ap Ned me 22/2. J23 ™ qs woes RS Ednotorsomonounc comes ei — SE Sil vy . : Ea] a [Sorc] Sina ogee palate salp wig arma Te PUR ee, if weids’ ance - |n2}3)23}| 29) ~~ os canon minecty=: [Sea ops [renal ee | = iia — a | Ear TeT ANS pend CONN fetid py SSE Lani oe] MB le meal a se cl som [Pec hins|aafais|ole [OS | sgh dh tle lemme, —>| 2”? Cpa | [ ina dist Lube | peayngty ngs co? USS flop eal | SSMU” | lenge =n Dyer ractils | sda Beanee of reli aa oa agile [WR ili an al |e i | Aisles | 4/28) Be lol anosean, | ds Cucnne em Peeesla/6(ze |e/6 | WB - Heats Tanna TP [eerie 24/28] yep] Te OE lee he Mined aia. "eee ee fd along th aa tly i Suntalate 4 INH akin | acne we | dc pap cle SF elneg —afO9 pat ete sel feooerrs0-+ 0% - ChaMed ng RPMS Rs i nc mail g ea ds eye Meares” pn pele ogame + Cat, | gen Pace, wfc {me ([laleiae strate ppt} w Dextard ewok D Nat, elution we framediite ail st the yp orocanar wae selina” an, e pet a go tetas oes | Frac of tei sarc a a bpTg iat Wags of |i pintate | fre [hate aeluln be a heal preci Fructese via laguteus ation o i> Me rae 3) Tost sce isis eh Slaw colar sn arch iapraut 306 a fon ae > Be cele tdacr e part srl fasta’) a me 7 | J tad udu) Bias dps | induc med clown | Susotne w0ae [tnd | Men pr | pant sn a of ee 4 ier mee ; ; rms > flucee ts sity aan | | ‘ MERIAL rem) = | _ | | oncotan ANHA BURMA UTA, 1M: 2O2DALP SHUI Gm2 28 ovine TE llsthale tai ema ietgané eapenmest y rat sen Mond fs tre Tan of te addled. Pit in nie yualitetiie analy ie punt iat fo ef Min 4? + ba bao, Oyecbatis (tiyeor) | Lratt amount fas vit Ceiba i fe ve land MEMS 8 ala ote | lerscoo- + we —> | | cascoon [ PE UAHA UE ei eae ine 0 [Fete] eer oo ec] 40 Pooretmpagemu® ‘PSeay on Ou *) | al ane of | ashe pap Lea ewan inn fate ard a ltr i educa ech fue ea ae dal Waa ty» Batty |ol He Olin (No) Plnmon sig cat) on pire Fn) A buon sg fi ‘eins adtelel | ppeans at pint BLM) eres avons Fetudghtenor—pfrecnng 00 ee Ail fap 500 ir au dptnglans L__. SS aa | Hyco prose itiservation Inference | Experiment | coseration “olin an| aie pace My past fale u ae Nii ca or yrs buat. ba Cr 0 we ae oy eating de aeve wie P 4 Pecoyr mp is "lat anmaman! | Nyt Ls eng es tech wel al louse (nh) ot { ae Have Mey se may Le pram pr ena aay oa Ge Ne sol fa" de coy bad cant ha pti | bat mye te le te ata mete aw lars cat Bast | Ae ae pov tt tae ail Maes emf Beat ccs manga | 7 i aaa Pigty was lf » aio na rs ok rroarea oa sat asad = Eom i eo | “A Ale Nhe ot 3 nctunna poet a 1 Geitlons tla) Goucde 5h t0L0g) + 50> Mg Loh. 24 ny Seen a int Niomeositen: ANUIHKA SHARMA seustnanse Ufa wie 2I9IALPS HAL G a os , eELUSSSEEEE SUE SHALUCEESTEIUUIIL , _ Pa ti elExp. No. pate: 49. Jo4]23 DETERMINATION OF THE pll CURVE OF AN ACID-BASE TITRATION Objective 7H out the este za ee astern are baat, pldaun the conecnbsatiin aa a the aida $i Observations & Calculations aol 1) Standardisation of NAOH soltion Molaityof oxtic aid soliton = O10 25M, Volumeofoxalic aid preted = pm L ut [4 O10 mL. 194.4mt | 19.4 38: 5mt 0 mL__| 4% 2mb_+ 4. | 0.0m | 1%4mL | L Conepudart valu Molaity ofthe base (NOH) ~ Ae haste, Nun Vou = pies et : ‘whan, I= Nomad 1 ain wala, of atti : and ne eee “ae te 7 ' > MyteonX Vaan Mane = Monatis% Voralic * Morale RE day Sibaex?x 10 > [Muuyi= 0.0257 0 006M Attach the following graphs 48) Graph of pH versus the volume of titrant added }) Graph of (ApH/AV) versus the volume of tran aed, where (ApH) is change in pH between two successive additions and AV is the incremental volume of titrant added, ‘ ( ( 4 ( ‘ Volume of the weak cid taken = 20m Ls ‘ ‘ ‘ ‘ ‘ ¢ ‘ Vong ofthe use ue a eehequvaencepot( bi om gat) = 24 B gL y; Myra X Veeu = Matas * Vinay (uwhire Mio raotansty, > Mana = 100258 x 206 Via volume stmt) 20 a = 0.0278M #0-028M pH at half tquiralince punt 4S. Pha of aciel 4ea stare prime a often ‘eased ose meted eee hy (Play pt ticday| ApH fav] Vout 2 [oe fe 25.44 bo] 0-2 | 9.35 2 | o45 [9 Jo» 5p pty} oS | 0.26 2 | nto [5 t0.ty bas] 0-5 | 0-4 08 JF [94 |4p.92 [rss 5 | 9.36 2 [008 [4 [ 945) 19-90 bol O5 | go 2 | 095 || a5 | dovay [009] 05 44 2 | ones 129] 26.5 | 44.94 lou 0-5 | o-08 orotg 15] 26 | A495 [oer os | pay | a ott [ef 265] s4-talod os | gon [a4] a 0.205 [29] 29 | 44.26 \poal os | poy 29-25] oad 0.5 | 0.34 boas 246 ttaelouelos | ony [29-95] 0.5 | he [7] 28 | g4.on 05] 05 | og [2825 124 0.2 | gzsraial 2851 44.99 inal 0-5 | p06 28-75] oe 0.2 | oar mast 94 | aoe betes | omy [ors Wie foil o.g —} 9-02 Jana, 0.2 151 Jy | gaio9 looses - | ove on | ¢-4 {etal 39.5] 44.99 loot) os | 062 |30-75) 02 | 36 ls 34 | 44.3o|oolos | ooy [3 0.2 | 4.45 |t34.6| 44.26 )ot10-5 | por [3475] OD | 4.4 [22s] 11,34 bor] 9.5 O04 |3295) 02 | 6.5 [es a5 [qq borl05 | o.94 32-25] ond | 9.56 be: A449 | Results: a Molaiy ofthe ven weakacidslaion =O} M rai 1k, ofthe given weak acid = 4.55 (pH at [phe that sstelen — ee Pd pay “hes ey Mark obtained: 5 Name of student ANUSHKA SHARMA Simaveotininsoc ULI ove 202 AL P9109-6ase TE eadiniade tiv amet 4 eats lg esta é mrames Aca spor ein etn: 9:303.q secompersiee DF te hasre, Nizay® Viyga= Neate, % V sey ? we oosd x to Nap Te Ny, = 0:0235N hp ‘rormalty aolation > me atin Sy th A wo » wa 26/4123 =z ~ O.OLWN ae madig =C30 fa, Tigo! pe Many * Vest (n= ype on85N Vouee 009N et = The siengh ofthe wsaown copper itn season = 21225 gi fhe ‘gwrmality (N) EPogucvelants aveyght Fe 0-00 85 x 247-4 ghee > bean = 242 gL a uote (, anetsien: ANUSHEA, SHARMA Semesttaner UCR’ We 2ODALPSINAGGue ls) poe weak ELECTROLYTE an ~ ~ ~ ov ov =~ wa, 6 ae DETERMINATION OF TOTAL ARDNESS OF WATER sss 1 detorenuie vthe telat drardnca “abe aor Sd vende Cnaten ‘Nera toner fit aS, 1,0) sto: ogee sale= 0 504 ‘Thee pf ice S73 22 unknown [6 ene, ‘ fe ce cee cae ies) ne | sua ant fae ‘ Ome | Qt9me— | 2bSmL 244 | 0.062 | nokxsyrS | 404 e 24SmL_ | 42. ¢me a4 3me Ochs 01 pain ao #[.%6 7 a TA eo tong —aaeetr [30 LC ci va yao | 9.006 a ne lim ES 7 auto 1 0.004 adele Nal womEN Trentart vlimEE SL) sn SS v = Vena = 24-3m Maas 2h ame eaten: ANUSHKA SHARMA UTR, | Im 22ALPSANAGE, x Veneers aa ee Tote bere Tobe [200054] Fe ewe eae TT . 22mL 28."5mt 6.3 nL er ee 3m I Contedant wilame= CMeae nent, 1 yx npc expressed as CaCO3 eulvatent To calculate hardness of wa [molecular weight of CaCO, {mole of EDTA = I mole af Ca” IN EDTA n thc compo METAL Nera te warm naga ai apes sea yeaa Hire ETA a 01005 6:3 — 0.00063N = 63x40" (N 50 2 Gato, We moleudan site y "aa Tam = Mvwhoe eb bus Ct ay 03 Sa 65st by 1y400 = 63x10 2[0.0kEa) efor md Mod) ardnes ofthe water sample expressed as CaCO, enivalent = 2 0.063 SL 0506391""x4000 = 6% Pom (as Seppm Agi Lo0typm Result ‘The hardness ofthe given water sample expressed as CaCO, equivalent= & 3 poy, H Bx to%a/t Mark obtained: (, Name fstudent ANUSHICA SHARMA oA : wet Wars wre: DODASPS 1476 6ovicaive Deformure the amour of eau pret uh the purin all Sy git ‘Observations & Calculation i) Standardisation of KMnO3 solution (A) Concentration of oxalic acid O, OLN, Volume of oxalic acid pipeted= 9 mL. S.No, [Inia burete Fina bureie | Volume of reading (mL) reading (mL) | KMaO, (mL) EE Om 4m | 204m 7 : Ome 0. Gmb | dy. Sm 3. Ome 29-4 mL} Jo. mL. | eeeeaeeeneeoen en SS wns farkMnO sivsn NO AR KVonate — 0.08240 0e(9, O05N) eboet Cleric ai finer KO, A) as aa So] Volume of KMnO, soon [Normality ofthe isorbane at S48 = ct ay |ston a latte ) lay 0 : 9 ON 0 nan rd eS pain | 2.0005 Daa POSEN 40x20" | 2 o.0040N | pba ge - DNA p| 15x10 * 3 0-0045N 0.654 2053=1e8H an quando N | ofl Perron 5x10 |® 5 aia 0.0045 N 407A Za Attach the graph of Absorbance of KMnO, Versus Concentration [Absorbance ofthe given anknows) KMaO, solution B)= 0.59 2. Gg ‘Concentration of the given (unkgown) KMnO. solution (B) = 4."5, 75 x 40" ce ' Pisa He HOdESE EMR AAO ec: ee. Oe ee A NI na BEB tn de® 6 Tame ou pas SrA GHARNA Signature of Insiructr: Won Ne QODDAL ASIN FE GExp. No Q KINETICS OF THE IODINATION OF ACETONE BY SPECTROPH onisane Ta gti ap “ait " Concenaton of of slain sk): () + 025M 56M Concentration oF HCI (toe): fy, 5M ‘Concentration of Acetone (sock) a Calibration Curve 2 |OTOMETRY. ‘nd Lie se ea fem Volume a Soaion al) Th “Rbsorbanee ° OM 0 : 00025 M oust : 0.005M 0828 : 0.0075 M 42944 : 0.01 M 4.518 > 0:0125M 4.923 Attach the following graph ; Graph of Absorbance vers (h] : Slope of Absorbance versus [1] plot 1) RatemeasuremensMVj=MaV, WOKE Me nralanty; Vie welume, Toa.4m-* Value] Volume] Volume | WO] Conca [ Cone ot | Cone of RE. | Ateone [ater | pees | orsxy (at see, | station | olan eav opsv ogee Tae} 30a | mE TAL 42M Faw] Boa] EOE TTL fe 0.005: T-Rowe | OL | OL | BO TDM 9-2 lo opeet 4 ZOm— 20mL | 40mL | 20m 44M) od ml 04 10Maludehrion | ek fee LE, Ap Sobani VAC) Peden a a 4 feat henal. Laas DOVE | 8908) OMA TTCATION 101—— Exp4 Exp! Exp? Exp} Time | asotane| | i | Aborbance Time |aserane| fay sans 0 | 0852) | o| 080+] | o 10426 © St, those! (losec) [2 lotoa| [4 4802) q|.0.835| [2 | o.ae4) [210-644 fo [as 3 fo.g23| [3 [o.agi) | 3 ose) 4ae log | [4 botou| | 4 loo) tite slow! (6 locas] [Slo5e2 |S) tbke 6 low | (6 l 0-655) | 6 lose} 6 4495 + loggu | [| o.caa) [#josuo | AL ttte Ded \ | _| NMSe eeu F FB BH¢ fousows)® (ut) 1 Couto gery Abn= 0, hk! initial tote: Trot at Attach the following graphs ‘Graph of Absotbance versus Time fr each ofthe rials 1b) Order wih respest to acctone Ry (sade of emp t) = R(0- 005)" (4.424 (0.1) aa op satay = = (0005! (2.24)8 Co y Duiding &, af ay! = & 60X10 y 4 10 X L075 ae oth wa bedon of anit le 4 ad, | pyc 1 (rom tpg cape sine sh rT i ‘ stone]. wy Th raph ute “4 | Cony) Fas) | Mr 4:42 | 0.4 [0.005 [0-010 |6-Lox105/0- ‘ * [aan [ona [tas [oars lacoxto fasta’ « P| aaa | 0.2 [0005 bo. 009 [2 toxs0it 13 ; i 142 | 04 0-040 |-0: 00% |4.34y10 4b ‘ fes= CEI Cage tT = 40s) yuhuw 4 da wren of suaction » ds pete | emit ‘ ii) Order Catelations : R (sad op) = k k (ow s)(10(08) ‘ Ra (nate ter i fo oan) (aan (0-998 ; Op Gao x 40-5 i fy “4 3gxue oe! t 2 Orel of sactien with, ageloe ‘ 1 ‘ vo ‘ ' ' ' ‘ ‘©) Order with respect to Ht a 1) =k(0-005)*(b.4142)1 (o.4)8 Ca na dls = (0005 )* (4.4094 (0. os R35 5 ; 0) = Gites *1 eee ° Baal Juaction wit Juspect te Ht. wateComant Casi (WAIL Rs the Haile of Hence) 2) Rat Conta tom Expeinan Cplacing the above rund wale =R[ooos] forpe [rage “Ad "R= b20x10% — 65.35 x 10M taint 44201 gen y got mt mt a oO 0.93 x10°5 Mt mutt Thus, the Hote tanstaat prom tmp 4 ia $823 [0.93x40 te] 8) Rate Constant fiom Experiment 2 Ry = R [0.008] [2.24] *0% ay D> ke Looxsot 44x 20% main DMxO4 A i) or 149% 10-54 geen * Thus, the sate Corkart: from enp 2 DWH ©) Rate Constant from Experiment 3 Ry 2 Ko 008) Lo-2)* [449}* Ske A8OxI0 = Bo.ZG07 5 Mt min VIL OD Hh 4.33% 107 Spyot get Thus, re paste coratant [rem erp 3 is 133% 40M eeong fo-or} (o-n*lt #2] sp 5 Mga Djs Hse = 3.07 SNM t Od x112 on (p05 Me iat 5 x: Thus, Mate conctonct frm op 4 = Obey 47 SM Me a sats | Conder ofthe reaction with spect to CHsCOCHs, = 4. (Order ofthe reaction with respect to H”, 4 : Orderoftereaionwinrepetioh, =O ‘ 5 M-tynt ; Average value of rate constant k= 1.03x 10°M 4 : Avoiage d ke 093414144394 O85) x10 ty 4 r = L025x10° y L0G x40 Ryty-16 Mark obtained: By 5” Name of student: ANUSH KA SH Sermmeotinincwr TAI Nu 202 2ALPSAN6 by