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Answer set 56 created with 5 answers from REGISTRY
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Answer set 57 created with 21 answers from CAPLUS
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1. Method for synthesis of inorganic nanocrystal with acetylacetonate salt
By Li, Linsong; Li, Xiaomin; Shen, Huaibin
From Faming Zhuanli Shenqing (2010), CN 101830445 A 20100915. Language: Chinese, Database: CAPLUS
The method comprises (1) synthesizing raw materials (metal chloride, nitrate, acetate, perchlorate, phosphate, etc.), (2) stirring the
above salt soln. and acetylacetone, adding precipitant, pptg., filtering, and drying to obtain acetylacetonate salt, and (3) synthesizing
nanomaterials (Group II-VI, Group I-III-VI, Cu, Ag, etc.). The invention has moderate activity of acetylacetonate, easy control of reaction
and strong operability. The inventive method is also suitable for synthesis of other nanomaterials (PbS, PbSe, PbTe, SnS, SnSe, SnTe,
MnS, MnSe, CaS, CaSe, InS, InSe, GaS, GaSe, CuS, Cu2S, CuInGaS, CuInGaSe, Cu2ZnSnS4, etc.).
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2. Flow method and reactor for manufacturing nanocrystals
By Yen, Brian K. H.; Guenther, Axel; Jensen, Klavs F.; Schmidt, Martin
From PCT Int. Appl. (2006), WO 2006137878 A2 20061228. Language: English, Database: CAPLUS
A population of nanocrystals having a narrow and controllable size distribution and can be prepd. by a segmented-flow method. The
nanocrystal precursor includes an M source and an X donor; the M source may be Cd, Zn, Mg, Hg, Al, Ga, In, or Tl and X may be O, S,
Se, Te, N, P, As, or Sb.
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3. Investigation of metal β-diketonates as parent materials for reference samples
By Yurchenko, O. I.; Shevtsov, N. I.; Mikhailova, L. I.; Belikov, K. N.; Titova, N. P.; Shkumat, A. A.
From Functional Materials (2005), 12(2), 405-408. Language: English, Database: CAPLUS
Stability of synthesized lead, Cd and Cr(III) β-diketonates and Hg(I) dimedonate in solid state and in dild. solns. was studied by
titrimetry and inductively coupled plasma optical emission spectrometry. It was shown, that the solid samples are stable during 5 years
and the solns. keep the concn. for 4 mo. Metal acetylacetonates are recommended as parent substances for manufg. of ref. samples
used for calibration of anal. instruments and accuracy control.
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4. Novel Coated-Wire Membrane Sensor Based on Bis(Acetylacetonato) Cadmium(II) for the Determination of Chromate Ions
By Ardakani, Mohammad Mazloum; Dastanpour, Ali; Salavati-Niasari, Masoud
From Microchimica Acta (2005), 150(1), 67-72. Language: English, Database: CAPLUS, DOI: 10.1007/s00604-005-0319-6
A new electrode based on a complex of chromate ions with bis(acetylacetonato) cadmium(II) as a carrier was developed for detection
of chromate in aq. soln. The electrode exhibited linear response with Nernstian slopes of -28.8 ± 0.5 mV per decade for chromate within
the concn. range of 2.5 × 10-6 - 0.1 M. The limit of detection as detd. from the intersection of the extrapolated linear segments of the
calibration plots was almost 1.0 × 10-6 M. The electrodes exhibited good selectivities for chromate. The response time of the electrode
was <25 s over the entire concn. range. The electrode can be used in the pH range 8.0-12.0 for chromate. It was used as an indicator
electrode in titrn. with Pb(NO3)2 and for the detn. of chromate ion in wastewater samples.
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5. Electrochemical reactions at sacrificial electrodes. Part X. Synthesis of cadmium chelates
By Banait, J. S.; Singh, Baljit
From Journal of the Electrochemical Society of India (1996), 45(2), 103-109. Language: English, Database: CAPLUS
Electrochem. reactions of malononitrile, di-Et malonate, Et cyanoacetate, cyanoacetamide, Et acetoacetate and acetylacetone (RH2)
were carried out at sacrificial cadmium anode using acetonitrile as solvent and tetrabutylammonium chloride as supporting electrolyte.
The products of these electrochem. reactions were identified as Cd(II) chelates by the elemental anal. and IR spectral studies.
Coordination compds. of these chelates with 1,10-phenanthroline and 2,2'-bipyridine also were synthesized electrochem. All these
reactions proceed with very high current efficiencies.
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6. Synthesis of cadmium pentamethylcyclopentadienyl complexes
By Cummins, C. C.; Schrock, R. R.; Davis, W. M.
From Organometallics (1991), 10(10), 3781-5. Language: English, Database: CAPLUS, DOI: 10.1021/om00056a063
The prepn. of red, light-sensitive cadmium bis(pentamethylcyclopentadienide) has been effected by reaction of Cd(acac)2 with 2 equiv
of LiCp* in the dark. CdCp*2 forms a weak adduct with 1,2-dimethoxyethane (DME). A Schlenk-type equil. exists when CdCp*2 is
mixed with an equimolar amt. of Cd[N(SiMe3)2]2, giving solns. from which (CdCp*[N(SiMe3)2])2 can be crystd. Single-crystal x-ray
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diffraction revealed the dimeric nature of the latter complex, which displays bridging silylamides and terminal Cp* ligands. Bonding of
the Cp* ligand to cadmium in this complex is regarded primarily as σ in character, but a weak dative interaction between the diene
HOMO and the empty cadmium pz orbital is plausible in view of structural parameters. The structure detn. is believed to be the first on
any complex contg. either a cadmium amide or a cadmium pentamethylcyclopentadienide linkage.
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7. Organic compounds of selected metals with possible application in electronics
By Majewski, Jacek; Krompiec, Stanislaw; Achmatowicz, Selim
From Prace Naukowe Instytutu Technologii Elektronowej Politechniki Wroclawskiej (1986), 34, 112-17. Language: English, Database: CAPLUS
The organometallic compds. of 2,4-pentadione, acetylacetone, and rosin with major component abietic and levopimaric acids and Ru,
Pd, P, Au, Ti, Si, Cu, Cd, Zr, Pb, V, Bi, Cr and Ni, potentially useful in electronics were synthesized. Soly. of these prepns. in the
selected org. solvents varies within 1-30% by wt. in terms of metal or its oxide and the obtained solns. are stable and co-operated well
with each other. Derivatog. anal. showed that thermal decompn. of the synthesized compds. occurs at 100-450° and results in metal or
its oxide.
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8. Electrosynthesis of acetylacetonates of some divalent metals
By Arakelyan, N. M.; Eremyan, A. B.; Isabekyan, S. E.; Papayan, S. A.; Darbinyan, E. G.
From Armyanskii Khimicheskii Zhurnal (1983), 36(9), 617-19. Language: Russian, Database: CAPLUS
The synthesis was studied of acetylacetonates of Ni, Co, Zn, Cu, Cd and Fe by electrochem. reaction of the metals with acetylacetone
in abs. MeOH and EtOH. The most suitable solvent is MeOH, which has a higher dielec. permeability (ε = 33) and increases the elec.
cond. of the system at the same molar concn. of the initial compd. Electrolysis was conducted on a soln. contg. 0.5 mL/L of
acetylacetone with a supporting electrolyte of KCl or LiCl at room temp. while mixing at c.d. 1.0-2.0 A/dm2 and at a potential on the
electrodes of 4-6 V. The quantity of electricity used was 3-4 A-h. The electrodes were Ni, Co, Zn, Cu, Cd, and Fe. The products were
examd. by studying their IR spectra.
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9. The electrochemical synthesis of β-diketonato complexes of cadmium(II), and their adducts; the crystal and molecular
structure of Cd(acac)2phen
By Bustos, Luis; Green, James H.; Hencher, J. Lawrence; Khan, Masood A.; Tuck, Dennis G.
From Canadian Journal of Chemistry (1983), 61(9), 2141-6. Language: English, Database: CAPLUS, DOI: 10.1139/v83-372
Title complexes Cd(RCOCHCOR1)2 (R = R1 = Me; R = CF3 R1 = Me, Me2CH, Me2CHCH2, Me3C, Ph, 2-naphthyl) were prepd. in
good yield by the direct, room-temp. electrochem. oxidn. of the metal into a soln. of RCOCH2COR1 in MeCN. Adducts
Cd(RCOCHCOR1)2L (L = 2,2'-bipyridine, 1,10-phenanthroline (phen), Me2NCH2CH2NMe2) were prepd. in situ, or by subsequent
addn. of the ligand to the electrolytic soln. X-ray studies show that the mol. structure of both Cd(acac)2phen [acac = (MeCO)2CH] and
Cd(CF3COCHBz)2phen is based on a CdO4N2 kernel, distorted from octahedral stereochem. by the bite of the ligands.
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10. PVC heat stabilizing metal acetylacetonates
By Matthews, John C.; Wood, Louis L.
From U.S. (1969), US 3474464 A 19691021. Language: English, Database: CAPLUS
Metal acetylacetonates (I), useful as heat stabilizers for PVC, are prepd. by treating excess 2,4-pentanedione with a metal oxide or
hydroxide, cooling the resulting soln., and sepg. the pptd. I.
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11. Simple method for preparation of zinc, cadmium, mercuric and cobalt acetylacetonates
By Hassanein, M.; Hewaidy, I. F.
From Zeitschrift fuer Anorganische und Allgemeine Chemie (1970), 373(1), 80-2. Language: English, Database: CAPLUS, DOI: 10.1002/zaac.19703730113
M(acac)2 [M(II) = Zn, Cd, Hg, Co; Hacac = acetylacetone] andCo(acac)3 were prepd. by mixing MO or Co3O4, resp., with
acetylacetone at room temp. in the presence of the proper solvent. The structure of the complexes was confirmed on the basis of uv
spectra, m.ps., elemental anal., and x-ray methods.
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12. Relation between the composition of a complex and the optimum degree of acidity for its extraction
By Budesinsky, Bretislav
From Collection of Czechoslovak Chemical Communications (1967), 32(5), 1688-97. Language: German, Database: CAPLUS
Theoretical relations were derived between the optimum pH values for the extn. of a complex and its compn., the distribution coeff. of
electroneutral particles of the complex-forming reagent, and the concurrent reactions of the reagent with protons or of the metal cation
with OH-. The validity of the relations derived was verified by extg. 26 metal cations by means of the dithizone, 8-hydroxyquinoline,
acetylacetone, thenoyltrifluoroacetone, and cupferron in the systems H2O-CHCl3 or H2O-C6H6. The theory is applicable only if the org.
solvent is practically immiscible with water.
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13. Fractional sublimation of various metal acetylacetonates
By Berg, E. W.; Hartlage, Frederick R., Jr.
From Analytica Chimica Acta (1965), 33(2), 173-81. Language: English, Database: CAPLUS, DOI: 10.1016/S0003-2670(01)84872-8
cf. CA 62, 13875b. The sublimation recrystn. temp. zones of 21 metal acetylacetonates (Mn+(AA)n) (I) were detd. at 1 mm. pressure in
a wire-wound brass tube (11 mm. inner diam. × 1 m. long) jacketed vacuum sublimator (11 mm. outer diam. borosilicate glass tube)
giving const. continuous temp. gradients of 25-270, 25-170, or 25-100° for the different powerstat settings. Approx. 6 in. of the low
temp. end of the tube was free of windings to facilitate cooling with a 0° bath. Small Al boats contg. the I samples were placed in the
high temp. end of the app., which was closed with a small capillary tube admitting a slow stream of air; and the low temp. end was
connected to a vacuum line at 1 mm. Hg pressure. The sublimed I was left in the app. for 1-2 hrs., the glass tube was removed from the
heating jacket, and the I was recovered by cutting out the appropriate section of the glass tube, and removing the I mech. or by
dissolving with a solvent. The sublimation temp. zones of I compds. are: Ca(AA)2 203-167; Mg(AA)2 141-120; Cd-(AA)2 137-117;
Zr(AA)4 102-77; V(AA)3 111-94; Cr(AA)3 106-80; Rh(AA)3 118-96; Ni(AA)2 111-88; Pt(AA)2 102-80; Cu(AA)2 102-82; Th(AA)4 116-
78; Mn(AA)2 90-70; Fe(AA)3 85-66; Co(AA)2 88-67; Pd(AA)2 94-74; Hg(AA)2 75-55; Ga(AA)3 92-70; In(AA)3 85-66; Al(AA)3 81-60;
Zn(AA)2 38-31; and Be(AA)2 31-15°. The method of prepg. I was described previously (loc. cit.). To det. the recoveries, the I
sublimates of Fe, Be, Al, Mg, and Ni were analyzed for the resp. metal content by decompg. with HNO3, evapg. the soln. to dryness,
dissolving the residue and dilg. to vol. with H2O, and analyzing an aliquot. Fe3+, Be2+, Al3+, and Mg2+ were detd. photometrically with
1,10-phenanthroline, p-nitrophenylazoorcinol, aluminon, and Eriochrome Black T, resp.; Ni2+ was detd. with dimethylglyoxime. In all
other cases, the recoveries were detd. from the loss in wt. during the sublimation. The latter method gave results with the Fe, Be, Al,
Mg, and Ni I sublimates which were consistent with direct analysis. The recoveries of some of the I by sublimation with a temp. gradient
of 170-15° are Al 98.5, Be 101, Fe 95.8, Mg 67.7, Ni 91.8, Cd 87.3, Co 99.4, Cu 94.0, Ga 99.1, Pd 98.8, and Zn 92.6%. No trace of
metal impurity was detected in any sublimed I. Mg(AA)2 was not very stable, and some decompn. reduced the recovery. Mixts. of
Mg2+, Al3+, and Be2+ salts were treated with Ac2CH2, and the I were collected, washed, dried, and sublimed in the app., with a temp.
gradient of 170-15°. Al3+ and Be2+ were recovered as sep. pure I fractions; but the recoveries of the ions were not quant. because of
incomplete pptn. of I. However, the sublimation of the Al(AA)3 and the Be(AA)2 gave quant. recoveries. Fractional sublimation (170-15°
) of mixts. of Ni(AA)2, Fe(AA)3, and Be(AA)2 gave quant. recoveries of pure Be(AA)2, ≤83% recoveries of pure Ni(AA)2, and Fe(AA)3
contg. some overlapping Ni(AA)2 impurity. Fractional sublimation (170-15°) of mixts. of Cu(AA)2 and Fe(AA)3 gave 70% recovery as
pure Cu(AA)2. A sample of com. RhCl3 was converted to Rh(AA)3, which was sublimed as described. Mg(AA)2 as a contaminant of the
RhCl3 was detected as a 1-cm. long white cryst. zone immediately adjacent to the 118° and of the Rh(AA)3 zone. Fractional
sublimation of numerous I mixts. may be achieved.
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14. The extraction behavior of metal acetylacetonates
By Shigematsu, Tsunenobu; Tabushi, Masayuki
From Bulletin of the Institute for Chemical Research, Kyoto University (1961), 39, 35-42. Language: Unavailable, Database: CAPLUS
-The extn. behavior of acetylacetonate with CHCl3 was studied for Al, Be, Cd, Co, Co, Cu, Fe(III), Ga, Hf, In, Pb, Mg, Ni, Sr, U, Y, and
Zn at pH 2-12, and is discussed as a function of the ionization potential. An increase in the potential results in a rise in the max. per
cent extn. and in a decrease in the pH value for unit distribution ratio. This relation is attributed to an increase in the covalency of the
bond, which is related to the soly. in the org. solvent.
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15. Utilization of complex formation for separation and determination of elements by extraction method
By Alimarin, I. P.; Gibalol, I. M.
From Vestnik Moskovskogo Universiteta (1956), (No. 5), 55-9. Language: Unavailable, Database: CAPLUS
Acetylacetone (I) and di-Na ethylenediaminetetraacetate (II) produce complexes of different stability with different elements. The
complexes of I, contrary to complexes of II, are readily extd. by org. solvents such as CCl4. The Fe, Be, Cd, Co, Ni, Mn, Cu, Pb, and Zn
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complexes of I were studied with respect to their extn. by CCl4 in the presence of II. Beryllium can be completely extd. by CCl4 at pH 9.
For the sepn. of Be from Fe, 5 mL. of 15% soln. of I, 7 mL. of 0.05M II, 2 drops of concd. NH4OH, and 7 mL. of CCl4 are added to 15
mL. of pH 2-3 soln. contg. BeSO4 and FeCl3. The mixt. is shaken 5 min., the org. phase sepd., the extn. repeated twice adding the
same reagents with the exception of II. To the org. phase 20 mL. H2O and 15 mL. HCl is added, the aq. layer evapd. until the vol. is
halved, and Be is pptd. by NH4OH and detd. gravimetrically as BeO. Beryllium is extd. almost completely, Fe is not extd. For the sepn.
of small quantities of Co from Fe the soln. is neutralized by NH4OH to pH 3-4, 8-10 mL. of 0.05M II, 5-6 mL. 15% I, 2.5 mL. concd.
NH4OH, and 7 mL. of CCl4 are added and shaken in a separatory funnel for 3-4 min. The extn. is repeated twice, adding identical
quantities of I and CCl4. Cu, Ni, Pb, Cd, Zn and Mn can be sepd. from Fe by this method.
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16. A new method of preparing some acetylacetonate complexes
By Jones, Mark M.
From Journal of the American Chemical Society (1959), 81, 3188-9. Language: Unavailable, Database: CAPLUS
The reaction between basic solns. of metal complexes and acetylacetone was used to prep. corresponding acetylacetonate complexes
of MoO2++, Th(IV), Cu(II), Be(II), Al(III), and diamminebis(2,4-pentanediono)nickel(II). Similar conditions produced basic complexes
with Zn(II), Cd(II), La(III), Co(II), Ce(IV), and UO2++ but no complexes with W(VI), Cr(III), and Si(IV).
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17. Catalytic production of poly(ethylene terephthalate)
By Easley, Wm. K.; Lawson, Julian K.; Ballentine, James B.
No Corporate Source data available (1958), US 2857363 19581021. Language: Unavailable, Database: CAPLUS
Poly(ethylene terephthalate) is produced by reaction of ethylene glycol anti di-Me terephthalate using 0.01-2.0% by wt. of a metal
enolate catalyst which is formed from an aliphatic diketone (5-8 C atoms) and having its C:O groups sepd. by 1 C atom. The metal is
Zn, Cd, Co, Mn, or Mg. In the 1st step, ethylene glycol and di-Me terephthalate react at atm. pressure and 150-220° to give MeOH,
which is removed, and bis(2-hydroxyethyl) terephthalate. In the 2nd step, the monomer is polymerized at 0.1-5 mm. and 220-300°
under N. Ethylene glycol is formed and distd. off during the process. Both steps take place in the presence of the above catalyst. Times
required for the 2 steps are decreased from 3-6 and 1-10 hrs. to 0.5-1.5 and 0.5-4 hrs., resp. The linear condensation polyesters thus
produced have specific viscosities of 0.1-1.0 and a suitable for formation of fibers and films. Use of the acetylacetonates of the above
metals as catalysts is specifically claimed.
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18. Light absorption of chelate complexes. II. Mechanism of light absorption of acetylacetone complexes
By Kiss, Arpad I.; Csaszar, Jozsef
From Acta Chimica Academiae Scientiarum Hungaricae (1957), 13, 49-56. Language: Unavailable, Database: CAPLUS
The absorption spectra of the acetylacetonates of Be(II), Mg(II), Zn(II), Cd(II), Al(III), Th(IV), Cr(III), Mn(III), Fe(III), Co(III), Co(II), Ni(II),
Pd(II), and Cu(II) were measured between 210 and 2000 mµ. In those complexes in which the central metal atom has no partially filled
orbitals the absorption bands are those of the acetylacetonate ion and those due to an electron-transfer reaction. When the central
metal atom has partially filled d-orbitals term-splitting bands are also found, the no. depending on the ground state and the symmetry of
the potential field of the complex. The term splitting is such as to confirm the electrovalent character of these complexes.
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19. The use of complexing agents for separating and determining elements by the extraction method
By Alimarin, I. P.; Gibalo, I. M.
From Ser. Fiz.-Mat. i Estestven. Nauk (1956), (No. 3), 55-9. Language: Unavailable, Database: CAPLUS
A discussion is given of the behavior of the complexes formed by Fe(III), Be, Cd, Co, Ni, Mn, Cu, Pb, and Zn with acetylacetone on
extn. with CCl4 in the presence of complexon(III). The conditions are detd. for the quant. extn. of Be acetylacetonate by CCl4 in the
presence of complexon (III). This method can be used for the sepn. of Be from Fe and of small amts. of Co from Fe.
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20. The use of complexing agents for separating and determining elements by the extraction method
By Alimarin, I. P.; Gibalo, I. M.
From Vestnik Moskovskogo Universiteta (1956), 11(No. 5). Language: Unavailable, Database: CAPLUS
A discussion is given of the behavior of the complexes formed by Fe(III), Be, Cd, Co, Ni, Mn, Cu, Pb, and Zn with acetylacetone on
extn. with CCl4 in the presence of complexon(III). The conditions are detd. for the quant. extn. of Be acetylacetonate by CCl4 in the
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presence of complexon (III). This method can be used for the sepn. of Be from Fe and of small amts. of Co from Fe.
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21. Behavior of metal anthranilates in buffered solutions
By Holmes, F.; Reed, K. G.; Crimmin, W. R. C.
From Analytica Chimica Acta (1956), 15, 312-16. Language: Unavailable, Database: CAPLUS, DOI: 10.1016/0003-2670(56)80056-1
The sensitivity of the reaction between anthranilic acid and metal ions has been detd. Except in the case of Cu and Ag, the acetate
buffers decrease the sensitivity appreciably. Ag+, Cd++, Co++, Cu++, Ni++, and Zn++ were found to give ppts. in HOAc-acetate buffers
and the pH values are given. The pH values of incipient pptn. for the following ions are: Cu++ 1.5, Ni++ 2.0, Co++ 2.6, Zn ++ 3.1, Pb++
3.4, Cd++ 3.5, and Mn++3.8.
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