi-
tion selection of surfactant flooding as an enhanced oil recovery ends.
1. Introduction
Surfactant flooding, which is normally classified as a subset of chemical enhanced oil recovery (EOR)
methods, has been taken as a solution to enhance the oil displacement sweep efficiency through decreas-
ing the interfacial tension between oil and water (McAuliffe, 1973; Dranchuk et al., 1974; Johnson, 1976;
Kalfoglou, 1977; Farouq Ali et al., 1979; Mannhardt et al., 1990; Tsau et al., 2000; Grigg and Svec, 2003;
Liu et al., 2007).
Dependency of critical micelle concentration (CMC) of Zyziphus Spina Christi (ZSC) to nanosilica
is not yet reported in the literature. This article focuses on micellization behavior of ZSC in aqueous
solutions contain nanosilica. CMC measurement of the surfactant was determined via employing a con-
ductivity method for aqueous phase. Results from this research are demonstrated and explained in detail
in subsequent sections.
CONTACT Alireza Bahadori alireza.bahadori@scu.edu.au School of Environmental Science and Engineering, Southern Cross
University, Lismore,Australia.
Color versions of one or more of the figures in the article can be found online at www.tandfonline.com/lpet.
© Taylor & Francis Group, LLC
1056 M.-A. AHMADI ET AL.
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Figure . (a) The image of ZSC observed under TEM. (b) The image of nanosilica under TEM.
PETROLEUM SCIENCE AND TECHNOLOGY 1057
Reprinted with permission from Mohammad Ali Ahmadi and Seyed Reza Shadizadeh, Adsorption of novel nonionic surfactant and
particles mixture in carbonates: Enhanced oil recovery implication, Energy & Fuels, :–. Copyright American Chemical
Society.
Downloaded by [University of Exeter] at 11:59 21 July 2016
2. Experimental
2.1. Surfactant
One of the most popular trees in southern of Iran is ZSC. According to open literature ZSC contain high
concentration of saponins (Kjellim and Johansson, 2010). It should be mentioned here that saponins are
natural surface-active substances (surfactants) present in more than 500 plant species and the same as
other surfactant have hydrophilic and hydrophobic parts such as triterpenoid or steroid backbone and
saccharide residues (Hostettmann and Marston, 1995; Guglu-Ustundag and Mazza, 2007; Stanimirova
et al., 2011).
Through our research, we implemented extracted brown powder from leaves of ZSC, which contains
cyclopeptide alkaloids, as well as, saponin glycosides, and several flavonoids (Hostettmann and Marston,
1995; Guglu-Ustundag and Mazza, 2007; Stanimirova et al., 2011). To achieve main goal of current work,
the sugar-based surfactant was extracted from the leaves by spray dryer method while implemented
leaves of ZSC were collected from south of Iran (Khuzestan State) and the total extracted powder contains
Saponin and Flavonoids. In addition, Image under TEM for extracted powder from ZSC leaves are shown
in Figure 1a.
Figure . Conductivity versus surfactant concentration. Reprinted from Fuel, , M. A. Ahmadi and S. R. Shadizadeh, Experimental inves-
tigation of adsorption of a new nonionic surfactant on carbonate minerals, –, Copyright , with permission from Elsevier.
1058 M.-A. AHMADI ET AL.
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2.2. Nanoparticles
To obtain high precise results through this study, ultrapure nanosilica particles in different states were
implemented. According to wettability of the surface of the silica nanoparticles, they can be classified
into two types: hydrophilic silica nanoparticle (NSHI) and hydrophobic silica nanoparticle (NSHO).
To assess the referred purpose of this research, AEROSIL R 816 and AEROSIL 200 were carried out as
partially hydrophobic and hydrophilic nanoparticles which they were purchase from Degussa. Physical
properties of AEROSIL R816 and AEROSIL 200 are demonstrated in Table 1. In addition, Image under
TEM for hydrophobic nanosilica is illustrated in Figure 1b.
Thickening and thixotropic effects of nanosilica at a given concentration depend to a great extent
on the intensity of the dispersing. Therefore the dispersion method is of crucial importance. As rec-
ommended by the producing companies, good results are achieved with ultrasonic homogenizer. An
ultrasonic homogenizer (UT-1200) has been implemented in this study to disperse the nanosilica parti-
cles in the aqueous media. The silica powder was weighed, wetted by the dispersing media (i.e., water)
and then dispersed using the ultrasonic homogenizer for more than 5–6 h.
probe of the conductivity meter in solution to guarantee the accuracy and precision of solutions electrical
conductance.
ica. Conductivity measurements revealed that at constant surfactant concentration, nanosilica presence,
either hydrophilic or slightly hydrophobic, had a very small effect on solution conductivity as shown
in Figure 6 for ZSC-AEROSIL 200/AEROSIL R816 systems. However, it seems that both nanoparticles
influence the surfactant micellization properties particularly its CMC. As can be seen in Figure 6, co-
existence of ZSC and AEROSIL 200 nanosilica in a solution leaded to a CMC value lower that the one
for sole ZSC system. Figure 6 represents the CMCs of different systems considered in this study, it can
be seen that the presence of both nanoparticles have resulted in surfactant molecules to aggregate into
micelles at lower concentrations. This phenomenon is more severe for higher nanoparticle concentra-
tions.
The observed phenomenon may be related to surfactant-nanoparticle interactions. Ignoring the little
amount of surfactant adsorption on nanoparticle surface, the similar negative electrical charge on the sur-
factant hydroxyl groups and nanoparticle surface results in an electrostatic repulsion between surfactant
molecules toward each other and prompts the micellization process. Moreover, the hydrophilic nanopar-
ticles make the bulk solution unfavorable for hydrophobic surfactant tails and increase their affinity to
form micelles. Obviously, in such a situation, micelle aggregates form in lower concentration and CMC is
reduced, when nanoparticle concentration increase, the repulsion forces become stronger (due to larger
number of nanoparticles). Also, the bulk solution becomes more hydrophilic. As a result, micellization
occurs even at lower concentrations. Another important point that may be inferred from Figure 6 is that
the dramatic reduction of CMC is more considerable for hydrophilic AEROSIL 200 nanoparticles. As
mentioned previously, the presence of these nanoparticles intensifies the hydrophilic characteristics of
the solvent. As general rule, in aqueous medium, the greater the dissimilarity between the surfactant
hydrophobic chain and solvent, the grater the aggregation number. Consequently, sharper decrease in
CMC value is observed respect to AEROSIL R816 slightly hydrophobic nanoparticles.
4. Conclusions
Through this research, effects of the addition of different nanosilica particles on the micellization and
the micellar growth of ZSC in aqueous solution have been systematically investigated. From the results
obtained from this work the following conclusion can be drawn: ignoring the little amount of surfac-
tant adsorption on nanoparticle surface, the similar negative electrical charge on the surfactant hydroxyl
groups and nanoparticle surface results in an electrostatic repulsion between surfactant molecules toward
each other and prompts the micellization process. In aqueous medium, the greater the dissimilarity
between the surfactant hydrophobic chain and solvent, the grater the aggregation number. Consequently,
sharper decrease in CMC value is observed respect to AEROSIL R816 slightly hydrophobic nanoparti-
cles.
PETROLEUM SCIENCE AND TECHNOLOGY 1061
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