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Chapter 1 7 X Ray Diffraction
Chapter 1 7 X Ray Diffraction
Chapter 1 7 X Ray Diffraction
CHAPTER 1-7:
Email: nvdung@hcmut.edu.vn
2θ deviation
Beam 1
Beam 2
d
Crystal
X-ray beam
Diffracted beam
Diffracted beam
Incident beam
Incident beam
Single crystal
Polycrystal
Detector
Monochrome
filter
Crystal
Monochrome
filter
X-ray beam
d hkl
=2 sin n sin Lattice plane
n 1 0.34 20.7º Level 1 (110)
= 2d nh nk nl sin
Level 2 (110)
2 0.69 43.9º
Or (220)
SC All No
A material has a cubic structure with the following diffraction angles ():
1 2 3 4 5 6 7
9.3 13.26 16.32 19.01 21.27 23.41 25.44
sin 0.162 0.229 0.281 0.326 0.363 0.397 0.430
sin2 0.026 0.053 0.079 0.106 0.132 0.158 0.185
dhkl 4.768 3.359 2.742 2.365 2.124 1.939 1.794
t (kích thước tinh thể) is the mean size of the ordered (crystalline) domains,
which may be smaller or equal to the grain size, which may be smaller or equal
to the particle size.
Dr. Nguyen Van Dung, Faculty of Chemical Engineering, HCMUT
43
MICROPOROUS MATERIALS (ZSM-5 ZEOLITES)
https://pubs.rsc.org/en/content/articlelanding/2018/RA/C7RA11763A
https://pubs.acs.org/doi/10.1021/acsomega.8b02332
Dr. Nguyen Van Dung, Faculty of Chemical Engineering, HCMUT
45
MICROPOROUS MATERIALS (OMS-2)
https://link.springer.com/article/10.1007/s10562-019-02828-1
https://pubs.acs.org/doi/10.1021/jp0300593
https://www.mdpi.com/2073-4344/9/7/606/htm
https://www.mdpi.com/1996-1944/11/5/779
https://pubs.rsc.org/en/content/articlelanding/2014/ta/c4ta00379a/unauth
https://www.researchgate.net/publication/275545331_Supplementary_Information_2007-JACS-
Mesoporous_carbon_single-crystals_from_organic-organic_self-assembly_SI
Dr. Nguyen Van Dung, Faculty of Chemical Engineering, HCMUT
48
Ag/TiO2 NANOCOMPOSITE
https://link.springer.com/article/10.1007/s00339-017-1240-7
https://doi.org/10.1166/jnn.2016.11029
Dr. Nguyen Van Dung, Faculty of Chemical Engineering, HCMUT
50
CELLULOSE NANOCRYSTALS
Crystallinity index
(độ tinh thể)
IAM/I002 x 100%
https://doi.org/10.1590/1980-5373-MR-2019-0192
Dr. Nguyen Van Dung, Faculty of Chemical Engineering, HCMUT