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GUIDED REVISION LEADER + ENTHUSIAST COURSE
LEADER + ENTHUSIAST COURSE

ORGANIC CHEMISTRY GR # 11 GUIDED REVISION PLAN

1. Which one is correct for the products of the given reaction

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(A) only X and Z are formed (B) Z > Y (amount)
(C) X > Y (amount) (D) Y > X (amount)
2. Which one will undergo hydrolysis (solvolysis) more rapidly amongst the given pairs of compounds

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I II III IV
(A) x>y y>x x>y x>y

(B) y>x y>x x>y x>y

(C) x>y x>y y>x y>x
(D) y>x y>x x>y y>x

3. The correct order of SN2 / E2 ratio for the % yield of product of the following halide is –

(P) (Q) (R) CH3 – CH2 – I (S)

(A) R > S > Q > P (B) R > Q > S > P (C) P > R > S > Q (D) Q > P > R > S

ORGANIC CHEMISTRY / GR # 11 (Set-3) E-1/4

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(i) Grignard reagent (excess)

4. Phenyl ester 'P', 'P' can be
(ii) H+

Ph Me Ph Ar Ph Me
(A) (B) (C) (D)
H OH Me OH Et OH

5. The slowest chain propagation step of the following reaction is

R 2O 2
CH4 + SO2Cl2   CH3Cl + SO2 + HCl


(A) RO + CH4  ROH + CH3 (B)  CH3 + SO2Cl2  CH3Cl +  SO2 Cl

(C)  SO2 Cl  SO2 +  Cl (D) Cl + CH4  HCl +  CH3

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6. Observe the following diagram for relative boiling points of different alkanes. Identify the
hydrocarbons X, Y, Z, W, R.

Z
W
X
R

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Alkanes

(X) (Y) (Z) (W) (R)

(A)

(B)

(C)

(D)

7. The end product of following reaction is :

O O +
CH3MgBr PhMgBr H
(1) (2) (3)
O

(A) -diketone (B) -Hydroxy acid (C) 1, 2-Diol (D) -Hydroxy ketone

ORGANIC CHEMISTRY / GR # 11 (Set-3) E-2/4

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H – C  C Na NaNH I  (CH2 )7  Cl NaCN H3 O  H / Pd / CaCO / Quinoline

8. E       
2
        2    
3

 
(1) (2) (3 ) ( 4) (5 ) (6 )

Identify the compound 'E'.

(A) 1-Fluorodecane (B) 1-Bromo-8-Fluorooctane
(C) 1-Bromo-7-Fluoroheptane (D) 1-Bromo -11-Fluoroundec -2-yne

9. The compound 'X' can be synthesized by using the reagents.

(I) + CH3MgBr (II) +

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(III) + (IV) +
(A) I and III (B) I, II, III (C) All (D) I, II only
Multiple Correct Type :
10. An aromatic chiral compound G (C8H8Br2) on treatment with NaOH/DMSO gives H (C8H9BrO). On
heating ‘G’ with potassium tert-butoxide I (C8H7Br) is formed. With one equivalent of methyl magne-

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sium bromide in ether p-bromoisopropylbenzene is formed which observations is/are correct about these
reactions.

(A) (I) is an optically inactive aromatic alkene (B) H is an optically active alcohol

(C) G =

(D) Benzylic halide gives nucleophilic substitution with faster rate than aryl halide
Passage for (Q.No. 11 to 13)
Observe the following reactions and given answers

ORGANIC CHEMISTRY / GR # 11 (Set-3) E-3/4

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11. Which of the following structure represents the transition state of slow step of reaction I.

(A) (B)

(C) (D)

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12. Which of the reaction (I – IV) involves rearrangement of reaction intermediate.

(A) I only (B) I, III (C) II, III, IV (D) I, II, III

13. Planar reactive intermediates are formed in reactions :

(A) I, III (B) II, III (C) I, II (D) I, III, IV

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Matrix Match type :
14. Compare the properties of two isomeric products x and y formed in the following reaction.


1. CCl4 / KOH/ , 2. H
 
Re imer Tiemann Reaction

Match the following :

Integer Type :
15. Calculate molecular weight of the lowest alkane containing a sequence of 10, 20, 30 and 40 carbon atoms.

ORGANIC CHEMISTRY / GR # 11 (Set-3) E-4/4

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