Analyze coking of 1 ton of coal according to the following

Solution:

1. Ash analysis
∑ 𝑚𝑎𝑠ℎ,𝑖𝑛 = ∑ 𝑚𝑎𝑠ℎ,𝑜𝑢𝑡 → 𝑚𝑎𝑠ℎ = 6.7% 𝑚𝑐𝑜𝑎𝑙 = 67 𝑘𝑔
Note: ash only exists in output in coke.
2. Coke analysis
𝑚𝑎𝑠ℎ 67000
𝑚𝑐𝑜𝑘𝑒 = = ≅ 690.722 𝑘𝑔
9.7% 97
58826
𝑚𝐶 = 87.8% 𝑚𝑐𝑜𝑘𝑒 = ≅ 606.454 𝑘𝑔
97
536
𝑚𝐻 = 0.8% 𝑚𝑐𝑜𝑘𝑒 = = 5.526 𝑘𝑔
97
402
𝑚𝑁 = 0.6% 𝑚𝑐𝑜𝑘𝑒 = ≅ 4.144 𝑘𝑔
97
737
𝑚𝑆 = 1.1% 𝑚𝑐𝑜𝑘𝑒 = ≅ 7.6 𝑘𝑔
97
3. 𝑆 analysis
1.4% 𝑚𝑐𝑜𝑎𝑙 𝑚𝑆,𝑐𝑜𝑘𝑒
∑ 𝑛𝑆,𝑖𝑛 = ∑ 𝑛𝑆,𝑜𝑢𝑡 → 𝑛𝑆,𝑐𝑜𝑎𝑙 = 𝑛𝑆,𝑐𝑜𝑘𝑒 + 𝑛𝑆,𝑔𝑎𝑠 → = + 𝑛𝑆,𝑔𝑎𝑠
32 32
621
𝑛𝑆,𝑔𝑎𝑠 = ≅ 0.2 𝑘𝑚𝑜𝑙𝑒
3104
4. Dry gas analysis
4349
𝑉𝐻2 𝑆 = 22.4𝑛𝐻2 𝑆 = 22.4𝑛𝑠,𝑔𝑎𝑠 = ≅ 4.48 𝑚3
970
𝑉𝐻2 𝑆 434700
𝑉𝑑𝑟𝑦 𝑔𝑎𝑠 = = ≅ 344.726 𝑚3
1.3% 1261
𝑉𝐶6 𝐻6 = 0.9% 𝑉𝑑𝑟𝑦 𝑔𝑎𝑠 = 3.1 𝑚3
𝑉𝐶2 𝐻4 = 2.1% 𝑉𝑑𝑟𝑦 𝑔𝑎𝑠 = 7.24 𝑚3
𝑉𝐶𝐻4 = 27.5% 𝑉𝑑𝑟𝑦 𝑔𝑎𝑠 = 94.8 𝑚3
𝑉𝐶𝑂2 = 4.8% 𝑉𝑑𝑟𝑦 𝑔𝑎𝑠 = 16.55 𝑚3
𝑉𝐶𝑂 = 2.2% 𝑉𝑑𝑟𝑦 𝑔𝑎𝑠 = 7.584 𝑚3
𝑉𝐻2 = 55.4% 𝑉𝑑𝑟𝑦 𝑔𝑎𝑠 = 190.98 𝑚3
𝑉𝑂2 = 2.9% 𝑉𝑑𝑟𝑦 𝑔𝑎𝑠 = 10 𝑚3
𝑉𝑁2 = 1.5% 𝑉𝑑𝑟𝑦 𝑔𝑎𝑠 = 5.171 𝑚3
𝑉𝐻2 𝑆 = 1.3% 𝑉𝑑𝑟𝑦 𝑔𝑎𝑠 = 4.48 𝑚3
𝑉𝑁𝐻3 = 1.4% 𝑉𝑑𝑟𝑦 𝑔𝑎𝑠 = 4.826 𝑚3
5. 𝑁 analysis
1.4% 𝑚𝑐𝑜𝑎𝑙
∑ 𝑛𝑁,𝑖𝑛 = ∑ 𝑛𝑁,𝑜𝑢𝑡 → 𝑛𝑁,𝑐𝑜𝑎𝑙 = 𝑛𝑆,𝑐𝑜𝑘𝑒 + 𝑛𝑁,𝑡𝑎𝑟 + 2𝑛𝑁,𝑁2 + 𝑛𝑁,𝑁𝐻3 →
14
𝑚𝑁,𝑐𝑜𝑘𝑒 𝑉𝑁 𝑉𝑁𝐻3
= + 𝑛𝑁,𝑡𝑎𝑟 + 2 × 2 + → 𝑛𝑁,𝑡𝑎𝑟 = 0.026857 𝑘𝑚𝑜𝑙𝑒
14 22.4 22.4
6. Tar analysis
𝑚𝑁 14𝑛𝑁
𝑚𝑡𝑎𝑟 = = = 34.1816 𝑘𝑔
1.1% 1.1%
𝑚𝐶 = 88.7% 𝑚𝑡𝑎𝑟 = 30.319 𝑘𝑔
𝑚𝐻 = 6.2% 𝑚𝑡𝑎𝑟 = 2.119 𝑘𝑔
7. Wet gas analysis
∑ 𝑛𝐻,𝑖𝑛 = ∑ 𝑛𝐻,𝑜𝑢𝑡 → 𝑛𝐻,𝑐𝑜𝑎𝑙 = 𝑛𝐻,𝑐𝑜𝑘𝑒 + 𝑛𝐻,𝑡𝑎𝑟 + 𝑛𝐻,𝑑𝑟𝑦 𝑔𝑎𝑠 + 2𝑛𝐻,𝐻2 𝑂 𝑣𝑎𝑝𝑜𝑟 → 𝑛𝐻,𝐻2 𝑂 𝑣𝑎𝑝𝑜𝑟 =
8. Volatile matter analysis
𝑉𝑣𝑜𝑙𝑎𝑡𝑖𝑙𝑒 𝑚𝑎𝑡𝑡𝑒𝑟 = 22.4(𝑛𝐶6 𝐻6 + 𝑛𝐶2 𝐻4 + 𝑛𝐶𝐻4 + 𝑛𝐻2 𝑆 + 𝑛𝑁𝐻3 ) = 114.446 𝑚3
 𝑆𝑢𝑚𝑚𝑎𝑟𝑦
In/out Stream Species 𝑤𝑡 (𝒌𝒈) 𝑤𝑡% 𝑉 (𝒎𝟑 ) 𝑉% 𝑛 (𝒌𝒎𝒐𝒍𝒆)
𝐶 735 73.5
𝐻 46 4.6
𝑁 14 1.4
Input Coal 𝑂 48 4.8
𝑆 14 1.4
𝐻2 𝑂 76 7.6
𝐴𝑠ℎ 67 6.7
𝐶 606.454 87.8
𝐻 5.526 0.8
Coke 𝑁 4.144 0.6
𝑆 7.6 1.1
𝐴𝑠ℎ 67 9.7
𝐶 30.319 88.7
Tar 𝐻 2.119 6.2
𝑁 0.376 1.1 0.026857
𝐶6 𝐻6 3.1 0.9
𝐶2 𝐻4 7.24 2.1
𝐶𝐻4 94.8 27.5
𝐶𝑂2 16.55 4.8
𝐶𝑂 7.584 2.2
Dry Gas
𝐻2 190.98 55.4
𝑂2 10 2.9
𝑁2 5.171 1.5
𝐻2 𝑆 4.48 1.3 0.2
Output
𝑁𝐻3 4.826 1.4
𝐶6 𝐻6
𝐶2 𝐻4
𝐶𝐻4
𝐶𝑂2
𝐶𝑂
Wet Gas 𝐻2
𝑂2
𝑁2
𝐻2 𝑆
𝑁𝐻3
𝐻2 𝑂
𝐶6 𝐻6
𝐶2 𝐻4
Volatile
𝐶𝐻4
Matter
𝐻2 𝑆
𝑁𝐻3