Electrochemistry Lec 2 Nitesh Devnani

MOLE
CONCEPT
THEORY PYQ NCERT
NITESH DEVNANI
t.me/neetpreparationadda247
MOLE
CONCEPT
THEORY PYQ NCERT
NITESH DEVNANI
PHYSICS DAY2 # NEETIO2YY
#
S.No. CHAPTER DATES

1. Electrochemistry Part 1 - 18th Oct
2. Electrochemistry Part 2 - 19th Oct
3. Electrochemistry - PYQ I PART 3

>
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4. Chemical Kinetics - One shot 23rd Oct

5. Chemical Kinetics - PYQ 26th Oct
6. Solutions - One shot 28th Oct
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ELECTROCHEMISTRY
* 10:00 AM
-
-
Electrochemical
* well ANODE=-ve Conidation C
Galvanic cell
CATHODE +ve
=
(Reduction(
in
Electrolysis ANODEthe Cordations
*
conductance
*
Electrochemical cell *convents chemical
mugy
into
electrical
energy
ne- <
I INVERTED
emoves
*
from
CATHODE
->
UTUBE
w
ANODE TO
e a k E
↓ d current
from
e KNOS a * moves
K2SOY
e Cr
INERT
e ELECTRO
G
C to A
souce
e
LUTE G
etent
e
an
C
DANIEL
Ele 2e
+
CELL
-
- openi c i t No revent
-Covidation (
ANODE:
encs) -> int(aq) +

e
CATRODE: -
CReduction)
atay)
+
fe -
-
(u(s)
OVERALL
8 -
<n(s) +
((aq) ->
In+(aq) +
(a(s)
RXN
Main Points -
Ve the
Anode to Cathode.
electron move
*
from
Cathode to Anode.
current
from
* move
WIRE
*
Current in outer circuit
i s due to electrons
in inner circuit
is due to ions
Current
*
SOLUTION
Functions of Salt Bridge
Neutralise
* the solution
vicuit
completes the
*
Properties of Inert Electrolyte
↳
KC, KNOz, K2 SOY
should not
*
- participate
in reaction
Mobilityof
*
-
and
cation should
anion
be
same;
*
Representation of cell
ANODE8 -
zucs) -> ent(aq) fe
+
CATHODE? - Cut (aq) +

e
-
-
(uls)
OVERALL
8 -
<n(s) +
cut(aq) -> In+(29) + als)
RXN
CATHODE
ANODE
2n(s)/ent(ag) Cu(ag)/(uls)
↓ SARL BRIDGE
NOTWA
(Danda) is
Eltrode
*
always formed of
SOLID substance
In" (aq.)
2n(s) 24 (a.) 4eg)
* + -> +
reduction
O
ocudation CATHODE
ANODE
encs)/2nt(aq.) (q.) /42(g),

+
n Pt(s)
Inest
&
etectode
+
6
*
G2O7aq) Fe(aq.)+
->
Gay.) I
Fe(aq.)
Oxidation
Reduction ANODE
CATHODE
PtCs), Fet(aq.1/Fet(ag)(/Gofar.1/clag.), Pt(s)
*
Net cell reaction
Sn/s)
**
/Sntcaq.) 1/42(g)/clag.), Pt(s)
ANODE CATHODE
ANODE: -Sn(s) -
intla) +
/ ne-
CATHODE 8 -
(g) +
xe -
-
aaag)) x 2
OVERALL
RXN
8-
Sn(s)+CUalg)-- Sncar) +nlag.)
Overall
*
Run Mein Kabhi
Bhi e Nahi
↑
Dekheuge;
Electrode potential
-
electrode Potential bw
generated
*
e
e zn
-
y
e
electrode and
electrolytic
- --
et--- solution
-
-
25
Inte
-
-
- -
-
- - -
Electrode Potential Oxidation
Potential
ANODE
V
Eznient Ecalate
Potential
Reduction
EAglAgEFeFet3
CATHODE
Ezntlen EutIm
E
Ag'Ag
STANDARD POTENTIAL
ELECTRODE E
measured at
Potential 290K and IM cove
Standard Oxidation
Potential SOP
-
-
Eznlent E
Agingt
Standard Reduction
Potential
Ezutlen
Earl-Foni+ Exed
↓ ↓
ANODE CATHODE
Question
EAA+2 0.3V
= ovidation
Es =0.6V Reduction
Ear= Eoni+ Ead

= 0.3 + 0.6
=0.9V
Question Jiski value Badi
*
ENATE=0.3V ouidation. Mogi, Usko

Profe
Kareuge;
EBIB 0.5V
= oundation
t ulti
Doosre
*
Eq+/A =
=
0.3 Reduction
Kordeuge;
Face=konit Gra
0.5
=
(-0.3)
+
0.2V
=
Question
EA*A= O.OV reduction
EBB = 0.31 reduction
EB1Bt =-0.3 ovidation
Far 0.5V
=
Significance of Electrode Potential
Electrode Potential value the
tendency of an
gues
*
element to oxidised reduced.

get
or
Jiskivalue Badi-> uski Zada

2
Tendency + E0.5V
1) ze
+
A A E 0.8V I x X
-
- + = e -
B B
T
E 1.3V 2)
+
y xe-Y E1.7V
2)
-
=
e
=
- =
↳
↳ Mor get oxidised
wants
to
get
tendency
to
reduced More
Better
reducing Agent : Better
ovdisingAgent
SPONTANEOUS PROCESS:
*
-
RELATION BIW AG and Eas To

Afue Aap Hota Hai
A4L0=> Far>0
AG= -
nF Fall NON SPONTANEOUS PROCESS: -
Hote
Nabi
To
Afre Aap
Gibbs
14-change
in
fu mugy A4>0=> Eun <0
electron
n - No.
of
constant
F->
Faraday's
96500C
QUESTION
A - At 2
+ 2eE 0.0V =
1G =
-1004]
E AG=
G100x2
2A-> 2A+2 ue- 0.0V
=
=
-
200
E- Intensive
Proputy KI
A4 -Extensive
Profuty
NERST EQUATION VVVV IMP
-
-tempuative
Eul
Fae= ->
Quotient
Ino-reaction
LaF -
Faraday's
universal
gas
↳woo
constant
electrons
-
constant
at
NERST
eq 290k
Eal
-x
Ear=
2900lg e
E
At 298k
Ear=Eul-al log o -
-
#REACTION dUOTIENT ↑
solid-
TRICK 8
Ignore
-
->
en
Ignaul
-
cont
aquedus
-
Pressure
Partial
gaseous
-
2n(s)
* +
Gulag.) ->
in(eg.) +
G(s)
O dut
=
Reactant
0 [n+h]
=
[cutz]
actlag)
*
->C2G) +ce-
D Puz
=
[C-32
2A(q.)
* + 3B(s) -
32(g) 5D(aq)
+
B 0 (PC) [D]5
=
AAI2
QUESTION
an 0
=
2)
=
0.
Pt(aq)
=
Pt(s)-> re-
+
E
=
0.5V; [t] 0.
=
EptlOt=?
E" i
coral log
E = -
Y
E
0.5-gh log
=
Do A
log 2 = 0.3 ⑰ log-log to
b
log
a -"o
dog 3 0.47
log
=
=bloga
log
1x 10
dog
==
5 0.69
=
= 0.7
-
I
-
dog
=
10 1
QUESTION
x(x+ (0.1m) 1/4-10.01m)/y

2
Ex1x+2 0.5V
=
Ey/4+ 3 0.2V
=
HYDROGEN POTENTIAL
*
OXIDATION: -
42(9) -24Cay)
+ 2e-Evalnt= 0
REDUCTION: CHY8q.) 41(9) Ent=

-
-
2e
+
- 0
STANDARD
*
HYDROGEN is
ELECTRODE ZERO
SHE = 0
Because
hydrogen taken
is as
refunct
-
HYDROGEN- Potential
Reduction
-
Iam E 0
24t(aq.) H2g)
-
+ 2e - =
[t]
D*ys*
0 =
Pr
E EP-
al log log(H]
=
=
=
e
E (H
al log
0
=
-
9x(() log [H
=
-
Reduction
E =
=
0.0591X Pr -
-
Reduction
Hydrogen
-
-
E -0.0591XPy
=
Oxidation
Hydrogen =
E +
0.0591XOn
-
Potential
Reduction
E -0.0591
= x PH
=- 0.0591X 3
CONCENTRATION CELL
CATHODE
ANODE
zu zn
- -
- -
- -
~ - -
- - ↑
-
- -
-
-
-
- - -
-
~ ~ - ~
-
- -
-
↳
M >
↳
-
-
↑
InSOY Inson
CN 22
ANODE:-Zn(s)- InTaq) + ce- E=
x not
CN
CATHODE: -Int(aq) +
2e-- Inis) E -
=
xrolt
C2
Eur= Foxit Ered

↑
-
x ( x)
+ -
- ⑧
Concentration
cell) Ea=0
ANODE: -
Ins in(ag)
-> e
-
CATHODE: -
Int(aq)
+
e zx)
-
C2
OVERALL
8 -
Intlog.) -> Int(ag)
RXN CA
C2
9 []
=
c1
=
[InC2
Fuel=Eul- in
oal log
Full=
0-cal log a
Ene=
gal log t cathode
E -
Ear-gal log - Anode
#
ANODE CATHODE
Full-foul allog
-2nfs) Intelay) e-
Far--wal log
-
->
ANODE:
2n+ (aq) Ce z/() Face=

sal log a
-
CATUUDE: -
+ -
22
↓
Orsall
8 -
Int(aq) -> Integ Ive 22 >
Run CA C1
Ca
0 Ca>,
=
s
AGCO E Ean TO
I cathode concentist
Jab Anode
*
same
cell
*
I RELATION B/W AC, E and
keg: -
At
equilibrium, AG TO
·
Ear 0 =
Ener=
9 ca log ke
Keq
=
SPONTANEOUS
ERST ED A40=> Eat o

↳
og keg >0
Ease=Evr-0, log o ↳
n
Keg >N
Er
59, log Ye
0 =
-
NOW SOON TANEOUS
A4>0=> EucO
↳
logkeg 20
↳
key <N
ELECTROLYSIS
*
ANODE -> Ave (onidation)
Break CATHODE--ve (oduction)
electricity down
Breakdown substance
of
*
a
using chely
Electrolysisis NON SPONTANEOUS
*
-
-
↳ B-
>alley
I Electrolysisof Motten Nase
CATUODETITIS
move towards
cation
*
ANODE
Cathode
move towards Amode

Anion
*
- -
-
- -
.....
-
CATAE8 -
Nat +e-Na(s)
-NET-
-
e-
ANOD E. -
Uz(g)
-
O
- +
-
-
-
2)
Electrolysisof 4,0
f02(g)
2
2Ht
-
ANODE 8-
H20 -> ce
+
+
OXIDATION
CATHODE: -
re+ cio 42)
->
+ con
REDUCTION
ANODE -
IO2G
CATUODE->
2F
--
-
charge
42(g)
2 RS
⑧ --
O
# *
Nitesh Tur
->
2RS 2RS
+
*
3) Electrolysisof aqueous Nach
↳
*
electrochemical
series
CASE:-using
etrode
-
INERL
-
-
Nat c-Nace"
comfullion
HT on-420
CATHODE: - 2e +240 ->

H2 + 204-
ANODE : --->
Ilater
Wing My
attac
CASES 8
- as
Nat u- Nall
H OH H20
+e-
ANODE8-C -
G(g)
CATHODE:-Mat + e
-
-
of
Nals); of formation
Amalgam
Na-rg
All -B
HC 7 Acid
-
(aq)
-
7) Electrolysisof H2S0y
-> same as wate
CASEII-Dil H, soy
-
45 SOu?-MISOY ---
compellion
NO
competitionof OH-MO
CATHODE:
-42(g)
40 2n++ae-
ANODE: IOT
-
CASE2 %-Conc. H28208 Marshal
-
-
H2SOy Ariel
8
⑧
4son2 H2SOn
It on-
no-o-o-s-on
!
40
disulphuri Aid
perovy
CATHODE 8-
H22g)
ANODE 8-2SO4- SOg + Le-
I
Marshal's H2S200
Acid
5) Electrolysisof aq.CusOn
INERT electrode
CASE:
-
- -using
Cut sOy2
** OH-
Cut + (uls)
-
CATHODE? -
2e -
VODE:- H20 -
2 +2e 24T
+
electrodes
ingpu
CASE 2 8 -
-
- CATHODE: -
ANODE
CATHODE
C IMPURE
cat + 2e
-
- ((1)
PURE
Ge u
a a
=
C
ANODE8 -
i Cels)-Cut(9)+ ze
w
a
·
- - - -
~
-
-
des
-
CusOn
-
Mass Anode
of
- - -
888
-
-
-
ago-- ↑
↳ Mass is
cathode
of
ANODE
Refiningof MUD
Ag, An, ot
-
-
⑳@°
11.2 + 22.4
Water
33.0h
I
water
Electrolysis of
x 22.4
&F
-more02(g) =7 = 1.22
=
I mole 22.42
M2G) -> 1x22.4
=
*
E
#FARADAY's LAW
mole electron->90500c
charge
on
↑
Faraday
-
-
* On
passing IT
charge, one
↑
gram equivalent
is
deposited
not
equivalent
Molal Mass
Egnt= --
ny
Nat charge 3 239 Na
IF
deposit
=> =
Mgth change =12g Mg deposit

IF =>
Alt3 IF
chag I
=>
98
=
Al
deposit
Y
A
FIRST LAW ELECTROLYSIS
OF
Wa
W =
20 letrochemical
->
equivalent
1
2 =
a It
=
A GNTIO
W =
2 It -
--
I =
E E=
Equivalent
not
96500
D
W= Ext
96500
*
z = E I 63.5
-
-
96500 2 x 96500
Notes
-
-
Y
* ⑰
not (a 40 20
Eg.
=
=
+2 2
Ca ↳ AF
-
-
Y
SECOND LAW ELECTROLYSIS
A OF
X
I ↓ ↓
Sims
A
g
was
Isame unent) - -
-
- ↑ ----
- - -
↑
WAg
~
-- e
- -
- -
- -
-
- -
G
Ag
Was *
Eq ut a
WAg x
Eqct Ag
QUESTION
is
Same current
passed through Ag' and a solution. What
not
of
he
deposited
is
if silver
deposited 100g.
is
Wg+=E
Wart? Ea
1.08 108
I
-
I
War
-
*
03:5
-
ELECTROLYTIC SOL *
A CONDUCTANCE OF
A-area of crosstion
↳
~
-
-
-
-
-
-
-
-
- -
Electrolyte
-
all
-
-
--
· Resistance (R): -
9
A
=
=
unit
RA 8 -
ohm
·(A
-
resistivity GX1= K
-
A
· Conductance(a)
R I cell constant
of
Recriprocal
↳ =
A
G
= unit: -Ohm
=
I
well Conductivity
Oh
Conductance
-
L who
(v)
or
conductivity siemens
i
(Xm)
Molar conductivity
·
molar solution
↳
conductivityof a
Im = kX1000
-
unit:-Sm" mot
M
Equivalentconductivity
-
(E)
conductively of grain equivalent
↳ solution
DE =100 -Smegt
unit:
N
bw
Relation Im and IE 8-
Xm Kx1000 N
Mxdy
= =
& E kX1000
-
XE = &X
-
100
Mxny
E
DEX Dy Dm =
*
M = Dot
k = I
e
Xm e
1000 =00x10-to
=
DE =x1000
-
k
=
7x1000
0.5
METALLIC CONDUCTOR
⑦
4
74=> Resistance => Conductance I
⑦ Electrolytic
conduction
-
mobilityof hous
TP conductance 4
=>

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MOLE

S.No. CHAPTER DATES

3. Electrochemistry - PYQ I PART 3

4. Chemical Kinetics - One shot 23rd Oct

7. Solutions - PYQ 30th Oct

NATS (NEET ADDA Test Series) Planner

Properties of Solids and Liquids (Mechanical Anatomy of Flowering Plant,

Nitrogen Cotaining Compounds,

encs) -> int(aq) +

CATHODE? - Cut (aq) +

encs)/2nt(aq.) (q.) /42(g),

PtCs), Fet(aq.1/Fet(ag)(/Gofar.1/clag.), Pt(s)

Ear= Eoni+ Ead

ENATE=0.3V ouidation. Mogi, Usko

EBB = 0.31 reduction

EB1Bt =-0.3 ovidation

element to oxidised reduced.

Jiskivalue Badi-> uski Zada

RELATION BIW AG and Eas To

x(x+ (0.1m) 1/4-10.01m)/y

REDUCTION: CHY8q.) 41(9) Ent=

Eur= Foxit Ered

2n+ (aq) Ce z/() Face=

ERST ED A40=> Eat o

move towards Amode

CATHODE: - 2e +240 ->

Mgth change =12g Mg deposit

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