nfo a) examination qd the colour of the salt the smell of the salt » Not! oted eating test pry pinch of the salt in abe and noted the vag observations : volved Gas @ Sublimation <) Decrepitation @) Fusion © Colour of the residue Charcoal cavity test Med 2 pinch of the salt with cable the quantity of Na,CO, | Md heated the mixture on a fare cavity in the reducing . % alt nitrate test o the above white residue ‘a drop of cobalt nitrate fone and heated in oxidising es nly the given salt for acidic and hasic radicals. Observations White No specific odour Acolourless gas having pungent smell evolved. The gas gave white fumes when a glass rod dipped in aqueous ammonia is brought near the mouth of the test tube. No sublimate formed. No crackling sound observed. Salt does not fuse. White White residue. No characteristic colour. ee | ae Cu", Fe, Bel, Ni2*, Mn?*, | Co? absent NH,’, 5% and CH,COO™ may | be absent. Some hydrated Cr. may be present. Br or f Ammonium halides, aluminium chloride, iodide may be absent. Lead nitrate, barium nitrate, sodium chloride, chloride and potassium iodide may be absent potassium Alkali (sodium, salts may be absent. potassium, Zn**, Pb** may be absent. Zn?*, Pb? absent. Mn? etc. may be zn", Mg*, AB, PO,*, maybe | absent.Observations 7 e test aaa a jaste of the salt in Persistent grassy green flame Ba?* present. ; PrepattCland performed flame on prolonged heating he test A | 6. Borax bead test | Did not perform this test since Cu? NP, Fe, Mas g4p a aes given salt was white be absent | | 7. Dil. sulphuric acid test : | Treated a pinch of the salt with No gas evolved. C0, 8”, No, +50 -maybe | Gil, H,SO, and warmed. absent | je. 8. KMn0, test | Toapinch of the salt added dil Pink colour of KMnO, was! Cl may be present | 37. 4,50, warmandthenadropof| charged with evolution of Kind, solution yellowish green gas having | : characteristic pungent smell. | hs. 8. Conc. sulphuric acid test | eated a pinch of the salt with | Acolourless gashaving pungent Cl may be present cone. sulphuric acid. smell evolved. The gas gave - white fumes when a glass rod dipped in NH,OH solution was brought near the mouth of the test tube. 10. Confirmatory tests for reparation of Sodium Carbonate extract i Took about 1 g of the salt,| Labelled the filtrate obtained as added double the quantity of | sodium carbonate extract (S.E) | CO, and about 10 ml of water. Boiled for some time, cooled and filtered. (a) Silver nitrate test | Acidified a portion of S.B A white precipitate formed Cl confirmed. wth HNO. Boiled cooled | which was soluble in NHL Or and added silver nitrate aes =e ¢ |b) Manganese dioxide test Heated 2 smal | ete i ea] pm ylow ge hving| cone mice dioxide and pastumed starch iodide paps | 11. on nae with) Noammonia gas evolved. NH,’ absent. = : 2. ee : Original Shook pinch ofthe sale with Solution obtained Labeleditas Orga 9 eos) — (oe| —“geperiment Observations Inference apart of the OS. added 1-2 = lsof dilute hydrochloric acid, ,. qnrough @ part of the above * solution, passed H,S gas, et 3 Tp the remaining solution, “ dded a pinch of solid ammonium chloride, Boiled the solution, cooled it and added excess of ammonium hydroxide solution . Through a part of this solution, passed H,S gas. . To the remaining ammonical solution added ammonium carbonate solution. . Confirmatory test for Barium Filtered the above white ppt. Dissolved the ppt. in hot dilute acetic acid. (a) Pot. chromate test. To one Part of the above solution, added a few drops of pot. chromate solution. (b) Flame test. Performed flame test with the salt. No ppt. formed. No ppt. formed. No ppt. formed. No ppt. formed. White ppt. formed. Yellow ppt. Persistent grassy green flame on prolonged heating. Group I absent. (Pb?* abse Group II absent (Pb?*, Cu?* absent) Group III absent. (Fe*, Al? absent) Group IV absent. (Zn?", Mn*, Ni?-, Co?*, abse Group V present. (Ca, Ba?>, Sr?* may be prese Ba® confirmed. Ba? confirmed. tsuut Acid radical: Cl Basic radical: Ba”.