Cat 5

Sec: Incoming.Jr.IIT_*CO.
SC Date: 30-08-20
Time: 3HRS Max. Marks: 183
30-08-20_ Incoming.Jr.IIT _*CO SUPER CHAINA_Jee-Adv_CAT-5_SYLLABUS
PHYSICS: PRESENT WEEK (80%): Impulse, 2D collision & Variable mass

systems
PREVIOUS WEEK (20%): Conservation of linear Momentum & 1 D
collisions (Excluding variable mass, impulse and 2D collision)
CUMULATIVE (25%):NLM (Without Friction)
CHEMISTRY: PRESENT WEEK (50%): Liquid Solutions and Colligative
Properties :Raults law and its application, colligative properties,
Abnormal colligative properties & Van't Hoff factor,Abnormal
Colligative properties, Henry's law, Different types of distillation,
Ideal solution and non ideal solutions, Azeotropic mixtures, DG
mixing, Dsmixing.
PREVIOUS WEEK (25%):Ionic Equilibrium-II: Buffer solution &
Buffer capacity, Solubility of sparingly soluble salts and solubility
product, Indicator, Acid base titration curves
CUMULATIVE (25%): 1. Geometrical isomers
2. Fajan's rule & Applications 3. First law of thermodynamic

MATHEMATICS: PRESENT WEEK (50%): Onto, into, one-one, many-one functions,
Range of a function (avoid use of differentiation )
PREVIOUS WEEK (25%):FUNCTIONS : Real valued function of a
real variable & their Domains, Sum, difference, product and
quotient of two functions, Odd / even / periodic functions
CUMULATIVE (25%): STRAIGHT LINE
Narayana IIT Academy 30-08-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-5_Q’P
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 183
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 7) Questions with Single Correct Options +3 -1 7 21
One of More Correct Options Type
Sec – II (Q.N : 8 – 14) +4 -2 7 28
(partial marking scheme) (+1)
Questions with Comprehension Type
Sec – III (Q.N : 15 – 18) +3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 61
CHEMISTRY
Sec – II (Q.N : 26 – 32) +4 -2 7 28
Sec – III (Q.N : 33 – 36) +3 0 4 12
Total 18 61
MATHEMATICS
Sec – II (Q.N : 44 – 50) +4 -2 7 28
Sec – III (Q.N : 51 – 54) +3 0 4 12
Total 18 61
PHYSICS Max. Marks: 61
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
1
1. The coefficient of restitution between a snooker ball and the side cushion is . If the
3
ball hits the cushion and then rebounds at right angles to its original direction, What
are the angles between side cushion and direction of motion of ball before & after the
collision?
A) 45º & 45º respectively B) 15º & 75º respectively
C) 75º & 15º respectively D) 60º & 30º respectively
2. The friction coefficient between the horizontal surface and each of the block shown in
the figure is 0.2. The collision between the blocks is perfectly elastic. Find the
separation between them when they come to rest. (Take g = 10 m/s2 )
A) 5 cm B) 7 cm C) 8 cm D) 4 cm
3. A ball of mass m = 1 kg falling vertically with a velocity 0  2m / s strikes a wedge of

mass M = 2 kg kept on a smooth, horizontal surface as shown in figure. If impulse
between ball and wedge during collision is J. Find the impulse on wedge from ground
during impact.
J J J
A) upwards B) upwards C) J upwards D) upwards
3 2 4
4. Two blocks of equal mass m are connected by an unstretched spring and the system is
kept at rest on a frictionless horizontal surface. A constant force F is applied on one of
the blocks pulling it away from the other as shown in figure. If the extension of the
spring is x0 at time t, find the displacement of the two blocks at this instant.
Ft 2 Ft 2 Ft 2 x0 Ft 2 x0
A)  x0 &  x0 B)  & 
2m 2m 3m 2 3m 2
1  Ft 2  1  Ft 2  1  Ft 2  1  Ft 2 
C)   x0 &   x0  D)   x0 &   x0 
2 m  2 m  2  2m  2  2m 
5. A small block of mass m is placed on top of a smooth hemisphere also of mass m

which is placed on a smooth horizontal surface. If the block begins to slide down due
to a negligible small impulse, it looses contact with the hemisphere when the radial
line through vertical makes an angle  . Then choose the correct equation describing 
A) cos3 ( )  6 cos   4  0 B) cos3 ( )  4 cos   4  0
C) cos3 ( )  6 cos   6  0 D) cos 2 ( )  6 cos   5  0
6. Two large rigid vertical walls A and B are parallel to each other and separated by 10
m. A particle of mass 10 g is projected with an initial velocity of 20 m/s at 450 to the
horizontal from point P on the ground, such that AP = 5 m. The plane of motion of the
particle is vertical and perpendicular to the walls. Assuming that all the collisions are
perfectly elastic, find the total number of collisions suffered by the particle with the
walls before it hits ground. Take g = 10 m/s2.
A) 3 B) 4 C) 5 D) 6
7. To test the manufactured properties of 10N steel balls, each ball is released from rest
as shown and strikes a 450 inclined surface. If the coefficient of restitution is to be e =
0.8, determine the distance s, where the ball must strike the horizontal plane at A. (g =
9.8 m/s2)
A) 1.2 m B) 1.53 m C) 0.8 m D) 0.93 m
SECTION-II
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 7 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of
which ONE or MORE THAN ONE are correct.
Marking scheme: +4 for all correct options, 0 if not attempted and -2 in all wrong cases.
8. In case of rocket propulsion, choose the correct options.
A) Momentum of system always remains constant
B) Newton’s third law is applied
C) If exhaust velocity and rate of burning of mass is kept constant, then acceleration of
rocket will go on increasing
D) Newton’s second law can be applied
9. A ball is projected from the ground at some angle with horizontal. Coefficient of
restitution between the ball and the ground is e. Let a, b and c be the ratio of times of
flight, horizontal range and maximum height in two successive paths then:
1 1 1 1
A) a  B) b  C) c  D) c 
e e e2 e
10. Three particles A, B and C start moving simultaneously with constant velocities from
three places. The starting places are collinear and that of B is somewhere in between
those of A and C. In the absence of C, particles A and B would have collided t1 time
after they started and in the absence of B, particles A and C would have collided t2
time after they started. What would have happened, if A were not present ?
A) If t2  t1 , particles B and C may or may not collide.
B) If t2  t1 , particles B and C collide in the interval (t1, t2).
C) If t2  t1 , particles B and C must collide at an instant t  t2 .
D) If t2  t1 , particles B and C must collide in the interval [ t1, t2].
11. A uniform rope is tied between a nail A on the wall and a nail B on the ground. The
rope without touching the ground anywhere assumes a curved shape known as “
catenary”. Tangents at the ends A and B of this catenary make angles  and  with
the vertical respectively. Which of the following conclusions can you make?
A) Horizontal component of the tensile force in the rope is uniform.
B) Vertical component of the tensile force increases with height.
C) Angle  can be greater than angle. 
D) Angle  cannot assume a value of 00.
12. Two identical sleeves A and B each of mass m can slide without friction on a fixed
horizontal rod. A load C of mass 2m is suspended from the mid-point of a light
inextensible cord of length l  3 3 m connecting the sleeves A and B. Initially the
sleeves are at a separation l and the load is held motionless. What can you conclude
for subsequent motion after the load is released? Acceleration of free fall is 10 m/s2.
A) Maximum speed of the sleeves is 10 m / s
B) Maximum speed acquired by the load C is 2 5 m / s .
C) The load descends a height 1.5 m to acquire maximum speed.
D) Before the sleeves collide, the net force on the system consisting of the sleeves, the
cord and the load becomes zero once.
13. A small block rests on flat bottom of a deep bowl that is placed on a horizontal floor.
There is no friction between the block and the bowl as well as between the bowl and
the floor. Total mass of the bowl and the block is M. If the bowl is given a horizontal
velocity by a sharp hit, the block rises to a maximum height h sliding on the walls of
the bowl. Which of the following statements are correct?
A) Maximum kinetic energy of the bowl is Mgh.
B) If the bowl is lighter than the block, minimum kinetic energy of the bowl is zero.
C) To predict minimum kinetic energy of the bowl, we must know ratio of the masses.
D) To predict maximum as well as minimum kinetic energy of the bowl, we must

know ratio of the masses.
14. A dumbbell is constructed by fixing small identical balls at the ends of a light rod of
length l . The dumbbell stands vertically in the corner formed by a frictionless wall and
frictionless floor. After the bottom end is slightly pushed towards the right, the
dumbbell begins to slide. Value of which of the following quantities vanish, when the
upper ball is leaving the wall.
A) Tensile force in the rod
B) Acceleration of the lower ball
C) Acceleration of the upper ball
D) Normal reaction from floor on the lower ball

SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph For Questions 15 and 16:
A bomb of mass ‘5m’ at rest explodes into three parts of masses 2m, 2m and m. After
explosion, the equal parts move at right angles with speed  each.
15. Find the speed of the third part.
A) 2  B) 3 2  C) 2 2  D) 3
16. Find the Energy released in the explosion.
A) 3m 2 B) 6m 2 C) 5m 2 D) 4m 2

A constant force F is applied on a trolley of initial mass m0 kept over a smooth surface.
Sand is poured gently over the trolley at a constant rate of (  ) kg/s. (Initially the trolley
is at rest)
17. Find the acceleration of the trolley as a function of time (  is instantaneous speed)
F   F   F   F  
A) B) C) D)
m0   t m  (t )
2
0
2
m0  t m0   t
18. What is the velocity of the trolley as a function of time?
Ft Ft Ft Ft  m0 
A) B) C) D) ln  
m0   t m0   t m0  2  t m0   t 
CHEMISTRY Max. Marks: 61
SECTION – I
19. Consider the following statements and select the correct option
(I) The concentration of Fe3 will increase in a solution of Fe  OH 3 when H 

 
decrease (Given K sp of Fe  OH 3 is 4  10 18 at 298 K).
(II)In a mixture of NH4Cl and NH4OH in water, when a further amount of NH4Cl is
added, the pH of mixture will decrease.
(III) an aqueous solution of NH4I and HCO2K will be basic and acidic respectively.
A)only (I) is correct B)only (II) is correct
C)only (III) is correct D)(II) and (III) are correct
2 2
20. 2.5 ml of M weak monoacidic base ( Kb  1012 ) is titrated with M HCl in water.
5 15
The concentration of H  at equivalence point is :

 K w  1  1014 , all data given at 250 C 
A) 3.7  10 13 M B) 3.2  107 M
C) 3.2  102 M D) 2.7  102 M
21. A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of 290 mm at
300K. The vapour pressure of propyl alcohol is 200 mm. If the mole fraction of ethyl
alcohol is 0.6, its vapour pressure ( in mm) at the same temperature will be
A) 360 B) 350 C) 300 D) 700
22. Two liquids A and B are mixed at temperature T in a certain ratio to form an ideal
solution. It is found that the partial pressure of A, i.e., pA is equal to pB . What is the
total pressure of the liquid mixture in terms of PA0 and PB0 ? ( PA 0 & PB0 are vapour
pressure of liquid A & B in their pure state)
PA0 PB0 2PA0 PB0 2PA0 2PB0

A) B) C) D)
PA0 +PB0 PA0 +PB0 PA0 +PB0 PA0 +PB0
23. If 0.1M H 2SO4 aq  shows a freezing point 0.3906O C , then, what is the Ka 2 for
H 2SO 4 (assume molarity & molality of solution are same and first dissociation is 100%
K f of H 2 O  1.86K kg.mol 1.)
A) 0.122 B) 0.0122
C) 1.11103 D) 1.57  10 4
24. Out of following which one has maximum ionic character -
A)NaCl B)KCl C)CaCl2 D)MgCl2
25. When a gas is subjected to adiabatic expansion it gets cooled due to -
A)Loss in heat
B) Increase in internal energy
C)Due to repulsion between molecule
D) Energy spent in doing work
SECTION-II
26. 20ml of 0.1M HCN is titrated with 0.1M NaOH. The following curve is obtained for
this titration at 25°C.
pH 7
C
x
3.0
10 ml
Volume of base added
Which of the following are correct statements ?
A) The K a of HCN is about 10 5 B) The value of x is 5
C) At point ‘C’ [HCN] : [CN-] is 10 2 D) At point ‘C’ [HCN] = 0

27. The vapour pressure of two pure liquids A and B which form an ideal solution are 500
and 800 torr respectively at 300 K. A liquid solution of A and B for which the mole
fraction of A is 0.60 is contained in a cylinder closed by a piston on which the
pressure can be varied. The solution is slowly vaporized at 300 K by decreasing the
applied pressure. For the composition of vapour YA and YB  when first bubble formed
& for the composition of last droplet  X A & X B  of liquid remaining in equilibrium
with vapour, which are correct ?
A) yA  0.64; yB  0.36 B) y A  0.48; yB  0.52
C) xA  0.74; xB  0.26 D) xA  0.26; xB  0.74
28. The composition of vapour over a binary ideal solution is determined by the
composition of the liquid. If XA and YA are the mole fractions of ‘A’ in the liquid and
vapour respectively, then at the value where YA  XA is maximum. (Take PA0 & PB0 as
vapour pressures of pure A and B)
PA0 PB0  PB0

A) X A is B) Total pressure is PA0 PB0
PA0  PB0
 
2
PA0  PB0
C) X A is D) Total pressure is PA0 PB0
P  P 
2
0 0
A B
29. Two beakers À` & `B` containing 20 gram CaCl2 in 100 gram water and 20 gram
NaCl in 100 gram water respectively are placed side by side and covered by a jar at
298K. The jar is evacuated, after some time when equilibrium is reached, which
among the following statement is/are correct at 298K?
A) CaCl2 solution will have lesser vapour pressure than NaCl solution before
equilibrium
B) mass of water in beaker A is less than the mass of water in beaker B at

equilibrium
C) mole fraction of NaCl is less than mole fraction of CaCl2 at equilibrium
D) both the solution will have same osmotic pressure at equilibrium.

30. For which of the following pairs of compounds are the CORRECT notation given
A)
B)
C)
D)
31. When heat is supplied to an ideal gas in an isothermal process, which of the following
statements are incorrect -
A)Gas will do positive work
B) Gas will do negative work
C)Kinetic energy of gas will increase
D) Gas will not obey the law of conservation of energy
32. Which of the following compounds do not exhibit geometrical isomerism ?

C6H5
A) C6H5  N  N  C6H5 B) C NOH
C6H5
CH3
CH3
C) D) C CH2
CH3
CH3
SECTION – III
(PARAGRAPH TYPE)
Properties such as boiling point, freezing point and vapour pressure of a pure
solvent change when solute molecules are added to get homogeneous solution. These
are called colligative properties. Applications of colligative properties are very useful
in day-today life. One of its examples is the use of ethylene glycol and water mixture
as anti-freezing liquid in the radiator of automobiles.
A solution M is prepared by mixing ethanol and water. The mole fraction of ethanol in
the mixture is 0.8.
Given: Freezing point depression constant of water  K water

f   1.86 K kg mol 1
Freezing point depression constant of  K ethanol
f   2.0 K kg mol 1
Boiling point elevation constant of water  K bwater   0.52 K kg mol 1
Boiling point elevation constant of ethanol  K bethanol   1.2 K kg mol 1
Standard freezing point of water = 273 K
Standard freezing point of ethanol = 155.7 K
Standard boiling point of water = 373 K
Standard boiling point of ethanol = 351.5 K
Vapour pressure of pure water = 32.8 mm Hg
Vapour pressure of pure ethanol = 40 mm Hg
Molecular weight of water  18 g mol 1
Molecular weight of ethanol  46 g mol 1 = 46 g mol−1
In answering the following questions, consider the solutions to be ideal dilute

solutions and solutes to be non-volatile and nondissociative
33. The freezing point of the solution M is
A) 155.2K B) 140.6K C) 152.6K D) 144.8K
34. The vapour pressure of the solution M is
A) 36.3 mm Hg B) 32.0 mm Hg C) 30 mm Hg D) 28 mm Hg

Two buffer systems can be prepared from a weak dibasic acid and its salts. The first
consists of free acid H2A and its conjugate base NaHA, and the second makes use of
the acid NaHA and its conjugate, Na2A. It is permissible to introduce the simplifying
assumption that only one of the equilibria is important in determining the hydrogen
ion concentration of the solution.
For a buffer solution prepared from NaHA and Na2A, the second dissociation will
ordinarily predominate and the equilibrium
HA +  H2A + OH ; is disregarded

H2O 
35. The hydrogen ion concentration for a buffer solution that is 2M in H3PO4 and 1.5 M in
KH2PO4. K a = 7.11  10-3; K a = 6.34  10-8; K a = 4.5  10-13

1 2 3
A) 9.48  10-3M B) 6.48  10-3 M
C) 4.5  10-3 M D) 5.4  10-3 M
36. The concentration of HPO24 in the above solution is
A) 9.48  10-3 B) 6.48  10-9
C) 6.34  10-8 D) 1.00  10-5

MATHEMATICS Max. Marks: 61
SECTION – I
 x 2  1, x 1
37. Consider the function f  x    . Let m be the number of integral
  nx, 1  x  e
solutions of the equation f  x   f  x  and n be the number of integers in the range
of g  x   2  f   x  then
A) m + n = 4 B) m–n = 2 C) m = 2n D) mn = 12
38. Let f : R  [1, ) be defined as f  x   log10  

3x 2  4x  k  1  10 . If f  x  is an onto
function, then number of possible rational values of k is
A) 0 B) 1 C) 2 D) more than 2
39. Consider Triangle ABC lying in xy plane having vertices B(12, 19), C(23, 20) and
area equal to 70 sq. units. If coordinates of vertex A are (a, b) and slope of the line
containing the median to side BC is (–5), then the least possible value of (a + b) is
A) 47 B) 27 C) 17 D) 7
The sum of all elements in the range of function f  x     r  sin x  x  0,  ,n  N
n
40.
   r
r 1
 denotes greatest integer function  is :

A) n 2  n  1 B) n 2  n C) n 2  n  1 D) n 2  n  1
41. A variable line L = 0 passing through origin O, meets the lines L1 : x  2y  3  0 and
L 2 : x  2y  4  0 at points A and B respectively. A variable point P is taken on L = 0
1 1 1
such that 2
 2
 , Then locus of P is
OP OA OB2
A) 25  2y  x   144 B) 25  2y  x   144
2 2
C) 144  2y  x   25 D) 144  2y  x   25
2 2
42. Let k be the maximum value of the function defined by f  x   min  e x , 2  e 2  x,8  . If
x  x   k 
 0, then number of non negative integral values of x is
x 2   k  x  12
[Note: [k] denotes greatest integer function less than or equal to k]

 x  1   k  1 where D and R denote the

2
43. Let f : D  R be defined as: f  x  

 x  2    3k  4 
2
domain of f and the set of all real numbers respectively. If f is a surjective mapping,
then number of integers in the range of k is :
SECTION-II
44.  
Let O(0, 0), A(6, 0) and B 3, 3 be the vertices of OAB . Let R be the region
consisting of all those points P lying inside OAB which satisfy the inequality
d  P,OA   minimum  d  P,OB  ,d  P,AB   , where d  P,OA  ,d  P,OB  and d  P,AB 
represents the distances of P from the sides OA, OB and AB respectively, then
6 3
A) Region R is a triangle, where sum of ordinates of vertices is
64 3
3 3
B) Region R is a triangle, where sum of ordinates of vertices is
64 3

C) area of region R is 9 2  3 
D) area of region R is 3 2  3 
 4x 
45. Let f  x     sgn  x 2  x  1 , then
 
[Note: [k] denotes greatest integer function less than or equal to k and sgn(x)
represents the signum function of x]
A) Range of f(x) contains atleast one integer but not more than seven and no irrational
value in [–2, 2]
B) f(x) is many one function in [–2, 2]
C) f(x) is not a periodic function in [–2, 2]
D) f(x) is neither even nor odd function in [–2, 2]

46. Let the domain of f(x) is (0, 1). If the domain of y  f  e x   f  ln x  is D, then D is a
subset of
 1  1
A)  1,   B)  2e,0  C)  e 2 ,  2  D)  e,e 
 e  e 
Consider the function f  x   e  [Note: 

x
47. . represents the fractional part function]
A) Number of integers in the range of the function is 2
B) Number of solutions of f(x) = e–x is 2
C) f(x) is many one function
D) Let g  x   e  x then number of solution of f  x   g  x  is 1
 
Let f  x    x  log 2020  2020  x r  . Identify the correct statement(s). [Note: {y} and
10
48.
r 1
 
[y] denotes the fractional part function and greatest integer function respectively.]
A) f(e) = 10e – 20
B) f     1
C) the number of solutions of the equation f(x) = x is 10
D) the number of solutions of the equation f(x) = 2x is 5
49. Let f : R  R and f  x  

x 4
 1 x 2  x   x 4  2
, then f(x) is
x2  x  1
A) one-one function B) many-one function
C) onto function D) into function
50. Let f(x) be a monic polynomial (leading coefficient =1) of degree 5, such that
f  k   6  k  k  1,2,3,4,5 Then f(6) is less than or equal to:
A) 50 B) 100 C) 150 D) 200

SECTION – III
(PARAGRAPH TYPE)
Consider the function f  x   x 2  2x  1  x  R.
51. Let g(x) = f(x) +3x–1, then the range of y  g  x  does not contain
A) –4 B) –2 C) 0 D) 2
52. Which of the following is incorrect?
A) equation f  x   k has 4 distinct real roots, if k   2, 1
B) equation f  x   k has 3 distinct real roots, if k  1
C) equation f  x   k has 2 distinct real roots, if k   1,  
D) equation f  x   k has no real solution, if k   , 2 

Consider square OACB, where O is origin. A line passing through vertex A intersects
the diagonal OC at D internally, side OB at E internally and side CB at F externally.
Given that length of AD is 5 units and D divides AE in ratio 4:3 internally, Now
answer the following:
53. The area of triangle OAF is
A) 35/2 B) 25 C) 49/2 D) 26
54. Let O be the reflection of O along AD. Then length of circumference of circum-circle
of AOE is:
7 35 49
A) 7 B)  C)  D) 
4 4 4
Sec:Incoming.Jr.IIT _*COSC CAT-5 Date: 30-08-20
Time: 3HRS 2017-P2 Max.Marks:183
KEY SHEET
PHYSICS
1 D 2 A 3 B 4 D 5 A
6 B 7 D 8 BCD 9 ABC 10 AC
11 ABD 12 BCD 13 ABC 14 AB 15 C
16 B 17 A 18 B
CHEMISTRY
19 B 20 C 21 B 22 B 23 B
24 B 25 D 26 ABC 27 BC 28 AD
29 BD 30 ABC 31 ACD 32 BD 33 D
34 B 35 A 36 D
MATHEMATICS
37 D 38 B 39 B 40 D 41 B
42 C 43 A 44 AC 45 ABCD 46 BCD
47 ABCD 48 AB 49 BD 50 CD 51 A
52 C 53 C 54 C
Narayana IIT Academy 30-08-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-5_Key & Sol’s
SOLUTIONS
PHYSICS
1.
2.
3.
4.
5.
6.
7.
8. Conceptual
9.
10. Conceptual
11.
12.
13.
14. Conceptual
15.
16.
17.
18.
CHEMISTRY
19. Solution – B
Solubility of Fe  OH 3 decreases with increase in concentration of OH   or
decrease in concentration of  H  
Addition of further amount of NH 4Cl will increase the concentration of NH 4
and thus the ionization of NH 4OH is suppressed. This lowers the OH  
concentration and thus pOH increases or pH decrease
In NH 4 I solution, NH 4 ion hydrolyses giving H 3O  , thus making the solution
acidic while in HCO2 K solution, HCO2 ion hydrolyses to give OH  , thus
solution is basic in nature.
20. Solution – C
2 2
BOH  HCl  BCl  H 2O 2.5    v2  v2  7.5ml
5 15
TOTAL VOLUME = 7.5+2.5=10 ML
CONCENTRATION OF SALT IN THE MIXTURE
M 1V1 ( Base)  M 1V2 ( Base)
2
 2.5  M 2  10
5
M 2  0.1
1
PH   PKw  PKb  log c 
2
1
= 14  12  (1)   1.5
2
 H   0.032M

21. Solution – B
ACCORDING TO RAOULT’S LAW
P  p A  pB  p A0 x A  pB0 xB
OR 290  p A0   0.6   200  1  0.6 
OR 290   0.6   p A0  0.4  200
OR p A0  350mm
22. Solution – B
PA = P B
XA . PA0 = XB. PB0
X A PB0

X B PA0
XA PB0
1  1 0
XB PA
1 P0  P0
 A 0 B
XB PA
PA0
XB =
PA0  PB0
PB0
Similarly, X A 
PA0  PB0
2 PA0 .PB0
PT = PA0 .X A  PB0 .X B 
PA0 .PB0
23. Solution – B
Tf  i K f m; i  2.1
H 2SO 4  H   HSO 4
O C C
HSO 4  H   SO 42 
C 1    C C
 H    C  C ; SO 24   C
equil equil
 HSO 4   C 1   
equil
C 1     C  C  C C 1     C
i  2.1 ; Ka 2   0.0122
C C 1   
24. Sol.[B] Due to larger size of Potassium it has least degree of polarization so it has maximum
ionic character.
25. Sol.[D] U = q + w (Expansion)
q = 0 in adiabatic process
U = w = -ve
Expansion work is –ve as Energy spent in doing work 
26. Solution – ABC
For weakacid
 H    K a  C
103  K a  0.1
K a  105 M.
 After 50% neutralization (addition of 1 meq base to 2 meq acid) a buffer
of a maximum
Capacity is formed.
 pH = pKa = 5
 At equivalent point KCN in formed which undergoes anionic hydrolysis to give
basic solution.
 Hance at pH = 7 the solution is buffer.
 7  5  log
 HCN 
CN  

 HCN   102
CN  
27. Solution – BC
Ptotal  0.6  500  0.4  800  300  320  620 torr

When 1st bubble is formed X A  0.6 X B  0.4
X A PAo 0.6  500

 Bubble composition : YA  
Ptotal 620
When last droplet vapourises : YA  0.6; YB  0.4
X A .500
0.6   X A  0.74
 Droplet composition : 620
 X B  0.26
28. Solution – AD
x A PA0
yA  by subtracting x A from both the sides

PB0  PA0  PB0 x A 
x A PA0
yA  x A   xA

PB0  PA0  PB0 x A 
Differentiating above expression w.r.t x A
d  yA  x A 

PA0

x A PA0 PA0  PB0  1

dx A 
PB0  PA0  PB0  
 PB0  PA0  PB0 x A 
 
2

The value of xA at which y A  x A has a maximum value can be obtained by
setting the above differential equation to zero.
PA0 PB0  PB0
 xA 
PA0  PB0
So the pressure for the above xA value = PA0 PB0
29. Solution – BD
Since moles of CaCl2 (0.54) is less then moles of NaCl (0.68) before
equilibrium, so Solution of CaCl2 will have higher vapour pressure then NaCl
solution.
Water will transfer from beaker À` CaCl2 solution to beaker `B` NaCl solution
so beaker À will have lesser mass of water than beaker `B`
30. Solution – ABC
Option D is not showing geometrical isomerism
31. Sol.[ACD] In isothermal process
q = –w
q is +ve
so, gas will do negative work.  only B is correct.
32. Solution – BD
(A)
C6H5 C6H5
& C6H5
N N
N N
C6H5
(C)
H
CH3
CH3
H & CH3
H
CH3 H
33. Key:(D)
Tt  K f  m
= 10.87K
Freezing point of solution M is 155.7 – 10.87 = 144.83K
34. Key:(B)
P = 0.8*40 = 32mm of Hg
35,36
We assume that the dissociation of H 2 PO 4 is negligible, that is  HPO42  and
 PO34  <<  H 2 PO4  and H3PO4]. Then,
[H3PO4]  CH PO  2.00 M
3 4
[H2PO4-]  CKH PO  1.50 M

2 4
3
7.11  10  2.00 7.11  10 3  2.00
 H3O  

 9.48  10 M  H3O  
3 
 9.48  10 3 M
1.50 1.50
We now use the equilibrium constant for Ka2 to show that [HPO42-] can be
neglected:
 H 3O    HPO24  9.48  10 3  HPO 24 
  K a2  6.34  10 8
 H 2 PO 4 

1.50
 HPO2-4  = 1.00  10-5 M
and our assumption is valid. Note that  PO43  is even smaller than  HPO42 
MATHS
37. m = 4, n = 3
38. 3x 2  4x  k  1  0  x  R
  0  16  4  3   k  1
1
k
3
39. A may be (20, 7) or (15, 32)
 x  x  x
40. S  1  sin    2  sin   ......   n  sin 
 1  2  n
n  n  1  x   x   x
S  sin   sin   .........  sin 
2  1  2  n
Where x   0, 
 n  n  1 n  n  1 
S    1, 
 2 2 
41. Let p  r  ;A  r1  ;B  r2 
1 1 1  C  2S  C  2S
2 2
 2 2 2 
r r1 r2 9 16
 25  x  2y   144
2
x  x  7
42. K  7  0
x 2  7x  12
43. K   0,1
44.
O A
 4x 
45. f x   ; x   2,2
 
4x  8 8  4x
  ,     2,54,2.54
   
 4x 
    3, 2, 1,0,1,2
46. Domain is x   e, 1
47. Conceptual.
48. f  x   10x  10  x   x 
49. f
x 4
 1 x 2  x    x 4  1  1
 x4  1 
1
x  x 1
2
x  x 1
2
 f  0  Into function and f is many-one function.

50. f  x    x  1 x  2  x  3 x  4  x  5    6  x 
f  6   5  4  3  2  1  120
51,52. g  x   x 2  x  2   x  2  x  1
g(x): & f(1×1) is
–2 1 –1
–2
53-54.
B(0,a) C(a,a)
O(0,0) A(a,0)
 7 
Upon solving A  7,0  ;D  3,3 ;E  0,21/ 4  ;F  ,7 
 2 
1 49
OAF   7  7 
2 2

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Sec: Incoming.Jr.IIT_*CO.

30-08-20_ Incoming.Jr.IIT _*CO SUPER CHAINA_Jee-Adv_CAT-5_SYLLABUS

PHYSICS: PRESENT WEEK (80%): Impulse, 2D collision & Variable mass

2. Fajan's rule & Applications 3. First law of thermodynamic

A) 45º & 45º respectively B) 15º & 75º respectively

C) 75º & 15º respectively D) 60º & 30º respectively

3. A ball of mass m = 1 kg falling vertically with a velocity 0  2m / s strikes a wedge of

5. A small block of mass m is placed on top of a smooth hemisphere also of mass m

A) cos3 ( )  6 cos   4  0 B) cos3 ( )  4 cos   4  0

C) cos3 ( )  6 cos   6  0 D) cos 2 ( )  6 cos   5  0

A) 1.2 m B) 1.53 m C) 0.8 m D) 0.93 m

A) Momentum of system always remains constant

B) Newton’s third law is applied

D) Newton’s second law can be applied

C) If t2  t1 , particles B and C must collide at an instant t  t2 .

D) If t2  t1 , particles B and C must collide in the interval [ t1, t2].

A) Horizontal component of the tensile force in the rope is uniform.

B) Vertical component of the tensile force increases with height.

C) Angle  can be greater than angle. 

D) Angle  cannot assume a value of 00.

B) Maximum speed acquired by the load C is 2 5 m / s .

C) The load descends a height 1.5 m to acquire maximum speed.

A) Maximum kinetic energy of the bowl is Mgh.

D) To predict maximum as well as minimum kinetic energy of the bowl, we must

A) Tensile force in the rod

B) Acceleration of the lower ball

C) Acceleration of the upper ball

D) Normal reaction from floor on the lower ball

15. Find the speed of the third part.

16. Find the Energy released in the explosion.

A) 3m 2 B) 6m 2 C) 5m 2 D) 4m 2

Paragraph For Questions 17 and 18:

18. What is the velocity of the trolley as a function of time?

(I) The concentration of Fe3 will increase in a solution of Fe  OH 3 when H 

decrease (Given K sp of Fe  OH 3 is 4  10 18 at 298 K).

A)only (I) is correct B)only (II) is correct

C)only (III) is correct D)(II) and (III) are correct

The concentration of H  at equivalence point is :

A) 3.7  10 13 M B) 3.2  107 M

C) 3.2  102 M D) 2.7  102 M

A) 360 B) 350 C) 300 D) 700

PA0 PB0 2PA0 PB0 2PA0 2PB0

24. Out of following which one has maximum ionic character -

A)NaCl B)KCl C)CaCl2 D)MgCl2

25. When a gas is subjected to adiabatic expansion it gets cooled due to -

B) Increase in internal energy

C)Due to repulsion between molecule

D) Energy spent in doing work

Which of the following are correct statements ?

A) The K a of HCN is about 10 5 B) The value of x is 5

C) At point ‘C’ [HCN] : [CN-] is 10 2 D) At point ‘C’ [HCN] = 0

A) yA  0.64; yB  0.36 B) y A  0.48; yB  0.52

C) xA  0.74; xB  0.26 D) xA  0.26; xB  0.74

PA0 PB0  PB0

B) mass of water in beaker A is less than the mass of water in beaker B at

C) mole fraction of NaCl is less than mole fraction of CaCl2 at equilibrium

D) both the solution will have same osmotic pressure at equilibrium.

32. Which of the following compounds do not exhibit geometrical isomerism ?