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【SDS No. B09034003BD200】

Ｓａｆｅｔｙ Ｄａｔａ Ｓｈｅｅｔ
Issue Date : Jan. 25, 2017
n.ap. = not applicable. n.av. = not available.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

TRADE NAME : STAFOAM DFC

MANUFACTURER : NOF CORPORATION AMAGASAKI PLANT
1-56, OHAMA-CHO, AMAGASAKI, HYOGO 660-0095, JAPAN
EMERGENCY PHONE : TEL. +81-6-6419-7483 FAX. +81-6-6416-8135
E-MAIL ADDRESS : g_amg_kmsds@nof.co.jp
RESPONSIBLE AND EMERGENCY PHONE :
NOF AMERICA CORPORATION (New York Office) [Vendor]
TEL. +1-914-681-9790 FAX. +1-914-681-9791
E-mail Address : g_cdo_kmsds@nof.co.jp

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

Light yellow viscous liquid. May cause serious eye damage. Irritating and toxic gases may be
generated by decomposition or combustion.

GHS CLASSIFICATION.
PHYSICAL HAZARDS.:
Flammable liquids. : Not classified.
HEALTH HAZARDS.
ACUTE TOXICITY (ORAL) : Category 5.
ACUTE TOXICITY (DERMAL) : Classification not possible.
ACUTE TOXICITY (INHALATION:GAS) : n.ap.
(INHALATION:VAPOUR) : n.ap.
(INHALATION:DUST,MIST) : Classification not possible.
SKIN CORROSION/IRRITATION : Classification not possible.
SERIOUS EYE DAMAGE / EYE IRRITATION : Category 1.
RESPIRATORY SENSITIZATION : Classification not possible.
SKIN SENSITIZATION : Not classified.
GERM CELL MUTAGENICITY : Classification not possible.
CARCINOGENICITY : Category 2.
REPRODUCTIVE TOXICITY : Classification not possible.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE)
:Category 2. (Liver)
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE)
:Category 2. (Respiratory tract)
ASPIRATION HAZARD: Classification not possible.
ENVIRONMENTAL HAZARDS.
HAZARDOUS TO THE AQUATIC ENVIRONMENT. (ACUTE) : Category 2.
HAZARDOUS TO THE AQUATIC ENVIRONMENT. (CHRONIC) : Not classified.
HAZARDOUS TO THE OZONE LAYER. : Classification not possible.
LABEL.
PICTOGRAM:

SIGNAL WORD.: Danger.

HAZARD STATEMENT. : Obtain special instructions before use.
Causes serious eye damage.
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【SDS No. B09034003BD200】
Suspected of causing cancer.
May cause damage to liver
May cause damage to through prolonged or repeated exposure.
Toxic to aquatic life.
PRECAUTIONARY STATEMENT.
PREVENTION : Wear protective gloves/protective clothing/eye protection/face protection.
Do not breathe dust/fumes/gas/mist/vapours/spray.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not eat, drink or smoke when using this product.
Avoid release to the environment.
RESPONSE : If in eyes, rinse cautiously with water for above 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a poison center or doctor.
If exposed or concerned, get medical advice.
Call a poison center or doctor/physician if you feel unwell.
Get Medical advice/attention if you feel unwell.
Collect spillage.
STORAGE : Store container tightly closed in well-ventilated place.
DISPOSAL : Dispose of contents/container in accordance with local/ regional/ national/
international regulation.
DIRECTION FOR USE : See instructions on this Safety Data Sheet.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Components
Component: CAS No.: Wt(%):
Coconut oil, reaction products with diethanolamine 8051-30-7 86－89
1,2,3-Propanetriol 56-81-5 7－9
Ethanol, 2,2'-iminobis- 111-42-2 4－7

4. FIRST AID MEASURES

INHALATION :Remove victim to fresh air and keep at rest in a position comfortable for breathing.
As the need arises, seek medical advice.
SKIN : Wash with plenty of water and soap. As the need arises, seek medical advice.
EYES : Flush eyes immediately with large amounts of water for at least 15 minutes.
If irritation persists, get medical attention.
INGESTION : Do not induce vomiting. If the victim is conscious and not convulsing, give water
or milk to drink, and get immediate medical attention.
PROTECTION FOR FIRST-AIDES: Refer to section 8.

5. FIRE-FIGHTING MEASURES

FLAMMABLE PROPERTIES
Flash point : 174℃ (Cleveland open cup)
Flammable limits in air : LEL = 0.9 Vol% UEL = n.av. [1,2,3-Propanetriol]
EXTINGUISHING MEDIA : Carbon dioxide, foam and dry chemical powder.
FIRE & EXPLOSION HAZARDS : On combustion, generates toxic gases. (e.g., Nitrogen oxides)
FIRE-FIGHTING EQUIPMENT : Wear positive pressure self-contained breathing apparatus.
Wear full protective clothing.

6. ACCIDENTAL RELEASE MEASURES

Wear protections (e.g., protective gloves, goggles and gas respirator) during work.
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Prevent the spilled material entering into a river or sewers.
Small Spill and Leak: After absorb with sawdust, earth, sand, waste, etc. wash away the
remainder with soapy water in order not to spill into a river or a canal.
Large Spill and Leak: Because of prevention of more flow to neighborhood, prevent flow by
surrounding with the earth and sand, etc. and recover in a drum, etc.
Use tools not to spark.

7. HANDLING AND STORAGE

Caution; Combustible.
HANDLING : Establish a washing equipment for eyes and body near the handling area.
Ventilate a work area enough.
Avoid contact with eyes.
Wear adequate protections (e.g., protective gloves and goggles, etc.)
Wash thoroughly hands, face, etc., and gargle after handling.
STORAGE : Store in cool and well ventilated place and keep container closed.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS : Local exhaust ventilation is necessary in the vapor, hume, mist
or dust atmosphere of the product.
EXPOSURE GUIDELINES : ACGIH(2016); TWA 1mg/m3, [Diethanolamine]
OSHA Z-1-A 3ppm(15mg/m3) , [Diethanolamine]
ACGIH(2016); TWA 10mg/m3 , [Glycerin mist]
PERSONAL PROTECTION
Respiratory protection : As the need arises, use an effective gas respirator to a organic solvent.
Hand protection : Protective gloves.
Eye protection : Protective goggles.
Skin protection : Anti-electrostatic work clothes.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Light yellow viscous liquid.

Odor : Distinct odor.
pH : 9.6-10.6
Coagulation point : ca. -7 ℃
Specific gravity : 1.01 (20℃)
Viscosity : 980 mPa・s (20℃)
Solubility in water : Soluble.

10. STABILITY AND REACTIVITY

STABILITY : Stable under normal storage and handling conditions.

Amine value and pH change forming a carbonate by a carbonic acid gas in the air.
REACTIVITY : Easily forms salt with acids.
HAZARDOUS DECOMPOSITION PRODUCTS : Nitrogen oxides and Acrolein.

11. TOXICOLOGICAL INFORMATION

ACUTE TOXICITY
LD50 2,700mg/kg (Oral, Rat) [Principal component : Lauric acid diethanolamide]
LD50 12,600mg/kg (Oral, Rat) [1,2,3-Propanetriol]
LD50 780~12,760mg/kg (Oral, Rat) [Ethanol, 2,2'-iminobis-]
LD50 3,300mg/kg (Oral, Mouse) [Ethanol, 2,2'-iminobis-]
LD50 2,000mg/kg (Oral, Guinea pig) [Ethanol, 2,2'-iminobis-]
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LD50 2,200mg/kg (Oral, Rabbit) [Ethanol, 2,2'-iminobis-]
LD50 11,900μL/kg (Dermal, Guinea pig) [Ethanol, 2,2'-iminobis-]
LD50 >10,000mg/kg (Dermal, Rabbit) [1,2,3-Propanetriol]
LD50 7,640μL/kg (Dermal, Rabbit) [Ethanol, 2,2'-iminobis-]
LOCAL EFFECT
Skin corrosion : n.ap.
Skin irritation : [Ethanol, 2,2'-iminobis-]
Mild. (Draize method, Rabbit, 500mg/24h)
[Coconut oil, reaction products with diethanolamine]
Weak irritation. (Occlusive patch test, Rabbit, 500mg/24h)
[Principal component : Lauric acid diethanolamide]
Severe. (Draize method, Rabbit, 500μL)
[1,2,3-Propanetriol]
Mild. (Draize method, Rabbit, 500mg/24h)
Eye irritation : [Ethanol, 2,2'-iminobis-]
Severe. (Draize method, Rabbit, 750μg/24h)
[Principal component : Lauric acid diethanolamide]
Moderate. (Draize method, Rabbit, 100μL)
[1,2,3-Propanetriol]
Mild. (Draize method, Rabbit, 500mg/24h)
GERM CELL MUTAGENICITY
Negative.(Mutagenicity test,Salmonella typhimurium TA98, TA100) [Fatty acid diethanolamide]
Negative.(Ames test) [1,2,3-Propanetriol]
CARCINOGENICITY
[Coconut oil diethanolamine condensate]
IARC : 2B. (Probably carcinogenic to humans.)
[Ethanol, 2,2'-iminobis-]
IARC : 2B. (Probably carcinogenic to humans.)
ACGIH : A3. (Confirmed animal carcinogen with unknown relevance to humans.)
CHRONIC TOXICITY
[Ethanol, 2,2'-iminobis-]
Repeated or prolonged contact with eyes may cause a corneal damage or conjunctivitis.
[1,2,3-Propanetriol]
Repeated or prolonged contact with high concentration glycerin to skin may cause rough skin
and inflammation.

12. ECOLOGICAL INFORMATION

PERSISTENT/BIODEGRADABLE
[N,N-bis(hydroxyethyl)fatty acid amide. (Fatty acid: C=6－18)]
Degradation: 53~62%(BOD). Activated sludge: 30ppm. Concentration: 100ppm. 2weeks.
[Ethanol, 2,2'-iminobis-.]
Degradation: 51%(BOD). Activated sludge: 30ppm. Concentration: 100ppm. 3weeks.
[1,2,3-Propanetriol]
Degradation: 63%(BOD). Activated sludge: 30ppm. Concentration: 100ppm. 2weeks.
AQUATIC TOXICITY
LC50(96) >540,000μg/L, Cyprinodon variegates [Ethanol, 2,2'-iminobis-.]
LC50(96) 54,000,000μg/L, Oncorhynchus mykiss [1,2,3-Propanetriol]
EC50(48) 2,640μg/L, Daphnia. [Ethanol, 2,2'-iminobis-]

13. DISPOSAL CONSIDERATIONS

May be burned in an adequate incinerator in accordance with all applicable regulations.

Any disposal practice must be in compliance with local, state, and federal laws and regulations
(contact local or state environmental agency for specific rules).
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14. TRANSPORT INFORMATION

IMDG : Not hazardous material.

UN No. : None.

15. REGULATORY INFORMATION

TSCA STATUS: EC No.:

Coconut oil, reaction products with diethanolamine On TSCA Inventory list. 232-483-0
1,2,3-Propanetriol On TSCA Inventory list. 200-289-5
Ethanol, 2,2'-iminobis- On TSCA Inventory list. 203-868-0

16. OTHER INFORMATION

The statements in this bulletin were made to the best of our knowledge and as accurate as possible.
They are given for information only. They don't constitute a contractual guarantee of a product's
properties.