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Full Download Book Nano Optics Fundamentals Experimental Methods and Applications Micro and Nano Technologies PDF
Full Download Book Nano Optics Fundamentals Experimental Methods and Applications Micro and Nano Technologies PDF
Edited by
SABU THOMAS
YVES GROHENS
GUILLAUME VIGNAUD
NANDAKUMAR KALARIKKAL
JEMY JAMES
Elsevier
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Notices
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Harith Ahmad
Photonics Research Center, University of Malaya, Kuala Lumpur, Malaysia
Stuart Bowden
Quantum Energy for Sustainable Solar Technology (QESST) Engineering Research Center,
Arizona State University, Tempe, AZ, United States
Dermot Brabazon
I-Form, Advanced Manufacturing Research Centre, & Advanced Processing Technology
Research Centre, School of Mechanical and Manufacturing Engineering, Dublin City
University, Dublin, Ireland
Jenu V. Chacko
Laboratory for Optical and Computational Instrumentation (LOCI), University of Wisconsin at
Madison, Madison, WI, United States
Balu Chandra
International School of Photonics, Cochin University of Science and Technology, Cochin,
Kerala, India
Judith M. Dawes
MQ Photonics Research Center, Department of Physics and Astronomy, Macquarie University,
Sydney, NSW, Australia
Joydeep Dutta
Functional Materials division, Materials and Nano-Physics Department, ICT School, KTH
Royal Institute of Technology, Stockholm, Sweden
Nitin Eapen
International and Inter University Centre for Nanoscience and Nanotechnology, Mahatma
Gandhi University, Kottayam, Kerala, India
Karsten Fleischer
I-Form, Advanced Manufacturing Research Centre, & Advanced Processing Technology
Research Centre, School of Mechanical and Manufacturing Engineering, Dublin City
University, Dublin, Ireland
Stephen Goodnick
Quantum Energy for Sustainable Solar Technology (QESST) Engineering Research Center,
Arizona State University, Tempe, AZ, United States
Yves Grohens
FRE CNRS 3744, IRDL, University of Southern Brittany, Lorient, France
Banshi D. Gupta
Physics Department, Indian Institute of Technology Delhi, New Delhi, India
ix
x Contributors
Anisha Pathak
Physics Department, Indian Institute of Technology Delhi, New Delhi, India
Hazli Rafis Abdul Rahim
Department of Electrical Engineering, Faculty of Engineering, University of Malaya, Kuala
Lumpur; Universiti Teknikal Malaysia Melaka, Melaka, Malaysia
Siti Aisyah Reduan
Photonics Research Center, University of Malaya, Kuala Lumpur, Malaysia
Carsten Rockstuhl
Institute of Theoretical Solid State Physics; Institute of Nanotechnology, Karlsruhe Institute of
Technology, Karlsruhe, Germany
Swasti Saxena
Department of Applied Physics, Sardar Valla Bhai National Institute of Technology, Surat,
Gujarat, India
Vivek Semwal
Physics Department, Indian Institute of Technology Delhi, New Delhi, India
Ashin Shaji
Institute of Physics, Slovak Academy of Sciences, Bratislava, Slovakia
Sithara P. Sreenilayam
I-Form, Advanced Manufacturing Research Centre, & Advanced Processing Technology
Research Centre, School of Mechanical and Manufacturing Engineering, Dublin City
University, Dublin, Ireland
Ankit Kumar Srivastava
School of Applied Natural Science, Adama Science and Technology University, Adama, Ethiopia
Mark Tame
Department of Physics, Stellenbosch University, Stellenbosch, South Africa
Kavintheran Thambiratnam
Photonics Research Center, University of Malaya, Kuala Lumpur, Malaysia
Siddharth Thokchom
National Institute of Technology Manipur, Imphal, India
Sabu Thomas
School of Chemical Sciences; International and Inter University Centre for Nanoscience and
Nanotechnology, Mahatma Gandhi University, Kottayam, Kerala, India
Zian Cheak Tiu
Photonics Research Center, University of Malaya, Kuala Lumpur, Malaysia
Jijo P. Ulahannan
Department of Physics, Government College, Kasaragod, Kerala, India
Guillaume Vignaud
FRE CNRS 3744, IRDL, University of Southern Brittany, Lorient, France
About the Editors
xiii
xiv About the Editors
1. Introduction
Nanomaterials are abundant in nature, since everything in our world is composed of very
small particles. As a result, nanotechnology is always inspired by nature and natural phe-
nomena. The properties of the materials created by nature through evolutionary pro-
cesses are highly efficient or optimal, hence the use of natural materials directly in the
development of nanotechnology is of great importance. Now scientists have a clear idea
of how to create nanoscale materials with unique properties that never existed before.
Products using nanomaterials are now available in the market, such as nanoscale silver
as an antibacterial [1], sunscreen with nanoscale titanium dioxide that prevents sunburn
[2], application in the field of electronics as in batteries, targeted drug delivery, nanofilms
for coatings, water filtration, etc. [3] Molecular-level manipulation is the ultimate base of
nanotechnology, but that doesn’t mean that this field of science always deals only with
artificial materials.
In nature, molecules organize themselves into complex structures that could support
life, similar to the present nanotechnology that we are used to. Nature constructs every-
thing atom by atom, and understanding the basic principle of natural systems will help
nanoscientists to design artificial nanomaterials. For example, oncologists are looking into
nanotechnology as a potential way to treat cancer with targeted drug delivery by the use
of nanomedicine [4]. The inspiration for this is from the viruses that seek out a specific
type of cell to attack in a living organism. Similarly, optically transparent materials have
been improved by imitating the nanostructures found in the wings of insects. Finding
inspiration from nature’s nanotech is becoming big business nowadays.
Nano-optics or nanophotonics has become a serious topic of research over the past
decades. The interaction of light with nanometer-scale particles has developed into a new
and separate branch from conventional photonics research topics due to its massive pres-
ence in the natural world and also from an application point of view. On the nanometer
scale, materials including metals, semiconductors, dielectrics, and polymers exhibit inter-
esting properties, especially optical properties [5]. Particles that come under a size range of
nanometers show special phenomena that are not predictable as in their bulk counter-
parts. Making use of these properties of the nanoparticles in the field of optics and pho-
tonics is the core of nanophotonics [6]. The major aim of this chapter is to give a brief
introduction to the presence of nanotechnology and nanophotonics in the natural world
rather than the artificially created nano universe. Without going into deeper theoretical
aspects, this chapter presents an overall picture of the influence and existence of nano-
technology in nature.
Fig. 1 Some of the common optical phenomena happening in nature: (A) double rainbow and
supernumerary rainbows on the inside of the primary arc; (B) very bright sun dogs in Fargo, North
Dakota; (C) the reflection of Mount Hood in Mirror Lake; (D) a 22° halo around the sun, as seen in
the sky over Annapurna Base Camp, Annapurna, Nepal. ((A) Eric Rolph at English Wikipedia (https://
commons.wikimedia.org/wiki/File:Double-alaskan-rainbow.jpg), “Double-alaskan-rainbow,” size and
shape of the image by Ashin Shaji, https://creativecommons.org/licenses/by-sa/2.5/legalcode; (D) Anton
Yankovyi (https://commons.wikimedia.org/wiki/File:Halo_in_the_Himalayas.jpg), size and shape of the
image by Ashin Shaji, https://creativecommons.org/licenses/by-sa/4.0/legalcode.)
3. Nanotechnology in nature
Nanoscience and nanotechnology always find inspiration from nature. Some common
nanostructures that are visible in nature include inorganic materials such as carbonaceous
soot, clay, organic natural thin films, and a variety of organic nanostructures such as pro-
teins, insects, and crustacean shells. These structures cause a range of behaviors in nature
together with the wettability of surfaces, the brightness of butterfly wings, and also the
adhesive properties of the lizard’s foot.
The coloration of many varieties of beetles and butterflies is created by sets of rigor-
ously spaced nanoscopic pillars. Fabricated from sugars like chitosan, or proteins like ker-
atin, the widths of slits between the pillars are designed to control light to attain certain
colors or effects like iridescence. One advantage of this strategy is resilience. Pigments
tend to bleach with exposure to light; however, structural colors are stable for remarkably
long periods.
From nature: Optics, nanotechnology, and nano-optics 5
A study of structural coloration in metallic-blue marble berries [13] where the spec-
imens collected in 1974, that had maintained their color despite being long dead. Sim-
ilarly, a lotus leaf is an example of an engineered surface because of its physical and
chemical conditions at the micro- and nanometer scale, able to provide a self-cleaning
effect. Wilhelm Barthlott, a German botanist, is considered to be the discoverer of the
Lotus effect [14] as he applied for its patent in 1994. He found out that the combination
of the chemical makeup of the surface and also the micro-and nano-projections on the
surface were the reason behind the effect. The protrusions [15] of the lotus leaf are
10 μm high, with every protrusion covered in bumps of a hydrophobic, waxy material
that is roughly 100 nm in height. The chitin polymer and epicuticular wax projections
allow the leaf to trap air. Water droplets ride on the tips of the projections and result in a
bed of air to make a super-hydrophobic surface (Fig. 2). Scientists designed this behavior
Fig. 2 Examples of self-cleaning surfaces in nature and their SEM images [16]. (Permission has been
granted through the Copyright Clearance Center’s Rights Link service.)
6 Nano-optics
into the product Lotusan®, a self-cleaning paint. This paint mimics the microstructure of
the surface of a lotus leaf once it dries and cures within the environment. Small peaks and
valleys on the surface minimize the contact area for water and dirt, keeping the surface
clean. Various merchandise is currently on the market that mimics this hydrophobic
property, including consumer goods, spray coatings, plungers, toilet fixtures, automotive
components, etc.
Researchers at several universities are synthesizing biomimetic nanocomposites to
form robust materials to be used in lightweight armor systems, structures in transportation
systems, sturdy electronics, aerospace applications, etc. Nature has evolved an advanced
bottom-up approach for fabricating nanostructured materials that have great mechanical
strength and toughness. One of nature’s toughest materials is nacre, which is best known
as the iridescent mother-of-pearl made by mollusks. Mollusks produce nacre by depos-
iting amorphous calcium carbonate (CaCO3) onto porous layers of polysaccharide chitin.
The mineral then crystallizes, producing stacks of CaCO3 that are separated by layers of
organic material. Its strength comes from the brick-like assembly (interlocked) of the
molecules [17].
A lizard’s feet will bind firmly to any solid surface in a short time, and detach with no
apparent effort (Fig. 3). This adhesion is purely physical, with no chemical interaction
between the feet and the surface. The active adhesive layer of the gecko’s foot is a
branched nanoscopic layer of bristles known as “spatula” that measure about 200 nm
in length. Several thousand of those spatulae are connected to micron-sized “seta.” Both
spatulae and seta are fabricated from very flexible keratin. Although research into the finer
details of the spatulae’s attachment and detachment mechanism is in progress, the actual
fact is that they operate with no sticky chemicals. It is an impressive piece of design by
Mother Nature. That they are self-cleaning, immune to self-matting (the seta don’t stick
to each other), and detached by default (including from each other) are other interesting
features of geckos’ feet [18, 20]. These options have prompted ideas and suggestions that
in the future, glues, screws, and rivets may all be made by a single method, casting keratin
or similar material into completely different molds.
Magnetotactic bacteria possess the extraordinary ability to sense minute magnetic
fields, together with the Earth’s own magnetic field, using tiny chains of nanocrystals
known as magnetosomes (Fig. 4). These are grains sized between 30 and 50 nm, made
from either magnetite (a type of iron oxide) or, less commonly, greghite (an iron-sulfur
combo). Several types of magnetosomes work together to provide a foldable “compass
needle” that is many times more sensitive than its artificial counterparts. Magnetotactic
bacteria are pond-dwelling and only need to navigate short distances. However, their
precision is incredible. By varying the grain size, these bacteria can store information
since the growth is controlled by the most magnetically sensitive atomic arrangements
[22]. However, oxygen and sulfur combine rapidly with iron to provide magnetite,
greghite, or more than 50 other compounds, only a couple of which are magnetic. Hence
Fig. 3 Nanoengineered structures from nature: (A) microstructure and schematic illustration of gecko feet [18]; (B) micro/nanoarchitecture in the
wings of a butterfly [19]. (Permission has been granted through the Copyright Clearance Center’s Rights Link service.)
8 Nano-optics
Fig. 4 Different morphology of magnetotactic bacteria: (A) vibrios; (B) rods (Bar ¼ 1.0 μm) and (D);
(C) coccoid (Bar ¼ 200 nm); (E) spirilla: (F) multicellular organism (Bar ¼ 1.0 μm) [21]. (Permission has
been granted through the Copyright Clearance Center’s Rights Link service.)
advanced technologies are needed to produce selectively the proper kind, and build the
magnetosome chains. Such manual skill is presently beyond our reach; however, in
future, scientists may learn a way to mimic these structures.
obvious potential technological applications that arise from breaking the diffraction bar-
rier are super-resolution microscopy and ultra-high-density information storage. How-
ever, the field of nano-optics is by no means restricted to technological applications and
instrumental design. Nano-optics additionally opens new doors to basic analysis on
nanometer-sized structures [23, 24].
Nature has developed numerous nanoscale structures to achieve distinctive optical
effects. An outstanding example is photosynthetic membranes that use light-harvesting
proteins to absorb daylight and then channel the excitation energy to different neighbor-
ing proteins [25]. The energy is guided to a so-called reaction center where it initiates a
charge transfer across the cell membrane. Other examples of nanophotonics in nature
include sophisticated nano diffractive structures commonly found in insects like butter-
flies and other animals to produce attractive colors and effects like those on a peacock’s
feather. Insect wings have ordered hexagonal close-packed array structures made of chi-
tin. The difference in spacing (from 200 nm to 1 μm) between these small structures
allows the wings to serve as self-cleaning and antireflective coatings, along with providing
improved mechanical strength and aerodynamics. It also functions as a diffraction grit-
ting, which produces iridescence. Iridescence originates as a result of the interaction
of light with the physical structure of the surface. In the Morpho butterfly, the spaces
between the ribs of the wing form natural photonic crystals, leading to a brilliant blue
color (Fig. 5). No pigments or chemicals are involved in this process. Researchers are
exploring these nanostructures as a way for controlling and manipulating the flow of
light, which is vital in optical communication.
Additionally, researchers have found that when they coat the Morpho wings with a
layer of heat-absorbing carbon nanotubes, the shift in reflected wavelength of light will
indicate very small temperature changes (Fig. 6). Hence, these sensors could someday be
used to discover inflamed or burned areas in people or points of wear and tear due to
friction in machines.
Another example is a moth’s eye, which has very small bumps on its surface. These
bumps are hexagonal-shaped structures that are a few hundred nanometers tall and
separated (Fig. 7). Since these patterns are smaller than the wavelength of visible light
(350–800 nm), the surface of the moth’s eye can absorb more light, since it has only very
low reflectance for visible light. Therefore, the visibility of a moth in dark conditions is
much better than a normal human eye because these nanostructures can absorb light very
efficiently. Scientists have been inspired to use similar artificial nanostructures to improve
the absorption of infrared light in a particular type of thermo-voltaic cell to make it more
efficient [29].
A new aim within the study of animal optical structures is to decipher and emulate the
animal’s genetic manufacturing process. Animals contain the ultimate factories within
them, which means they engineer via nanomachinery and molecular self-assembly,
and also the results are excellent, based on the previously reported results [30]. Maybe,
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CHAPTER XIV
FURTHER RESEARCHES
Boys and girls, as a rule, reach the age of eight or nine, perhaps
ten, before any event of importance interrupts the even tenor of their
lives. Then the assembly of the men, which when the harvest is over,
meets daily in the baraza, decides where the unyago is to be
celebrated in the current year. Since all the adjacent districts have
now taken their turn in bearing the expense of the ceremony, it is a
point of honour that our village should invite them this time. The
resolution is soon carried into effect; the moon is already on the
wane, and the celebration must take place before the new moon. The
unyago presents exactly the same features in all the tribes of this
region. The men erect a circle—larger or smaller as circumstances
may require—of simple grass huts in an open space near the village.
In this space the opening and closing ceremonies are performed; the
huts are intended for the candidates to live and sleep in. Such an
arena, with all its appurtenances in excellent preservation, was the
circle of something over fifty yards’ diameter which I was enabled to
photograph when visiting the echiputu at Akuchikomu. The charred
remains of a similar lisakasa, as the system of huts is called in Yao,
were to be seen near the road on this side of Akundonde’s—the relics
of a former festival.