CHEMISTRY (GLORIFIRE)

BATCH: JR PINNACLE PATTERN: JEE-MAIN

PHASE: V PET-3

TEST DATE: 11.04.2024 PAPER SETTER: DSNR

SINGLE CORRECT TYPE QUESTIONS (20)

31. O

O
A
NaBH LiAlH
(B)  4
CH OH
 
4
3

O
A and B are
O
OH

O in both cases
(A) in both cases (B)
OH

OH
OH
O

OH O
(C) (D) Formation of A and B is not possible
OH

OH OH
31. C
32. CHO

OH OH

CH3 CH3

The above conversion can be done by

(A) NaBH4 (B) HCl/AlCl3
(C) CHCl3/NaOH (D) All of the above
32. C

33. The process of converting alkyl halides into alcohols involves_____________.

(A) Addition reaction (B) Substitution reaction

(C) Dehydrohalogenation reaction (D) Rearrangement reaction

33. B
34. The product obtained from reaction between HCHO and CH3MgBr is?
(A) Ethanol (B) t-butyl alcohol (C) iso propyl alcohol (D) n-propanol
34. A

35. 112 L of a gas is produced at STP by 412 g of ROH with CH3MgI. The mol.wt. of alcohol is
(A) 32 g (B) 41.2 g (C) 82.4 g (D) 156 g
35. C
36. LiAlH4 converts acetic acid into?
(A) CH3COCH3 (B) CH4 (C) C2H5OH (D) CH3OH
36. C

37. The product formed when C6H5CH2MgBr reacts with HCHO is

(A) C6H5 CH2 CH2OH (B) C6H5 – CH(OH) – CH3
(C) p – (OH) – C6H4 – CH2 – CH3 (D) m-(CH3)-C6H4CH3
37. A
38. Acetaldehyde reacts with CH3MgBr followed by acidic hydrolysis to form -
(A)CH3CH2OH (B) CH3CHOHCH3 (C) CH3CH2CH2OH (D) None of these
38. B

39. Me
SOCl2 
Ph C—OH  
in C5H5N
H
Which statement is true for the above reaction?
(A) Retention of configuration (B) Inversion of configuration
(C) Inversion and Retention both (D) None
39. B
40. Which one/ones of the following reactions will yield 2-propanol ?
i) CH3 MgI
i) CH CHO 
3  ii) H2 O
i) C2H5MgI
ii)
HCHO ii) H2 O


(A) only (i) (B) only (ii) (C) Both ( i ) & (ii ) (D) None of the above.

40. A

41. Which of the following statements isincorrect?

(A) Bridgehead halides are inert towards both SN 1 and SN 2 reactions
(B) the first step in both SN 1 and E-1 reactions is the same
(C) SN 2 reactions proceed with total retention of configuration
(D) All of these
41. C
 MgBr
42. Which of the following compound on reaction with
CH2CH2OH
followed by hydrolysis gives
CH2 – CH2

(A) CH3–CHO (B) O (C)CH3–CH2–CHO (D) O

42. B

43. Ethyl alcohol in presence of I2/KOH give yellow crystals of....……..

(A) CHI 3 (B) CH 3 I (C) CH 2 I 2 (D) C 2 H 5 I
43. A
44. Which of the following compounds gives trichloromethane(Chloroform) on distillating with bleaching powder(
CaOCl2(aq) ).
(A)Methanal (B)Phenol (C)Ethanal. (D)Methanol

44. C

45. Which of the following compound gives a ketone with Grignard reagent ( followed by hydrolysis )
(A)Formaldehyde ( HCHO) (B)Ethyl alcohol ( CH3CH2OH)
(C)Methyl cyanide ( CH3 CN) (D)Methyl iodide ( CH3 I)
45. C
46. Which one of the following will give maximum yield of R–Br? (In the following reaction)
CCl4
Br  
CH3COOAg + 2  R–Br ;
CH3CH  CH3  COOH CH3CH2CH2COOH
(A) (B)
(C)
 CH3 3 C  COOH (D) All will give same yield
46. B

47. SOCl 2
?
H3C OH ether
The major product is
Cl
A) H3C Cl B) CH2
H3C

CH3
C) H3C D) CH2
H3C
Cl

47. B
 2
48. In which alkyl halide, SN mechanism is most favoured ?

A. CH3Cl B. CH3CH2Cl C. (CH3)2CHCl D.

48. A
49. Identify the major organic product in the following reaction.
F
Na SCH3

O 2N Br

F SCH3

A) O 2N SCH3 B) O 2N Br

SH3C F F

C) O 2N Br D) H3CS Br

49. B
 O

O 1. NaBH4
Product
50. H 2. H3 O, 
O
Identify structure of major product in the above reaction, from the following ?

O
OH
(A) (B) (C) CH2OH (D) O
OH
OH
50. D
 INTEGER: 10

51. How many of the following can reduce Aldehydes Ketones into corresponding alcohols.
(a) LiAlH 4 in THF
(b) NaBH 4 in Ethanol
(c) BH 3 inTHF
(d) Metal  Hydrogen (Metal = Ni, Pt, Pd)
(e) Zinc in Acetic acid
51. 5

52. How many of the following can reduce Carboxylic acids into corresponding alcohols.
(a) LiAlH 4 in THF
(b) NaBH 4 in Ethanol
(c) BH 3 inTHF
(d) Metal  Hydrogen
52. 2
53. How many of the following statements are correct about NaBH 4 in Ethanol
(a) it can reduce ester into corresponding alcohol
(b) it can reduce acylhalides into corresponding alcohol
(c) it can reduce aldehyde into corresponding alcohol
(d) it can reduce carboxylic acid into corresponding alcohol
(e) it is more powerful reducing agent than LiAlH 4 in THF
53. 2

54. How many of the following statements are correct about LiAlH 4 in THF
(a) it can reduce ester into corresponding alcohol
(b) it can reduce acylhalides into corresponding alcohol
(c) it can reduce aldehyde into corresponding alcohol
(d) it can reduce carboxylic acid into corresponding alcohol
(e) it is more powerful than NaBH 4 in Ethanol
54. 5
55. How many among the following compounds are reduced by Lithium aluminium hydride

O Cl
C

O O

O
A B C D E F G H

55. 5

H3C
56.

Cl2
h
 The number of monochloroderivatives
H3C CH3
(excluding stereoisomers) formed is/are………..

56. 6
57. PhCOCH 3 Ph CH CH3
OH
How many of the following reagents can be used for the above transformation

LiAlH4,

NaBH4, in Ethanol

NH2NH2/KOH/,

Zn-Hg / HCl ,

B2H6 .THF,

57. 5

58. In the given reaction

Cl
3 Cl
4 S 1
2
C H 3O H 
N

 Pr oduct
1 eq u iva len t
O Cl
which Chlorine group is replaced by OCH3 ,as indicated in structure :

58. 2
59. In Haloform reaction of Acetone(CH3COCH3 ) requires ' x ' moles of halogens(X2) and ' y ' moles of
Base(NaOH). The the value of (x + y ) = ………
59. 7

60.

How many hydrogen atoms are present in B

60. 6