elAsSMAte alasSMALe

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FINAL PUNCH KCET2020 endethec mic

Heat albsorbed) Tsothermal
THERMODYNAMTC(S Exotheamic
Heat evolved
AT-O

:SYNOPsIS Reversi ble

Isocheric
Avzo
pro ceels i
exothemic

both divedkion ocesse

System SuTTeundlings
endethemi Isoberic
AP-o
9s4ve
enexo Ivevessible
Opeo System Sunameli Cyclie proces
mattes procesS
paoeeecs i
eneo
sumod AUE cone divechion Pdalbatic
Typeof close, System AH Cannet be
3evesed
Systems
Ttoet Ss hem.
m suuoundasExtensive propesy: Propestiss
depenc on ameunt of moakte
in he Sqstem:
whih
preen

sta funckon Vasialles hat depends Ex: Mass, velume, Enthalp, Entrupy
onle en the iniial 4inal shob e f Hearcapoti4, fyee enuoy inhene ene191
system Ex:Pretsue intema
velumeene
P ancion ntensive propeah: Propestheg cohieh dene
Vasiable wbese vakse depends eo depend on he amnant ef matte presen
he padth llewed Syshem n eSstem,
Ex oerk, he E: Press Temp, densiy, Me, 8P, Viseatit
Surfece ensien,Retrace tnelex, sp.hemt
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Etene htensive Massdentik
Volume
Extenshe Nerde elom ein rieversible enpaniton
Intena eneis (U)Sum of ll Wimev-P Av =-Pef-Vi)
pe eneg Presend in syshn,

AE@AU= Wprmdud=rea chaiw Werk dene in 1sotheema eveTble

panaien ef lden gas:
Av Con be calkMeled b usina
Bomb calerimete. WE-2.3o3 n &T log a
ist lauseHheme canamics We-2.303 nRT log P
Eneag an nehea be created
nor be dlesthoyedCon be coeatecl
rom one foim to anethe form AH Enthalpy:
To enegy of meunihvease 1s Tot Het abserbed ev releajed
remains Constant. luainqTeachto at cons fun
pnessua
DE U
tA-AU PAv
Stan cemuesico
o s k dene on the system; wGve)
DH= AU+ AngRT
woT k dene by theSystem: -Ve) Ang: No. of qaseanns- No.ef gastus
PToclucs reactants
Heal aloserbed b the system
1tve ww Enthelp change at conskentpresM
H e is veleased by the System
=AH
2-ve Erthay change at conthant velume
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Mola heat copaci (Cm)
TherlereAHEaU+PD men heatheat rqurelo
rause theemp f 2 mole ef
Lp y+ PAv o
Substemre hrong 1c
1 +AngRT Cm
(C)teet capa tyiThe amouni ofheat L mA C AT ATE T2T
sequire to Tatsehe emperallune of heat required to raise the temp
Hhe systerm hrogh from T t T2
mEmass ofsubstance C sp.heat
PHeak capeciy,C= CAT
Heal paei y atonstant
alume Cy
Speciie heat
heai e w redl
capaci ty:(9 Amaunt
alse he empa
of
Hea onpoi y et consant
o ef the uestanee h r a h
prissue1p Cp
Ex: Sp.heat atacl esate Cp-Cv R
2 cal
4-18 3
CP==atomicilf of gas
So Gc
Meneatommu =l.66
m: mass of Subsfance,
NE ET
MA
dialomtc ho
JEE
Trieemre = 3 o
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Hesss lao Ja reachem Cap 2 H fos madien: Chonge ín ethal

by more than cme mole o Substance ss
be token place numbe shenane
Step er îna ef steps iSfome directHy hom selemertt
enthaly chang mauns same n Thenr mest shauble fo1m
3 H cem bus tHen: st
A 8 Change in endthalpr hen
le efa Substanceis comple
one mole
el burni in oxy9en

AcH is ahwaysDegahe
4AH hydsalien. change in enthal
hen one mole e anhydlo
Disferent pes of ectha pies Sostance cem bine
Yequred no.f
with h e
atu moleules
O Enthalpy f heat Reacten A,) Coyert tinto nydated comp
Amount of change ohen
no. a meles eactants qvenina H fugten: Chanqein entholpy
loalanced Chemic equateo have Shen
Compledely eact give the preksh cme mele ofselie connt
into iquid ad its Mp.
AsHHp-Ha 6) AH Vapusiseten', one mele of
DrH depends on Nalneef Txn lrqwd Convesteel to vapou et ils
physiensates of reactenh BP.
pmcaucs, QuantiHes
enctents Allotopie forms AH Sublimaieon ane mele of
Temp Selie Converted into vapoww
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8) Ethaley of soluhon: oYhe ameunt ofenesgy reun

Change in erthalpyohen one to s eciate ans mele o oenels
mole of Suubsenee s osehed in Dxesen between the ado ms in the
encesssdates so hat futhe gaseouS State,
dliluton doesnet invae on het
Change. Fov dioam molecaas ke
Ha,o N CLt,Fheo bone
eneigids are equal her
)Enhelpr eNeuhalrelin
Chongenenthalp ehen
hssocieen nexgy
One qram egunaeat ef an a i
polypely odto miemoletule,
sCompletely pekalued by 1 AvaeC+ 2Ha en
equivadent of a bese in dilule
soluhen In CP4 allfoxY C-H bonc
HC NaoHA NaCl+
BA
H eneagies ae net eqel.

-5%1 kTmo So tH = 427439r 4S2434

Nol: AH neuiolizalion of, shong 416 E me7
eSheng bease okiay1 1
Comiten
Please Nete h a t
to)Bend enet9y: er Benel elissecato
enei9y
Amaunt ef eneagy eleased cshen ene
A2Beclans
nele f bones are formed foo he
selateel atoms in goseas Stale ec
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Poge

Born-Hober ycle:
Latice enag1 can be DS ='S2-S1 rey =
CSelarel by ing his
Ex Lotice enetgy lof NaC As-Ye
dertase
-IE
AH H u HTE-EGE
dies Dryice s+VNe
Llathke enegyM Proteins unduge denautusathon
enhropy deeenes increatos,

Secencl L of Thexmeolynam Erhopy Chenag dusine phase

rensumo ionj:
A spentaneersl prDcesses are
hermeely nemicauy irveasible. As As superehes
System
Entropyf theuniveses sie=AHfasian
alap inCreasing. MP
ASvaposr Hvegoay
(S)EnhopY Meaguye ot BP
diserdes. ness os Yandlenness, asusimadt Hub
4 S wt Km
Athe Gascng =o Revexaible
Entrop ,
sclid laud 4 gas 0 a Tevei
sysemtusadig ble
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Spantaneous Droceess Efecr of tempelaluse on

which occus e h e ofilg Spentoneilg
or ate iniHhen,
OLn

AH AS Remask s
NmSpernta necu doenot occu

of ts n , -Ve Ve Alwaysve Spentaneous

atal Temp
Gibbs Free enessy: G). Ve Ne Alays+ve Nonspen tane
Maximeum enelay
amuni oene
availa.ble for System do usef
to

door.G H - T s ve+ve Atlo1We Nen Spe ntan

AGA-1AS Pt hiqhT-Ye sponfanerus

AGE-Ne spemhaneaus
ve Ne Atlow),ve spentane
AG+Ne Nanspon haneous
At htahT We Non-spontanea
AG co Equili bmu
Note a l spenaneass eachoorOe
meesta.ble and rade_ y 9
oi be meo

La f Themedyramity
Entopy of pestecHy crysialline
Subsance af akselute ero Zero kelmM
is cen o be Ze