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MH-CET | Chemistry

Name: _______________ Chemistry 11th CC Test 1 Date:

Date08/03/2024
: 11.03.24
Roll No: __________ Answer Key
Time: 45 Minutes Marks: 50

1. Volume occupied by 1 molecule of water is (XI-7 Adsorption and Colloids => (Topic Name) =>

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......... . Adsorption isotherm)
A. 9.0× 10−23cm3 B. 3× 10 −23 cm3
Solution (Explanation).
C. 6.023× 10 −23 cm3 D. 5.5× 10 −23 cm3 Extent of adsorption surface are of adsorbent.

EM
(XI-1 Some Basic Concepts of Chemistry => (Topic Larger the surface area of the adsorbent, greater is
Name) => Mole concept and molar mass) the extent of adsorption.

Solution (Explanation). 4. Which of the following reactions is a redox

Since density of water is 1 g reaction?
Volume of 1 mole of 18 g of A.
B.
AD
C.
2. In bleaching powder ( ), the oxidation D.
state / states of Cl is / are ......... .
(XI-4 Redox Reactions => (Topic Name) =>
A. 1− B. 0 Oxidation number)
C. 1− , 1+ D. 1− , 0
Solution (Explanation).
(XI-4 Redox Reactions => (Topic Name) =>
Oxidation number)
AC

Solution (Explanation).

5. The formal charge on hydrogen atom in water

molecule is ......... .

3. Identify the INCORRECT statement from the A. 0 B. − C. 1 D. +

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following.
(XI-3 Chemical Bonding => (Topic Name) =>
A. Increase in B. Increase in Kossel and Lewis approach to chemical bonding)
temperature pressure increases
decrease the the amount of Solution (Explanation).
extent of adsorption till a
adsorption. saturation is
reached.
C. Adsorption may D. Particle size of
be monolayered or the adsorbent
multilayered. will not affect the
amount of 6. Which of the following after bromination gives
adsorption. ?
 A. B. C. D.
10. The IUPAC name of is
(XI-9 Hydrocarbons => (Topic Name) => Alkanes)
......... .
Solution (Explanation).
A. 2-fluoro-4-chloro- B. 3-fluoro-5-chloro-
2,4-diethylpentane 3-methyl-5-
ethylhexane
C. 3-chloro-5- D. 3,5-dimethyl-5-
fluoro-3,5- fluoro-3-
dimethylheptane chloroheptane

Y
(XI-8 Basic Principles of Organic Chemistry =>
7. Hydrogenation of vegetable oils to form (Topic Name) => Classification of organic
vegetable ghee in presence of finely divided Ni compounds)
represents

EM
A. homogeneous Solution (Explanation).
B. heterogeneous
catalysis catalysis
C. enzyme catalysis D. selective catalysis
(XI-7 Adsorption and Colloids => (Topic Name) =>
Catalysis)
11. Number of monochloroderivatives obtained on
Solution (Explanation). chlorination of 2,2-dimethylbutane in UV light are
As reactant, vegetable oil and nickel catalyst are in ......... .
AD
different phase i.e., liquid and solid respectively, it is A. 5 B. 4 C. 3 D. 2
heterogeneous catalysis.
(XI-9 Hydrocarbons => (Topic Name) => Alkanes)

8. KO2 is used in space and submarine as it ......... . Solution (Explanation).

A. absorbs CO2 and B. absorbs moisture
increases O2
concentration
AC

C. absorbs CO2 D. produces O3

The number of molecules = n x
(XI-5 Elements of Groups 1 and 2 => (Topic Name)
=> Alkali metals and elements of group 2)
Among the given species, one with smallest number
Solution (Explanation). of moles contains smallest number of molecules. As
0.44 g i.e. 0.01 mole is smallest among the all,
it has smallest number of molecules.
9. Number of possible alkynes with formula C5 H8
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is ......... . 12. If are the amounts of gases NH3 , N2

A. 2 B. 3 C. 4 D. 5 and CO2 adsorbed on an adsorbent of unit mass
then the order of liquification of gases is ......... .
(XI-9 Hydrocarbons => (Topic Name) => Alkynes)
A. B.
Solution (Explanation). C. D.
There are 3 alkynes possible for the molecular
(XI-7 Adsorption and Colloids => (Topic Name) =>
formula .
Factors affecting adsorption of gases on solids)
(a)
(b)
Solution (Explanation).
(c) The gas which can be easily liquified can be easily
adsorbed.
The order of liquefaction of gases is
 hence the order of extent of Electromeric effect observed in double bond system
adsorption will be, . i.e. bond. Aldehydes contain Hence
aldehyde will show an electromeric effect.
13. When slaked lime is passed through excess
CO2 , it forms ......... . 16. The number of lone pairs of electrons in 6.8
mg of ammonia is ......... .
A. CaCO3 B. Ca(HCO3 )2
A. B.
C. Ca2 HCO3 D. CaCl2
C. D.
(XI-5 Elements of Groups 1 and 2 => (Topic Name)
=> Alkali metals and elements of group 2) (XI-1 Some Basic Concepts of Chemistry => (Topic

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Name) => Mole concept and molar mass)
Solution (Explanation).
Solution (Explanation).
Molar mass of ammonia ,

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14. he density of the gas is 1.4 kg m−3 at 35 °C
and 730 torr. Hence the number of molecules per
cm3 of the gas is ......... . There is one lone pair of electrons of each
molecule.
A. 2.28 × 10 19 B. 1.034 × 10 22 the total number of lone pair of electrons
C. 8.69 × 10 21 D. 3.12 × 10 20
AD
(XI-6 States of Matter : Gaseous and Liquid States 17. Resonance structure cannot be shown by .........
=> (Topic Name) => Gas laws) .

Solution (Explanation). A. dimethyl ether B. nitrate anion

Molar mass of gas is, C. carboxylate anion D. toluene
(XI-8 Basic Principles of Organic Chemistry =>
AC

(Topic Name) => Theoretical basis of organic

reactions)

Solution (Explanation).
Dimethylether has no conjugated system of bonds.

18. Which of the following is INCORRECT?

A.
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B.
15. Which of the following exhibit electrometric
effect?
A. Alkanes B. Aldehydes C.
C. Alkylhalides D. Alkylamines
(XI-8 Basic Principles of Organic Chemistry =>
(Topic Name) => Theoretical basis of organic
reactions) D.

Solution (Explanation).
(XI-8 Basic Principles of Organic Chemistry => C. D.
(Topic Name) => Classification of organic
compounds)
(XI-9 Hydrocarbons => (Topic Name) => Alkynes)
Solution (Explanation).
Solution (Explanation).

Addition takes place according to Markovnikov‘s

rule.

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19. Equal volumes of two nonreacting gases with
pressures 200 mmHg and 600 mmHg are placed in
separate containers. If two vessels are connected 22. IUPAC name of the compound is

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together at constant temperature, the total pressure
......... .
of the mixture is ......... .
A. 300 mmHg B. 500 mmHg A. 1-fluoro-4- B. 4-fluoro-1-methyl-
methyl-2- 3-nitrobenzene
C. 400 mmHg D. 600 mmHg nitrobenzene
(XI-6 States of Matter : Gaseous and Liquid States C. 4-methyl-1-fluoro- D. 2-fluoro-5-methyl-
=> (Topic Name) => Gas laws) 2-nitrobenzene 1-nitrobenzene
(XI-8 Basic Principles of Organic Chemistry =>
Solution (Explanation). (Topic Name) => Classification of organic
AD
At constant temperature, the volumes are doubled. compounds)
So the pressures will be halved. In the mixtures, the
partial pressures will be 100 mm and 300 mm. Solution (Explanation).
Total pressure

20. What is the IUPAC name of the following

compound?
AC

23. Which is NOT an example of macro molecular

colloid?
A. 1,1-Dimethyl-2- B. 3,3-Dimethyl-1-
A. Polythene B. Soap
cyclohexenol cyclohexen-6-ol
C. 6,6-Dimethyl-1- D. 4,4-Dimethyl-2- C. Nylon D. Proteins
cyclohexen-3-ol cyclohexenol (XI-7 Adsorption and Colloids => (Topic Name) =>
(XI-8 Basic Principles of Organic Chemistry => Colloids)
(Topic Name) => Classification of organic
compounds) Solution (Explanation).
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Soap is not macromolecular colloid but it is

Solution (Explanation). associated colloid. Polythene, Nylon, Proteins are
macromolecular colloids.

24. If x is amount of adsorbate and m is amount of

adsorbent, which of the following relations is not
related to adsorption process?
21. What is the major product expected from the
A. = f (P) at B. = f (T) at
following reaction?
CH3 – C ≡ C – H constant T constant P

B. C. P = f (T) at D. =PT
A.
constant
(XI-7 Adsorption and Colloids => (Topic Name) =>
Adsorption isotherm)

Solution (Explanation).
For adsorption,

25. In covalent bond, a difference of 1.7 in 28. Hexane on boiling with oleum gives ......... .
electronegativities of the combining atoms produces
A. hexene B. hexanesulphonic
an ionic character of about ......... .
acid

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A. 50% B. 30% C. 90% D. 70% C. SO3 D. hexylsulphate
(XI-3 Chemical Bonding => (Topic Name) => (XI-9 Hydrocarbons => (Topic Name) => Alkanes)
Covalent character of ionic bond)
Solution (Explanation).

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Solution (Explanation). Sulphonation of alkanes generally takes place only
50% if there are more than six carbon atoms in their
26. An atom of the element ‘X’ has the mass chain. Sulphonation is usually carried out in
of 6.65 × 10 −23 g. The element ‘X’ is ......... . presence of oleum.

A. calcium B. potassium
C. copper D. gold
(XI-1 Some Basic Concepts of Chemistry => (Topic
AD
Name) => Mole concept and molar mass)
29. Ferric chloride has more covalent character
than ferrous chloride since ......... .
Solution (Explanation).
Mass of one atom of element ‘X’ A. Fe in ferric B. Fe3+ in ferric
chloride has chloride has
molar mass of an element is the mass of 1 mole of higher greater size than
an element in gram and it is equal to its atomic mass charge(Fe3+) Fe2+ in ferrous
in u. chloride
AC

the mass of 1 mole of element ‘X’

C. Fe2+ and Fe3+ D. Fe3+ has greater
have same size charge and
This is atomic mass of Ca i.e. 40 u smaller size than
An element ‘X’ is calcium. Fe2+
(XI-3 Chemical Bonding => (Topic Name) =>
27. 2-Methylbut-2-ene on oxidation with hot Parameters of covalent bond)
KMnO4 solution produces ......... .
A. CH3 COOH Solution (Explanation).
Since ion has more charge and less size than
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B. ion, has more polarizing power than .

Hence ferric chloride has more covalent
C. nature than ferrous chloride .

D. 30. Which among the following statements is NOT

true about homologous series of organic
(XI-9 Hydrocarbons => (Topic Name) => Alkenes) compound?
A. All members have B. All members of
Solution (Explanation).
similar chemical series have same
properties. type of carbon
skeleton.
 C. All members of D. Each member of
series are a series differs by Solution (Explanation).
represented by two carbon atoms Total number of triatomic molecules
same general and two H atoms
formula. from its
neighbouring
member.
34. The oxidation state of chromium in the final
(XI-8 Basic Principles of Organic Chemistry =>
product formed by the reaction between KI and
(Topic Name) => Introduction)
acidified potassium dichromate solution is ......... .

Y
Solution (Explanation). A. + 4 B. + 6 C. + 2 D. + 3
In homologous series of organic compound each
(XI-4 Redox Reactions => (Topic Name) => Redox
member of a series differs by one carbon atom and
reaction and electrode potential)
two H atoms ( ) from its neighbouring

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member.
Solution (Explanation).
In the reaction of acidified with KI,
31. Which of the following molecules has linear chromium is reduced from +6 to + 3 oxidation state.
geometry?
A. BeF2 B. C2 H4 C. SO2 D. ClF3

(XI-3 Chemical Bonding => (Topic Name) =>

Valence bond theory) 35. Chemisorption involving gas-solid system is
usually exothermic except ......... .
AD
Solution (Explanation).
A. adsorption of H2 B. adsorption of H2
BeF2
on Nickel on glass
32. Which among the following oxiacids of
C. adsorption of O2 D. adsorption of CO2
phosphorus shows a tendency of
on Pt on tungsten
disproportionation?
(XI-7 Adsorption and Colloids => (Topic Name) =>
A. Phosphinic acid B. Orthophosphoric
Types of adsorption)
acid
AC

C. Phosphonic acid D. Pyrophosphoric Solution (Explanation).

acid
(XI-4 Redox Reactions => (Topic Name) => Redox
reaction and electrode potential)
Solution (Explanation).
Adsorption of gases on solids generally involves
evolution of heat, i.e., exothermic except adsorption
of on glass which is endothermic. During this
process heat is absorbed due to dissociation of
hydrogen.

36. What is the IUPAC name of the following

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compound?

A. 3-Hydroxy-1- B. 3-
methyl Methylcyclopentan
cyclopentane -3-ol
33. The number of atoms in 0.2 mole of a triatomic
C. 3- D. 3-Methylpentan-
gas is ......... .
Methylcyclopentan 1-ol
A. B. ol
C. D. (XI-8 Basic Principles of Organic Chemistry =>
(XI-1 Some Basic Concepts of Chemistry => (Topic (Topic Name) => Nomenclature of organic
Name) => Mole concept and molar mass) compounds)
 40. The percentage composition in a sample of
Solution (Explanation). is observed as Ca = 40%, C = 12% and O =
48%, if law of definite composition is obeyed, then
the mass of calcium in 10 −2 kg of a sample from
another source must be ......... .
A. 0.8 g B. 1.6 g C. 3.2 g D. 4.0 g
37. The number of sigma (σ) and pi ( ) bonds (XI-1 Some Basic Concepts of Chemistry => (Topic
present in a molecule of bromobenzene are ......... . Name) => Laws of chemical combination)
A. six and three B. thirteen and three

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Solution (Explanation).
C. seven and three D. twelve and three
(XI-8 Basic Principles of Organic Chemistry =>
(Topic Name) => Structural representation of

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organic molecules)

Solution (Explanation).

41. The number of moles of formed by

burning 0.01 mole of phosphorus is ......... .
A. 0.005 B. 0.01
[6 sigma] C – C bond
C. 0.02 D. 0.03
[6 sigma] C – H bond
AD
[3 Pi] bond (XI-1 Some Basic Concepts of Chemistry => (Topic
12 sigma and 3 pi bond Name) => Mole concept and molar mass)

Solution (Explanation).
38. In the titration of NaCl with AgNO3 , using
fluorescein as an indicator, the change at the end
point is ......... .
A. reddish pink to B. pale yellow to
AC

colourless green 42. Total number of electrons in an orbit is given

by ......... .
C. pale yellow to D. white to pale
reddish pink yellow A. 2 n B. 2 n 2 C. n 2 D.
(XI-7 Adsorption and Colloids => (Topic Name) =>
(XI-2 Structure of Atom => (Topic Name) =>
Applications of adsorption)
Quantum mechanical model of an atom)

Solution (Explanation).
Solution (Explanation).
pale yellow to reddish pink
2n2
39. Which of the following shows shiny
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43. Which of the following alkyne on treating with

appearance?
H2 SO4 and HgSO4 gives acetone?
A. Nitrogen B. Carbon
A. B.
C. Iodine D. Sulfur
C. D.
(XI-1 Some Basic Concepts of Chemistry => (Topic
Name) => Introduction) (XI-9 Hydrocarbons => (Topic Name) => Alkynes)

Solution (Explanation). Solution (Explanation).

Iodine shows shiny appearance i.e. lustre whereas
elements nitrogen, carbon, sulfur do not show
lustre.
 A. Ea − E > E − Eb B. Ea − E < E − Eb
44. The hybridization of oxygen in H2 O2 is ......... . C. Ea − E = E − Eb D. none of these
A. sp B. sp 3 C. sp 2 D. sp 3 d (XI-3 Chemical Bonding => (Topic Name) =>
(XI-3 Chemical Bonding => (Topic Name) => Molecular orbital theory)
Valence bond theory)
Solution (Explanation).
Solution (Explanation). Energy of bonding molecular orbital is lowered by
 while energy of antibonding
molecular orbital is raised by  .

Y
According to MOT, is more than 
Each oxygen atom has two bond pairs and two lone
pairs. There are four sp3 hybrid orbitals on each
oxygen atom. 48. What is the oxidation number of carbon in cane
sugar?

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A. − 6 B. + 6 C. + 3 D. Zero
45. In case of alkali metals, the covalent character
decreases in the order ......... . (XI-4 Redox Reactions => (Topic Name) =>
A. MF > MCl > MBr B. MF > MCl > MI > Oxidation number)
> MI MBr
Solution (Explanation).
C. MI > MBr > MCl D. MCl > MI > MBr >
> MF MF
(XI-3 Chemical Bonding => (Topic Name) =>
AD
Parameters of covalent bond)
49. The electron-deficient molecule is ......... .
Solution (Explanation). A. BeCl2 B. BCl3 C. CCl4 D. PCl5
When the cation is same in all halides, the
(XI-3 Chemical Bonding => (Topic Name) =>
polarizability of an anion increases with the
Valence bond theory)
increase in the size of the anion,

Hence polarization and covalent character Solution (Explanation).

The compound which does not contain any lone
AC

decreases as MI > MBr > MCl > MF.

pair of electrons is called electron deficient
compound. Boron electronic configuration (B)= 
46. The metal that cannot be obtained by
, , . The three valence electrons of B are
electrolysis of an aqueous solution of its salt is
used to make bond with Cl in . Therefore it
......... .
does not contain any lone pair of electrons and it is
A. Cr B. Ag C. Ca D. Cu electron deficient.
(XI-5 Elements of Groups 1 and 2 => (Topic Name)
=> Alkali metals and elements of group 2) 50. Hybrid orbital forms ......... .
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A. sigma bond B. pi bond

Solution (Explanation).
Ca being highly electropositive has high reduction C. sigma or pi bond D. ionic bond
potential, hence can’t be reduced to Ca. (XI-3 Chemical Bonding => (Topic Name) =>
Therefore, it can’t be obtained by the electrolysis of Valence bond theory)
aqueous solution of its salt.
Solution (Explanation).
47. If E is the energy of combining atomic orbitals Since hybrid orbital which has one lobe of
of a homoatomic molecule giving bonding and maximum electron density, it can form sigma bond
antibonding molecular orbitals of energies Eb and only.
Ea respectively, then ......... .
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AC
AD
EM
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