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Consumer Chemistry - SLM Q3 Module 1
Consumer Chemistry - SLM Q3 Module 1
QUARTER 3 – MODULE 1
(Week 1-2)
Chemistry in
Everyday Life
What I Need to Know
This module was designed and written with you in mind. It is here to help you
master the nature of Chemistry in Everyday Life. The scope of this module permits
it to be used in many different learning situations. The language used recognizes the
diverse vocabulary level of students. The lessons are arranged to follow the standard
sequence of the course. But the order in which you read them can be changed to
correspond with the textbook you are now using.
What I Know
Choose the letter of the best answer. Write the chosen letter on a separate sheet of
paper.
1. Active ingredients in shampoos that help remove oil and dirt off the scalp and
hair are called:
a. lipids c. surfactants
b. powders d. emulsifiers
2. Which of the following is true about cosmetics?
a. used as beautifying agent
b. help in enhancing appearance
c. help in treating skin infection
d. all of these
3. Ointments are mixtures that contain petroleum jelly, wax or oil, and are used in
salons as:
a. pomades c. styling wax
b. hair pastes d. all of these
4. All of the following are basic ingredients of cosmetics except _________
a. color c. emulsifier
b. flavor d. preservative
5. Substances that soften skin, and are used in cosmetics are:
a. water c. emulsifier
b. emollients d. softener
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6. It is known as “synthetic pearl” and is used to provide shimmering effects in
some cosmetic products.
a. Bismuth chloride c. Bismuth oxychloride
b. Bismuth dichloride d. Bismuth hypochloride
7. Which of the following is categorized as a cosmetic product?
a. deodorant c. baby powder
b. eye make-up d. all of these
8. The red color use in red lipstick and is listed as carmine in the ingredient list is
extracted from which of the following insects?
a. red ants c. cochineal
b. lady bug d. lilioceros
9. Which of the following is a natural color used in cosmetic products that comes
from plants?
a. iron oxide c. coal tar
b. beet powder d. mica flakes
10. Cosmetic manufacturers do not list fragrance as one of the ingredients because
it is considered as __________
a. regulated c. trade secret
b. restricted d. secret ingredient
11. Naturally occurring material used by the ancients for ceremonial lip tints and
rouge preparations.
a. henna c. red ochre
b. annato d. frankincense
12. Which of the following is a naturally derived thickener used in cosmetics?
a. Gelatin c. cetyl palmitate
b. Carbomer d. all of these
13.Eye paints used by the ancients that consisted primarily of a copper-based
green ore
a. azurite c. malachite
b. galena d. crushed charcoal
14. Early skin ointments was prepared by combining animal fat with fragrant
substances like:
a. kohl c. galena
b. myrrh d. azurite
15. Glycerin prevents cosmetic product from drying out; glycerin in cosmetics is:
a. emulsifier c. moisturizer
b. humectant d. preservative
3
Lesson
1 Cosmetics
Cosmetics are consumer products that we use every day; when one hears
the word cosmetics, one instantly thinks of a woman applying, blush, mascara,
lipstick, etc. But cosmetics can be so much more. In this module, you will explore
more about cosmetics; the science behind cosmetic products.
https://www.watsons.com.ph/
https://www.businessoffashion.com/articles/beauty/beauty-industry-remakes-product-pitches-in-
the-age-of-coronavirus
What’s In
Cosmetic comes from the Greek word, kosmetikos- kosmos, order of arrangement;
kosmein which means to 'adorn' (addition of something decorative to a person or a
thing). It may be defined as a substance which comes in contact with various parts
of the human body like skin, hair, nail, lips, teeth, and mucous membranes etc.
Cosmetics are generally mixtures of chemical compounds, some derived from
natural sources and many being synthetics.
The appearance of skin care formulation dates to around 3000 B.C.E. in ancient
Egypt. Most concoctions were prepared from natural materials. Cleopatra is said to
have bathed in donkeys' milk to keep her skin smooth and supple. One naturally
occurring material used by the ancients was red ochre, or iron oxide. Lumps of red
ore were formed when iron oxidized or rusted. The red iron oxide was found in
burial tombs in ceremonial lip tints and rouge preparations. It was also used to
draw the ancient cave pictures of animals, and is still used in many makeup
formulations today. Eye paints have also been found at ancient gravesites. These
paints consisted primarily of a copper-based green ore called malachite that was
mined from nearby quarries. Animal fat was combined with fragrant substances
such as frankincense and myrrh to produce early skin ointments. More
sophisticated creams and lotions were fine-tuned through trial and error and
passed down over many generations.
Today, cosmetics are considered as essential components in life. They not
only, attract the people towards it but also impart psychological effects. It has
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gained popularity in the last 3-4 decades and its use has been increased
exponentially both-in males and females.
What’s New
What is It
5
Water
Water forms the basis of almost every type of cosmetic product, including
creams, lotion, make-up, deodorants, shampoos and conditioners. Water plays an
important role in the process, often acting as a solvent to dissolve other ingredients
and forming emulsions for consistency. Water used in the formulation of cosmetics
is not your everyday regular tap water, it must be “ultra-pure” - that is, free from
microbes, toxins and other pollutants. It is usually listed as aqua in ingredients on
labels.
Emulsifiers
The term emulsifier refers to any ingredient that help to keep unlike
substances (such as oil and water) from separating. Many cosmetic products are
based on emulsions
(http://www.emulsifiers.org/ViewDocument.asp?Itemld=11&Title=What)- small
droplets of oil dispersed in water or small droplets of water dispersed in oil. Since
oil and water do not mix no matter how much you shake, blend or stir, emulsifiers
are added to change the surface tension between the water and oil, producing a
homogenous and well-mixed product with an even texture. Examples of emulsifiers
used in cosmetics include polysorbates, laureth-4 and potassium cetyl sulfate.
Emulsions are used in creams and lotions to give then an even texture.
Preservatives
Preservatives are important ingredients. They are added to cosmetics to
extend their shelf life and prevent the growth of microorganisms such as bacteria
and fungi, which can spoil the product and possibly harm the user. Since most
microbes lives in water, the preservatives used need to be water-soluble.
Preservatives used in cosmetics can be natural or synthetic (man-made), and
perform differently depending on the formulation of the product. Some require low
levels around 0.01%, while others will require levels as high as 6%.
Some of the more popular preservatives include parabens, benzyl alcohol, salicylic
acid, formaldehyde and tetrasodium EDTA (ethylenediaminetetra-acetic acid)
Thickeners
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acid polymer that is water-swellable and can be used to form clear gels. Other
examples include cetyl palmitate, and ammonium acryloyldimethyltaurate.
Emollient
Emollients soften the skin by preventing water loss. They are used in a wide
range of lipsticks, lotions and cosmetics. A number of different natural and
synthetic chemicals work as emollients, including beeswax, olive oil, coconut oil
and lanolin, as well as petrolatum (petroleum jelly), mineral oil, glycerine, zinc
oxide, butyl stearate and diglycol laurate. Emollients help to prevent water loss.
Colouring agents/pigments
Red lips, smoky eyes and rosy cheeks; it is the purpose of many cosmetics to
accentuate or alter a person’s natural colouring. A huge range of substances are
used to provide the rainbow of appealing colours you find in the makeup stand.
Mineral ingredients can include iron oxide, mica flakes, manganese, chromium
oxide and coal tar. Natural colours can come from plants, such as beet powder, or
from animals, like the cochineal insect. The latter is often used in red lipsticks and
referred to on your ingredient list as carmine, cochineal extract or natural red 4.
Pigments can be split into two main categories: organic, which are carbon-based
molecules (i.e., organic in the chemistry context, not to be confused with the use of
the word to promote ‘natural’ or ‘non-synthetic’ or ‘chemical-free’ products) and
inorganic which are generally metal oxides (metal + oxygen and often some other
elements too). Inorganic should not be confused with ‘synthetic’ or ‘unnatural’ as
most of the inorganic metal oxide pigments do occur naturally as mineral
compounds.
The two most common organic pigments are lakes and toners. The lake pigments
are made by combining a dye colour with an insoluble substance like alumina
hydrate. This causes the dye to become insoluble in water, making it suitable for
cosmetics where water-resistant or waterproof properties are desired.
A toner pigment is an organic pigment that has not been combined with any other
substance.
The inorganic metal oxide pigments are usually duller than the organic pigments,
but are more resistant to heat and light, providing a longer-lasting colour.
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No matter how effective a cosmetic may be, no one will want to use it if it
smells unpleasant. Consumer research indicates that smell is one of the key factors
in a consumer’s decision to purchase and/or use a product.
Fragrances are not just used in perfumes; they are also in creams, lotions to
give appealing smell. Chemicals, both natural and synthetic, are added to
cosmetics to provide an appealing fragrance. Even ‘unscented’ products may
contain masking fragrances to mask the smell of other chemicals.
The term ‘fragrance’ is often a generic term used by manufacturers. A single
listing of fragrance on your product’s ingredient list could represent dozens or even
hundreds of unlisted chemical compounds which were used to create the final
individual fragrance.
Creams
Creams are semi-solid emulsions which contain mixtures of oil and water.
Their consistency varies between liquids and solids. Salve (medical ointment for
soothing purpose) and unguent (soothing products) preparations in earlier days led
to the development of cleansing and cold creams. With the help of additives such as
emulsifying agents and newer techniques, the preparation of creams has become
easy.
Creams are classified according to their functions.
1. Cleansing and Cold Creams.
2. Foundation and Vanishing Creams.
3. Night and Message Creams.
4. Hand and Body Creams.
5. All-purpose Creams is Cleansing and Cold Creams
https://www.spot.ph/shopping/beauty-skincare/69672/10-skin-savers-for-banishing-dark-
spots-a1503-20170327-lfrm
Powders
http://ecowastecoalition.blogspot.com/2018/02/some-talcum-powder-products-lack.html
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purposes). Powders have different physical properties when compared to the liquid
preparations. They have very fine particle size, which helps in producing large
surface area per unit weight. This helps in proper dispersion of powder, which
covers the large surface area of the body.
Deodorants
https://kemi.taenk.dk/bliv-groennere/test-chemicals-deodorants
Perfumes
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with a very low content of perfume and some moisturizing ingredients added to give
softness to baby skin. Other cosmetics, such as aftershave lotions also contain a
high content of perfumes, in the range of 0.5%–2%.
https://www.sciencedirect.com/topics/chemistry/perfume
What’s More
BEESWAX CARMINE
COCHINEAL EMULSIFIER
EMULSIONS EMOLLIENT
FRAGRANCE SHINE
GLIMMER GLYCERIN
PARABENS PIGMENT
THICKENERS WATER
PRESERVATIVES
It’s against the law for a cosmetic to contain any ingredient that makes the product
harmful when consumers use it according to directions on the label, or in the
customary or expected way. This is true whether or not there is a regulation that
specifically prohibits or restricts the use of the ingredient in cosmetics.
The one exception is for coal-tar hair dyes, which the law treats differently.
Under the law, FDA cannot take action against a coal-tar hair dye for safety
10
reasons as long as it has a special warning statement on the label and directions
for a skin test. The caution statement reads as follows:
Caution - This product contains ingredients which may cause skin irritation on
certain individuals and a preliminary test according to accompanying directions
should first be made. This product must not be used for dyeing the eyelashes or
eyebrows; to do may cause blindness.
It’s also important to understand that some cosmetics that are safe when
people use them correctly may be unsafe when used the wrong way. Cosmetics
must have any directions for use or warning statements needed to make sure
people use the products safely. For example, some ingredients may be safe in
products such as cleansers that we wash off the skin immediately, but not in
products that we leave on the skin for hours. Similarly, ingredients that are safe for
use on the hair or nails may be unsafe when used on the skin or near the eyes.
Under U.S. law, cosmetic products and ingredients, other than color additives, do
not need FDA approval before they go on the market. Cosmetic manufacturers have
a legal responsibility for the safety and labeling of their products. FDA can and
does take action against cosmetics on the market that do not comply with the law.
https://www.fda.gov/cosmetics/cosmetics-laws-regulations/prohibited-restricted-
ingredients-cosmetics
Directions: Summarize what you have learned from the lesson by completing
the sentences using words given from the box below. Use a separate paper
for your answers.
11
What I Can Do
For example:
NOTE!
You may use internet sources to find the formula of the substances. Information about the function
of different ingredients can also be found at http://www.makingcosmetics.com/.
The first one is done for you using the example shown. You may add rows as necessary
Based on the analysis, would you suggest this product to your friends? Why/why
not
12
Assessment
Multiple Choice. Choose the letter of the best answer. Write the chosen letter on a
separate sheet of paper.
1. An acrylic acid polymer that is water-soluble and can be used to form clear
gels:
a. Silica c. carbomer
b. gelatin d. guar gum
2. Which of the following is true about preservatives used in cosmetics?
a. are all natural
b. are all synthetic
c. need to be water soluble
d. need to be viscous
3. An ingredient that keeps oil and water from separating.
a. Emulsion c. emulsifier
b. Emollient d. thickener
4. Which of the following is a lipid thickener that is added to cosmetic
emulsions?
a. silica c. xanthan gum
b. bentonite d. carnauba wax
5. Which of the following is a preservative used in cosmetics?
a. formaldehyde c. cetyl palmitate
b. cetyl alcohol d. aluminum silicate
6. Semi-solid emulsions which contain mixture of oil and water.
a. lotion c. deodorant
b. creams d. powder
7. An ingredient in cosmetics listed as aqua.
a. water c. solvent
b. color d. emollient
8. Which of the following is a mineral thickener?
a. bentonite c. cetyl palmitate
b. carnauba wax d. stearic acid
9. Used in deodorants that prevents bacterial growth in the underarm area.
a. glycerin c. paraben
b. triclosan d. zinc oxide
10. Which of the following is a humectant that prevents deodorant from drying
out?
a. triclosan c. sodium stearate
b. triethanolamine d. propylene glycol
11. The color in red lipsticks listed as carmine is derived from a/an:
a. plant c. animal
b. insect d. mineral
12. Thickeners that absorb water and oils to increase viscosity of product.
a. lipid thickener c. protein thickener
b. mineral thickener d. synthetic thickener
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For numbers 13-15, refer to the following product label:
Additional Activities
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4. Set the container on a sunny windowsill and allow the flower petals to soak
in the oil for 24 hours. Shake gently and strain through a double layer of
cheesecloth. Discard the old petals.
5. Prepare new petals, following steps 1 and 2, and cover with the oil you've
already used. Allow the petals to steep for 24 hours. Repeat the process,
using the same oil, for 3 days or until the fragrance reaches the desired
strength.
6. Store your fragrant oil in a glass bottle in a cool dry place. Use in potpourri
or crafts, or wear as a perfume.
Source: https://www.hunker.com/13410895/how-to-extract-essential-oils-
scents-from-flowers
References
Caret, R.L.,et.al. 1997.Principles and Applications of Inorganic, Organic, &
Biological Chemistry. McGraw-Hill: USA
https://www.researchgate.net/publication/325023106_Textbook_of_Cosmetic_For
mulations
https://www.science.org.au/curious/people-medicine/chemistry-cosmetics
https://www.canstockphoto.com/images-photos/cosmetics.html
https://www.watsons.com.ph/
https://www.businessoffashion.com/articles/beauty/beauty-industry-remakes-
product-pitches-in-the-age-of-coronavirus
https://www.spot.ph/shopping/beauty-skincare/69672/10-skin-savers-for-
banishing-dark-spots-a1503-20170327-lfrm
https://thestudentscientist.org/2018/06/03/thechemistryofdeodorants/
https://www.sciencedirect.com/topics/chemistry/perfume
https://www.hunker.com/13410895/how-to-extract-essential-oils-
scents-from-flowers
15
16
What's More
What I Activity 1. What’s in Cosmetics?
Know
15.b
1. c 14.d
2. d 13.b
3. d 12.b
4. b 11.b
5. b 10.d
6. c 9. b
7. d 8. a
8. c 7. a
9. b 6. b
10.c 5. a
11.c 4. d
12.a 3. c
13.c 2. c
14.b 1. c
15.b
ment
Assess
What I have Learned
protect, external, emulsifiers, moisturizers,
fragrances, artificial, health, unsafe, doses,
chemicals
What I Can Do
Answers vary depending on the cream/product
analyzed
Answer Key
LEARNING ACTIVITY SHEET
MODULE 1: CHEMISTRY IN EVERYDAY LIFE
(WEEK 1-2)
17
LEARNING ACTIVITY SHEET
MODULE 1: CHEMISTRY IN EVERYDAY LIFE
(WEEK 1-2)
Classification
Ingredient according to Structural Formula Natural/Synthetic
function (if possible)
(emulsifier,
fragrance, etc.)
Based on the analysis, would you suggest this product to your friends? Why/why
not
18