Spotlight_Crux (2023-24) Day-1_PPT_Chemistry

Solution

1. Answer (A, B, D)
n. factor of KMnO4 in acidic medium = 5
In faintly basic/neutral medium = 3
2. Answer (A, D)

n.f. for C2O42 or HC2O41 with K2Cr2O7 = 2

n.f. for HC2O41 with HCl = 1 and C2O42 with HCl = 2.

3. Answer (C)
MnO2  NH4  2 SO4  2H2SO4  MnSO4  NH4  2 S2O8  2H2O
n 2 n 2 1
n
2

4. Answer (C)
Let the two metal carbonates be MCO3 and M’CO3. Let M be 13.6% by weight
Weight of sample = 2.5 g
13.6
Weight of metal M   2.5  0.34 g
100
Weight of CO2 evolved = 1.33g
1.33
Moles of CO2 evolved =  0.0302
44

 Weight of CO32 in the sample = 0.0302 × 60 = 1.812 g

2.5  0.34  1.812

 % of M'   100  13.92%
2.5
5. Answer (A, B, C)
H2S + I2  2HI + S
Eq. of H2S = equivalent of I2
 nH2S  2  2.40  0.02

 nH2S  2.40  102 m moles

 % of S in steel sample

2.4  10 3  32
=  100
0.3  100
= 0.256%
6. Answer (A, B, D)
For equimolar mixture of H2SO4 and SO3
x + 80 + x × 98 = 10

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100
 x
178
100
 % labelling = 100   18
178
= 110.11%
For equal mass mixture
MSO3  50 g

50
MSO3   18  11.25
80
 % labelling = 111.25%
Strength of an oleum sample can not be less than 100
7. Answer (65)
Applying PV = nRT for CO
PV 750  20
Moles of CO nCO     8.01  10 4
RT 760  0.0821  300  1000
1 n 1
CO  O2  CO2 , CO   2
2 nO2 1
2

nCO 8.01  104

 
Moles of O2 required nO2   2

2
2KClO3  2KCl + 3O2
As 3 moles of O2 are given by 2 mole of KClO3

8.01  10 4 2 8.01  10 4
 mol of O2 are given by =  mol of KClO3
2 3 2
= 2.66 × 10–4 mol of KClO3
 Weight of KClO3 = 2.66 × 10–4 × 122.5 gm = 3.26 × 10–2 gm

3.26  102
 % of KClO3 in the mixture =  100  65%
0.05
8. Solution
3Pb NO3 2  Cr2  SO 4 3  3PbSO4   2Cr  NO3 3
m moles  initial  45  0.25 25  0.1 0 0
 11.25  2.5  limiting reagent 
m moles  final  3.75 0 7.5 5

Hence, m moles of PbSO4 precipitate = 0.075

Final volume of solution = 70 ml

Pb2   3.75  5.36  102 M

70

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NO3   3.75  2  5  3  22.5  0.32 M Cr 3   2.5  2  5

 7.14  102 M
70 70 70 70
9. Solution
12  WCO2  100
%C 
44  Wsubs tan ce

%C  44  Wsubs tan ce
 WCO2 
12  100
69  44  0.20
=  0.506 g
12  100
2  WH2O  100
%H 
18  Wsubs tance

%H  18  Wsubs tance
 WH2O 
2  100
4.8  18  0.2
=  0.0864 g
2  100
10. Answer (A)  (Q, R); (B)  (S); (C)  (P); (D)  (Q)

(A) Cl   50  3  150  1  3  600  3M

200 200
0.1
(B) Molality =  1000  6.17 m
0.9  18
10
(C) Molality = 60  1000  1.85 m
90
10.95
(D) Molarity of HCl = 36.5  1000  3 M
100
11. Answer (C)
As per Bohr’s postulate
nh
mvr 
2
nh
So, v 
2 mr

1
KE  mv 2
2
2
1  nh 
So, KE  m 
2  2mr 

a 0  n2
Since, r 
z

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So, for 2nd Bohr orbit

a0  22
r  4a0
1

1  2 2 h2 
KE  m 2
2  4 2m2   4a  
0

h2
KE 
32 2ma02
12. Answer (D)
Energy of photon corresponding to second line of Balmer series for Li2+ ion

2 1 1
= 13.6   3  2  2 
2 4 
27
= 13.6 
16
Energy needed to eject electron from n = 2 level in H-atom

 1 1 
= 13.6  12   2  2 
2  
13.6

4
K.E. of ejected electron
9  3 13  6  27  4 
= 13.6    13.6  
16 4  16 

13. Answer (C)

Radial node occurs where probability of finding e– is zero
 2 = 0 or  = 0

 6  6   2  0;   3  3

3  3  3  a0
For maximum distance r 
2 Z
14. Answer (C)

1  1 1  n2  4 
 R 2  2   R 
 2 n   4n2 

4 n2
  2 … (i)
R n 4

n2
Given   k  … (ii)
n2  4
Comparing equation (i) and (ii) we have

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4
K
R
15. Solution

2  10 21
From PV = nRT we know that n 
6.023  1023

2  1021
7.57  103  10 3   8.314  T
6.023  10 23
T = 274.2 K
1/2 1/2
 3RT   274.2 
Urms      3  8.314   103 
 M   28 
= 494.22 m sec–1
UMP
 0.82, UMP  405.26 m sec 1
Urms

PV 100V
16. Z  0.5 that is , V = 0.112 litre
RT 0.0821 273 

 a 
If ‘b’ is negligible then  P  2   V   RT . Now substituting the required values we get
 V 
a
 99.88 or a = 1.253 litre2mol–2 atm
 0.1122
17. Solution

r1 M2 P1
 
r2 M1 P2

n1t 2 M2 P1
 
n2 t1 M1 P2

1 57  Mg  0.8
Or    
38 1  28  1.6

Mg = 252
Thus, compound is XeF6 because it can have only one xenon atom (since for two xenon atom 2 × At. Wt. of
Xe = 2 × 131 = 262, i.e. greater than 252)
18. Solution

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2.8
Number of moles of N2 in vessel (A) at T1   0.1
2.8
12.7
Number of moles of I2 in vessel (A) at T1   0.05
254
T2
Vessel (A) is heated to T2 and the evacuated vessel (B) is heated to . On opening stop cock I2 sublimes
3
in (A) and its vapours condense to solid I2 in (B). Let the number of moles of N2 moved from (A) to (B) at
equilibrium be x.
x
So,  0.1  x  
3
0.3
 x
4
 0.7 g of N2 is present in (A) and 2.1 g of N2 is present in (B).
19. Answer (6)
Let the molecular formula of hydrocarbon be CxHy.
 y y
C x Hy   x   O2  xCO2  H2O
 4 2
 y
Volume reacted 10 ml 10  x    
 4
Since, the remaining gas occupied 70 ml
 Total volume left = 70 = VO2  VCO2

VCO2  20 mL

x=2
Where VO2 = volume of oxygen left and VCO2 = volume of CO2 produced

 VO2  70  20  50 ml

 y
80  10  x    50
 4
y
x 3
4
y
1
4
y=4
20. Answer (B)
KE1 1
KE1 = hv1 – hv0; KE2 = hv2 – hv0 it is given that; 
KE2 K

hv1  hv 0 1 Kv  v 2
 ; Kv1  v 2   v 0 K  1 ; v 0  1
hv 2  hv 0 K K 1



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