CHEMI GNOSI

S CHM 111E-EXAM
RELATEDPRACTICE 2022/2023SESSI
ON
QUESTION(RPQ)ON
SOLUTI
ONS&COLLI
GATI
VEPROPERTI
ES

1.Whatarecol
ligat
ivepropert
iesus
efulf
or?

a)Det
ermi
ningboi
lingandmel
tingt
emperat
ure

b)Det
ermi
ningmol
armas
s

c)Det
ermi
ningequi
val
entwei
ght

d)Det
ermi
ningvan’
tHof
ffact
or

2.Thef
oll
owi
ngaret
hecharact
eri
sti
csofani
deal

s
olut
ionexcept
---
-

A.Changei
nvol
ume(
expans
ionorconcent
rat
ion)onmi
xing

B.∆Hmi
xing=0

C.Raoul
t’sl
aw i
sobeyed

D.Noheats
houl
dbeabs
orbedorevol
vedduri
ngmi
xing

3.
Thef
oll
owi
ngsarecharact
eri
sti
csofanon-
ideal

s
olut
ionexcept
---
--

A.Raoul
t’sl
aw i
sobeyed

B.∆Hmi
xing=0

C.Sol
uti
onmayabs
orborrel
eas
eheat

D.∆Vmi
xing≠0

4.Ani
sobari
cproces
sisonei
nwhi
ch-
--

A.Thet
emperat
ureoft
hes
yst
em remai
nscons
tant

B.Pres
sureoft
hes
yst
em remai
nscons
tant
C.Vol
umeoft
hes
yst
em remai
nscons
tant

5.Col
ligat
ivepropert
iesdependon-
--
--
--
--
--
--

A.Thenat
ureoft
hes
olut
epart
icl
esdi
ssol
vedi
nsol
uti
on

B.Thenumberofs
olut
epart
icl
esi
nsol
uti
on

C.Thephys
icalpropert
iesoft
heoft
hes
olut
epart
icl
edi
ssol
vedi
nsol
uti
on

D.Thenat
ureoft
hes
olventpart
icl
es-s
olut
ion

6.Whi
choft
hef
oll
owi
ngi
sacol
ligat
ivepropert
y?

A.Rel
ati
vel
oweri
ngoff
lui
dpres
sure

B.Decreas
einboi
lingpoi
nt

C.Decreas
einf
reezi
ngpoi
nt

D.Changei
nvol
umeaf
termi
xing

7.I
fthepres
sureofagasi
scons
tantandt
hevol
umei
sdecreas
edf
rom 2vt
ov,t
he
t
emperat
ureoft
hegaswi
llbe-
--

-
A.I
ncreas
ed

B.St
ayt
hes
ame

C.Decreas
ed

D.Changerandoml
y

8.Quart
enarySol
uti
onscont
ains_
__noofcomponent
ssol
uti
ons
???a.1b.2c.4✓✓
d.
3

9.Whi
chi
sagas
-sol
idmi
xture??a.H2(
g)onBrb.H2(
g)onAsc.H2(
g)onpd✓✓

10.Numberofmol
esofs
olut
epres
enti
nas
olventi
scal
led_
_?a.Mol
ari
tyb.
Mol
ali
ty✓✓c.Nor
mal
it
y

11.TheAMOUNTexpres
sedwhent
heconcent
rat
ionofas
olut
eismi
nimali
s__
?a.
Part
spermi
lli
on✓✓b.Percent
agebymas
sc.Normal
ity
12.Whi
chi
sas
oli
d-LI
QUI
Dsol
uti
on??

a.NH4Br✓✓b.CH3Ic.Sodi
um amal
gamat
e

13.Henry'
slaw waspropos
edi
n1803

14.Sol
id-
LIQUI
Dsol
uti
onsobeysLeChart
eli
er'
sLaw

15.Gas
-li
qui
dsol
uti
onobeysLeChart
eli
er'
sLaw andHenry'
slaw

16.Li
qui
d-Li
qui
dsol
uti
onsobeysmai
nlyRAOULT'
SLAW

17.BUNSENCOEFFI
CIENTAREASSOCI
ATEDWI
THGAS-
LIQUI
DSOLUTI
ON

18.VOLATI
LE&NON-
VOLATI
LE,ENTHALPYOFMI
XING,VOLUMEOF
MI
XING,
IDEAL&NON-
IDEALSOLUTI
ON,POSI
TIVE&NEGATI
VEDEVI
ATI
ON,
RAOULT'
SLAW CURVE&VAPOURPRESSUREAREas
soci
atedt
oLi
qui
d-Li
qui
d
s
olut
ions
.

19.Sol
uti
onst
hatobeysRaoul
'sl
aw areI
DEALSOLUTI
ONSWHI
CHCONTAI
NS
MOLECULESOFSOLVENTSANDSOLVENTWHI
CHARESI
MILARI
NSTRUCTURE
ANDPOLARI
TY,WHEREENTHALPYOFMI
XING&VOLUME=0.

20.Exampl
esofI
deals
olut
ionsare[
C6H14:Hexane&C7H16:Hept
ane,
C7H9:
Tol
uene& C4H9Cl
:But
ylChl
ori
de(
als
oknownasn-
but
ylchl
ori
de)
& C4H9Br:
But
ylBromi
de(
als
oknownasn-
but
ylbromi
de)
,CCl
4:CarbonTet
rachl
ori
de&Si
Cl4:
Si
liconTet
rachl
ori
de

21.St
ateHenry'
slaw Henry'
slaw s
tat
est
hatt
heamountofgasdi
ssol
vedi
nal
iqui
d
i
sdi
rect
lyproport
ionalt
othepart
ialpres
sureoft
hegasabovet
hel
iqui
d.

22.Whati
sanazeot
ropi
cmi
xture??Anazeot
ropei
sami
xtureoft
woormore
l
iqui
dst
hathasacons
tantboi
lingpoi
ntandcompos
iti
on.I
tcannotbes
eparat
ed
i
ntoi
tsi
ndi
vidualcomponent
sbys
impl
edi
sti
llat
ion.

23.Somenearl
yidealmi
xturesare:i
),et
hyl
enebromi
deandet
hyl
enechl
ori
dei
i)n-
hexaneandn-
hept
ane.i
ii)benzeneandt
oluenei
v)n-
but
ylchl
ori
deandn-
but
yl
bromi
de.v)carbont
etrachl
ori
deands
ili
cont
etrachl
ori
de

24.Expl
ains
olubi
lit
ycurves
olubi
lit
ycurvei
sagrapht
hatdepi
ctst
hes
olubi
lit
yof
as
olut
einas
olventasaf
unct
ionoft
emperat
ure.I
tshowshow t
hes
olubi
lit
y
changeswi
thi
ncreas
ingordecreas
ingt
emperat
ure.Thecurvet
ypi
cal
lys
tart
sata
l
ow s
olubi
lit
yatl
ow t
emperat
uresandi
ncreas
esast
het
emperat
ureri
ses
.
25.Expl
ainRaoul
t'scurveRaoul
t'scurvei
sagraphi
calrepres
ent
ati
onoft
he
rel
ati
ons
hipbet
weent
hemol
efract
ionofacomponenti
nthel
iqui
dphas
eandi
ts
corres
pondi
ngvaporpres
sure.Thecurves
howsal
inearrel
ati
ons
hipf
ori
deal
s
olut
ions
,butdevi
atesf
rom l
ineari
tyf
ornon-
ideals
olut
ions
.

26.Pos
iti
veDevi
ati
onoccursWHENVAPOURPRESSUREOFANONI
DEAL
SOLUTI
ONI
SHI
GHERTHANTHATOFANI
DEALSOLUTI
ONOFSI
MILAR
CONCENTRATI
ON

27.Negat
iveDevi
ati
onoccursWHENVAPOURPRESSUREOFANONI
DEAL
SOLUTI
ONI
SLOWERTHANTHATOFANI
DEALSOLUTI
ONOFSI
MILAR
CONCENTRATI
ON

28.Cl
ass
ifySt
eel≈≈≈>Sol
id-
Sol
id,
,,
,sodi
um amal
gram ≈≈≈>Sol
id-
Sol
idandSoda
wat
er≈≈≈>Sol
id-
LIQUI
D

29.Accordi
ngt
oleChart
eli
er'
sLaw SOLUTI
ONSOFI
ONI
CSUBSTANCESI
NCREASE
I
NWATERWI
THI
NCREASEI
NTEMPERATURE.

30.Fact
orsaf
fect
ingt
heSol
ubi
lit
yofGas
esarePRESSURE,NATUREOFGAS
(
Sol
ventf
orm)ANDTEMPERATURE (P.
N.T)

31.Whi
choft
hef
oll
owi
ngobs
ervat
ionsdemons
trat
escol
ligat
ivepropert
ies
?

a)A0.
1M NaCls
olut
ionhasahi
ghervapourpres
suret
han0.
1M CaCl
2sol
uti
on.

b)A0.
1M KOHs
olut
ionf
reezesatl
owert
emperat
uret
hanpurewat
er

c)Purewat
erf
reezesatahi
ght
emperat
uret
hanpuremet
hanol
.

Ans
wer:
a)andb)
.

32.I
nacl
osedcont
ainer,vapourpres
sureofal
iqui
ddependsupon

A.Vol
umeoft
hecont
ainer

B.Temperat
ure

C.Vol
umeoft
hel
iqui
d

D.Al
loft
heaboveAns
wer:b)Temperat
ure
33.Whi
choft
hef
oll
owi
ngaqueouss
olut
ionshast
hehi
ghes
tvapourpres
sureat300
K?

A.1M Na3PO4

B.1M CaCl
2

C.1M KNO3

D.1M C6H12O6

Ans
wer:d)1M C6H12O6

34.Def
ine

Hypert
oni
csol
uti
ons

Hypot
oni
csol
uti
ons

Ans
wer:

a)I
fthewat
erf
lowsoutoft
hecel
lswhenpl
acedi
nas
olut
ion,i
tshri
nksandt
he
s
olut
ioni
ssai
dtobehypert
oni
c.

b)I
fwat
erf
lowsi
ntot
hecel
lsandt
heys
wel
lwhenpl
acedi
nas
olut
ion,t
hent
he
s
olut
ioni
ssai
dtobehypot
oni
c.

35.Whyi
sos
mot
icpres
surepref
erabl
etoot
hercol
ligat
ivepropert
ies
?

Ans
wer:Theos
mot
icpres
suremet
hodhasanadvant
ageoverot
hermet
hods
becaus
epres
surei
smeas
uredatroom t
emperat
ureandmol
ari
tyoft
hes
olut
ioni
s
us
edi
nst
eadofmol
ali
ty.
Itsmagni
tudei
slargei
ncompari
sont
oot
hercol
ligat
ive
propert
ies
,eveni
nverydi
lut
esol
uti
ons

36.Det
ermi
net
heel
evat
ionoft
heboi
lingpoi
ntofaaqueouss
olut
ionwi
th1molof
s
olut
e(gl
ucos
e).
(dens
ity=1.
2g/
mL)

A.Kb B.0.
2Kb C.0.
02Kb D.
0.98Kb

Ans
wer:d)0.
98Kb
Expl
anat
ion:

Dens
ityofs
olut
ion=Mas
sofs
olut
ion/
Vol
umeofs
olut
ion

1.
2g/
mL=Mas
sofs
olut
ion/1000mL

Mas
sofs
olut
ion=1200g=1.
2Kg

Now,gl
ucos
eact
sasas
olut
eint
hes
olut
ion,andi
tsmol
armas
sis180g.

Mas
sofs
olvent=Mas
sofs
olut
ion-
Mas
sofs
olut
e=1200–180=1020g=1.
02Kg

Mol
ali
tyofs
olut
ion,m =Mol
esofs
olut
e/Wei
ghtofs
olvent
(Kg)

=1/
1.02=0.
98

El
evat
ioni
nboi
lingpoi
nt,ΔTb=Kb×m =0.
98Kb

37.Whi
chl
aw s
tat
est
hat“
themol
efract
ionofs
olut
eequal
stherel
ati
vel
oweri
ngi
n
vapourpres
sure”f
oradi
lut
esol
uti
on?

A.Dal
ton’
slaw

B.Raoul
t’sl
aw

C.Henry’
slaw

D.Avogadosl
aw

38.
Whi
choneoft
hef
oll
owi
ngi
snotacol
ligat
ivepropert
y?

A)Os
mot
icpres
sure

B)El
evat
ionofboi
lingpoi
nt

C)Surf
acet
ens
ion

D)Depres
sioni
nfreezi
ngpoi
nt

39.Whi
choft
hef
oll
owi
ngf
act
ori
nfl
uencet
heVaporpres
sure

A)Surf
acearea

B)I
ntermol
ecul
arf
orce

C)Temperat
ureD)Al
loft
heabove
40.????Freezi
ngpoi
ntdepres
sioni
smeas
uredby

A)Beckmann’
smet
hod

B)Ras
t’scamphormet
hod

C)Bot
hAandB

D)Noneoft
hes
e

41.Whenanonvol
ati
les
olut
eisaddedt
oas
olvent
,thef
reezi
ngpoi
ntoft
hes
olvent

A)remai
nthes
ame

B)i
ncreas
e

C)decreas
e

D)noneoft
hes
e

42.Whi
chi
sanott
ruecri
teri
onf
orani
deas
olut
ion?

A.Freeenergyofmi
xing=0

B.Vol
umeofmi
xing=0

C.Ent
hal
pyofmi
xing=0

D.ObeysRaoul
t’sl
aw

Ans
wer:
Freeenergyofmi
xing=0

43.Thenumberofgram equi
val
ent
soft
hes
olut
edi
ssol
vedperdm3oft
hes
olut
ioni
scal
led

A.Formal
ity

B.Mol
ari
ty

C.Mol
ali
ty

D.Normal
ity

Ans
wer:Normal
ity

44.I
so-
osmot
ics
olut
ionsaret
hos
ewhi
chhavet
hes
ame

A.Vaporpres
surel
oweri
ng

B.Boi
lingpoi
ntel
evat
ion
C.Mol
ali
ty

D.Os
mot
icpres
sure

Ans
wer:Os
mot
icpres
sure

45.Themol
ari
tyofas
olut
ioncont
aini
ng4gNaOHper500mLofs
olut
ioni
s(Molmas
s=40)

A.0.
1

B.0.
4

C.0.
3

D.0.
2

Ans
wer:0.
2

46.
Thet
emperat
ureatwhi
cht
woconj
ugat
esol
uti
onschangei
ntoonehomogeneous
s
olut
ioni
scal
led

A.Cons
olut
etemperat
ure

B.Eut
ect
icpoi
nt

C.Cri
ticalt
emperat
ure

D.Trans
iti
ont
emperat
ure

Ans
wer:Cons
olut
etemperat
ure

47.Whats
yst
emsperf
orm ef
fect
ivel
yatt
het
ops
oli
dtemperat
ure?

A.Tri
ethyl
ami
ne-wat
er

B.Ani
linewat
er

C.Ni
cot
ine-wat
er

D.Phenol
-wat
er

Ans
wer:Ni
cot
ine-wat
er

48.Sol
uti
onswi
thcomponent
swhi
chobeysRaoul
t’sl
aw overt
heent
irecompos
iti
onrange
arecons
ideredt
obe

A.I
deals
olut
ions

B.Regul
ars
olut
ions
C.Di
lut
esol
uti
ons

D.Reals
olut
ions

Ans
wer:I
deals
olut
ions

49.Accordi
ngt
oHenry’
slaw,t
hemol
efract
ionofagas(
x)di
ssol
vedi
nas
olventi
srel
ated
t
othepres
sureoft
hegas

A.x=k√P

B.P=kx

C.x=k/
P

D.P=k/
x

Ans
wer:x=k√P.

50.Thel
aw whi
chrel
atest
hes
olubi
lit
yofagast
oit
spres
surei
scal
led

A.Hennery’
slaw

B.Nerns
tlaw

C.Os
twal
d’sl
aw

D.Raoul
t’sl
aw

Ans
wer:Hennery’
slaw

51.Thenumberoff
ormul
awei
ghtoft
hes
olut
edi
ssol
vedperdm3oft
hes
olut
ioni
scal
led.

A.Formal
ity

B.Normal
ity

C.Mol
efract
ion

D.Mol
ali
ty

Ans
wer:Formal
ity

52.Whi
choff
oll
owi
ngpropert
ydoesnotdependupont
henumberofs
olut
epart
icl
es?

A.El
evat
ioni
nB.
P.

B.Boi
lingpoi
ntoft
hes
olvent

C.Depres
sioni
nF.
P
D.Os
mot
icpres
sure

Ans
wer:Boi
lingpoi
ntoft
hes
olvent

53.Whi
chi
snotacol
ligat
ivepropert
y?

A.Ref
ract
ivei
ndex

B.Depres
sioni
nF.
P.

C.El
evat
ionofB.
P.

D.Loweri
ngofV.
P.

Ans
wer:Ref
ract
ivei
ndex

54.Fordi
lut
esol
uti
onscol
ligat
ivepropert
iesdependon

A.Thenumberoft
hes
olut
epart
icl
esandi
rres
pect
iveoft
henat
ureoft
hes
olut
eand
s
olvent

B.Thenumberoft
hes
olut
epart
icl
esandont
hei
rnat
ure

C.Thenumberoft
hes
olut
epart
icl
esandnat
ureofs
olut
eands
olvent

D.Thenumberoft
hepart
icl
esoft
hes
olut
eandnat
ureofs
olvent

Ans
wer:Thenumberoft
hepart
icl
esoft
hes
olut
eandnat
ureofs
olvent

55.Theos
mot
icpres
sureofas
olut
ionwi
thdef
ini
tecompos
iti
on

A.Vari
esi
nvers
elyast
hevol
umeandast
het
emperat
uredi
rect
ly

B.Vari
esi
nvers
elyast
het
emperat
ure

C.Vari
esdi
rect
lyast
hevol
umeandt
emperat
ure

D.I
ndependentoft
het
emperat
ureandvari
esi
nvers
elyast
hevol
ume

Ans
wer:Vari
esi
nvers
elyast
hevol
umeandast
het
emperat
uredi
rect
ly

56.Whi
chs
olut
ionwoul
dexhi
bitabnormalcol
ligat
ivepropert
ies
?

A0.
1M gl
ucos
e

B.0.
1M urea

C.0.
1M s
ucros
e

D.0.
1M NaCl
Ans
wer:.
0.1M NaCl

57.Doal
lbi
omol
ecul
ars
olut
ionsexhi
bitCOLLI
GATI
VEPROPERTI
ES??

A.TRUE

B.FALSE

Ans
wer:Fal
se.

58.St
art
ingwi
thpureNH4Cl
,thef
oll
owi
ngi
ses
tabl
ishedNH4CL⇄ NH3+HCl
.Thenumber
ofcomponent
sint
hes
yst
em i
s

A.Three

B.Two

C.One

D.Maybet
woort
hree

Ans
wer:
One

59.Whati
sthenormal
ityof2.
3M H₂
SO4s
olut
ion?

A.4.
6N

B.0.
23N

C.2.
3N

D.0.
46N

Ans
wer:
023N

60.Therel
ati
vel
oweri
ngofvaporpres
sureofas
olut
ionont
headdi
tionofnon-
vol
ati
le
s
olut
e

A.I
sequalt
othes
um oft
hemol
efract
ionoft
hes
olut
eands
olvent

B.I
sequalt
othemol
efract
ionofs
olut
e

C.Dependsupont
henat
ureoft
hes
olut
e

D.Dependsupont
henat
ureoft
hes
olut
eands
olvent

Ans
wer:I
sequalt
othemol
efract
ionofs
olut
e