nget -aldeer

AA'SPTipet hy 3ersi Hytin(on innent spsMia t

Preatton oo caibenes CHa
While we Prepvuing the canbenes 2tihes srglet Castbene ox Teipet caotene
tomed 1 0324
The Taiplet carbene Boemed en peclal pepazation tfne
J6 the Photche mleal Elshey pbtoochemieal Sensltisahie
used innent gas_ cAsecl tnd the time ont tiple te' conbene
ormef.
Dthet wise ader poepanariun sed to mahe sigler Canben
Sirglet:cH
CH2 Na hY h
CHa=NEN CHta -NN
Rea
-) 'zuberm?
hrCH2 Prekien)

Sensiisah
ntemedi
) Fom a- aze ketone i 2.
ht
Smembt
cayeoowa singlet
hy
Reactyi
preortiy

groupT>By>e
Substi thunt Len
K-oH
CtHzclz Dfchloro Casbene
k-oH
CHlaI R-c-cuN,
Hc-cl ccl2
Sauiy sliminase )

halogens ane best aing teavtng groue tan othoo

elaydon
el

CHde(ome) ome 0me

Ghoina'e too group

li! memetel rim Sasy to tosnm

 Simmon -Smith. Gu/za
5- Zimmenmen -Smh Eajent

Couyole 9Binglet

bchemical xn !
1. tas canbehe adds to a csc double bond to ve a ycoprane estem
The singlet prorut
canbne
a <treo specofe poclect .uhere as Trilet casbcha
will e a mixtune o the produet C=c
eHcla lome ) d
(C-cl
Ome
Ome

siglet
Srglet Canbene stees spehi product
CH cla (ome)
HOH
ca, oms ome
Singlet cHs

cis
-ome
Gyare ets
CHathlhv
)

ds CHz CHNelholsenstsen +

triplet
back
tabens
se

e) cH>Jlznlu
H
yluct)
OH .
CH2T,/nlu

I4 the Zmmetman Smith Teamtanmnt as

sed the lopry
formatin the Same daecHon ab OH
 Poineple tor canbene -
theoye It wi|) eact with highly rfeh elechron
Canbene is the e dofrnt
H9hly e nch e=cmecns the cEc do bond hawe highest
umben oh substftutfon

Cc SutsRtutin)
omenen ntth eagens.The
Th
The cabene s gereated om te Cef
Caibene s h¡hy seleotve bor the c=c
a alyialahet poat
CHa

ch
The crbene s genthatecl Grom
OH

cttg Enparsfoon
The cas bene adds to hetengolic compouml
CHca k-ÖH

absec

Vecrujt
Cabenehctere
3) Canbenes ufll wndesgo AeAYYagement to gve keten.
R-cH =C0
kke rene ot
diugo hetoe
Ketene

R -CN EC= + Nu
Nu
TeunaliselA
 K-cH sczD +R-N
RuN R-cH2-4NHR
ph arnide'

2)

(3) ho

Dh,a,

gh +ot ph
PAe=Co
ph ph r
Ph
2)
RieCH

3)
ho

4)

5)

B-keto mabonyli
wtl wnda dear
o autt
Entra prhipe

bogltm,
 C-4 insentin -
alken
R-cth-Cta -CH CH:
alkene

(H inseatirg alkene ,3 3-memberes

5 sb membere memened nng <4stemjf membed s
RcHEcH
-cH Smenbod
fomaton
tte lartegt fosmatton 6-mien be rng Prodleet
ome

ame
phatorc

A
Rha tona
-COg Tne

(aaben fsm betcuceEh thi

e00me

5) Corbene wn ba atacked by Nu i
- ’ u CH
erch
eh CoA

coost
coc
Cooet
poelem tron cloylen
CHels cclz c93Ma
e)
koy

kOH OMe
eme

B
Cu()

hilcH3o
A

a) CHcl
ko
cel

b) CH CDRJC
k-OH cl

1CHOR

Livig group
ome

CH2Ia
Cuti)
CHs Crouscc
write thuplan

(or) beo

ho

e) cclzcooNa
-ome
Cua Cot ome

Coost